scholarly journals Features of diffusion processes in the preparation of prepregs by the method of layered application of components

Author(s):  
I. V. Cheremukhina

The modern production of products made of composite materials based on thermosetting binders is mainly based on the use of pre – impregnated reinforcing technical threads-prepregs. The binder used for such semi-finished products must meet two important technological requirements: have a low reactivity (high viability) when stored in the temperature range from -5 to +25 ° C and the ability to adjust the curing time at the molding temperatures of the product. To eliminate the disadvantages of the traditional method of obtaining polymer composite materials, to improve their strength characteristics and reduce the cost of the resulting reinforced composites, it is proposed to use the method of layered application of components. The essence of the method consists in layer-by-layer impregnation of the fibrous filler with a binder solution, and then a developed curing system consisting of an amine hardener that prevents the interaction of the hardener with the resin under storage conditions and protective polymer emulsions. The binder-filler system is activated only at an elevated temperature under curing conditions. It is established that the optimal parameters for processing by direct pressing of the pre-pegs components obtained by the method of layer deposition are a pressure of 15 MPa and a temperature of160-170 ?С with a pressure exposure of 15 minutes. If you get products by winding, then for such products, heat treatment for 6 hours at a temperature of 120 ?С is optimal. In the conditions of forming products, that is, at an elevated temperature and at an increased pressure, the mutual diffusion of components occurs due to the movement of oncoming flows. Oligomeric molecules from the resin volume diffuse from the inner layer to the outer one, and the components of the curing system meet them from the outer layer to the inner one. The method of layered application of components makes it possible to create a macroheterogenic system of interpenetrating polymer meshes in the contact area of sequentially applied layers. The result of the research is an increase in the shelf life, the viability of prepregs (up to 10 days) and an improvement in the complex of physical and mechanical properties of composites: the destructive stress during static bending increases to 60 %, during dynamic bending (impact) - up to 50 %. The use of carboxymethylcellulose as a protective polymer provides higher indicators of the studied properties than when using butadiene styrene latex as a protective polymer..

Author(s):  
А. В. Еремин ◽  
О. А. Волокитина ◽  
Н. Ю. Алимова

Постановка задачи. Разработать рецептуры шлаковых асфальтобетонных смесей с оптимальным содержанием битума, исследовать их физико-механические свойства и на основании полученных результатов выявить преимущества и обосновать комплексное применение отходов металлургической промышленности на стадии проектирования конструкций дорожных одежд. Результаты. Проведены испытания образцов материалов конструктивных слоев в лабораторных условиях, дана оценка физико-механическим и прочностным характеристикам на основе определения фактического модуля упругости путем послойного измерения прогибов дорожной одежды на экспериментальном участке. Выводы. Полученные результаты исследований свидетельствуют о возможности применения шлаковых материалов в составе различных слоев нежесткой дорожной одежды на стадии проектирования конструкции. Выявлены преимущества использования шлаковых материалов в процессе строительства автомобильных дорог за счет сокращения затрат на материалы и в процессе эксплуатации с позиции безопасности и экологичности. Problem statement. To develop formulations of slag asphalt concrete mixtures with an optimal bitumen content, to study their physical and mechanical properties, and, on the basis of the results obtained, to identify the advantages and substantiate the integrated use of metallurgical industry waste at the stage of designing pavement structures. Results. The tests of samples of materials of structural layers in laboratory conditions were carried out, an assessment of the physical-mechanical and strength characteristics was given based on the determination of the actual modulus of elasticity by layer-by-layer measurement of the deflections of the pavement in the experimental section. Conclusions. The obtained research results indicate the possibility of using slag materials in the composition of various layers of non-rigid pavement at the design stage of the structure. The advantages of using slag materials in the process of building highways by reducing the cost of materials and in the process of operation from the standpoint of safety and environmental friendliness are revealed.


Author(s):  
I.R. Antypes ◽  
◽  
V.V. Zaitsev ◽  

Currently, the use of composite materials is increasingly used in various areas of the national economy, including the aviation industry. The materials of this article are devoted to the study of the use of composite materials for the manufacture of aircraft landing gear in comparison with the traditionally used brand of steel. As a result of the work carried out, it was found that the slope made of carbon fiber showed a critical stress twice as high as its design made of 30xgsn2a steel. In addition, carbon plastics are superior to high-strength steel in terms of specific strength, stiffness, and tensile strength.


Polymers ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1369
Author(s):  
Sanjeev Kumar ◽  
Lalta Prasad ◽  
Vinay Kumar Patel ◽  
Virendra Kumar ◽  
Anil Kumar ◽  
...  

In recent times, demand for light weight and high strength materials fabricated from natural fibres has increased tremendously. The use of natural fibres has rapidly increased due to their high availability, low density, and renewable capability over synthetic fibre. Natural leaf fibres are easy to extract from the plant (retting process is easy), which offers high stiffness, less energy consumption, less health risk, environment friendly, and better insulation property than the synthetic fibre-based composite. Natural leaf fibre composites have low machining wear with low cost and excellent performance in engineering applications, and hence established as superior reinforcing materials compared to other plant fibres. In this review, the physical and mechanical properties of different natural leaf fibre-based composites are addressed. The influences of fibre loading and fibre length on mechanical properties are discussed for different matrices-based composite materials. The surface modifications of natural fibre also play a crucial role in improving physical and mechanical properties regarding composite materials due to improved fibre/matrix adhesion. Additionally, the present review also deals with the effect of silane-treated leaf fibre-reinforced thermoset composite, which play an important role in enhancing the mechanical and physical properties of the composites.


Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4284
Author(s):  
Lvtao Zhu ◽  
Mahfuz Bin Rahman ◽  
Zhenxing Wang

Three-dimensional integrated woven spacer sandwich composites have been widely used as industrial textiles for many applications due to their superior physical and mechanical properties. In this research, 3D integrated woven spacer sandwich composites of five different specifications were produced, and the mechanical properties and performance were investigated under different load conditions. XR-CT (X-ray computed tomography) images were employed to visualize the microstructural details and analyze the fracture morphologies of fractured specimens under different load conditions. In addition, the effects of warp and weft direction, face sheet thickness, and core pile height on the mechanical properties and performance of the composite materials were analyzed. This investigation can provide significant guidance to help determine the structure of composite materials and design new products according to the required mechanical properties.


1976 ◽  
Vol 55 (5) ◽  
pp. 730-732 ◽  
Author(s):  
M. Braden ◽  
E.E. Causton ◽  
R.L. Clarke

The absorption and desorption of water by seven composite materials are diffusion processes, with the diffusion coefficient decreasing with concentration. The magnitude of the diffusion coefficients were consistent with diffusion occurring in the resin phase. Although most materials showed reversible behavior during repeated sorption-desorption cycles, one material showed irreversible breakdown.


2021 ◽  
Vol 887 ◽  
pp. 110-115
Author(s):  
G.A. Sabirova ◽  
R.R. Safin ◽  
N.R. Galyavetdinov

This paper presents the findings of experimental studies of the physical and mechanical properties of wood-filled composites based on polylactide (PLA) and vegetable filler in the form of wood flour (WF) thermally modified at 200-240 °C. It also reveals the dependence of the tensile strength, impact strength, bending elastic modulus, and density of composites on the amount of wood filler and the temperature of its thermal pre-modification. We established that an increase in the concentration of the introduced filler and the degree of its heat treatment results in a decrease of the tensile strength, impact strength and density of composite materials, while with a lower binder content, thermal modification at 200 °C has a positive effect on bending elastic modulus. We also found that 40 % content of a wood filler heated to 200 °C is sufficient to maintain relatively high physical and mechanical properties of composite materials. With a higher content of a wood filler, the cost can be reduced but the quality of products made of this material may significantly deteriorate. However, depending on the application and the life cycle of this product, it is possible to develop a formulation that includes a high concentration of filler.


2021 ◽  
Vol 14 ◽  
Author(s):  
Aniket Yadav ◽  
Piyush Chohan ◽  
Ranvijay Kumar ◽  
Jasgurpreet Singh Chohan ◽  
Raman Kumar

Background: Additive manufacturing is the most famous technology which requires materials or composites to be fabricated with layer by layer deposition strategy. Due to its lower cost, higher accuracy and less material wastage; this technology is used in almost every sector. But in many applications there is a need to alter the properties of a product in a certain direction with the help of some reinforcements. With the use of reinforcements, composite layers can be fabricated using additive manufacturing technique which will enhance the directional properties. A novel apparatus is designed to spray the reinforcement material into the printed structures in a very neat and precise manner. This spray nozzle is fully automated, which works according to tool-paths generated by slicing software. The alternate deposition of layers of reinforcement and build materials helped to fabricate customized composite products. Objective: The objective of present study is to design and analyze the working principle of novel technique which has been developed to fabricate composite materials using additive manufacturing. The apparatus is numerically controlled by computer according to CAD data which facilitates the deposition of alternate layers of reinforcement and matrix material. The major challenges during the design process and function of each component has been explored. Methods: The design process is initiated after comprehensive literature review performed to study previous composite manufacturing processes. The recent patents published by different patent offices of the world are studied in detail and analysis has been used to design a low cost composite fabrication apparatus. A liquid dispensing device comprises a storage tank attached with a pump and microprocessor. The microprocessor receives the signal from the computer as per tool paths generated by slicing software which decides the spray of reinforcements on polymer layers. The spraying apparatus moves in coordination with the primary nozzle of the Fused Filament Fabrication process. Results: The hybridization of Fused Filament Fabrication [process with metal spray process has been successfully performed. The apparatus facilitates the fabrication of low cost composite materials along with flexibility of complete customization of composite manufacturing process. The anisotropic behaviour of products can be easily controlled and managed during fabrication which can be used for different applications.


2020 ◽  
Vol 4 (157) ◽  
pp. 7-11
Author(s):  
V. Zhvan ◽  
V. Donenko ◽  
S. Kulish ◽  
A. Taran

The article is devoted to the effective analysis of trench and trenchless pipeline laying technologies. In the course of the work, an analytical review of pipeline assembly was performed, the main technological parameters, the scope of each method, and their advantages and disadvantages were determined. List of considered pipeline laying methods: trenching, horizontal directional drilling, mechanical puncture, hydraulic puncture, microtunneling and punching. The article analyzes the classical trench method and the most widely used trenchless ones: horizontal directional drilling; mechanical puncture; hydraulic puncture; microtunneling; punching. Each of these methods has several advantages and disadvantages. The choice of the optimal method of laying the pipeline depends on many factors: the physical and mechanical properties of soils and hydrogeological conditions, the length and diameter of the pipeline, the presence of other communications, buildings and structures, as well as the budget that customers have. Work time is the last deciding factor. Based on the results of the analysis of pipeline laying technologies and expert survey of construction industry experts, the cost table of each method was compiled, outlining the main characteristics of the technology: length of pipeline, speed of work, scope, cost, and the advantages and disadvantages of each of the considered methods. The conclusions about the use of each of the pipeline laying methods were made. Each of the methods has its advantages and disadvantages, so to choose the method of work it is necessary to conduct a comprehensive assessment of technological parameters, cost, scope and timing of work. The cost of lay-ing the pipeline consists of the following factors: conducting research; selection of diameter and determination of pipeline length; choice of laying method and equipment necessary for the works; selection of equipment, shut-off and control equipment and other materials arranged on the pipeline; terms of performance of works. Taking into account these factors, an estimate is made, which determines the cost of installation of a particular pipeline. After the analysis, we can conclude that among the methods of trenchless laying of pipelines can be identi-fied horizontally directional drilling, it is this method of laying the pipeline will be appropriate to use for our region. The drilling technique allows to carry out pipelines under obstacles, to pull long segments of networks, to repair site damage. This method is universal and can be used in almost any environment. Keywords: trenches, horizontal directional drilling, mechanical puncture, hydraulic piercing, microtunnelling, punching, pipeline.


Author(s):  
O. V. Karmanova ◽  
S. G. Tikhomirov ◽  
E. V. Lintsova ◽  
L. V. Popova

Studies of experimental adhesion modifiers based on a mixture of fatty acids from the production of light vegetable oils. The properties of rubber compounds and their vulcanizates obtained using experimental adhesion promoters KK with cobalt content from 7.5 to 16.5% are investigated. The plastic-elastic and vulcanization properties of the properties of breaker rubber compounds based on polyisoprene, the physical and mechanical properties of breaker rubbers and the bond strength in the “rubber-brass-plated steel cord system” were studied. When testing belt rubbers containing experienced adhesion promoters or an imported analog of Manobond 680C, the following features were revealed. The plasticity of the prototypes was in the range of 0.2-0.4. This indicates satisfactory processing properties. The Mooney viscosity of the prototypes was lower than that of the production sample. The use of experienced adhesion promoters instead of the analogue (Manobond 680C) increases the resistance to scorching. On the basis of the analysis of elastic-strength properties, it was found that in terms of the conditional tensile strength, the prototypes were inferior to the serial ones. However, rubbers containing the KK-12, KK-13.5, KK-15 promoters met the control standards. The tensile elongation at break of the experimental rubbers is higher than that of the serial sample. This may indicate the formation of a more uniform cure network in the presence of the test products. When testing rubber-metal-hard composites, it was noted that, under normal conditions, the experienced adhesion promoters have advantages over Manobond 680C. However, at elevated temperatures, under conditions of salt and steam-air aging, they are slightly inferior to Manobond 680C. It has been established that the experimental adhesion promoters provide the required set of technical properties of belt rubbers with a CO2 + content of 12–16.5% wt. Thus, it is possible to recommend the adhesion promoters KK 12, KK-13.5, KK 15 for practical use in the composition of belt rubber compounds. This will allow replacing a foreign-made product and reducing the cost of production.


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