scholarly journals High Piezoelectric Conversion Properties of Axial InGaN/GaN Nanowires

2018 ◽  
Author(s):  
Nikoletta Jegenyes ◽  
Martina Morassi ◽  
Pascal Chrétien ◽  
Laurent Travers ◽  
Lu Lu ◽  
...  
Keyword(s):  
State Of The Art ◽  
Electrical Energy ◽  
Piezoelectric Response ◽  
Average Output ◽  
Gan Nanowires ◽  
Piezoelectric Energy ◽  
Atomic Force ◽  
Maximum Value ◽  
Promising Perspective ◽  
First Time

We demonstrate for the first time efficient mechanical to electrical energy conversion using InGaN/GaN nanowires (NWs). Using an atomic force microscope equipped with a modified Resiscope module, we analyse the piezoelectric energy generation of GaN NWs and demonstrate an important enhancement when integrating in their volume a thick In-rich InGaN insertion. The piezoelectric response of InGaN/GaN NWs can be tuned as a function of the InGaN insertion thickness and position in the NW volume. The energy harvesting is favoured by the presence of a PtSi/GaN Schottky diode which allows to efficiently collect the piezo-charges generated by InGaN/GaN NWs. Average output voltages up to 330 ± 70 mV and a maximum value of 470 mV per NW has been measured for nanostructures integrating 70 nm-thick InGaN insertion capped with a thin GaN top layer. This latter value establishes an increase of about 35% of the piezo-conversion capacity in comparison with binary p-doped GaN NWs. By considering these output signals, we estimate a maximum power density generated by one layer of dense InGaN/GaN-based NW of about 3.3 W/cm2. These results settle the new state-of-the-art for piezo-generation from GaN-based NWs and offer a promising perspective for extending the performances of the piezoelectric sources.

scholarly journals Методы атомно-силовой микроскопии для исследования суперпротонных кристаллов

2020 ◽  
Vol 90 (11) ◽  
pp. 1843
Author(s):  
Р.В. Гайнутдинов ◽  
А.Л. Толстихина ◽  
Е.В. Селезнева ◽  
И.П. Макарова
Keyword(s):  
Atomic Force Microscopy ◽  
Surface Morphology ◽  
Ammonium Sulfate ◽  
Paraelectric Phase ◽  
Piezoelectric Response ◽  
Force Microscopy ◽  
Atomic Force ◽  
Microscopy Data ◽  
The Stability ◽  
First Time

Complex studies of new superprotonic crystals - acidic salts of potassium – ammonium sulfate (K1-x(NH4)x)3H(SO4)2, x ≥ 0.57 were carried out. Data on surface morphology, domain structure and conductivity of samples were obtained using atomic force microscopy. For the first time, the stability and degradation of the surface of superprotonic crystals were studied at the nanoscale. Based on piezoelectric response microscopy data, it was found that when the temperature decreased from 296 to 282 K, the (K0.43(NH4)0.57)3H(SO4)2 crystal transits from the paraelectric phase to the ferroelectric one.

Electronic performance of GaN nanowires cathode under electric field

2021 ◽  
pp. 2150230
Author(s):  
Siyuan Huang ◽  
Lei Liu ◽  
Feifei Lu
Keyword(s):  
Electric Field ◽  
Quantum Efficiency ◽  
Internal Field ◽  
Photogenerated Carrier ◽  
Gan Nanowires ◽  
Maximum Value ◽  
Electronic Performance ◽  
Gan Nanowire ◽  
First Time ◽  
Theoretical Results

The built-in electric field of exponential doping can promote the concentration of the photogenerated carrier center to the top surface of the nanowire. The external electric field also can bend the motion trajectory of the emitted electrons toward the collecting side. These field-assisted methods promote the quantum efficiency. In this paper, the emission theory of a single GaN nanowire photocathode is studied for the first time. The effects of height and width of the nanowire, wavelength, intensity of electric field on quantum efficiency of uniformly doped or exponentially doped GaN nanowire photocathodes were explored. It shows that the top of the exponentially doped cathode has a higher quantum efficiency than uniformly doped cathode. With the absence of the field, quantum efficiency of a uniformly doped cathode reaches a maximum value of 55.29% when the width is 150 nm and the wavelength is 220 nm. The form of exponentially doped cathode can generate an internal field. With the internal field, a maximum value rises 56.73% when the height is 900 nm and the wavelength is 230 nm. The theoretical results can direct the preparation of this kind of photocathode.

scholarly journals Structure-Properties Correlation of Cross-Linked Penicillin G Acylase Crystals

Crystals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 451
Author(s):  
Marta Kubiak ◽  
Janine Mayer ◽  
Ingo Kampen ◽  
Carsten Schilde ◽  
Rebekka Biedendieck
Keyword(s):  
Mechanical Stability ◽  
Structural Characteristics ◽  
Penicillin G ◽  
Bacillus Species ◽  
Diffusion Limitations ◽  
Small Water ◽  
Long Term Stability ◽  
Atomic Force ◽  
First Time

In biocatalytic processes, the use of free enzymes is often limited due to the lack of long-term stability and reusability. To counteract this, enzymes can be crystallized and then immobilized, generating cross-linked enzyme crystals (CLECs). As mechanical stability and activity of CLECs are crucial, different penicillin G acylases (PGAs) from Gram-positive organisms have proven to be promising candidates for industrial production of new semisynthetic antibiotics, which can be crystallized and cross-linked to characterize the resulting CLECs regarding their mechanical and catalytic properties. The greatest hardness and Young’s modulus determined by indentation with an atomic force microscope were observed for CLECs of Bacillus species FJAT-PGA CLECs (26 MPa/1450 MPa), followed by BmPGA (Priestia megaterium PGA, 23 MPa/1170 MPa) and BtPGA CLECs (Bacillus thermotolerans PGA, 11 MPa/614 MPa). In addition, FJAT- and BtPGA CLECs showed up to 20-fold higher volumetric activities compared to BmPGA CLECs. Correlation to structural characteristics indicated that a high solvent content and low number of cross-linking residues might lead to reduced stability. Furthermore, activity seems to be restricted by small water channels due to severe diffusion limitations. To the best of our knowledge, we show for the first time in this study that the entire process chain for the characterization of diverse industrially relevant enzymes can be performed at the microliter scale to discover the most important relationships and limitations.

scholarly journals State-of-the-Art Char Production with a Focus on Bark Feedstocks: Processes, Design, and Applications

Processes ◽  
2021 ◽  
Vol 9 (1) ◽  
pp. 87
Author(s):  
Ali Umut Şen ◽  
Helena Pereira
Keyword(s):  
State Of The Art ◽  
Lignocellulosic Materials ◽  
Heating Rates ◽  
Production Methods ◽  
Slow Pyrolysis ◽  
Production Studies ◽  
Lignocellulosic Feedstocks ◽  
Thermochemical Method ◽  
Superior Surface ◽  
First Time

In recent years, there has been a surge of interest in char production from lignocellulosic biomass due to the fact of char’s interesting technological properties. Global char production in 2019 reached 53.6 million tons. Barks are among the most important and understudied lignocellulosic feedstocks that have a large potential for exploitation, given bark global production which is estimated to be as high as 400 million cubic meters per year. Chars can be produced from barks; however, in order to obtain the desired char yields and for simulation of the pyrolysis process, it is important to understand the differences between barks and woods and other lignocellulosic materials in addition to selecting a proper thermochemical method for bark-based char production. In this state-of-the-art review, after analyzing the main char production methods, barks were characterized for their chemical composition and compared with other important lignocellulosic materials. Following these steps, previous bark-based char production studies were analyzed, and different barks and process types were evaluated for the first time to guide future char production process designs based on bark feedstock. The dry and wet pyrolysis and gasification results of barks revealed that application of different particle sizes, heating rates, and solid residence times resulted in highly variable char yields between the temperature range of 220 °C and 600 °C. Bark-based char production should be primarily performed via a slow pyrolysis route, considering the superior surface properties of slow pyrolysis chars.

scholarly journals UV Inscription and Pressure Induced Long-Period Gratings through 3D Printed Amplitude Masks

Sensors ◽  
2021 ◽  
Vol 21 (6) ◽  
pp. 1977
Author(s):  
Ricardo Oliveira ◽  
Liliana M. Sousa ◽  
Ana M. Rocha ◽  
Rogério Nogueira ◽  
Lúcia Bilro
Keyword(s):  
State Of The Art ◽  
Low Cost ◽  
Resonance Wavelength ◽  
Complex Structures ◽  
Pressing Method ◽  
Long Period ◽  
Long Period Gratings ◽  
3D Printed ◽  
Mechanical Pressing ◽  
First Time

In this work, we demonstrate for the first time the capability to inscribe long-period gratings (LPGs) with UV radiation using simple and low cost amplitude masks fabricated with a consumer grade 3D printer. The spectrum obtained for a grating with 690 µm period and 38 mm length presented good quality, showing sharp resonances (i.e., 3 dB bandwidth < 3 nm), low out-of-band loss (~0.2 dB), and dip losses up to 18 dB. Furthermore, the capability to select the resonance wavelength has been demonstrated using different amplitude mask periods. The customization of the masks makes it possible to fabricate gratings with complex structures. Additionally, the simplicity in 3D printing an amplitude mask solves the problem of the lack of amplitude masks on the market and avoids the use of high resolution motorized stages, as is the case of the point-by-point technique. Finally, the 3D printed masks were also used to induce LPGs using the mechanical pressing method. Due to the better resolution of these masks compared to ones described on the state of the art, we were able to induce gratings with higher quality, such as low out-of-band loss (0.6 dB), reduced spectral ripples, and narrow bandwidths (~3 nm).

scholarly journals Electro-Quasistatic Animal Body Communication for Untethered Rodent Biopotential Recording

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Shreeya Sriram ◽  
Shitij Avlani ◽  
Matthew P. Ward ◽  
Shreyas Sen
Keyword(s):  
Lower Energy ◽  
Sensor Node ◽  
State Of The Art ◽  
The Body ◽  
Animal Body ◽  
Current State ◽  
Communication Modalities ◽  
First Time ◽  
Biopotential Recording

AbstractContinuous multi-channel monitoring of biopotential signals is vital in understanding the body as a whole, facilitating accurate models and predictions in neural research. The current state of the art in wireless technologies for untethered biopotential recordings rely on radiative electromagnetic (EM) fields. In such transmissions, only a small fraction of this energy is received since the EM fields are widely radiated resulting in lossy inefficient systems. Using the body as a communication medium (similar to a ’wire’) allows for the containment of the energy within the body, yielding order(s) of magnitude lower energy than radiative EM communication. In this work, we introduce Animal Body Communication (ABC), which utilizes the concept of using the body as a medium into the domain of untethered animal biopotential recording. This work, for the first time, develops the theory and models for animal body communication circuitry and channel loss. Using this theoretical model, a sub-inch$$^3$$ 3 [1″ × 1″ × 0.4″], custom-designed sensor node is built using off the shelf components which is capable of sensing and transmitting biopotential signals, through the body of the rat at significantly lower powers compared to traditional wireless transmissions. In-vivo experimental analysis proves that ABC successfully transmits acquired electrocardiogram (EKG) signals through the body with correlation $$>99\%$$ > 99 % when compared to traditional wireless communication modalities, with a 50$$\times$$ × reduction in power consumption.

scholarly journals Thermoelectric Sensor Coupled Yagi–Uda Nanoantenna for Infrared Detection

Electronics ◽  
2021 ◽  
Vol 10 (5) ◽  
pp. 527
Author(s):  
Waleed Tariq Sethi ◽  
Olivier De Sagazan ◽  
Mohamed Himdi ◽  
Hamsakutty Vettikalladi ◽  
Saleh A. Alshebeili
Keyword(s):  
State Of The Art ◽  
Infrared Detection ◽  
Single Element ◽  
Center Wavelength ◽  
Resonance Response ◽  
Thermal Measurements ◽  
Radiation Induced ◽  
Thermoelectric Sensor ◽  
Junction Array ◽  
First Time

We present an experimental demonstration of a thermoelectric sensor coupled with a nanoantenna as an alternative option for detecting infrared energy. Two nanoantenna design (single element and an array) variations based on Yagi-Uda technology and one separate nano-thermoelectric junction array were fabricated and tested. The nanoantennas were tuned to operate and respond at a center wavelength of 1550 nm (193.5 THz) optical C-band window, but they also exhibited a resonance response when excited by lasers of various wavelengths (650 nm and 940 nm). The radiation-induced electric currents in the nanoantennas, coupled with a nano-thermoelectric sensor, produced a potential difference as per the Seebeck effect. With respect to the uniform thermal measurements of the reference nanoantenna, the experiments confirmed the detection properties of the proposed nanoantennas; the single element detected a peak percentage voltage hike of 28%, whereas the array detected a peak percentage voltage hike of 80% at the center wavelength. Compared to state-of-the-art thermoelectric designs, this was the first time that such peak percentage voltages were experimentally reported following a planar design based on the Seebeck principle.

scholarly journals Domain Adaptation Using a Three-Way Decision Improves the Identification of Autism Patients from Multisite fMRI Data

2021 ◽  
Vol 11 (5) ◽  
pp. 603
Author(s):  
Chunlei Shi ◽  
Xianwei Xin ◽  
Jiacai Zhang
Keyword(s):  
Machine Learning ◽  
Domain Adaptation ◽  
Recognition Accuracy ◽  
State Of The Art ◽  
Autism Spectrum ◽  
Fmri Data ◽  
Target Domain ◽  
Sample Distribution ◽  
Machine Learning Methods ◽  
First Time

Machine learning methods are widely used in autism spectrum disorder (ASD) diagnosis. Due to the lack of labelled ASD data, multisite data are often pooled together to expand the sample size. However, the heterogeneity that exists among different sites leads to the degeneration of machine learning models. Herein, the three-way decision theory was introduced into unsupervised domain adaptation in the first time, and applied to optimize the pseudolabel of the target domain/site from functional magnetic resonance imaging (fMRI) features related to ASD patients. The experimental results using multisite fMRI data show that our method not only narrows the gap of the sample distribution among domains but is also superior to the state-of-the-art domain adaptation methods in ASD recognition. Specifically, the ASD recognition accuracy of the proposed method is improved on all the six tasks, by 70.80%, 75.41%, 69.91%, 72.13%, 71.01% and 68.85%, respectively, compared with the existing methods.

scholarly journals High resolution nanoscale chemical analysis of bitumen surface microstructures

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Ayse N. Koyun ◽  
Julia Zakel ◽  
Sven Kayser ◽  
Hartmut Stadler ◽  
Frank N. Keutsch ◽  
...  
Keyword(s):  
Secondary Ion Mass Spectrometry ◽  
Force Microscopy ◽  
Photo Oxidation ◽  
Atomic Force ◽  
Para Phase ◽  
Key Sites ◽  
Respective Surface ◽  
Surface Domains ◽  
Surface Microstructures ◽  
First Time

AbstractSurface microstructures of bitumen are key sites in atmospheric photo-oxidation leading to changes in the mechanical properties and finally resulting in cracking and rutting of the material. Investigations at the nanoscale remain challenging. Conventional combination of optical microscopy and spectroscopy cannot resolve the submicrostructures due to the Abbe restriction. For the first time, we report here respective surface domains, namely catana, peri and para phases, correlated to distinct molecules using combinations of atomic force microscopy with infrared spectroscopy and with correlative time of flight—secondary ion mass spectrometry. Chemical heterogeneities on the surface lead to selective oxidation due to their varying susceptibility to photo-oxidation. It was found, that highly oxidized compounds, are preferentially situated in the para phase, which are mainly asphaltenes, emphasising their high oxidizability. This is an impressive example how chemical visualization allows elucidation of the submicrostructures and explains their response to reactive oxygen species from the atmosphere.

A hierarchical oxygen vacancy-rich WO3 with “nanowire-array-on-nanosheet-array” structure for highly efficient oxygen evolution reaction

2019 ◽  
Vol 7 (12) ◽  
pp. 6730-6739 ◽  
Author(s):  
Jinxiang Diao ◽  
Wenyu Yuan ◽  
Yu Qiu ◽  
Laifei Cheng ◽  
Xiaohui Guo
Keyword(s):  
Oxygen Vacancy ◽  
Oxygen Evolution Reaction ◽  
Oxygen Vacancies ◽  
State Of The Art ◽  
Nanowire Array ◽  
Nanowire Arrays ◽  
Nanosheet Array ◽  
Nanosheet Arrays ◽  
Array Structure ◽  
First Time

Hierarchical vertical WO3 nanowire arrays on vertical WO3 nanosheet arrays with rich oxygen vacancies were synthesized via a simple and facile method, and the outstanding OER performance which is superior to that of most reported state-of-the-art catalysts was reported for the first time.

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