Measurement of interfacial area and intensity of mass transfer in the gas phase in a packing with significant dependence of the interfacial area on the density of irrigation

1984 ◽  
Vol 49 (11) ◽  
pp. 2463-2477
Author(s):  
Jan Červenka ◽  
Zdeněk Brož ◽  
Václav Kolář
Keyword(s):  
Sodium Hydroxide ◽  
Flow Rate ◽  
Strong Dependence ◽  
Interfacial Area ◽  
Cocurrent Flow ◽  
Pseudo First Order Reaction ◽  
First Order ◽  
Expanded Metal ◽  
Side Resistance ◽  
Density Of Irrigation

The dependence has been measured of the interfacial area and the number of transfer units for gas side resistance controlled absorption on the flow rate of gas and liquid at counter- and cocurrent flow arrangement. The measurements have been carried out for a vertical expanded metal sheet packing exhibiting a strong dependence of the interfacial area on the density of irrigation. The interfacial area has been measured by absorption of carbon dioxide into a solution of sodium hydroxide under the conditions of the pseudo first order reaction. The number of transfer units has been measured by absorption of sulphur dioxide also into a solution of sodium hydroxide. In addition, the pressure drop has been correlated against the flow rate of gas and liquid.

The gas side mass transfer coefficient in the turbulent flow in a packing with a significant dependence of the interfacial area on the density of irrigation

1984 ◽  
Vol 49 (12) ◽  
pp. 2756-2762
Author(s):  
Jan Červenka ◽  
Václav Kolář
Keyword(s):  
Mass Transfer ◽  
Transfer Coefficient ◽  
Mass Transfer Coefficient ◽  
Gas Flow ◽  
Interfacial Area ◽  
Two Phase ◽  
Expanded Metal ◽  
Significant Dependence ◽  
Experimental Values ◽  
Density Of Irrigation

A theoretically derived relationship has been applied for the gas-side mass transfer coefficient to experimental values of kG. The experimental data have been obtained under the two-phase flow of gas and liquid in a plane vertical packing manufactured of the expanded metal sheet. This packing exhibits a significant dependence of the extent of interfacial area, and hence the geometry of the channel available for gas flow, on the density of irrigation.

scholarly journals Oxidative degradation of gentamicin present in water by an electro-Fenton process and biodegradability improvement

2019 ◽  
Vol 17 (1) ◽  
pp. 1017-1025
Author(s):  
Mohamed Réda Arhoutane ◽  
Muna Shueai Yahya ◽  
Miloud El Karbane ◽  
Kacem El Kacemi
Keyword(s):  
Chemical Oxygen Demand ◽  
Biological Process ◽  
Oxidative Degradation ◽  
Oxygen Demand ◽  
Polluted Water ◽  
Applied Current ◽  
Pseudo First Order Reaction ◽  
First Order ◽  
Appropriate Treatment ◽  
By Products

AbstractIn the context of environmental protection, where there is a need to develop effective operations for carrying out appropriate treatment of polluted water by pharmaceuticals. Therefore, the present study aims at evaluating the degradation for gentamicin through electro-Fenton (EF) operation, through taking into consideration the effect of several parameters of experimental in the process, namely, the concentration of initial gentamicin, the applied current and the Fe+2 (II) quantities. The (EF) operation employed involves a carbon-felt as cathode and platinum as anode at pH 3. Studies for the gentamicin kinetics is monitored by HPLC giving a pseudo-first order reaction following by a chemical oxygen demand, with a reached degree of mineralization 96% after of four hours of treatment through current 100 mA/cm2 with 0.1 mM of Fe+2. We find that the degradation for molecule of gentamicin is accompanied by an augmentation of the biodegradability, assesse through the Biochemical Oxygen Demand (BOD5) on chemical oxygen demand (COD) ratio, that augmentation from 0 to 0.41 before treatment after 30 min for EF treatment, showing that there is potential for conjugation of the EF process and the biological process. Furthermore, the by-products have been identified on the basis of HPLC-MS/MS results.

scholarly journals Kinetics and Mechanism of the Change of the 4-Nitrobenzylthio-System into 4,4′-Diformylazoxybenzene in Alkaline Dioxane-Water Media

1985 ◽  
Vol 40 (11) ◽  
pp. 1128-1132
Author(s):  
Y. Riad ◽  
Adel N. Asaad ◽  
G.-A. S. Gohar ◽  
A. A. Abdallah
Keyword(s):  
Acetic Acid ◽  
Sodium Hydroxide ◽  
Rate Constants ◽  
Main Product ◽  
Reaction Medium ◽  
Aqueous Dioxane ◽  
Proton Abstraction ◽  
First Order ◽  
Water Media ◽  
Different Temperatures

Sodium hydroxide reacts with α -(4-nitrobenzylthio)-acetic acid in aqueous-dioxane media to give 4,4'-diformylazoxybenzene as the main product besides 4,4'-dicarboxyazoxybenzene and a nitrone acid. This reaction was kinetically studied in presence of excess of alkali in different dioxane-water media at different temperatures. It started by a fast reversible a-proton abstraction step followed by two consecutive irreversible first-order steps forming two intermediates (α -hydroxy, 4-nitrosobenzylthio)-acetic acid and 4-nitrosobenzaldehyde. The latter underwent a Cannizzaro's reaction, the products of which changed in the reaction medium into 4,4'-diformylazoxybenzene and 4,4'-dicarboxyazoxybenzene. The rate constants and the thermodynamic parameters of the two consecutive steps were calculated and discussed. A mechanism was put forward for the formation of the nitrone acid.Other six 4-nitrobenzyl, aryl sulphides were qualitatively studied and they gave mainly 4,4'-diformylazoxybenzene beside 4,4'-dicarboxyazoxybenzene or its corresponding azo acid.

The effect of the textile industry dye bath additive EDTMPA on colour removal characteristics by ozone oxidation

2007 ◽  
Vol 55 (10) ◽  
pp. 145-153 ◽  
Author(s):  
T. Ölmez ◽  
I. Kabdaşlı ◽  
O. Tünay
Keyword(s):  
Organic Matter ◽  
Textile Industry ◽  
Reaction Rates ◽  
Textile Dye ◽  
Pseudo First Order Reaction ◽  
Ozone Oxidation ◽  
Reactive Dyeing ◽  
First Order ◽  
Organic Matter Oxidation ◽  
Pseudo First Order

In this study, the effects of the phosphonic acid based sequestering agent EDTMPA used in the textile dye baths on colour and organic matter removal by ozone oxidation was experimentally investigated. Procion Navy HEXL dyestuff that has been commonly used for the reactive dyeing of cellulose fibers was selected as the model component. The organic matter oxidation by ozone was determined to obey the pseudo-first order kinetics as they are treated singly or in combination. COD removal rates obtained from pseudo-first order reaction kinetics showed that oxidation of Navy HEXL alone (0.0947 L/min) was faster than that of EDTMPA (0.0171 L/min) and EDTMPA with dye (0.0155 L/min) at pH 3.0. It was also found that reaction rates of single EDTMPA removal and EDTMPA and dye mixture removal increased as the reaction pH was increased from 3.0 to 10.5.

Multifactorial optimization of the decolorisation parameters of wastewaters resulting from dyeing flowers

2009 ◽  
Vol 59 (7) ◽  
pp. 1361-1369 ◽  
Author(s):  
Edison Gil Pavas ◽  
Miguel Ángel Gómez-García
Keyword(s):  
Hydrogen Peroxide ◽  
Organic Matter ◽  
Experimental Design ◽  
Order Reaction ◽  
Pseudo First Order Reaction ◽  
First Order ◽  
Effluent Standards ◽  
Degradation Of Dyes ◽  
Pseudo First Order ◽  
Dyes Mixture

This work deals with the treatment of the wastewaters resulting from the process of dyeing flowers. In some local cases for growing flowers near to Medellín (Colombia), wastewater color was found to be one of the main problems in meeting local effluent standards. Wastewaters were treated by photodegradation process (which includes photocatalysis) to achieve the degradation of dyes mixture and organic matter in the wastewater. A multifactorial experimental design was proposed, including as experimental factors the following variables: pH, and the concentration of both catalyst (TiO2) and hydrogen peroxide (H2O2). According to the obtained results, at the optimized variables values, it is possible to reach a 99% reduction of dyes, a 76.9% of mineralization (TOC) and a final biodegradability of 0.834. Kinetic analysis allows proposing a pseudo first order reaction for the reduction, the mineralization, and the biodegradation processes.

scholarly journals Spent mushroom substrate: a crucial biosorbent for the removal of ferrous iron from groundwater

2021 ◽  
Vol 3 (1) ◽  
Author(s):  
D. Menaga ◽  
S. Rajakumar ◽  
P. M. Ayyasamy
Keyword(s):  
Ferrous Iron ◽  
Tamil Nadu ◽  
Contaminated Water ◽  
Spent Mushroom Substrate ◽  
Pseudo First Order Reaction ◽  
Time Intervals ◽  
New Approach ◽  
First Order ◽  
Sorption Ability ◽  
Pseudo Second Order

Abstract A new approach was carried out with the spent mushroom substrate (SMS) of Pleurotus florida on ferrous iron (Fe2+) removal using live, dead and pretreated substrate. In this study, the various dosage levels of SMS namely, 0.25, 0.50, 1.0 and 1.50 g/50 mL were used for the removal of Fe2+ at different time intervals for 90 min. The effect of various temperatures and pH on Fe2+ removal was studied with optimized dosages and time intervals. The biosorption potential of P. florida SMS was checked against the iron-contaminated groundwater collected from in and around Salem, Namakkal and Dharmapuri districts of Tamil Nadu. The biosorption data were obtained and analyzed in terms of their kinetic behavior. Among the SMS of P. florida, the live SMS showed potential Fe2+ removal (100%) from aqueous metal solution in all the tested concentrations. SMS of P. florida showed high potential removal of Fe2+ in neutral pH, at room temperature and explored an efficient sorption ability (100%) in the tested water sample (SW10). The adsorption kinetic values fitted very well with pseudo-second-order when comparing with pseudo-first-order reaction. FTIR, SEM and EDX analysis proved the accumulation of Fe2+ by the SMS. The present study confirmed that the live SMS of P. florida may serve as a potential and eco-friendly biosorbent for removal of Fe2+ from the iron-contaminated water. Graphic abstract

scholarly journals Reuse of Newspaper As An Adsorbent For Cu (II) Removal By Citric Acid Modification

2018 ◽  
Vol 156 ◽  
pp. 02012 ◽  
Author(s):  
Mardiah ◽  
Rif’an Fathoni ◽  
Pratiwi Pudyaningtyas ◽  
Hamdania Gamu ◽  
Rinaldy
Keyword(s):  
Citric Acid ◽  
Adsorption Process ◽  
Kinetic Studies ◽  
Order Reaction ◽  
Acid Modification ◽  
Pseudo First Order Reaction ◽  
First Order ◽  
Pseudo Second Order ◽  
Heavy Metal Adsorbent ◽  
The Impact

High Consumption of paper, bring the impact of the waste paper itself. And the utilization of the paper is limited to recycled products and crafts, whereas paper such as newspaper still contains cellulose that can be potential to be used as a heavy metal adsorbent. In this study, newspaper was dissolved in sodium bicarbonate to reduce various impurities and then was reacted with citric acid (CA). The modified adsorbent was characterized by FTIR and was tested for adsorb Cu(II) in artificial solution. After adsorption process, the solution was filtered and analysed using Atomic Absorption Spectrophotometer (AAS). The adsorption experimental data was fitted to Langmuir, Freundlich, Tempkin, and Dubinin-Radushkevich for equilibrium model and was fitted to pseudo first order reaction and pseudo second order reaction for kinetic studies. The result showed that CA-modification newspaper able to remove heavy metals Cu(II) in solution.

Reliability approach for the side resistance of piles by means of the total stress analysis (α Method)

2007 ◽  
Vol 44 (11) ◽  
pp. 1378-1390 ◽  
Author(s):  
C. Cherubini ◽  
G. Vessia
Keyword(s):  
Stress Analysis ◽  
Undrained Shear Strength ◽  
Clayey Soils ◽  
Total Stress ◽  
First Order ◽  
Side Resistance ◽  
Reliability Method ◽  
Real Size ◽  
Bored Piles ◽  
Adhesion Factor

The evaluation of the pile–soil adhesion plays a fundamental role in the estimation of the side resistance for total stress analysis. Over the years, researchers have presented proposals for adhesion factor formulations even though only a few of them have shown a certain agreement in numerical and (or) methodological terms. Hence, several real-size experimental analyses have improved the understanding of the pile–soil adhesion phenomenon and mechanism. Nevertheless, the undrained shear strength (cu) values depend on the experimental technique employed. Such results force engineers to make a difficult choice among various formulations. A reliability analysis is performed in this paper to take into consideration the variations in formulations and values of the side resistance of bored piles in clayey soils. This study involves piles having different lengths and diameters, which are supposed to be bored in Matera clays. Such soil is characterized by means of laboratory investigation campaign, and its mechanical and stochastic main features are reported here. Values of reliability index β are calculated by means of the first-order reliability method.

scholarly journals KINETICS OF PALM OIL TRANSESTERIFICATION IN METHANOL WITH POTASSIUM HYDROXIDE AS A CATALYST

2010 ◽  
Vol 8 (2) ◽  
pp. 219-225
Author(s):  
Yoeswono Yoeswono ◽  
Triyono Triyono ◽  
Iqmal Tahir
Keyword(s):  
Activation Energy ◽  
Palm Oil ◽  
Rate Constants ◽  
Potassium Hydroxide ◽  
Catalyst Concentration ◽  
Time Interval ◽  
Pseudo First Order Reaction ◽  
Exponential Factor ◽  
Potassium Methoxide ◽  
First Order

A study on palm oil transesterification to evaluate the effect of some parameters in the reaction on the reaction kinetics has been carried out. Transesterification was started by preparing potassium methoxide from potassium hydroxide and methanol and then mixed it with the palm oil. An aliquot was taken at certain time interval during transesterification and poured into test tube filled with distilled water to stop the reaction immediately. The oil phase that separated from the glycerol phase by centrifugation was analyzed by 1H-NMR spectrometer to determine the percentage of methyl ester conversion. Temperature and catalyst concentration were varied in order to determine the reaction rate constants, activation energies, pre-exponential factors, and effective collisions. The results showed that palm oil transesterification in methanol with 0.5 and 1 % w/w KOH/palm oil catalyst concentration appeared to follow pseudo-first order reaction. The rate constants increase with temperature. After 13 min of reaction, More methyl esters were formed using KOH 1 % than using 0.5 % w/w KOH/palm oil catalyst concentration. The activation energy (Ea) and pre-exponential factor (A) for reaction using 1 % w/w KOH was lower than those using 0.5 % w/w KOH.   Keywords: palm oil, transesterification, catalyst, first order kinetics, activation energy, pre-exponential factor

scholarly journals A Study of Critical Heat Flux During Flow Boiling in Microchannel Heat Sinks

2011 ◽  
Vol 134 (1) ◽  
Author(s):  
Tailian Chen ◽  
Suresh V. Garimella
Keyword(s):  
Heat Flux ◽  
Critical Heat Flux ◽  
Flow Rate ◽  
Heat Input ◽  
Heat Sink ◽  
Flow Boiling ◽  
Strong Dependence ◽  
Heat Fluxes ◽  
Abrupt Decrease ◽  
Parallel Microchannels

The cooling capacity of two-phase transport in microchannels is limited by the occurrence of critical heat flux (CHF). Due to the nature of the phenomenon, it is challenging to obtain reliable CHF data without causing damage to the device under test. In this work, the critical heat fluxes for flow boiling of FC-77 in a silicon thermal test die containing 60 parallel microchannels were measured at five total flow rates through the microchannels in the range of 20–80 ml/min. CHF is caused by dryout at the wall near the exit of the microchannels, which in turn is attributed to the flow reversal upstream of the microchannels. The bubbles pushed back into the inlet plenum agglomerate; the resulting flow blockage is a likely cause for the occurrence of CHF which is marked by an abrupt increase in wall temperature near the exit and an abrupt decrease in pressure drop across the microchannels. A database of 49 data points obtained from five experiments in four independent studies with water, R-113, and FC-77 as coolants was compiled and analyzed. It is found that the CHF has a strong dependence on the coolant, the flow rate, and the area upon which the heat flux definition is based. However, at a given flow rate, the critical heat input (total heat transfer rate to the coolant when CHF occurs) depends only on the coolant and has minimal dependence on the details of the microchannel heat sink (channel size, number of channels, substrate material, and base area). The critical heat input for flow boiling in multiple parallel microchannels follows a well-defined trend with the product of mass flow rate and latent heat of vaporization. A power-law correlation is proposed which offers a simple, yet accurate method for predicting the CHF. The thermodynamic exit quality at CHF is also analyzed and discussed to provide insights into the CHF phenomenon in a heat sink containing multiple parallel microchannels.

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