scholarly journals Nanoscale chemical imaging by photoinduced force microscopy

2016 ◽  
Vol 2 (3) ◽  
pp. e1501571 ◽  
Author(s):  
Derek Nowak ◽  
William Morrison ◽  
H. Kumar Wickramasinghe ◽  
Junghoon Jahng ◽  
Eric Potma ◽  
...  
Keyword(s):  
Self Assembly ◽  
Low Cost ◽  
Near Field ◽  
Chemical Species ◽  
Real Space ◽  
Chemical Imaging ◽  
Chemical Components ◽  
Chemical Information ◽  
Force Microscopy ◽  
The Individual

Correlating spatial chemical information with the morphology of closely packed nanostructures remains a challenge for the scientific community. For example, supramolecular self-assembly, which provides a powerful and low-cost way to create nanoscale patterns and engineered nanostructures, is not easily interrogated in real space via existing nondestructive techniques based on optics or electrons. A novel scanning probe technique called infrared photoinduced force microscopy (IR PiFM) directly measures the photoinduced polarizability of the sample in the near field by detecting the time-integrated force between the tip and the sample. By imaging at multiple IR wavelengths corresponding to absorption peaks of different chemical species, PiFM has demonstrated the ability to spatially map nm-scale patterns of the individual chemical components of two different types of self-assembled block copolymer films. With chemical-specific nanometer-scale imaging, PiFM provides a powerful new analytical method for deepening our understanding of nanomaterials.

Chemical Imaging With a Scanning Probe Microscope

1999 ◽  
Vol 5 (S2) ◽  
pp. 970-971
Author(s):  
Dmitri A. Kossakovski ◽  
John D. Baldeschwieler ◽  
J. L. Beauchamp
Keyword(s):  
Beam Quality ◽  
Near Field ◽  
Ambient Air ◽  
Chemical Imaging ◽  
Scanning Probe ◽  
Scanning Tunneling ◽  
Visible Range ◽  
Spectrometric Analysis ◽  
Chemical Information ◽  
Near Field Scanning

Scanning Probe Microscopy (SPM) is a superb tool for topographical analysis of samples. However, traditional varieties of SPM such as Atomic Force, Scanning Tunneling and Near-field Scanning Optical Microscopy have limited chemical contrast capability. Recently, several advanced techniques have been reported which provide chemical information in addition to topographical data. All these methods derive advantage from combinations of scanning probe methodologies and some other, chemically sensitive technique. Examples of such approaches are: Near-field Scanning Raman Imaging, Near-field Scanning Infrared Microscopy and mass spectrometric analysis with laser ablation through fiber probes.In this contribution we report the development of a new method in this family of chemically sensitive scanning probe techniques: Laser Induced Breakdown Spectroscopy with Shear Force Microscopy, LIBS-SFM. Traditional LIBS experiments involve focusing a pulsed laser beam onto the sample and observing optical emission from the plasma formed in the ablation area. The emissions are mostly in the UV/visible range, and the signal is due to electronic transitions in excited atoms and ions in the plasma plume. The spectra are analyzed to identify chemical elements. The spatial resolution of LIBS is limited by the wavelength and beam quality of the laser used for ablation. The experiments may be conducted in vacuum, controlled atmosphere, or ambient air.

scholarly journals Enhanced Physical Absorption Properties of ZnO Nanorods by Electrostatic Self-Assembly with Reduced Graphene Oxide and Decorated with Silver and Copper Nanoparticles

2021 ◽  
Vol 19 (48) ◽  
pp. 66-78
Author(s):  
Lina Zeki Yahiya ◽  
Mohamed K. Dhahir
Keyword(s):  
Self Assembly ◽  
Low Cost ◽  
Zno Nanorods ◽  
Zinc Oxide Nanorods ◽  
Environmental Friendliness ◽  
Force Microscopy ◽  
Atomic Force ◽  
Transmission Electron ◽  
Oxide Nanorods ◽  
Scale Preparation

The preparation and characterization of innovative nanocomposites based on zinc oxide nanorods (ZNR) encapsulated by graphene (Gr) nanosheets and decorated with silver (Ag), and cupper (Cu) nanoparticles (NP) were studied. The prepared nanocomposites (ZNR@Gr/Cu-Ag) were examined by different techniques including Field Emission Scanning Electron Microscope (FESEM), Transmission electron microscopy (TEM), Atomic force microscopy (AFM), UV-Vis spectrophotometer and fluorescence spectroscopy. The results showed that the ZNR has been good cover by five layers of graphene and decorated with Ag and Cu NPs with particles size of about 10-15 nm. The ZNR@Gr/Cu-Ag nanocomposites exhibit high absorption behavior in ultraviolet (UV) region of spectrum. In comparison with ZNR, the ZNR@Gr/Cu-Ag nanocomposites reveal superior absorption in the entire region of 387–1000 nm. Moreover, the band gap decreases from 3.2 eV of ZNR to 1.2 eV for ZNR@Gr/Cu-Ag nanocomposites. Taking into account the superiority of ZNR@Gr/Cu-Ag nanocomposites in terms of easy fabrication, low cost method, and environmental friendliness which made it favorable for huge-scale preparation in many applications such as water splitting, sensor, solar cell, antibacterial and optoelectronic devices.

Confocal Raman Line-Scanned Imaging of Complex Geological and Histological Thin Sections

1997 ◽  
Vol 3 (S2) ◽  
pp. 817-818
Author(s):  
Fran Adar ◽  
Roussel Bernard ◽  
Alian Wang ◽  
Shari Hawi ◽  
Kasem Nithipathikom
Keyword(s):  
Spatial Resolution ◽  
Optical Radiation ◽  
Raman Band ◽  
Near Field ◽  
Chemical Species ◽  
Chemical Imaging ◽  
Large Area ◽  
Thin Sections ◽  
Chemical Image ◽  
Better Than

Chemical imaging of complex multi-component materials has important potential for the analyst in many fields of research. Raman imaging is of particular interest for several reasons. The Raman spectra contain detailed information on chemical species and crystalline phase. Because the Raman effect is excited by optical radiation, the spatial resolution, which is proportional to the wavelength of the light, is better than 1 μm. and with near field optical techniques currently under development, there is potential for even higher spatial resolution in the chemical image.The methods used to produce an image fall into essentially two categories - global imaging and confocal mapping. When creating global images, a large area of the sample is bathed in laser light. The light scattered by the sample is filtered to select a Raman band, and then that light is used to create an image of the sample on a two-dimensional detector.

scholarly journals Self-Assembly in Polyoxometalate and Metal Coordination-Based Systems: Synthetic Approaches and Developments

Inorganics ◽  
2018 ◽  
Vol 6 (3) ◽  
pp. 71 ◽  
Author(s):  
Stamatis Passadis ◽  
Themistoklis Kabanos ◽  
Yu-Fei Song ◽  
Haralampos Miras
Keyword(s):  
Self Assembly ◽  
Structural Characteristics ◽  
Chemical Components ◽  
Organic Chemical ◽  
Chemical Information ◽  
Design Element ◽  
Chemical Systems ◽  
Wide Range ◽  
Metal Organic ◽  
Synthetic Approaches

Utilizing new experimental approaches and gradual understanding of the underlying chemical processes has led to advances in the self-assembly of inorganic and metal–organic compounds at a very fast pace over the last decades. Exploitation of unveiled information originating from initial experimental observations has sparked the development of new families of compounds with unique structural characteristics and functionalities. The main source of inspiration for numerous research groups originated from the implementation of the design element along with the discovery of new chemical components which can self-assemble into complex structures with wide range of sizes, topologies and functionalities. Not only do self-assembled inorganic and metal–organic chemical systems belong to families of compounds with configurable structures, but also have a vast array of physical properties which reflect the chemical information stored in the various “modular” molecular subunits. The purpose of this short review article is not the exhaustive discussion of the broad field of inorganic and metal–organic chemical systems, but the discussion of some representative examples from each category which demonstrate the implementation of new synthetic approaches and design principles.

Characterizing Interlayer Sub-μm Features in Microelectronics Devices Using High-Resolution Scanning Probe-IR Spectroscopy and Imaging

2018 ◽  
Author(s):  
Anirban Roy ◽  
Qichi Hu ◽  
Honghua Yang ◽  
Peter De wolf ◽  
Sean W. King
Keyword(s):  
High Resolution ◽  
Cross Sections ◽  
Self Assembly ◽  
Organic Contaminants ◽  
Near Field ◽  
Electrical Characterization ◽  
Scanning Probe ◽  
Light Sources ◽  
Force Microscopy ◽  
Microscopy Techniques

Abstract High resolution scanning probe microscopy techniques combined with infrared (IR) light sources offer unique solutions to combined chemical/mechanical/electrical characterization of defects in nanoscale dimensions. Previously, atomic force microscopy combined with infrared (AFM-IR) technology has demonstrated its capability to characterize nano-patterned metal/low-k dielectrics, nanoscale organic contaminants, and directed self-assembly of block co-polymers used for advanced micro/nanofabrications. In this paper, two complementary nanoscale chemical analysis techniques, photothermal AFM-IR and scattering type scanning near-field optical microscopy, are implemented to isolate and characterize microelectronic device cross-sections. It is observed that both techniques are able to detect patterned features with a half-pitch less than 15 nm.

scholarly journals In-situ twistable bilayer graphene

2022 ◽  
Vol 12 (1) ◽  
Author(s):  
Cheng Hu ◽  
Tongyao Wu ◽  
Xinyue Huang ◽  
Yulong Dong ◽  
Jiajun Chen ◽  
...  
Keyword(s):  
Domain Walls ◽  
Near Field ◽  
Twist Angle ◽  
Bilayer Graphene ◽  
Real Space ◽  
Systematic Investigation ◽  
Force Microscopy ◽  
Atomic Force ◽  
Resonant Raman

AbstractThe electrical and optical properties of twisted bilayer graphene (tBLG) depend sensitively on the twist angle. To study the angle dependent properties of the tBLG, currently it is required fabrication of a large number of samples with systematically varied twist angles. Here, we demonstrate the construction of in-situ twistable bilayer graphene, in which the twist angle of the two graphene monolayers can be in-situ tuned continuously in a large range with high precision. The controlled tuning of the twist angle is confirmed by a combination of real-space and spectroscopic characterizations, including atomic force microscopy (AFM) identification of crystal lattice orientation, scanning near-field optical microscopy (SNOM) imaging of superlattice domain walls, and resonant Raman spectroscopy of the largely enhanced G-mode. The developed in-situ twistable homostructure devices enable systematic investigation of the twist angle effects in a single device, thus could largely advance the research of twistronics.

Development of the UHV-STM

1990 ◽  
Vol 48 (1) ◽  
pp. 322-323
Author(s):  
M. Iwatsuki ◽  
S. Kitamura ◽  
A. Mogami
Keyword(s):  
Surface Science ◽  
Real Space ◽  
Atomic Scale ◽  
Scanning Tunneling ◽  
Great Promise ◽  
Force Microscopy ◽  
Atomic Force ◽  
Stm Image ◽  
Surface Construction ◽  
Very High

Since Binnig, Rohrer and associates observed real-space topographic images of Si(111)-7×7 and invented the scanning tunneling microscope (STM),1) the STM has been accepted as a powerful surface science instrument.Recently, many application areas for the STM have been opened up, such as atomic force microscopy (AFM), magnetic force microscopy (MFM) and others. So, the STM technology holds a great promise for the future.The great advantages of the STM are its high spatial resolution in the lateral and vertical directions on the atomic scale. However, the STM has difficulty in identifying atomic images in a desired area because it uses piezoelectric (PZT) elements as a scanner.On the other hand, the demand to observe specimens under UHV condition has grown, along with the advent of the STM technology. The requirment of UHV-STM is especially very high in to study of surface construction of semiconductors and superconducting materials on the atomic scale. In order to improve the STM image quality by keeping the specimen and tip surfaces clean, we have built a new UHV-STM (JSTM-4000XV) system which is provided with other surface analysis capability.

Clathrin-Inspired Coating and Stabilization of Liposomes by DNA Self-Assembly

2019 ◽  
Author(s):  
Kevin N. Baumann ◽  
Luca Piantanida ◽  
Javier García-Nafría ◽  
Diana Sobota ◽  
Kislon Voïtchovsky ◽  
...  
Keyword(s):  
Self Assembly ◽  
Mechanical Stability ◽  
Lipid Vesicles ◽  
The Self ◽  
Force Microscopy ◽  
Atomic Force ◽  
Cryo Electron Microscopy ◽  
Further Development ◽  
Liposome Surface ◽  
Dna Coating

The self-assembly of the protein clathrin on biological membranes facilitates essential processes of endocytosis in biological systems and has provided a source of inspiration for materials design by the highly ordered structural appearance. By mimicking the architecture of clathrin self-assemblies to coat liposomes with biomaterials, new classes of hybrid carriers can be derived. Here we present a method for fabricating DNA-coated liposomes by hydrophobically anchoring and subsequently growing a DNA network on the liposome surface which structurally mimics clathrin assemblies. Dynamic light scattering (DLS), ζ-potential and cryo-electron microscopy (cryo-EM) measurements independently demonstrate successful DNA coating. Nanomechanical measurements conducted with atomic force microscopy (AFM) show that the DNA coating enhances the mechanical stability of the liposomes relative to uncoated ones. Furthermore, we provide the possibility to reverse the coating process by triggering the disassembly of the DNA coating through a toehold-mediated displacement reaction. Our results describe a straightforward, versatile, and reversible approach for coating and stabilizing lipid vesicles by an interlaced DNA network. This method has potential for further development towards the ordered arrangement of tailored functionalities on the surfaces of liposomes and for applications as hybrid nanocarrier.

Generalized Heterodyne Configurations for Photo-induced Force Microscopy

2019 ◽  
Author(s):  
Le Wang ◽  
Devon Jakob ◽  
Haomin Wang ◽  
Alexis Apostolos ◽  
Marcos M. Pires ◽  
...  
Keyword(s):  
Spatial Resolution ◽  
Repetition Rate ◽  
Modulation Frequency ◽  
High Harmonic ◽  
Chemical Imaging ◽  
Heterodyne Detection ◽  
Force Microscopy ◽  
Wide Range ◽  
The Difference ◽  
Afm Cantilever

<div>Infrared chemical microscopy through mechanical probing of light-matter interactions by atomic force microscopy (AFM) bypasses the diffraction limit. One increasingly popular technique is photo-induced force microscopy (PiFM), which utilizes the mechanical heterodyne signal detection between cantilever mechanical resonant oscillations and the photo induced force from light-matter interaction. So far, photo induced force microscopy has been operated in only one heterodyne configuration. In this article, we generalize heterodyne configurations of photoinduced force microscopy by introducing two new schemes: harmonic heterodyne detection and sequential heterodyne detection. In harmonic heterodyne detection, the laser repetition rate matches integer fractions of the difference between the two mechanical resonant modes of the AFM cantilever. The high harmonic of the beating from the photothermal expansion mixes with the AFM cantilever oscillation to provide PiFM signal. In sequential heterodyne detection, the combination of the repetition rate of laser pulses and polarization modulation frequency matches the difference between two AFM mechanical modes, leading to detectable PiFM signals. These two generalized heterodyne configurations for photo induced force microscopy deliver new avenues for chemical imaging and broadband spectroscopy at ~10 nm spatial resolution. They are suitable for a wide range of heterogeneous materials across various disciplines: from structured polymer film, polaritonic boron nitride materials, to isolated bacterial peptidoglycan cell walls. The generalized heterodyne configurations introduce flexibility for the implementation of PiFM and related tapping mode AFM-IR, and provide possibilities for additional modulation channel in PiFM for targeted signal extraction with nanoscale spatial resolution.</div>

scholarly journals Photocatalytic reduction of graphene oxide with cuprous oxide film under UV-vis irradiation

2020 ◽  
Vol 59 (1) ◽  
pp. 207-214 ◽  
Author(s):  
Yao Wang ◽  
Jianqing Feng ◽  
Lihua Jin ◽  
Chengshan Li
Keyword(s):  
Graphene Oxide ◽  
Photoelectron Spectroscopy ◽  
Low Cost ◽  
Photocatalytic Reduction ◽  
Force Microscopy ◽  
Atomic Force ◽  
Reduced Graphene ◽  
Reduction Efficiency ◽  
Metal Organic ◽  
Reduction Effect

AbstractWe have grown Cu2O films by different routes including self-oxidation and metal-organic deposition (MOD). The reduction efficiency of Cu2O films on graphene oxide (GO) synthesized by modified Hummer’s method has been studied. Surface morphology and chemical state of as-prepared Cu2O film and GO sheets reduced at different conditions have also been investigated using atomic force microscopy (AFM) and x-ray photoelectron spectroscopy (XPS). Results show that self-oxidation Cu2O film is more effective on phtocatalytic reduction of GO than MOD-Cu2O film. Moreover, reduction effect of self-oxidation Cu2O film to GO is comparable to that of environmental-friendly reducing agent of vitamin C. The present results offer a potentially eco-friendly and low-cost approach for the manufacture of reduced graphene oxide (RGO) by photocatalytic reduction.

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