scholarly journals Corrosion Behaviour of Passive Layer Growth by Controlling Additives of Nano-Metals-Phosphate to Pure Aluminum

2020 ◽  
Vol 13 (4) ◽  
pp. 1-9
Author(s):  
Hussein A. Hussein ◽  
Mohammed J. Kahdim ◽  
Alaa Abdulhasan Atiyah
Keyword(s):  
Aluminum Oxide ◽  
Corrosion Behaviour ◽  
Pure Aluminum ◽  
Xrd Analysis ◽  
Passive Layer ◽  
Layer Growth ◽  
Metal Phosphate ◽  
Cyclic Polarization ◽  
Cast Sample ◽  
Kinetics Of

This study investigates how microstructure and chemistry effects by Nano-Metal-Phosphate and the kinetics of growth passive layer and passivity breakdown. Additionally, the passive layer germination behavior on aluminum alloy 1050 with anticorrosive properties. The passive layer is an alloying method which allows an aluminum oxide to germinate. Morphologically and structurally, the aluminum oxide films were characterized using microscopy analyzes and XRD analysis. Results indicated that the reinforcements are well distributed and the grin size is downy. Corrosion behavior tested by Cyclic polarization exam and done at room temperature in (3.5 per cent NaCl) solution. The reinforcement increased the hardness for processed aluminum from Hv81.1 to HV=120.492 as castings. The parameter Nano-Metal-Phosphate has attenuated the current density of corrosion (7.15μA / cm2) compared to the as-cast sample results.

Influence of Composition, Concentration and Temperature of some Biological Liquids upon the Corrosion Behaviour of Titanum

2008 ◽  
Vol 59 (1) ◽  
pp. 17-24
Author(s):  
Rodica Popescu ◽  
Daniela Ionita ◽  
Florin Minculescu
Keyword(s):  
Lactic Acid ◽  
Body Temperature ◽  
Corrosion Behaviour ◽  
Passive Layer ◽  
Albumin Concentration ◽  
Cyclic Polarization ◽  
Low Concentrations ◽  
Human Body Temperature ◽  
Biological Liquids ◽  
The Stability

In order to investigate the corrosion behaviour of titan in aqueous solutions of lactic acid (1, 3 and 4% w) and albumin (2 and 10 % w) the cyclic polarization curves in potentiodynamic conditions were used. The corrosion parameters were estimated and their values were discussed as a function of acid lactic and albumin concentration and temperature. The stability of titan in investigated biological liquids was interpreted by involvment of the adsorption of either lactic acid or albumin onto the passive layer, a process which is favorised by moderate temperatures (as 370C � the human body temperature) as well as by low concentrations of lactic acid and albumin, respectively.

GROWTH KINETICS OF Cu(Al) SOLID SOLUTION IN Al/Cu DIFFUSION COUPLES

2004 ◽  
Vol 11 (03) ◽  
pp. 337-340 ◽  
Author(s):  
E. B. HANNECH ◽  
N. LAMOUDI ◽  
A. GASMI
Keyword(s):  
Solid Solution ◽  
Growth Kinetics ◽  
Early Stage ◽  
Pure Aluminum ◽  
Layer Growth ◽  
Solid Solution Phase ◽  
Diffusion Couples ◽  
Phase Layer ◽  
Initial Stage ◽  
Kinetics Of

The growth kinetics of the solid solution phase of aluminum in copper in diffusion couples of pure aluminum and copper has been investigated at 425°C using a scanning electron microscope. In the initial stage, the phase layer growth was found to obey the parabolic law, indicating that the rate-controlling process is diffusion. At longer times, the growth rate deviates from the kt-1/2 behavior of the early stage.

scholarly journals The Influence of Microstructure on the Passive Layer Chemistry and Corrosion Resistance for Some Titanium-Based Alloys

Materials ◽  
2019 ◽  
Vol 12 (8) ◽  
pp. 1233 ◽  
Author(s):  
Nader El-Bagoury ◽  
Sameh I. Ahmed ◽  
Ola Ahmed Abu Ali ◽  
Shimaa El-Hadad ◽  
Ahmed M. Fallatah ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Pitting Corrosion ◽  
Photoelectron Spectroscopy ◽  
Volume Fraction ◽  
Electrochemical Impedance ◽  
Passive Layer ◽  
Layer Growth ◽  
Uniform Corrosion ◽  
Cyclic Polarization ◽  
X Ray

The effect of microstructure and chemistry on the kinetics of passive layer growth and passivity breakdown of some Ti-based alloys, namely Ti-6Al-4V, Ti-6Al-7Nb and TC21 alloys, was studied. The rate of pitting corrosion was evaluated using cyclic polarization measurements. Chronoamperometry was applied to assess the passive layer growth kinetics and breakdown. Microstructure influence on the uniform corrosion rate of these alloys was also investigated employing dynamic electrochemical impedance spectroscopy (DEIS). Corrosion studies were performed in 0.9% NaCl solution at 37 °C, and the obtained results were compared with ultrapure Ti (99.99%). The different phases of the microstructure were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Chemical composition and chemistry of the corroded surfaces were studied using X-ray photoelectron spectroscopy (XPS) analysis. For all studied alloys, the microstructure consisted of α matrix, which was strengthened by β phase. The highest and the lowest values of the β phase’s volume fraction were recorded for TC21 and Ti-Al-Nb alloys, respectively. The susceptibility of the investigated alloys toward pitting corrosion was enhanced following the sequence: Ti-6Al-7Nb < Ti-6Al-4V << TC21. Ti-6Al-7Nb alloy recorded the lowest pitting corrosion resistance (Rpit) among studied alloys, approaching that of pure Ti. The obvious changes in the microstructure of these alloys, together with XPS findings, were adopted to interpret the pronounced variation in the corrosion behavior of these materials.

Correlations for Interaction Layer Growth in U-Mo/Al Dispersion Fuels

2017 ◽  
Vol 375 ◽  
pp. 29-39
Author(s):  
Boris A. Tarasov ◽  
Stepan N. Nikitin ◽  
Dmitry P. Shornikov ◽  
Maria S. Tarasova ◽  
Igor I. Konovalov
Keyword(s):  
Growth Rate ◽  
Growth Process ◽  
Aluminum Matrix ◽  
Layer Growth ◽  
Radiation Diffusion ◽  
Fission Rate ◽  
Interaction Layer ◽  
The Matrix ◽  
Mechanism And Kinetics ◽  
Kinetics Of

Paper presents the results of the growth rate of the interaction layer of uranium-molybdenum dispersed fuel in aluminum matrix and influence of silicon alloying on it. The growth process of amorphous interaction layer depends on the radiation diffusion which is proportional to the fission rate in the power of 1⁄4. The alloying of the matrix by silicon does not lead to a change in the mechanism and kinetics of the interaction layer growth, but only slows it down.

scholarly journals Study of Molten Salt Corrosion of Superni-75 using Termogravimetric Technique

1970 ◽  
Vol 3 (2) ◽  
pp. 77-82 ◽  
Author(s):  
TS Sidhu ◽  
S Prakash ◽  
RD Agrawal
Keyword(s):  
Corrosion Resistance ◽  
Molten Salt ◽  
Hot Corrosion ◽  
Corrosion Behaviour ◽  
Thick Layer ◽  
X Ray Diffraction ◽  
Salt Corrosion ◽  
Marine Engineering ◽  
The Given ◽  
Kinetics Of

The present study aims to evaluate the hot corrosion behaviour of the Ni-based alloy Superni- 75 in the molten salt environment of Na2SO-60%V2O5 at 900°C under cyclic conditions. The thermogravimetric technique was used to establish the kinetics of corrosion. X-ray diffraction, scanning electron microscopy/energy-dispersive analysis and electron probe microanalysis techniques were used to analyse the corrosion products. Superni-75 has successfully provided the hot corrosion resistance to the given molten salt environment. The hot corrosion resistance of the Superni-75 has been attributed to the formation of uniform, homogeneous and adherent thick layer of the scale consisting mainly of oxides of nickel and chromium, and refractory Ni(VO3)2. These oxides and refractory nickel vanadates have blocked the penetration of oxygen and other corrosive species to the substrate. Keywords: Hot corrosion, nickel-based alloy, superalloy, molten salt environment   DOI: 10.3329/jname.v3i2.922 Journal of Naval Architecture and Marine Engineering 3(2006) 77-82

scholarly journals Effect of Grain Refinement on the Dynamic, Mechanical Properties, and Corrosion Behaviour of Al-Mg Alloy

Metals ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1825
Author(s):  
Haitham M. Ahmed ◽  
Hussin A. M. Ahmed ◽  
Mohammed Hefni ◽  
Essam B. Moustafa
Keyword(s):  
Mechanical Properties ◽  
Grain Refinement ◽  
Corrosion Behaviour ◽  
Cast Alloy ◽  
Dynamic Properties ◽  
Damping Ratio ◽  
Xrd Analysis ◽  
Optical Microscope ◽  
Mg Alloy ◽  
Resonance Frequencies

In this investigation, aluminium Al-2.5% Mg cast alloy was modified by adding 0.5 Ti and 0.1 B wt % modifiers to investigate their impact on the dynamic behaviour, as well as the mechanical and microstructure properties. The dynamic properties were analysed experimentally using a free vibration impact test and predicted using finite element methods. This study used a high-resolution polarised optical microscope to analyse the microstructure of the studied alloys and X-ray Powder Diffraction (XRD) analysis to determine the developed phases. Microstructure and mechanical properties were mostly enhanced as a result of grain refining during solidification and through the metal segregation process. The microstructure analysis of the modified alloy showed a significant improvement in the grain refinement; hence, the grains were 10 times finer than the cast alloy. The modified Al-2.5% Mg/Ti-B alloy demonstrated reduced inter-granular corrosion (IGC) than the Al-2.5% Mg standard cast alloy. By incorporating Ti-B modifiers into the composition of the cast Al-Mg alloy, the ultimate tensile strength (UTS), strain (ε), and hardness values (HV) were increased by 30.5%, 100%, and 18.18%, respectively. The dynamic properties of the modified alloy showed an enhancement in the resonant (fn) and damping ratio (ζ) by 7% and 68%, respectively. The predicted resonance frequencies of the investigated alloys showed results close to the experimental dynamic tests.

Role of chromium in anomalous behaviour of the passive layer in Ni-Cr-Mo alloys in 1M HCl solution

CORROSION ◽  
10.5006/3767 ◽  
2022 ◽  
Author(s):  
Malvika Karri ◽  
Amit Verma ◽  
J.B. Singh ◽  
Sunil Kumar Bonagani ◽  
U.K. Goutam
Keyword(s):  
Corrosion Resistance ◽  
Electrochemical Impedance ◽  
Corrosion Behaviour ◽  
Underlying Mechanism ◽  
Passive Layer ◽  
X Ray ◽  
Superior Corrosion Resistance ◽  
Hcl Solution ◽  
Cr2o3 Layer

This work seeks to understand the underlying mechanism involved in passivity of Ni-Cr-Mo alloys in a less concentrated HCl solution (1M) by systematically varying contents of Cr and Mo solutes in model Ni-Cr-Mo alloys. Corrosion behaviour was evaluated based on potentiodynamic polarisation tests carried out in conjunction with electrochemical impedance and x-ray photoelectron spectroscopies of passive films that formed on alloys during their exposure to the HCl solution. Results have shown that an increase in Mo alone is not sufficient to improve the corrosion resistance of the alloys at lower concentrations of HCl. Optimum concentrations of Cr and Mo solutes have been found to be in the vicinity of ~17 wt.% Cr and ~19 wt.% Mo for superior corrosion resistance of the alloys. This was attributed to the protection of the Cr2O3 layer as a consequence of the enrichment of Mo6+ ions in the passive film in 1M HCl solution.

Kinetics of intermetallic compound layers and Cu dissolution at Sn1.5Cu/Cu interface under high magnetic field

2010 ◽  
Vol 25 (2) ◽  
pp. 359-367 ◽  
Author(s):  
Cong-qian Cheng ◽  
Jie Zhao ◽  
Yang Xu
Keyword(s):  
Magnetic Field ◽  
Intermetallic Compound ◽  
Lorentz Force ◽  
High Magnetic Field ◽  
Solubility Limit ◽  
Layer Growth ◽  
Ripening Process ◽  
Cu Substrate ◽  
Cu Dissolution ◽  
Kinetics Of

The kinetics of intermetallic compound (IMC) layer and Cu dissolution at Sn1.5Cu/Cu interface under high magnetic field was experimentally examined. It is found that the IMC layer growth is controlled by flux-driven ripening process. The high magnetic field promotes the growth of IMC layer, retards the dissolution of Cu substrate, and decreases the content of Cu solute at the liquid–IMC interface front. Based on the experimental results, it is considered that the magnetization induced by magnetic field promotes the ripening process for IMC layer growth. The Lorentz force dampening the convection and magnetization decreasing the Cu solubility limit can retard the Cu dissolution and change the solute distribution at the liquid–IMC interface front.

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