scholarly journals Evaluation of polymer binders in briquetting of coal fines for combustion applications

2021 ◽  
Vol 121 (3) ◽  
Author(s):  
D.L. Botha ◽  
N.T. Leokaoke ◽  
J. R. Bunt ◽  
H.W.J.P. Neomagus
Keyword(s):  
Compressive Strength ◽  
Polyvinyl Alcohol ◽  
Coal Tar ◽  
Mechanical Tests ◽  
Raw Material ◽  
Maximum Temperature ◽  
Mechanical And Thermal Properties ◽  
Fine Coal ◽  
Polymer Binders ◽  
Coal Powder

SYNOPSIS Coal briquetting traditionally makes use of high-dosage, nonpolymeric binders (such as coal tar pitch or molasses) or polyvinyl alcohol (PVA) at low dosages for the binding of fine and ultrafine coal. Due to constraints associated with the manufacturing and cost of PVA-bound briquettes, a novel polyacrylic binder was developed that could possibly be added in low dosages at room temperature. A set of formulations of two polyacrylic components (components A and B) was developed, from which an optimal binder mixture was determined. This formulation comprises 40wt.% component A and 10wt.% component B with a 0.04wt.% cross-linking additive, and the balance water. The uniaxial briquette compressive strength was used to obtain the optimal binder mixture. The binder mixture was added to the coal powder in dosages from 0.1 to 1.2wt.%. Mechanical tests and thermogravimetric analysis in an oxidized environment at a maximum temperature of 930°C were conducted. Binder-bound briquettes were compared to binderless briquettes and PVA-bound briquettes. Briquettes made from the polyacrylic formulation had uniaxial compressive strengths double that of the binderless briquette yield strength, as well as the minimum recommended compressive strength of 0.375 MPa. The organic binders did not affect the combustion of the briquettes, since the results compared well with the binderless briquettes. The polyacrylic formulation is considered to be a possible substitute for PVA in terms of mechanical and thermal properties and raw material cost. Keywords: briquettes, fine coal, polymer binders, polyvinyl alcohol, combustion.

scholarly journals Mechanical and Thermal Properties of UHPC Exposed to High-Temperature Thermal Cycling

2019 ◽  
Vol 2019 ◽  
pp. 1-12
Author(s):  
In-Hwan Yang ◽  
Jihun Park
Keyword(s):  
Thermal Conductivity ◽  
Tensile Strength ◽  
Compressive Strength ◽  
Thermal Properties ◽  
High Temperature ◽  
Thermal Cycling ◽  
Steel Fiber ◽  
Unit Weight ◽  
Maximum Temperature ◽  
Mechanical And Thermal Properties

The effects of high-temperature thermal cycling (temperatures up to 500°C) and steel fiber contents on the mechanical and thermal properties of ultrahigh-performance concrete (UHPC) containing polypropylene (PP) fibers were investigated in this study. The different maximum temperatures for thermal cycling included 300, 400, and 500°C. The mechanical properties, including the compressive strength and tensile strength, and thermal properties, including the unit weight and thermal conductivity, of the UHPC specimens were measured. The experimental results indicated that the compressive strength, tensile strength, unit weight, and thermal conductivity decreased as the temperature increased to 500°C. Test results showed that for each maximum temperature, the reduction of the thermal conductivities from one to six thermal cycles was not significant. The thermal conductivity of the UHPC decreased as the unit weight of the UHPC decreased, and the thermal conductivity also decreased as the compressive strength of the UHPC decreased. Scanning electron microscopy (SEM) analysis showed that the microstructures of the UHPC specimens exposed to high temperatures contained voids due to the PP fiber melting. The porosity of the UHPC specimens increased as the maximum temperature of the thermal cycles increased, which decreased the unit weights and thermal conductivities of the UHPC specimens. Moreover, the porosity at a temperature of 500°C increased by 60.0, 74.5, and 123.4% for steel fiber contents of 1.0, 1.5, and 2.0%, respectively. It might be due to incompatible thermal expansion between the concrete matrix and steel fiber.

scholarly journals A Novel Approach to Fabricate Foam Ceramics from Steel Slag

2020 ◽  
Vol 2020 ◽  
pp. 1-7
Author(s):  
Yu Zheng ◽  
Xudong Luo ◽  
Jinlong Yang ◽  
Wenlong Huo ◽  
Chi Kang
Keyword(s):  
Compressive Strength ◽  
Ph Value ◽  
Steel Slag ◽  
Raw Material ◽  
Solid Loading ◽  
Insulation Material ◽  
Ceramic Foams ◽  
Novel Approach ◽  
The Stability ◽  
First Time

A novel approach is used for fabricating steel slag foam ceramics based on the particle-stabilized foaming method. In this work, steel slag was used as the raw material and propyl gallate (PG) was used as the surface modifier. For the first time, steel slag ceramic foams were successfully fabricated based on particle-stabilized foams. The results show that the stability of the ceramic foams was closely related to the pH value and PG concentration. The porosity and compressive strength could be controlled by changing the solid loading of steel slag and sintering temperature. The porosity of steel slag foam ceramics ranged from 85.6% to 62.53%, and the compressive strength was from 1.74 MPa to 10.42 MPa. The thermal conductivity of steel slag foam ceramics was only 0.067 W (m·K)−1, which shows that it could be used as a thermal insulation material.

Incorporation of Wastes from Marble to Produce Brick Materials

2012 ◽  
Vol 174-177 ◽  
pp. 135-139
Author(s):  
Qing Bo Tian ◽  
Li Zong Chen ◽  
Li Na Xu ◽  
Yong Guang Fang
Keyword(s):  
Compressive Strength ◽  
Glass Fiber ◽  
Room Temperature ◽  
Wood Flour ◽  
Raw Material ◽  
Water Addition ◽  
Water Curing

A brick material was prepared with marble wastes as main raw material by pressure forming and water-curing at room temperature. With the increases of the amounts of water additions, the compressive strength increased gradually and obtained a highest value of 34.8MPa in the sample of the ratio of cement: wastes=20:100 at 17.0% water addition, above which the strength had an adverse change and decreased. The addition of glass fiber had small effects on the strength, water absorbing rate and density comparing with that of wood flour. The strengths of sample had changed obviously with the increment of the forming pressures. However, the strength would fall because of the lamination caused by the recovering effects of the wood flour in the sample with replacement of the wood flour to marble wastes, as the forming pressures were higher than 5.0 MPa.

scholarly journals Experimental Study on the Effect of Basalt Fiber and Sodium Alginate in Polymer Concrete Exposed to Elevated Temperature

Processes ◽  
2021 ◽  
Vol 9 (3) ◽  
pp. 510
Author(s):  
Seyed Esmaeil Mohammadyan-Yasouj ◽  
Hossein Abbastabar Ahangar ◽  
Narges Ahevani Oskoei ◽  
Hoofar Shokravi ◽  
Seyed Saeid Rahimian Koloor ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Vinyl Ester ◽  
Room Temperature ◽  
Elevated Temperatures ◽  
Basalt Fiber ◽  
Polymer Concrete ◽  
Strength Increase ◽  
Extensive Literature ◽  
Polymer Binders ◽  
Preliminary Phase

Polymer concrete contains aggregates and a polymeric binder such as epoxy, polyester, vinyl ester, or normal epoxy mixture. Since polymer binders in polymer concrete are made of organic materials, they have a very low heat and fire resistance compared to minerals. This paper investigates the effect of basalt fibers (BF) and alginate on the compressive strength of polymer concrete. An extensive literature review was completed, then two experimental phases including the preliminary phase to set the appropriate mix design, and the main phase to investigate the compressive strength of samples after exposure to elevated temperatures of 100 °C, 150 °C, and 180 °C were conducted. The addition of BF and/or alginate decreases concrete compressive strength under room temperature, but the addition of BF and alginate each alone leads to compressive strength increase during exposure to heat and increase in the temperature to 180 °C showed almost positive on the compressive strength. The addition of BF and alginate both together increases the rate of strength growth of polymer concrete under heat from 100 °C to 180 °C. In conclusion, BF and alginate decrease the compressive strength of polymer concretes under room temperature, but they improve the resistance against raised temperatures.

Effects of Steam Heat and Dry Heat Sterilization on Thermal and Mechanical Properties of Nylon and Policarbonate in Fabrication with Fused Filament

2021 ◽  
Vol 891 ◽  
pp. 150-163
Author(s):  
Jorge Mauricio Fuentes ◽  
Omar Flor Unda ◽  
Santiago Ferrandiz ◽  
Franyelit Suarez
Keyword(s):  
Mechanical Properties ◽  
Thermomechanical Analysis ◽  
Mechanical Tests ◽  
Effect Of Temperature ◽  
Mechanical And Thermal Properties ◽  
Scanning Calorimetry ◽  
Thermal Tests ◽  
Dry Heat ◽  
Izod Impact ◽  
Steam Heat

In this article presents evidence about performance of mechanical properties of polycarbonate and nylon materials, which are used in the additive manufacturing by deposition of molten material and that have been subjected to sterilization processes by moist heat at 121°C and dry heat at 140°C. This study provides useful information to consider the use of these materials in sanitary and sterile settings. Mechanical tests of tensile, flex, hardness, Izod impact, thermal tests in Differential Scanning Calorimetry DSC, Thermomechanical analysis TMA and Scanning Electron Microscopy SEM were performed. It is concluded that the mechanical and thermal properties have not been altered through the effect of temperature in sterilization processes.

USE OF THE MICROWAVE ENERGY FOR ALUMINUM WASTE FOAMING

2019 ◽  
Vol 25 (4) ◽  
pp. 43-49
Author(s):  
LUCIAN PAUNESCU ◽  
MARIUS FLORIN DRAGOESCU ◽  
SORIN MIRCEA AXINTE ◽  
ANA CASANDRA SEBE
Keyword(s):  
Thermal Conductivity ◽  
Compressive Strength ◽  
Porous Structure ◽  
Powder Mixture ◽  
Aluminum Foam ◽  
Fine Powder ◽  
Microwave Energy ◽  
Raw Material ◽  
Foaming Agent ◽  
Foaming Process

The paper presents an aluminum foam experimental technique using the microwave energy. The raw material was recycling aluminum waste processed by ecological melting and gas atomizing to obtain the fine powder required in the foaming process. The powder mixture was completed with dolomite as a foaming agent. The products had a fine and homogeneous porous structure (pore size between 0.4-0.9 mm). The density (1.17-1.19 g/cm3), the compressive strength (6.83-7.01 MPa) and the thermal conductivity (5.71-5.84 W/m·K) had values almost similar to the foams made by conventional methods.

scholarly journals Synthesis of Geopolymer from Inorganic Construction Waste

2013 ◽  
Vol 30 ◽  
pp. 45-51 ◽  
Author(s):  
Arbind Pathak ◽  
Vinay Kumar Jha
Keyword(s):  
Compressive Strength ◽  
Coal Fly Ash ◽  
Chemical Society ◽  
Raw Material ◽  
Curing Temperature ◽  
Alkali Concentration ◽  
Curing Time ◽  
Mass Ratio ◽  
Construction Waste ◽  
Alumino Silicate

Recently, the demolition of old houses and the construction of new buildings in Kathmandu valley are in the peak which in turn generates a huge amount of construction waste. There are two major types of construction wastes which are burden for disposal namely cement-sand-waste (CSW) and the coal fly ash (CFA). These construction wastes are rich source of alumino-silicate and thus used as raw material for the synthesis of geopolymer in this study. Geopolymers have been synthesized from CSW and CFA using NaOH-KOH and Na2SiO3 as activators. Some parameters like alkali concentration, amount of Na2SiO3 and curing time have been varied in order to improve the quality of geopolymeric product. The geopolymerization process has been carried out using 3-8M KOH/NaOH solutions, Na2SiO3 to CFA and CSW mass ratio of 0.25-2.00 and curing time variation from 5-28 days. The curing temperature was fixed at 40ºC in all the cases. 6M NaOH and 7M KOH solutions were found appropriate alkali concentrations while the ratio of sodium silicate to CSW and CFA of 0.5 and 1.75 respectively were found suitable mass ratio for the process of geopolymer synthesis. The maximum compressive strength of only 7.3 MPa after 15 days curing time with CSW raw material was achieved while with CFA, the compressive strength was found to be 41.9 MPa with increasing the curing time up to 28 days.DOI: http://dx.doi.org/10.3126/jncs.v30i0.9334Journal of Nepal Chemical Society Vol. 30, 2012 Page:  45-51 Uploaded date: 12/16/2013    

Performance of Nano-Silica Insulation Material Enhanced by High Humidity-Reinforcement Method

2016 ◽  
Vol 697 ◽  
pp. 433-436
Author(s):  
Shi Chao Zhang ◽  
Yu Feng Chen ◽  
Wei Wu ◽  
Hao Ran Sun ◽  
Guang Hai Wang ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Raw Material ◽  
High Humidity ◽  
Insulation Material ◽  
Condensation Polymerization ◽  
Drying Process ◽  
Nano Silica ◽  
Insulation Materials ◽  
The One ◽  
Strength Improvement

In this paper, fumed nano-silica as the main raw material, nano-silica insulation materials were prepared by the dry processing. Research on humidity-reinforcement of nano-Silica insulation materials has been carried out and analyzed. When hygroscopicity of samples reach to 23%, the compressive strength 1.65MPa is at twice the one without high humidity-reinforcement, while the thermal conductivities are almost the same. Then, the action mechanism of high humidity-reinforcement method was analyzed. In humidity-reinforcement method, as vapor enters, silica sol is formed in the gap between one aggregate particle and another, and various condensation polymerization occurred in the drying process, which lead to aggregates connection and compressive strength improvement.

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