Semi-Solid Processing and Properties of RE-Containing Mg Alloys

2016 ◽  
Vol 256 ◽  
pp. 75-80 ◽  
Author(s):  
Shu Sen Wu ◽  
Xiao Gang Fang ◽  
Shu Lin Lü ◽  
Li Zhao ◽  
Jing Wang

The RE-containing Mg alloys usually have big RE-rich intermetallic compounds distributed along grain boundaries. In this paper, a 3 wt.% RE containing Mg alloy is processed by combination of semi-solid slurry-making with ultrasonic vibration (UV) and squeeze casting. Results show that good semi-solid slurry with fine and spherical primary α-Mg particles can be obtained due to the effects of the cavitation and acoustic streaming induced by UV, and the average particle size and average shape factor are about 30 μm and 0.70 respectively. The RE-rich intermetallic compounds are refined and uniformly distributed along grain boundaries. With the increase of squeeze pressure from 0 MPa to 200 MPa during the casting of semi-solid slurry, the tensile strength and the elongation of the as-cast samples are increased continuously, which reach 182 MPa and 8.4% respectively. The microstructure is also analyzed with SEM, TEM, XRD and EDS, and the phase constitutions of this Mg-RE-Zn-Y-Zr alloy are mainly α-Mg matrix, α-Zr, W phase (Mg3Zn2Y3), I phase (Mg3Zn6Y) and T phase ((La,Ce)(Mg1-xZnx)11). The mechanism of refinement of RE-rich intermetallic compounds is also discussed.

2018 ◽  
Vol 159 ◽  
pp. 02036
Author(s):  
Sulardjaka ◽  
Sri Nugroho ◽  
Suyanto ◽  
Deni Fajar Fitriana

Mechanical characteristic of silicon carbide particle reinforced aluminum matrix composites produced by semi solid stir casting technique was investigated. Al7Si and Al7SiMg were used as metal matrix. High purity silicon carbida with average particle size mesh 400 was used as reinforcement particle. Aluminum matrix composites with variation of SiC: 5 %, 7.5 % and 10 % wt were manufactured by the semi solid stir casting technique. Stiring process was performed by 45 ° degree carbide impeller at rotation of 600 rpm and temperature of 570 °C for 15 minutes. Characteritation of composites speciment were: microscopic examination, density, hardness, tensile and impact test. Hardness and density were tested randomly at top, midlle and bottom of composites product. Based on distribution of density, distribution of hardness and SEM photomicrograph, it can be concluded that semisolid stir casting produces the uniform distribution of particles in the matrix alloy. The results also indicate that introducing SiC reinforcement in aluminum matrix increases the hardness of Al7Si composite and Al7SiMg composite. Calculated porosities increases with increasing wt % of SiC reinforcements in composite. The addition of 1 % Mg also increases the hardness of composites, reduces porosities of composite and enhances the mechanical properties of composites.


2008 ◽  
Vol 141-143 ◽  
pp. 451-456 ◽  
Author(s):  
Shu Sen Wu ◽  
Jun Wen Zhao ◽  
Li Ping Zhang ◽  
Ping An ◽  
You Wu Mao

The effect of processing parameters on the semi-solid microstructure has been investigated in the course of semi-solid slurry preparation of A356 Al alloy by ultrasonic vibration method. The A356 melt in temperature of 630660°C was poured into a special metal cup, and exposed to ultrasonic vibration at 20 kHz or isothermal holding for a certain time after vibration. The results show that the semi-solid slurry with primary α-Al crystals smaller than 90 μm and an average shape coefficient F S (SF was defined as SF4 A/L2P) above 0.5 could be prepared by ultrasonic vibration for a time less than 144 s. In the isothermal holding period after a short time of ultrasonic vibration, the average particle diameter increased with the increase of holding time, but F S decreased at first, and then increased a little. It was discovered that ultrasonic vibration is a good method to prepare semi-solid slurry with fine and relatively round primary crystals due to cavitation and acoustic streaming effects.


Author(s):  
Chenyang Zhang ◽  
Shengdun Zhao ◽  
Guanhai Yan ◽  
Yongfei Wang

Radial forging was introduced to the strain-induced step in the strain-induced melt activation process to prepare high-quality semi-solid A356.2 billet for the high solid fraction compression. Then, the deformation behaviour and microstructures at different compression velocities, temperatures and deformation zones were investigated. The results showed that radial forging can induce enough strain at 60% reduction of area to prepare ideal semi-solid microstructure. The microstructure had no obvious improvement at 75% reduction of area because the distortion energy may be saturated at 60%. During compression tests, the flow stress was sensitive to compression velocity ( Vc) but was insensitive to holding temperature ( Th), and it obeyed the power law [Formula: see text]. The average strain rate sensitivity was 0.2757, and the average apparent activation energy was 254.5 kJ/mol. The compression sample can be divided into hard deformation zone, transition deformation zone, severe deformation zone and free deformation zone. Different zones had different predominant deformation mechanisms which not only affected the morphology of the grains but also codetermined the flow stress. With increasing Vc and Th, the average particle size was increased from hard deformation zone, reached the maximum at severe deformation zone and then decreased at free deformation zone, while the opposite was the case for shape factor. At each deformation zone, the average particle size was increased while the shape factor was decreased with the increasing Vc because higher Vc caused more grains to merge into larger and more irregular grains, while the opposite was the case for the increasing Th because higher Th generated more liquid which helped to isolate the contacted particles and improve their spheroidization degree.


MRS Advances ◽  
2020 ◽  
Vol 5 (57-58) ◽  
pp. 2961-2972
Author(s):  
P.C. Meléndez-González ◽  
E. Garza-Duran ◽  
J.C. Martínez-Loyola ◽  
P. Quintana-Owen ◽  
I.L. Alonso-Lemus ◽  
...  

In this work, low-Pt content nanocatalysts (≈ 5 wt. %) supported on Hollow Carbon Spheres (HCS) were synthesized by two routes: i) colloidal conventional polyol, and ii) surfactant-free Bromide Anion Exchange (BAE). The nanocatalysts were labelled as Pt/HCS-P and Pt/HCS-B for polyol and BAE, respectively. The physicochemical characterization of the nanocatalysts showed that by following both methods, a good control of chemical composition was achieved, obtaining in addition well dispersed nanoparticles of less than 3 nm TEM average particle size (d) on the HCS. Pt/HCS-B contained more Pt0 species than Pt/HCS-P, an effect of the synthesis method. In addition, the structure of the HCS remains more ordered after BAE synthesis, compared to polyol. Regarding the catalytic activity for the Oxygen Reduction Reaction (ORR) in 0.5 M KOH, Pt/HCS-P and Pt/HCS-B showed a similar performance in terms of current density (j) at 0.9 V vs. RHE than the benchmark commercial 20 wt. % Pt/C. However, Pt/HCS-P and Pt/HCS-B demonstrated a 6 and 5-fold increase in mass catalytic activity compared to Pt/C, respectively. A positive effect of the high specific surface area of the HCS and its interactions with metal nanoparticles and electrolyte, which promoted the mass transfer, increased the performance of Pt/HCS-P and Pt/HCS-B. The high catalytic activity showed by Pt/HCS-B and Pt/HCS-P for the ORR, even with a low-Pt content, make them promising cathode nanocatalysts for Anion Exchange Membrane Fuel Cells (AEMFC).


2002 ◽  
Vol 721 ◽  
Author(s):  
Monica Sorescu

AbstractWe propose a two-lattice method for direct determination of the recoilless fraction using a single room-temperature transmission Mössbauer measurement. The method is first demonstrated for the case of iron and metallic glass two-foil system and is next generalized for the case of physical mixtures of two powders. We further apply this method to determine the recoilless fraction of hematite and magnetite particles. Finally, we provide direct measurement of the recoilless fraction in nanohematite and nanomagnetite with an average particle size of 19 nm.


1970 ◽  
Vol 26 (1) ◽  
pp. 16 ◽  
Author(s):  
S Balasubramanian ◽  
Rajkumar Rajkumar ◽  
K K Singh

Experiment to identify ambient grinding conditions and energy consumed was conducted for fenugreek. Fenugreek seeds at three moisture content (5.1%, 11.5% and 17.3%, d.b.) were ground using a micro pulverizer hammer mill with different grinding screen openings (0.5, 1.0 and 1.5 mm) and feed rate (8, 16 and 24 kg h-1) at 3000 rpm. Physical properties of fenugreek seeds were also determined. Specific energy consumptions were found to decrease from 204.67 to 23.09 kJ kg-1 for increasing levels of feed rate and grinder screen openings. On the other hand specific energy consumption increased with increasing moisture content. The highest specific energy consumption was recorded for 17.3% moisture content and 8 kg h-1 feed rate with 0.5 mm screen opening. Average particle size decreased from 1.06 to 0.39 mm with increase of moisture content and grinder screen opening. It has been observed that the average particle size was minimum at 0.5 mm screen opening and 8 kg h-1 feed rate at lower moisture content. Bond’s work index and Kick’s constant were found to increase from 8.97 to 950.92 kWh kg-1 and 0.932 to 78.851 kWh kg-1 with the increase of moisture content, feed rate and grinder screen opening, respectively. Size reduction ratio and grinding effectiveness of fenugreek seed were found to decrease from 4.11 to 1.61 and 0.0118 to 0.0018 with the increase of moisture content, feed rate and grinder screen opening, respectively. The loose and compact bulk densities varied from 219.2 to 719.4 kg m-3 and 137.3 to 736.2 kg m-3, respectively.  


Author(s):  
И.В. Бачериков ◽  
Б.М. Локштанов

При проектировании открытых и закрытых хранилищ измельченных сыпучих материалов древесных материалов, таких как щепа и опилки, большое значение имеет угол естественного откоса (статический и динамический) этих материалов. В технической литературе приводятся противоречивые сведения о величине этих углов, что приводит к ошибкам при проектировании складов. В справочных данных не учитываются условия, в которых эксплуатируются емкости для хранения сыпучих материалов, свойства и состояние этих сыпучих материалов. В свою очередь, ошибки при проектировании приводят к проблемам (зависание, сводообразование, «затопление» и т. д.) и авариям при эксплуатации бункеров и силосов на производстве. В статье представлены сведения, посвященные влиянию влажности и температуры на угол естественного откоса сыпучих материалов. На основании лабораторных и натурных экспериментов, проведенных с помощью специально разработанных методик и установок, была скорректирована формула для определения углов естественного откоса (статического и динамического) для измельченных древесных материалов в зависимости от их фракционного и породного состава, влажности (абсолютной и относительной) и температуры. При помощи скорректированной формулы можно определить угол естественного откоса древесных сыпучих материалов со среднегеометрическим размером частицы от 0,5 мм до 15 мм (от древесной пыли до технологической щепы) в различных производственных условиях. Статья может быть полезна проектировщикам при расчете угла наклона граней выпускающей воронки бункеров и силосов предприятий лесной отрасли и целлюлозо-бумажной промышленности. In the design of open and closed storage warehouses chopped wood materials for bulk materials such as wood chips and sawdust, great importance has an angle of repose (static and dynamic) of these materials. In the technical literature are conflicting reports about the magnitude of these angles, which leads to errors in the design of warehouses. In the referencesdoes not take into account the conditions under which operated capacities for storage of bulk materials, and properties and condition of the bulk material. The design errors lead to problems (hanging, arching, «flooding», etc.) and accidents in the operation of hoppers and silos at the mills. The article provides information on the impact of humidity and temperature on the angle of repose of granular materials. On the basis of laboratory and field experiments, conducted with the help of specially developed techniques and facilities has been adjusted formula for determining the angle of repose (static and dynamic) for the shredded wood materials depending on their fractional and species composition, humidity (absolute and relative) and temperature. It is possible, by using the corrected formula, to determine the angle of repose of loose wood materials with average particle size of from 0.5 mm to 15 mm (wood dust to pulpchips) in various operating conditions. The article can be helpful to designers in the calculation of the angle of inclination of the funnel faces produces bunkers and silos forest industries and pulp and paper industry.


2020 ◽  
Vol 27 (22) ◽  
pp. 3623-3656 ◽  
Author(s):  
Bruno Fonseca-Santos ◽  
Patrícia Bento Silva ◽  
Roberta Balansin Rigon ◽  
Mariana Rillo Sato ◽  
Marlus Chorilli

Colloidal carriers diverge depending on their composition, ability to incorporate drugs and applicability, but the common feature is the small average particle size. Among the carriers with the potential nanostructured drug delivery application there are SLN and NLC. These nanostructured systems consist of complex lipids and highly purified mixtures of glycerides having varying particle size. Also, these systems have shown physical stability, protection capacity of unstable drugs, release control ability, excellent tolerability, possibility of vectorization, and no reported production problems related to large-scale. Several production procedures can be applied to achieve high association efficiency between the bioactive and the carrier, depending on the physicochemical properties of both, as well as on the production procedure applied. The whole set of unique advantages such as enhanced drug loading capacity, prevention of drug expulsion, leads to more flexibility for modulation of drug release and makes Lipid-based nanocarriers (LNCs) versatile delivery system for various routes of administration. The route of administration has a significant impact on the therapeutic outcome of a drug. Thus, the non-invasive routes, which were of minor importance as parts of drug delivery in the past, have assumed added importance drugs, proteins, peptides and biopharmaceuticals drug delivery and these include nasal, buccal, vaginal and transdermal routes. The objective of this paper is to present the state of the art concerning the application of the lipid nanocarriers designated for non-invasive routes of administration. In this manner, this review presents an innovative technological platform to develop nanostructured delivery systems with great versatility of application in non-invasive routes of administration and targeting drug release.


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