scholarly journals Color in ostracode shells: taphonomy and paleotemperature interpretation

1992 ◽  
Vol 6 ◽  
pp. 172-172
Author(s):  
Mervin Kontrovitz ◽  
Jerry Marie Slack ◽  
Nigel R. Ainsworth ◽  
Richard D. Burnett

Interpretations of geologic history would be enhanced if taphonomic processes, including color changes in shells, were better known. This study deals with the origins and alteration of post-mortem colors in podocopid ostracodes. Modern shells were subjected to elevated temperatures and pressures in reactor vessels with sediments, simulating some burial conditions. Fossil shells from outcrops and boreholes were heated and treated with solvents, in an attempt to identify the coloring agent(s).Modern marine shells are white to pale yellow (Munsell 5Y 8/1 – 2.5Y 8/4). Upon heating at atmosphere, up to about 650°, they became slightly redder, slightly darker, and less color saturated, but never dark (Munsell “value” less than 5). From 650-850° they became yellower and lighter, and above 850° chalky and more yellow. Shells at elevated temperatures and pressures (T-P) with organic-poor sediments and/or iron compounds developed higher color values and lower chromas; they did not become dark. Thus, modern ostracode shells subjected to elevated T-P changed colors, but alone never attained the dark colors seen in many fossils. Only those heated in matured organic-rich sediment and/or crude oils became dark (dark grays, browns, and blacks), like some fossils. Fossil ostracodes from boreholes in Mesozoic and Cenozoic sedimentary rocks showed downhole color differences similar to those from experiments. That is, the colors of fossils are different in hue, value and chroma in different thermal zones and ostracode color appears to be broadly indicative of thermal history.Fossils near igneous intrusions are dark, while the lowered values and chromas of those in metamorphics also are correlatable with paleotemperatures. Reheated dark fossils lightened at about 375-450°, eventually becoming pale yellow to white, apparently indicating that organic coloring agents were driven off. This, and the fact that modern ostracodes develop dark colors only when heated in organic-rich substances, support the contention that the dark color originates from extrinsic organic materials. Pyritized shells become weak red (Munsell 10R 4/4) upon heating; thus, they can be distinguised from those colored by organics.Therefore, ostracode colors appear to be diagnostic of T-P and present the potential for use in paleotemperature reconstructions. A wide range of fossils, including conodonts, phosphatic brachiopods, scolecodonts, and palynomorphs are known to show recognizable and useful evidence of thermal maturation and it is proposed that ostracodes be added to the list.

Author(s):  
Ernest L. Hall ◽  
J. B. Vander Sande

The present paper describes research on the mechanical properties and related dislocation structure of CdTe, a II-VI semiconductor compound with a wide range of uses in electrical and optical devices. At room temperature CdTe exhibits little plasticity and at the same time relatively low strength and hardness. The mechanical behavior of CdTe was examined at elevated temperatures with the goal of understanding plastic flow in this material and eventually improving the room temperature properties. Several samples of single crystal CdTe of identical size and crystallographic orientation were deformed in compression at 300°C to various levels of total strain. A resolved shear stress vs. compressive glide strain curve (Figure la) was derived from the results of the tests and the knowledge of the sample orientation.


Alloy Digest ◽  
1975 ◽  
Vol 24 (5) ◽  

Abstract USS TENELON is a completely austenitic, nickel-free stainless steel with exceptionally high strength which is retained at elevated temperatures. It has excellent corrosion resistance in atmospheric and mild acid exposures and maintains nonmagnetic characteristics even when 60% cold reduced. It also has good stress-rupture and creep properties in the range 1200-1500 F. It has a wide range of applications. This datasheet provides information on composition, physical properties, elasticity, and tensile properties as well as fracture toughness, creep, and fatigue. It also includes information on high temperature performance and corrosion resistance as well as forming, heat treating, machining, joining, and surface treatment. Filing Code: SS-311. Producer or source: United States Steel Corporation.


2009 ◽  
Vol 1199 ◽  
Author(s):  
Ricardo Martinez ◽  
Ashok Kumar ◽  
Ratnakar Palai ◽  
Ram S. Katiyar

AbstractAsymmetric superlattices (SLs) with ferromagnetic La0.7Sr0.3MnO3 (LSMO) and ferroelectric Ba0.7Sr0.3TiO3 (BST) as constitutive layers were fabricated on conducting LaNiO3 (LNO) coated (001) oriented MgO substrates using pulsed laser deposition (PLD). The crystallinity, ferroelectric and magnetic properties of the SLs were studied over a wide range of temperatures and frequencies. The structure exhibited ferromagnetic behavior at 300K, and ferroelectric behavior over a range of temperatures between 100K and 300K. The dielectric response as a function of frequency obeys normal behavior below 300 K, whereas it follows Maxwell–Wagner model at elevated temperatures. The effect of ferromagnetic LSMO layers on ferroelectric properties of the SL indicated strong influence of the interfaces. The asymmetric behavior of ferroelectric loop and the capacitance-voltage relationship suggest development of a built field in the SLs due to high strain across the interfaces.


2014 ◽  
Vol 2014 ◽  
pp. 1-13 ◽  
Author(s):  
John B. Lowe ◽  
Richard T. Baker

Ordered mesoporous silica materials are of interest for a wide range of applications. In many of these, elevated temperatures are used either in the preparation of the material or during its use. Therefore, an understanding of the effect of high temperature treatments on these materials is desirable. In this work, a detailed structural study is performed on silicas with three representative pore structures: a 2-D hexagonal pore arrangement (SBA-15), a continuous 3D cubic bimodal pore structure (KIT-6), and a 3D large cage pore structure (FDU-12). Each silica is studied as prepared and after treatment at a series of temperatures between 300 and 900°C. Pore structures are imaged using Transmission Electron Microscopy. This technique is used in conjunction with Small-Angle X-ray Diffraction, gas physisorption, and29Si solid state Nuclear Magnetic Resonance. Using these techniques, the pore size distributions, the unit cell dimensions of the mesoporous structures, and the relative occupancy of the distinct chemical environments of Si within them are cross correlated for the three silicas and their evolution with treatment temperature is elucidated. The physical and chemical properties before, during, and after collapse of these structures at high temperatures are described as are the differences in behavior between the three silica structures.


2021 ◽  
Author(s):  
KHATEREH KASHMARI ◽  
PRATHAMESH DESHPANDE ◽  
SAGAR PATIL ◽  
SAGAR SHAH ◽  
MARIANNA MAIARU ◽  
...  

Polymer Matrix Composites (PMCs) have been the subject of many recent studies due to their outstanding characteristics. For the processing of PMCs, a wide range of elevated temperatures is typically applied to the material, leading to the development of internal residual stresses during the final cool-down step. These residual stresses may lead to net shape deformations or internal damage. Also, volumetric shrinkage, and thus additional residual stresses, could be created during crystallization of the semi-crystalline thermoplastic matrix. Furthermore, the thermomechanical properties of semi-crystalline polymers are susceptible to the crystallinity content, which is tightly controlled by the processing parameters (processing temperature, temperature holding time) and material properties (melting and crystallization temperatures). Hence, it is vital to have a precise understanding of crystallization kinetics and its impact on the final component's performance to accurately predict induced residual stresses during the processing of these materials. To enable multi-scale process modeling of thermoplastic composites, molecular-level material properties must be determined for a wide range of crystallinity levels. In this study, the thermomechanical properties and volumetric shrinkage of the thermoplastic Poly Ether Ether Ketone (PEEK) resin are predicted as a function of crystallinity content and temperature using molecular dynamics (MD) modeling. Using crystallization-kinetics models, the thermo-mechanical properties are directly related to processing time and temperature. This research can ultimately predict the residual stress evolution in PEEK composites as a function of processing parameters.


2011 ◽  
Vol 275 ◽  
pp. 204-207 ◽  
Author(s):  
Lenka Fusova ◽  
Pawel Rokicki ◽  
Zdeněk Spotz ◽  
Karel Saksl ◽  
Carsten Siemers

Nickel-base superalloys like Alloy 625 are widely used in power generation applications due to their unique properties especially at elevated temperatures. During the related component manufacturing for gas turbines up to 50% of the material has to be removed by metal cutting operations like milling, turning or drilling. As a result of high strength and toughness the machinability of Alloy 625 is generally poor and only low cutting speeds can be used. High-speed cutting of Alloy 625 on the other hand gets more important in industry to reduce manufacturing times and thus production costs. The cutting speed represents one of the most important factors that have influences on the tool life. The aim of this study is the analyses of wear mechanisms occurring during machining of Alloy 625. Orthogonal cutting experiments have been performed and different process parameters have been varied in a wide range. New and worn tools have been investigated by stereo microscopy, optical microscopy and scanning electron microscopy. Energy-dispersive X-ray analyses were used for the investigation of chemical compositions of the tool's surface as well as the nature of reaction products formed during the cutting process. Wear mechanisms observed in the machining experiments included abrasion, fracture and tribochemical effects. Specific wear features appeared depending on the mechanical and thermal conditions generated in the wear zones.


Chemosensors ◽  
2021 ◽  
Vol 9 (11) ◽  
pp. 317
Author(s):  
Zachary Brounstein ◽  
Jarrod Ronquillo ◽  
Andrea Labouriau

Eight chromophoric indicators are incorporated into Sylgard 184 to develop sensors that are fabricated either by traditional methods such as casting or by more advanced manufacturing techniques such as 3D printing. The sensors exhibit specific color changes when exposed to acidic species, basic species, or elevated temperatures. Additionally, material properties are investigated to assess the chemical structure, Shore A Hardness, and thermal stability. Comparisons between the casted and 3D printed sensors show that the sensing devices fabricated with the advanced manufacturing technique are more efficient because the color changes are more easily detected.


Materials ◽  
2021 ◽  
Vol 14 (22) ◽  
pp. 6751
Author(s):  
Konrad A. Sodol ◽  
Łukasz Kaczmarek ◽  
Jacek Szer ◽  
Sebastian Miszczak ◽  
Mariusz Stegliński

This article is motivated by civil fire safety. Fire-prevention engineering demands a wide range of information about building materials including alternative cements, for instance CSA-cement. Because of exposure of the cement-base material to a high temperature, its strength properties deteriorate due to dehydration connected with phase and microstructure changes. Previous research indicated that the main endothermic reaction of CSA-based composite, dehydration of ettringite, might be used as a cooling system for a metal structure during fire-load. This article examines visual assessment, microstructure, density, as well as flexural and compressive strength parameters of CSA-based composite after isothermal heating at temperatures from 23 °C to 800 °C. The results of SEM/EDS investigations showed that the calcium sulfoaluminate paste may start partially re-sintering above 600 °C. Mechanical tests revealed significant reduction of strength parameters but residual compressive strength was maintained in the whole temperature range e.g., 8 MPa at 800 °C. Additionally, visual assessment of the specimens indicated that it might be possible to predict the material temperature heating based on the specific surface color. These findings add to the evidence of general knowledge about CSA hydrates.


2020 ◽  
Author(s):  
Bassil El-Zaatari ◽  
Jacob Ishibashi ◽  
Julia Kalow

<div><p>Vitrimers are a class of covalent adaptable networks (CANs) that undergo topology reconfiguration via associative exchange reactions, enabling reprocessing at elevated temperatures. Here, we show that cross-linker reactivity represents an additional design parameter to tune stress relaxation rates in vitrimers. Guided by calculated activation barriers, we prepared a series of cross-linkers with varying reactivity for the conjugate addition—elimination of thiols in a PDMS vitrimer. Surprisingly, despite a wide range of stress relaxation rates, we observe that the flow activation energy of the bulk material is independent of the cross-linker structure. Superposition of storage and loss moduli from frequency sweeps can be performed for different cross-linkers, indicating the same exchange mechanism. We show that we can mix different cross-linkers in a single material in order to further modulate the stress relaxation behavior.</p></div>


Author(s):  
A Erdemir

Detailed tribological studies on diamond and diamond-like carbon (DLC) films have confirmed that these films are inherently self-lubricating and resistant to abrasive, adhesive and corrosive wear. Because of their high chemical inertness, they are also resistant to corrosion and oxidation (even at elevated temperatures). The combination of such exceptional qualities in these films makes them ideal for a wide range of demanding tribological applications (such as microelectromechanical systems, cutting tools, mechanical seals, magnetic hard disks, etc.). These films, available for more than three decades, have been used extensively for tooling and magnetic hard disk applications. Their potential in other application areas is currently being explored around the world. With the development of new and more robust deposition methods in recent years, it is envisioned that the production of high quality diamond and DLC films will become very cost effective and highly reliable for large-scale applications in the transportation and manufacturing sectors. In this paper, sliding wear mechanisms of diamond and DLC films will be presented. Specifically, it will be shown that, in general, the wear of these films is extremely low (mainly because of their exceptional hardness and low friction characteristics). Specific test conditions established during each sliding test, however, may dramatically affect the wear performance of certain diamond and DLC films. One of the dominant wear mechanisms relates to a phase transformation that is primarily the result of very high mechanical and thermal loadings of sliding contact interfaces. The transformation products (such as disordered graphite) trapped at the sliding interface may transfer to the mating surface and significantly affect friction and wear. This paper describes, in terms of structural and fundamental tribological knowledge, the ideal film microstructures and chemistry, as well as operational conditions under which diamond and DLC films perform the best and provide superlow friction and wear properties in sliding tribological applications.


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