Effects of CO2, N2, Air, and Nitrogen Salts on Spray Solution pH

1990 ◽  
Vol 4 (4) ◽  
pp. 910-912 ◽  
Author(s):  
Ronald W. McCormick
Keyword(s):  
Chemical Properties ◽  
Spray Nozzle ◽  
Monoammonium Phosphate ◽  
Solution Ph ◽  
Pressurized Water ◽  
Spray Solution ◽  
Physical Chemical ◽  
Water Ph ◽  
Urea Ammonium Nitrate ◽  
Reduced Water

Water samples from eight locations, ranging in pH from 7.1 to 8.5, were tested to determine the effect of carbon dioxide (CO2) pressurization on pH. After pressurization with CO2the pH of the water decreased 1.8 to 4.1 pH units. An increase of 0.4 to 1.2 pH units occurred after the CO2pressurized water exited a spray nozzle. The use of N2or air as a pressurizing gas had very little effect on pH. The addition of diammonium phosphate, urea-ammonium nitrate (UAN)3, or ammonium sulfate had only minor effects on water pH. The addition of monoammonium phosphate reduced water pH to 4.6 to 5.5. The physical/chemical properties and activity of a herbicide may be altered with the change in spray solution pH by using CO2to pressurize the spray solution.

Sethoxydim Response to Spray Carrier Chemical Properties and Environment

1994 ◽  
Vol 8 (3) ◽  
pp. 591-597 ◽  
Author(s):  
John D. Nalewaja ◽  
Robert Matysiak ◽  
Edward Szelezniak
Keyword(s):  
Low Temperature ◽  
Sodium Bicarbonate ◽  
Leaf Surface ◽  
Uv Light ◽  
Chemical Properties ◽  
Ammonium Hydroxide ◽  
Ammonium Salts ◽  
Uv Degradation ◽  
Solution Ph ◽  
Spray Solution

Experiments were conducted to determine the influence of spray carrier salts, UV light, and temperature on sethoxydim phytotoxicity to oat or yellow foxtail. Spray solution pH and ions present were both important to sethoxydim phytotoxicity to oat. Sodium and calcium salts were antagonistic to sethoxydim phytotoxicity only when the spray carrier pH exceeded 7. Ammonium salts and ammonium hydroxide were synergistic with sethoxydim, and the synergism was independent of spray solution pH. Ammonium sulfate, but not ammonium hydroxide, overcame sodium bicarbonate antagonism of sethoxydim. The antagonism of sethoxydim phytotoxicity by sodium bicarbonate was greatest in the presence of UV light and most pronounced when treated plants were exposed to mid-day sunlight. Sodium bicarbonate or low temperature may reduce the speed of sethoxydim absorption allowing for greater UV degradation of unabsorbed sethoxydim on the leaf surface.

The Influence of Adjusting Spray Solution pH on the Efficacy of Saflufenacil

2013 ◽  
Vol 27 (3) ◽  
pp. 445-447 ◽  
Author(s):  
Jared M. Roskamp ◽  
William G. Johnson
Keyword(s):  
Ammonium Sulfate ◽  
Weight Reduction ◽  
Seed Oil ◽  
Dry Weight ◽  
Final Solution ◽  
Solution Ph ◽  
Field Corn ◽  
Spray Solution ◽  
Initial Ph ◽  
Water Ph

Saflufenacil solubility and efficacy has been shown to be influenced by carrier water pH. This research was conducted to determine if altering the pH of a solution already containing saflufenacil would influence the efficacy of the herbicide. Saflufenacil at 25 g ai ha−1was applied to field corn in carrier water with one of five initial pH levels (4.0, 5.2, 6.5, 7.7, or 9.0) and then buffered to one of four final solution pH levels (4.0, 6.5, 9.0, or none) for a total of twenty treatments. All treatments included ammonium sulfate at 20.37 g L−1and methylated seed oil at 1% v/v. Generally, saflufenacil with a final solution pH of 6.5 or higher provided more dry weight reduction of corn than saflufenacil applied in a final pH of 5.2 or lower. When applying saflufenacil in water with an initial pH of 4.0 or 5.2, efficacy was increased by raising the final solution pH to either 6.5 or 9.0. Conversely, reduction in corn dry weight was less when solution pH of saflufenacil mixed in carrier water with an initial pH of 6.5 or 7.7 was lowered to a final pH of 4.0. When co-applying saflufenacil with herbicides that are very acidic, such as glyphosate, efficacy of saflufenacil may be reduced if solution pH is 5.2 or lower.

Differential Effects of UAN on Antagonism with Bentazon

1990 ◽  
Vol 4 (3) ◽  
pp. 620-624 ◽  
Author(s):  
B. Clifford Gerwick ◽  
Lisa D. Tanguay ◽  
Frank G. Burroughs
Keyword(s):  
Methyl Ester ◽  
Ammonium Nitrate ◽  
Differential Effect ◽  
Field Trials ◽  
Solution Ph ◽  
Differential Effects ◽  
Spray Solution ◽  
Giant Foxtail ◽  
Urea Ammonium Nitrate

The effect of urea ammonium nitrate (UAN) on the antagonism of sethoxydim, haloxyfop, or the methyl ester of haloxyfop activity by bentazon was evaluated in greenhouse and field trials on yellow and giant foxtail. Including UAN in the spray solution in the absence of bentazon did not enhance the activity of any of the three grass herbicides. However, adding UAN to sethoxydim or haloxyfop in the presence of bentazon decreased the bentazon antagonism of grass activity. Conversely, UAN increased bentazon antagonism of the activity of haloxyfop methyl ester. The differential effect of UAN was not linked to effects on spray solution pH.

scholarly journals Physical-chemical Background of the Potential Phase Transitions during Loss of Coolant Accidents in the Supercritical Water Loops of Various Generation IV Nuclear Reactor Types

2019 ◽  
Vol 63 (2) ◽  
pp. 333-339
Author(s):  
Gábor Györke ◽  
Attila R. Imre
Keyword(s):  
Pressure Drop ◽  
Supercritical Water ◽  
Nuclear Reactor ◽  
Chemical Properties ◽  
Initial Pressure ◽  
Pressurized Water ◽  
Physical Chemical ◽  
Loss Of Coolant ◽  
Flash Boiling ◽  
Water Reactors

Loss of coolant accidents (LOCA) are a serious type of accidents for nuclear reactors, when the integrity of the liquid-loop breaks. While in traditional pressurized water reactors, pressure drop can cause flash boiling, in Supercritical-Water Cooled reactors, the pressure drop can be terminated by processes with fast phase transition (flash boiling or steam collapse) causing pressure surge or the expansion can go smoothly to the dry steam region. Modelling the pressure drop of big and small LOCAs as isentropic and isenthalpic processes and replacing the existing reactor designs with a simplified supercritical loop, limiting temperatures for various outcomes will be given for 24.5 and 25 MPa initial pressure. Using the proposed method, similar accidents for chemical reactors and other equipment using supercritical fluids can be also analyzed, using only physical-chemical properties of the given supercritical fluid.

Chlorinated Organics in Nearshore Waters and Tributaries of the St. Clair River

1986 ◽  
Vol 21 (3) ◽  
pp. 344-350 ◽  
Author(s):  
Barry G. Oliver ◽  
Klaus L.E. Kaiser
Keyword(s):  
United States ◽  
Suspended Sediment ◽  
Waste Disposal ◽  
Large Volume ◽  
Water Samples ◽  
Chemical Properties ◽  
Low Level ◽  
Chemical Company ◽  
Physical Chemical ◽  
The Individual

Abstract The concent rat ions of hexachloroethane (HCE), hexachlorobutadiene (HCBD), pentachlorobenzene (QCB), hexachlorobenzene (HCB) and octachlorostyrene (OCS) in large volume water samples show that the major sources of these chemicals to the St. Clair River are Dow Chemical Company effluents and, to a lesser degree, Sarnia’s Township ditch which drains one of Dow’s waste disposal sites. Tributaries entering the river on both sides of the Canada/United States border contain measurable concentrations of these chemicals indicating low level contamination throughout the area. The degree of water/suspended sediment partitioning of the chemicals (Kp) was studied. Kp values for the individual chemicals changed in a manner consistent with changes in their physical-chemical properties.

Polymer-Graphene Nanoassemblies and their Applications in Cancer Theranostics

2020 ◽  
Vol 20 (11) ◽  
pp. 1340-1351 ◽  
Author(s):  
Ponnurengam M. Sivakumar ◽  
Matin Islami ◽  
Ali Zarrabi ◽  
Arezoo Khosravi ◽  
Shohreh Peimanfard
Keyword(s):  
Mechanical Stability ◽  
Chemical Properties ◽  
The Other ◽  
Hydrophilic Polymer ◽  
Two Dimensional ◽  
Normal Tissues ◽  
Physical Chemical ◽  
Anti Cancer ◽  
Good Biocompatibility ◽  
Cancer Theranostics

Background and objective: Graphene-based nanomaterials have received increasing attention due to their unique physical-chemical properties including two-dimensional planar structure, large surface area, chemical and mechanical stability, superconductivity and good biocompatibility. On the other hand, graphene-based nanomaterials have been explored as theranostics agents, the combination of therapeutics and diagnostics. In recent years, grafting hydrophilic polymer moieties have been introduced as an efficient approach to improve the properties of graphene-based nanomaterials and obtain new nanoassemblies for cancer therapy. Methods and results: This review would illustrate biodistribution, cellular uptake and toxicity of polymergraphene nanoassemblies and summarize part of successes achieved in cancer treatment using such nanoassemblies. Conclusion: The observations showed successful targeting functionality of the polymer-GO conjugations and demonstrated a reduction of the side effects of anti-cancer drugs for normal tissues.

scholarly journals Shellfish Chitosan Potential in Wine Clarification

2021 ◽  
Vol 11 (10) ◽  
pp. 4417
Author(s):  
Veronica Vendramin ◽  
Gaia Spinato ◽  
Simone Vincenzi
Keyword(s):  
Molecular Structure ◽  
Chemical Properties ◽  
Allergic Reactions ◽  
Chitin Content ◽  
Deacetylation Degree ◽  
Physical Chemical ◽  
Similar Chemical ◽  
Fungal Chitosan ◽  
Significant Difference ◽  
Fish Industry

Chitosan is a chitin-derived fiber, extracted from the shellfish shells, a by-product of the fish industry, or from fungi grown in bioreactors. In oenology, it is used for the control of Brettanomyces spp., for the prevention of ferric, copper, and protein casse and for clarification. The International Organisation of Vine and Wine established the exclusive utilization of fungal chitosan to avoid the eventuality of allergic reactions. This work focuses on the differences between two chitosan categories, fungal and animal chitosan, characterizing several samples in terms of chitin content and degree of deacetylation. In addition, different acids were used to dissolve chitosans, and their effect on viscosity and on the efficacy in wine clarification were observed. The results demonstrated that even if fungal and animal chitosans shared similar chemical properties (deacetylation degree and chitin content), they showed different viscosity depending on their molecular weight but also on the acid used to dissolve them. A significant difference was discovered on their fining properties, as animal chitosans showed a faster and greater sedimentation compared to the fungal ones, independently from the acid used for their dissolution. This suggests that physical–chemical differences in the molecular structure occur between the two chitosan categories and that this significantly affects their technologic (oenological) properties.

scholarly journals Electrospinning: A promising technique for drug delivery systems

2020 ◽  
Vol 59 (1) ◽  
pp. 441-454
Author(s):  
Carlos A. Martínez-Pérez
Keyword(s):  
Drug Delivery ◽  
Drug Delivery Systems ◽  
Chemical Properties ◽  
Delivery Systems ◽  
Extrinsic Factor ◽  
Promising Technique ◽  
Physical Chemical ◽  
Set Up ◽  
Final System ◽  
Intense Research

AbstractIn the last years, electrospinning has become a technique of intense research to design and fabricate drug delivery systems (DDS), during this time a vast variety of DDS with mainly electrospun polymers and many different active ingredient(s) have been developed, many intrinsic and extrinsic factor have influence in the final system, there are those that can be attributed to the equipment set up and that to the physical-chemical properties of the used materials in the fabrication of DDS. After all, this intense research has generated a great amount of DDS loaded with one or more drugs. In this manuscript a review with the highlights of different kind of systems for drug delivery systems is presented, it includes the basic concepts of electrospinning, types of equipment set up, polymer/drug systems, limitations and challenges that need to be overcome for clinical applications.

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