Characterization of Hemp (Cannabis sativa L.) Biodiesel Blends with Euro Diesel, Butanol and Diethyl Ether Using FT-IR, UV–Vis, TGA and DSC Techniques

2018 ◽  
Vol 11 (3) ◽  
pp. 1097-1113 ◽  
Author(s):  
M. N. Mohammed ◽  
A. E. Atabani ◽  
Gediz Uguz ◽  
Chyi-How Lay ◽  
Gopalakrishnan Kumar ◽  
...  
Keyword(s):  
Diethyl Ether ◽  
Cannabis Sativa ◽  
Biodiesel Blends ◽  
Ft Ir ◽  
Tga And Dsc

scholarly journals Synthesis and Characterization of New Dental Composite for Dentistry Based on Unsaturated Monomers and Nano-fillers by Photopolymerization

2020 ◽  
Vol 13 (1) ◽  
pp. 21-29
Author(s):  
Mahdi Saleh Mahdi ◽  
Mohammed Ali Mutar
Keyword(s):  
Dental Composite ◽  
Nano Composites ◽  
Nano Composite ◽  
Initiation System ◽  
Ft Ir ◽  
Tga And Dsc ◽  
Nano Size ◽  
As Solubility ◽  
Thermal Stability Of

In this study, dental nano-composite specimens were prepared by dispersion of various amounts of nano-sized fillers (HA, ZrO2, and SiO2) in a monomer system containing 60% Bis-GMA and 40% TEGDMA. 2,2 propyl bis-phenyl glycidyldimethacrylate (Bis-GMA) with unsaturated monomers were prepared. Camphor Quinone (CQ) of 1 wt %, 2-DiMethyl Amino Ethyl Methacrylate (DMAEMA) of 1 wt % have been applied in photo-initiation system for the purpose of initiating matrix resins’ co-polymerization. Wear resistance, flexural strength, hardness and compressive strength were measured. The results indicated an increase in the mechanical properties in the samples containing nano-size filler particles. It is interesting to note that, this improvement was observed at much lower nano-size filler content. Physicochemical properties, such as Solubility (SL), Water Sorption (WS) as well as the Volumetric Shrinkage (VS) have been examined. FT-IR as well as SEM have been utilized for implementing the characterization. SEM has been applied for showing particle size distribution as well as the particle agglomeration that is related to the treated nano-fillers in nano-composites. FT-IT is initially applied for identifying qualitative compositions regarding the nano-composites’ compositions. The Thermal stability of all dental nano-ocomposites was also studied using TGA and DSC techniques.

Physico-chemical Characterization of Hydrochloric Acid-treated Kaolin Clay: An Industry Approach as a Potential Catalyst

2020 ◽  
Vol 23 (3) ◽  
pp. 205-213
Author(s):  
Awinash Kumar ◽  
Pradip Lingfa
Keyword(s):  
Hydrochloric Acid ◽  
Chemical Characterization ◽  
Kaolin Clay ◽  
Bending Vibrations ◽  
Characterization Methods ◽  
Weight Percentage ◽  
Dta Analysis ◽  
Ft Ir ◽  
Tga And Dsc

Aim and Objective: This study explains the FT-IR, XRD, XRF, SEM/EDX, TGA, and DSC/DTA characterization of commercially available kaolin clay. The objective of this paper is to explore the prominent utilization of kandites clay and useful chemical aspects for the modification of kaolin clay minerals. Materials and Methods: The untreated kaolin sample has been procured in this experimental work from AksharChem, Gujrat, India. The kaolin clay was treated with 4M hydrochloric acid. FT-IR, XRD, XRF, SEM/EDX, TGA, and DSC/DTA characterization methods have been used. Results: Loss on ignition was found at 10.89%. The fingerprint region of the acid-treated sample has broad and more bending vibrations than untreated samples. The high weight percentage of Ti and CaCO3 were spotted in the scanning electron micrograph by both atomic % and weight %. The FT-IR revealed the functional group of Al-O, A1-OH, and Si-O. Conclusion: The morphology indicates that the presences of large particles are in the form of agglomerates. It was found that impurity like scandium vanished and manganese traced by the same atomic % 0.01 of zinc which had no presence after acid treatment. Thermogravimetric analysis indicates the sharp increments in heat flow in-between temperatures 0°C to 200°C and consequently increments in between 500°C to 550°C, a suitable range for the pyrolysis. Low amount of alumina and high amount of silica has been found out. TGA and DTA analysis satisfy the waste plastic valorization temperature ranges.

scholarly journals Comparative FT-IR Prospecting for Cellulose in Stems of Some Fiber Plants: Flax, Velvet Leaf, Hemp and Jute

2021 ◽  
Vol 11 (18) ◽  
pp. 8570
Author(s):  
Rodica Vârban ◽  
Ioana Crișan ◽  
Dan Vârban ◽  
Andreea Ona ◽  
Loredana Olar ◽  
...  
Keyword(s):  
Cannabis Sativa ◽  
Raw Materials ◽  
Screening Method ◽  
Qualitative Assessment ◽  
Crystalline Region ◽  
Plant Fibers ◽  
Practical Applications ◽  
Extraction Procedures ◽  
Ft Ir

Plant fibers are sustainable sources of materials for many industries, and can be obtained from a variety of plants. Cellulose is the main constituent of plant-based fibers, and its properties give the characteristics of the fibers obtained. Detailed characterization of cellulosic fibers is often performed after lengthy extraction procedures, while fast screening might bring the benefit of quick qualitative assessment of unprocessed stems. The aim of this research was to define some marker spectral regions that could serve for fast, preliminary qualitative characterization of unprocessed stems from some textile plants through a practical and minimally invasive method without lengthy extraction procedures. This could serve as a screening method for sorting raw materials by providing an accurate overall fingerprint of chemical composition. For this purpose, we conducted comparative Fourier Transform Infrared Spectroscopy (FT-IR) prospecting for quality markers in stems of flax (Linum usitatissimum L.), velvet leaf (Abutilon theophrasti Medik.), hemp (Cannabis sativa L.) and jute (Corchorus olitorius L.). Analysis confirmed the presence of major components in the stems of the studied plants. Fingerprint regions for cellulose signals were attributed to bands at 1420–1428 cm−1 assigned to the crystalline region and 896–898 cm−1 assigned to the amorphous region of cellulose. The optimization of characterization methods for raw materials is important and can find immediate practical applications.

scholarly journals Characterization of Flax and Hemp Using Spectrometric Methods

2021 ◽  
Vol 11 (18) ◽  
pp. 8341
Author(s):  
Luisa Andronie ◽  
Ioana Delia Pop ◽  
Rodica Sobolu ◽  
Zoriţa Diaconeasa ◽  
Alina Truţă ◽  
...  
Keyword(s):  
Antioxidant Capacity ◽  
Nutritional Value ◽  
Cannabis Sativa ◽  
Dry Weight ◽  
Linum Usitatissimum L ◽  
Protein Fiber ◽  
Ft Ir ◽  
Flax Seeds ◽  
Molecular Components

The comparison of the antioxidant activity of the studied seeds of fiber crop (hemp and flax) emphasized a hierarchy of antioxidant capacity. The purpose of the study was to investigate the antioxidant capacity and nutritional value of flax seeds (Linum usitatissimum L.) and hemp seeds (Cannabis sativa L.) in powder form. In this study, the FT-IR technique was utilized in order to detect molecular components in analyzed samples. Antioxidant capacity was evaluated with photochemical assay as well as humidity, protein, fiber, lipid and carbohydrate content. The FT-IR results reveal the presence of different bio-active compounds in hemp such as flavonoids, tannins, sugars, acids, proanthocyanidins, carotenoids and citric metabolites. The highest antioxidant capacity was observed in flax seeds, 18.32 ± 0.98, in comparison with hemp seeds, 4 ± 0.71 (μg/mg dry weight equivalent ascorbic acid). Regarding nutritional parameters, flax seeds showed the most increased content of protein, displaying average values of 534.08 ± 3.08, as well as 42.20 ± 0.89 of lipids and 27.30 ± 0.89 of fiber (g/100 g/sample). Hemp seeds showed the highest protein content of 33 ± 1.24 (g/100 g/sample).

Spectral Investigation on the Growth and Characterization of NLO Crystals of Thiourea Succinic Acid Single Crystal.

2015 ◽  
Vol 2 (2) ◽  
pp. 70-73
Author(s):  
Kannan.P ◽  
Thambidurai.S ◽  
Suresh.N
Keyword(s):  
Single Crystal ◽  
Succinic Acid ◽  
Slow Evaporation Technique ◽  
Absorption Studies ◽  
Dta Analysis ◽  
Evaporation Technique ◽  
Ft Ir ◽  
Ir Spectroscopic ◽  
Thermal Stability Of

Growth of optically transparent single crystals of thiourea succinic acid (TUSA) was grown successfully from aqueous solution by slow evaporation technique. The crystal structure was elucidated using the single crystal XRD. The various functional groups and the modes of vibrations were identified by FT-IR spectroscopic analysis. The optical absorption studies indicate that the optical transparency window is quite wide making its suitable for NLO applications. Thermal stability of the crown crystal carried out by TGA-DTA analysis.

Thermal Behaviour of Candesartan Active substance and in pharmaceutical compounds

2017 ◽  
Vol 68 (8) ◽  
pp. 1895-1902
Author(s):  
Ioana Cristina Tita ◽  
Eleonora Marian ◽  
Bogdan Tita ◽  
Claudia Crina Toma ◽  
Laura Vicas
Keyword(s):  
Thermal Behaviour ◽  
Active Substance ◽  
Pharmaceutical Research ◽  
Pharmaceutical Product ◽  
Nitrogen Atmosphere ◽  
Pure Substance ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Ft Ir

Thermal analysis is one of the most frequently used instrumental techniques in the pharmaceutical research, for the thermal characterization of different materials from solids to semi-solids, which are of pharmaceutical relevance. In this paper, simultaneous thermogravimetry/derivative thermogravimetry (TG/DTG) and differential scanning calorimetry (DSC) were used for characterization of the thermal behaviour of candesartan cilexetil � active substance (C-AS) under dynamic nitrogen atmosphere and nonisothermal conditions, in comparison with pharmaceutical product containing the corresponding active substance. It was observed that the commercial samples showed a different thermal profile than the standard sample, caused by the presence of excipients in the pharmaceutical product and to possible interaction of these with the active substance. The Fourier transformed infrared spectroscopy (FT-IR) and X-ray powder diffraction (XRPD) were used as complementary techniques adequately implement and assist in interpretation of the thermal results. The main conclusion of this comparative study was that the TG/DTG and DSC curves, together with the FT-IR spectra, respectively X-ray difractograms constitute believe data for the discrimination between the pure substance and pharmaceutical forms.

Preparation and Characterization of Soybean Oil-based Flame Retardant Rigid Polyurethane Foams Containing Phosphaphenanthrene Groups

2020 ◽  
Vol 17 (10) ◽  
pp. 760-771
Author(s):  
Qirui Gong ◽  
Niangui Wang ◽  
Kaibo Zhang ◽  
Shizhao Huang ◽  
Yuhan Wang
Keyword(s):  
Soybean Oil ◽  
Flame Retardant ◽  
Chemical Structure ◽  
Cell Structure ◽  
Polyurethane Foams ◽  
Limiting Oxygen Index ◽  
Rigid Polyurethane Foams ◽  
Degradation Activation Energy ◽  
Ft Ir

A phosphaphenanthrene groups containing soybean oil based polyol (DSBP) was synthesized by epoxidized soybean oil (ESO) and 9,10-dihydro-oxa-10-phosphaphenanthrene-10-oxide (DOPO). Soybean oil based polyol (HSBP) was synthesized by ESO and H2O. The chemical structure of DSBP and HSBP were characterized with FT-IR and 1H NMR. The corresponding rigid polyurethane foams (RPUFs) were prepared by mixing DSBP with HSBP. The results revealed apparent density and compression strength of RPUFs decreased with increasing the DSBP content. The cell structure of RPUFs was examined by scanning electron microscope (SEM) which displayed the cells as spherical or polyhedral. The thermal degradation and flame retardancy of RPUFs were investigated by thermogravimetric analysis, limiting oxygen index (LOI), and UL 94 vertical burning test. The degradation activation energy (Ea) of first degradation stage reduced from 80.05 kJ/mol to 37.84 kJ/mol with 80 wt% DSBP. The RUPF with 80 wt% DSBP achieved UL94 V-0 rating and LOI 28.3. The results showed that the flame retardant effect was mainly in both gas phase and condensed phase.

Isolasi Dan Karakterisasi Bentonit Alam Menjadi Nanopartikel Monmorillonit

2018 ◽  
Vol 3 (1) ◽  
pp. 12 ◽  
Author(s):  
Zaimahwati Zaimahwati ◽  
Yuniati Yuniati ◽  
Ramzi Jalal ◽  
Syahman Zhafiri ◽  
Yuli Yetri
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Particle Size ◽  
Surface Morphology ◽  
Average Diameter ◽  
Particle Size Analyzer ◽  
Ft Ir ◽  
Scanning Electron ◽  
Sedimentation Processes

<p>Pada penelitian ini telah dilakukan isolasi dan karakterisasi bentonit alam menjadi nanopartikel montmorillonit. Bentonit alam yang digunakan diambil dari desa Blangdalam, Kecamatan Nisam Kabupaten Aceh Utara.  Proses isolasi meliputi proses pelarutan dengan aquades, ultrasonic dan proses sedimentasi. Untuk mengetahui karakterisasi montmorillonit dilakukan uji FT-IR, X-RD dan uji morfologi permukaan dengan Scanning Electron Microscopy (SEM). Partikel size analyzer untuk menganalisis dan menentukan ukuran nanopartikel dari isolasi bentonit alam. Dari hasil penelitian didapat ukuran nanopartikel montmorillonit hasil isolasi dari bentonit alam diperoleh berdiameter rata-rata 82,15 nm.</p><p><em>In this research we have isolated and characterized natural bentonite into montmorillonite nanoparticles. Natural bentonite used was taken from Blangdalam village, Nisam sub-district, North Aceh district. The isolation process includes dissolving process with aquades, ultrasonic and sedimentation processes.  The characterization of montmorillonite, FT-IR, X-RD and surface morphology test by Scanning Electron Microscopy (SEM). Particle size analyzer to analyze and determine the size of nanoparticles from natural bentonite insulation. From the research results obtained the size of montmorillonite nanoparticles isolated from natural bentonite obtained an average diameter of 82.15 nm.</em></p>

Characterization of a new type of mead fermented with Cannabis sativa L. (hemp)

2021 ◽  
Author(s):  
Raffaele Romano ◽  
Alessandra Aiello ◽  
Lucia De Luca ◽  
Rosario Sica ◽  
Emilio Caprio ◽  
...  
Keyword(s):  
Cannabis Sativa ◽  
New Type
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