An explosive component in a December 2020 Milan earthquake suggests outgassing of deeply recycled carbon

Carbon dragged at sub-arc depths and sequestered in the asthenospheric upper mantle during cold subduction is potentially released after millions of years during the breakup of continental plates. However, it is unclear whether these deep-carbon reservoirs can be locally remobilized on shorter-term timescales. Here we reveal the fate of carbon released during cold subduction by analyzing an anomalously deep earthquake in December 2020 in the lithospheric mantle beneath Milan (Italy), above a deep-carbon reservoir previously imaged in the mantle wedge by geophysical methods. We show that the earthquake source moment tensor includes a major explosive component that we ascribe to carbon-rich melt/fluid migration along upper-mantle shear zones and rapid release of about 17,000 tons of carbon dioxide when ascending melts exit the carbonate stability field. Our results underline the importance of carbon-rich melts at active continental margins for emission budgets and suggest their potential episodic contributions to atmospheric carbon dioxide.

Mafic-ultramafic intrusion formed by multi-stage evolution of hydrous basaltic melts

The magmatic processes beneath the active continental margins are very complicated and affect structures and compositions of the arc roots. Neoproterozoic igneous rocks are widely distributed around the margins of the Tarim Block in NW China. The Xingdier mafic-ultramafic intrusion is a composite body, located at the northern margin of the Tarim Block, and consists of gabbro, pyroxenite, and peridotite units. The gabbro unit has a secondary ion mass spectrometry zircon U-Pb age of 727 ± 5 Ma. Rocks from the Xingdier intrusion have a large range of MgO (12.9−32.8 wt%) and SiO2 (43.0−57.9 wt%), and low K2O+Na2O (0.11−2.25 wt%) contents. They have right inclined chondrite-normalized rare earth element patterns with (La/Yb)N ratios of 2.2−8.6. Their primitive mantle normalized trace element patterns show arc-affinity geochemical features characterized by enrichment in Rb, Ba, Th, U, and Pb and depletion in Nb, Ta, and Ti. They have variable initial 87Sr/86Sr ratios (0.7063−0.7093), εNd(t) values (−2.9 to −7.8), 206Pb/204Pb (17.08−17.80), 207Pb/204Pb (15.42−15.49), and 208Pb/204Pb ratios (37.48−38.05), forming an evolution trend from the peridotite unit to the gabbro and pyroxenite units. Clinopyroxene in the three units is chemically similar to those formed in hydrous magmas. The spinel inclusions in olivine from the peridotite unit show unmixing texture and have high Al contents and oxygen fugacity of ∼FMQ+1. Therefore, the parental magma was probably derived from a lithospheric mantle enriched by slab-derived fluids. Rocks from the gabbro and peridotite units are proposed to have been derived from olivine-normative melts, whereas rocks from the pyroxenite unit are cumulates from the quartz-normative melts. Such contrasting parental magmas resulted from variable degrees of crustal contamination and fractional crystallization in the arc root.

Heavy Minerals Study of Sandstone from the Late Miocene-Early Pliocene Mukdadiya Formation; Kirkuk, Iraq: Implications for Provenance

Mukdadiya Formation (Late Miocene-Pliocene) exposed in the northeastern limb of Baba anticline fold in Kirkuk structure. The selected section was located in the Shoraw area, northeastern Kirkuk city, Iraq. Twenty sandstone samples were collected to study heavy minerals. The study indicates that opaque and epidote group minerals forming the main heavy minerals, followed by amphibole, pyroxene, garnet, and chlorite. According to heavy minerals assemblage, the source rocks are interpreted to be composed essentially of sedimentary followed by igneous and metamorphic rocks and the high contents of unstable and metastable minerals confirm their direct derivation from the adjacent primary source. Ultra-stable and metastable heavy minerals relationship indicated that the sandstone of the Mukdadiya Formation is immature and moderate stability and showed that these minerals couldn't be transported for very long distances close to the source area and not represents polycyclic grain. MF-MT-GM Ternary diagram showed that the studied samples fall within the field of active continental margins which is characterized by a relatively high percentage of minerals (MF˃GM) derived from mafic magmatic rocks.

Morphological rejuvenation on tectonic seamounts: insights from the Gorringe Bank, SW Iberian Margin

<p>Seamounts are spectacular bathymetric features common within volcanic and tectonically active continental margins. During their lifecycles, they evolve through stages of construction and destruction. Seamount chains on the Southwest Iberian Margin are prone to instability and collapse due to regionally complex tectonism with moderate to high seismicity. In this work we investigate collapse episodes during the lifecycle of the tectonic Gorringe Bank (GB), the largest submarine seamount offshore European margins, based on recurrence patterns of MTDs on the active thrust flank. Eight MTDs with relevant expression on the seismic data were analysed, four of estimated Miocene age and four on a Pliocene-Quarternary interval. Miocene MTDs are overall larger and correlate with the main uplift stages of the GB structure. Their distribution and relative timing suggest that failure-triggering earthquakes were common along the whole length of the GB. Pliocene to Quarternary MTDs tend to cluster along the northern half of the GB flank and are generally smaller. Based on our observations, we propose that the lifecycle of tectonic seamounts is marked by morphological rejuvenation episodes driven by tectonic activity between major collapse events or cycles. Tectonic-driven rejuvenation is thus key to hinder or obliterate evidence of past high-magnitude destructive events on tectonic seamount morphology.</p>

Causes of the Occurrence of A-Type Volcanic Rocks in Active Continental Margins (Southern Sikhote-Alin, Russian Far East)

––New isotope-geochemical data on the volcanic complexes of the South Yakut and Martel volcanic depressions in southern Primorye are presented. Their formation in the early Eocene (54.3 Ma) and Late Cretaceous (83.5 Ma), respectively, is evidenced by U–Pb zircon dating (LA-ICP-MS). Based on the geochemical characteristics, it is concluded that the volcanics are typical A-type igneous rocks. Their formation coincides with the sudden change in the vector of motion of the Pacific slab with respect to the continent in the Campanian and Paleocene–Eocene, which caused destruction of the slab with its probable discontinuity and the injection of the subslab asthenosphere. The effect of mantle fluids on the continental lithospheric-rock melting determined the generation of magmas with the specific geochemical features of A-type igneous rocks. The regularities of their composition are due to the deep-seated reduced F-rich fluids that caused the intense differentiation of magmas accumulating fluidized melts enriched in mobile components in the apical part.

Miocene Seep-Carbonates of the Northern Apennines (Emilia to Umbria, Italy): An Overview

The natural emission of methane-rich fluids from the seafloor, known as cold seepage, is a widespread process at modern continental margins. The studies on present-day cold seepages provide high-resolution datasets regarding the fluid plumbing system, biogeochemical processes in the sediment, seafloor seepage distribution and ecosystems. However, the long-term (hundreds of thousands to millions of years) evolution of cold seepage remains elusive. The identification and study of outcrop analogous now exposed on land represent a valuable method for better understanding the effects of geological processes and climate forcing on the development of cold seepage systems. Here, we provide an overview on Miocene seep-carbonate deposits of the northern Apennines (from Emilia to the Umbria-Marchean sector, Italy), based on decades of field research integrated with detailed sedimentological and geochemical investigations. We report a total of 13 seep-carbonate outcrops, which formed in three different structural settings of the paleo-accretionary wedge corresponding to wedge-top basins, outer slope and intrabasinal highs at the deformational front. We discuss the recurring lithostratigraphic occurrence of seep deposits and the main compositional features (carbonate facies, carbon and oxygen stable isotopes) in order to interpret the seepage dynamics, duration and infer the contribution of methane-rich fluids released by paleo-gas hydrates. The datasets presented in this study represent a valuable complete record of cold seepage spanning ~12 Myr, that can be used to better understand factors controlling the regional-scale spatial and temporal evolution of cold seepage systems at modern active continental margins.

Study of the petrography and tectonic settings of sills in Lavasanat district, Tehran (north of Iran)

The study area is located in Lavasanat District in the northeast of Tehran in Central Alborz zone. The outcrops are mainly linked to Karaj Formation, which belongs to the upper Eocene to Oligocene periods. In the study area, there are various plutonic rocks that are identified in the form of numerous dike and sill on the ground. These sills are injected in between sedimentary layers. The rocks forming the sills include the spectrum of gabbro, gabbro diorite, diorite, monzonite, and syenite. In some areas, these rocks have undergone alterations and have traces of the saussuritization and chloritization phenomena. There are also two generations of amorphous. The first generation is fully chloritized due to alteration while the second generation is unaltered. Unlike many diorites and monzonites, which typically have hornblendes, the neutral rocks such as diorite and monzonite lack hornblendes. Hence, their magmas were dry and dehydrated. Based on the geochemical studies conducted on 17 samples (15 sill samples and 2 host rock samples) and the diagrams of the tectonic settings of rocks, the study sills are in the WIN (within plate). However, two samples of the host rock are within the range of the active continental margins.

Sources of Heavy Minerals of the Neogene Clastics at Bekhme, Northern Iraq

Ten samples were collected from Injana and Mukdadiya Formations, representing 5 samples of fine grain sandstone (F) and 5 samples of very fine grain sandstone (VF). The heavy metals study showed that the opaque mineral recorded the highest percentage in comparison with other heavy metals. While, transparent minerals, including unstable minerals (Amphibole including Hornblend and Glaucophane) and (pyroxene including Orthopyroxene and Clinopyroxene), Metastable minerals including (Epidote, staurolite, Garnet, Kyanite) indicated metamorphic source, Ultrastable minerals (Zircon, Rutile, Tourmaline), Mica group (chlorite, biotite and muscovite). These accumulations indicate that the heavy minerals are derived from mafic igneous and metamorphic rocks mostly, as well as acidic igneous and reworked sediments. Ternary diagram of heavy metals stability showed that they are moderately stable due to the effect of the opaque mineral that have highest attention. Both sandstones for the Injana and Mukdadiya formations are derived from active continental margins. This source rocks may be represented by Taurus and Zagros Mountains.

Geochemistry and mineral chemistry of quartz mica schists within Iseyin-Oyan Schist Belt, Southwestern Nigeria

Background/Objectives: The Iseyin-Oyan schist belt is made up metasedimentary rocks, gneisses, granites and pegmatite intrusions. The study was aimed at identifying the schist within this belt and assess their metamorphism, geochemical characteristics and tectonic origin. Methods: Detailed geologic field mapping was undertaken where rocks were located, studied in-situ and identified. Samples of the schist were prepared for petrographic studies. Mineralogical contents were determined using X-Ray Diffraction technique. Polished sections were studied for mineral chemistry using Scanning Electron Microscope-Energy Dispersive Spectroscopy. Rock samples were analysed using X-Ray Fluorescence Spectroscopy and Inductively Coupled Plasma Emission Spectrometry. Geochemical data were elucidated using diverse geochemical discrimination diagrams. Findings: The schists are quartz mica schists and occur in close association with amphibolites, intrusive granitoids and pegmatites. The Mineral assemblage indicates upper (at the western part) to lower (at the central part) amphibolite facies grade metamorphism in the area. Pyrope-almandine garnets occur in quartz mica schist at the western parts reinforcing higher pressure-temperature metamorphic conditions. The concentration (in %) of SiO2 ranged from 56.4-71.6; Al2O3, 13.7-21.1; Fe2O3, 2-8; MgO, 0.7-2.4; and K2O, 2.1-5.5 supporting the evidence for differential degrees of metamorphism. Large iron lithophile and high field strength elements are similar to the average upper continental crust. Pronounced negative Europium anomaly pointed to the major roles played by feldspars during the geological processes. Plagioclase ranged from albite-oligoclase and oligoclase- andesine. The precursors of the quartz mica schist are possibly arkosic and greywacke sands deposited within the active continental margins. Evidence of uplift and overturning suggested for the differential metamorphism may be due to these events usually associated with active continental margins. Applications: This study has identified the once named undifferentiated schist in the study area to be quartz mica schist with details in their grades of metamorphism elucidated. Keywords: Quartz mica schist; geochemistry; mineral chemistry; Iseyin-Oyan schist belt; precambrian basement complex

The final stage of the Acid Island Arc magmatism in the Northern Urals

For the first time, the time of completion of the formation of calc-alkaline volcanic complexes of the Devonian Island Arc (Franian) in the Northern Urals was determined. It is shown that the late Devonian volcanic rocks of the Limka series have geochemical characteristics that bring them closer to the rocks of developed island arcs and active continental margins. The detected delay of the final episode of calc-alkaline volcanism in the Northern Urals in comparison with the similar event in the southern Urals may be due to the oblique nature of the subduction.