scholarly journals Synthesis of copolyesters with bio-based lauric diacid: structure and physico-mechanical studies

RSC Advances ◽  
2017 ◽  
Vol 7 (87) ◽  
pp. 55418-55426 ◽  
Author(s):  
Meiling Chen ◽  
Nesren A. H. Saada ◽  
Fei Liu ◽  
Haining Na ◽  
Jin Zhu

Copolyesters developed from bio-based long-chain dicarboxylic acid show promising mechanical properties that are helpful for their application as biodegradable materials.

2014 ◽  
Vol 52 (11) ◽  
pp. 949-956
Author(s):  
Hyunkyu Lim ◽  
Wonseok Yang ◽  
Young-Gil Jung ◽  
Shae K. Kim ◽  
Do-Hyang Kim

2020 ◽  
Vol 67 (2) ◽  
pp. 115-120
Author(s):  
Raisa A. Alekhina ◽  
Victoriya E. Slavkina ◽  
Yuliya A. Lopatina

The article presents options for recycling polymers. The use of biodegradable materials is promising. This is a special class of polymers that can decompose under aerobic or anaerobic conditions under the action of microorganisms or enzymes forming natural products such as carbon dioxide, nitrogen, water, biomass, and inorganic salts. (Research purpose) The research purpose is in reviewing biodegradable materials that can be used for the manufacture of products used in agriculture. (Materials and methods) The study are based on open information sources containing information about biodegradable materials. Research methods are collecting, studying and comparative analysis of information. (Results and discussion) The article presents the advantages and disadvantages of biodegradable materials, mechanical properties of the main groups of biodegradable polymers. The article provides a summary list of agricultural products that can be made from biodegradable polymer materials. It was found that products from the general group are widely used in agriculture. Authors have found that products from a special group can only be made from biodegradable polymers with a controlled decomposition period in the soil, their use contributes to increasing the productivity of crops. (Conclusions) It was found that biodegradable polymer materials, along with environmental safety, have mechanical properties that allow them producing products that do not carry significant loads during operation. We have shown that the creation of responsible products (machine parts) from biodegradable polymers requires an increase in their strength properties, which is achievable by creating composites based on them. It was found that the technological complexity of their manufacture and high cost are the limiting factors for the widespread use of biodegradable polymers at this stage.


Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1137
Author(s):  
Sascha Stanic ◽  
Thomas Koch ◽  
Klaus Schmid ◽  
Simone Knaus ◽  
Vasiliki-Maria Archodoulaki

Blends of two long-chain branched polypropylenes (LCB-PP) and five linear polypropylenes (L-PP) were prepared in a single screw extruder at 240 °C. The two LCB-PPs were self-created via reactive extrusion at 180 °C by using dimyristyl peroxydicarbonate (PODIC C126) and dilauroyl peroxide (LP) as peroxides. For blending two virgin and three recycled PPs like coffee caps, yoghurt cups and buckets with different melt flow rate (MFR) values were used. The influence of using blends was assessed by investigating the rheological (dynamic and extensional rheology) and mechanical properties (tensile test and impact tensile test). The dynamic rheology indicated that the molecular weight as well as the molecular weight distribution could be increased or broadened. Also the melt strength behavior could be improved by using the two peroxide modified LCB-PP blends on the basis of PODIC C126 or PEROXAN LP (dilauroyl peroxide). In addition, the mechanical properties were consistently enhanced or at least kept constant compared to the original material. In particular, the impact tensile strength but also the elongation at break could be increased considerably. This study showed that the blending of LCB-PP can increase the investigated properties and represents a promising option, especially when using recycled PP, which demonstrates a real “up-cycling” process.


Metabolites ◽  
2018 ◽  
Vol 8 (4) ◽  
pp. 91 ◽  
Author(s):  
Paul Wood ◽  
Michelle Donohue ◽  
John Cebak ◽  
Taylor Beckmann ◽  
Márcia Messias ◽  
...  

Background: There are currently no blood-based biomarkers for early diagnosis of colorectal cancer. Previous research has suggested that very-long-chain dicarboxylic acid (VLCDCA) 28:4 might be such a biomarker. Methods: Using high-resolution mass spectrometry, we analyzed VLCDCA 28:4 in the plasma of colorectal cancer patients in Italian [n = 62] and Brazilian [n = 52] cohorts. Additionally, we investigated individuals diagnosed with familial adenomatous polyposis (FAP; n = 27), one of the most important clinical forms of inherited susceptibility to colorectal cancer. Results: Decrements in plasma levels of VLCDCA 28:4 were monitored in colorectal cancer patients. These decreases were independent of the stage of tumor development and the individual’s age. However, no decrements in VLCDCA 28:4 were monitored in FAP patients. Conclusions: The plasma levels of VLCDCA 28:4 represent a potential biomarker of sporadic colorectal cancer. In addition, it is possible that resupply of this anti-inflammatory lipid may represent a new therapeutic strategy for CRC and inflammatory disorders.


Author(s):  
Galina S. Bozhenkova ◽  
Alexandra N. Tarakanovskaya ◽  
Oksana D. Tarnovskaya ◽  
Roman V. Ashirov

The article is devoted to the production of polymer by metathesis ring-opening polymerization under the influence of ruthenium initiator of type of Hoveyda-Grubbs II generation. The monomer used the mixture of dimethyl ether norbornene-2;3-dicarboxylic acid. The monomer was prepared by the Diels-Alder reaction of dicyclopentadiene and dimethyl maleate. The polymer was prepared in bulk of the monomer mixture. In this paper we have studied the physical and mechanical properties polydimethyl ether of norbornene-2;3-dicarboxylic acid; and assessed the impact of environmental factors on the change in properties of the polymer. As environmental factors; light; UV radiation; water; 0.1 M hydrochloric acid were applied; and accelerated aging conditions; which were held in a climate chamber. During performance we found that maintaining the polymer samples in the UV light chamber led to the slight increase in flexural modulus. In contrast; the polymer storage in water and in a hydrochloric acid solution for two months resulted in a slight decrease in the modulus of elasticity in bending index. These factors did not affect the change in the glass transition temperature of the polymer. Under the conditions of accelerated aging conducted for 1; 2 and 6 days after two cycles we observed the drop in modulus for bending of 8.5%; after 6 cycles of 13%. The glass transition temperature of polydimethyl ether of norbornene-2;3-dicarboxylic acid after 6 cycles decreased by only 3.4% in the climatic chamber. Studies have shown that the resulting polymer is resistant to water; hydrochloric acid; light and UV radiation; as well as it saves properties at a sufficient level for operation at conditions of accelerated aging. It should be noted that the tested polymer was prepared without additives; stabilizers and antioxidants. The proposed polymer can be used as a structural material for machine parts; including bulky.For citation:Bozhenkova G.S.; Tarakanovskaya A.N.; Tarnovskaya O.D.; Ashirov R.V. Influence of environmental factors on physical-mechanical properties of polydimethyl ether of norborene -2;3-dicarboxylic acid. Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol. 2017. V. 60. N 5. P. 68-73


2020 ◽  
Vol 49 (31) ◽  
pp. 10832-10838
Author(s):  
Janne-Petteri Niemelä ◽  
Nadia Rohbeck ◽  
Johann Michler ◽  
Ivo Utke

We tailor mechanical properties of molecular-layer-deposited inorganic–organic films through control over the organic precursor length, relevant for battery applications.


MRS Advances ◽  
2018 ◽  
Vol 3 (40) ◽  
pp. 2359-2364 ◽  
Author(s):  
Chaoxing Zhang ◽  
Jiajia Lin ◽  
Huinan Liu

ABSTRACTMagnesium (Mg)-based biomaterials have attracted increasing attention in biomedical applications, such as orthopaedic, cardiovascular, urological, and neural applications because of the biocompatibility, biodegradability, antibacterial properties, and excellent mechanical properties. However, rapid degradation of Mg is the major concern for many clinical applications. Alloying Mg with other elements and engineering proper surfaces are the two approaches to control the degradation of Mg-based biomaterials. Our lab has investigated several classes of Mg-based biodegradable alloys and various surface treatment methods for medical implant and device applications. This mini-review highlights key research progress on Mg-based biomaterials and suggests future directions for Mg-based biomaterials.


2000 ◽  
Vol 22 (5) ◽  
pp. 391-396 ◽  
Author(s):  
R. Lin ◽  
Z. Cao ◽  
T. Zhu ◽  
Z. Zhang

1989 ◽  
Vol 35 (11) ◽  
pp. 1031-1036 ◽  
Author(s):  
Malcolm C. Modrzakowski ◽  
William R. Finnerty

The microbial dissimilation of long-chain dialkyl ethers by Acinetobacter sp. H01-N involved a terminal methyl group oxidation of the dialkyl ether substrates, resulting in the formation of ether oxygen containing fatty acids of corresponding chain length. An internal carbon–carbon scission of the dialkyl ethers resulted in the formation of end-product ether fatty acids and corresponding dicarboxylic acids. Cellular carbon and energy were derived from the subsequent metabolism of the dicarboxylic acids. Dicarboxylic acid oxidation, activation, and identification of cellular dicarboxylic acids indicated dibasic acids as intermediates in the metabolism of dialkyl ethers.Key words: dialkyl ethers, dicarboxylic acids, fatty acids, Acinetobacter.


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