Tailoring Heat-Seal Properties of Biodegradable Polymers through Melt Blending

2017 ◽  
Vol 32 (5) ◽  
pp. 606-613 ◽  
Author(s):  
R. Y. Tabasi ◽  
A. Ajji
2007 ◽  
Vol 334-335 ◽  
pp. 1181-1184 ◽  
Author(s):  
Klaus Friedrich ◽  
Juergen Hoffmann ◽  
Mihail Evstatiev ◽  
Lin Ye ◽  
Yiu Wing Mai

In contrast to the classical composites, microfibrillar reinforced composites are not prepared via melt blending of the matrix and the reinforcing material. In fact, the reinforcing elements of this composite, the microfibrils, are created during processing. This advantage allows the manufacturing of a full biodegradable composite material with improved mechanical properties. Basing on a blend of two common biodegradable polymers, polylactide and polyglycolide, this new composite shows promising values under ambient conditions.


Author(s):  
Manju Rawat ◽  
Swarnlata Saraf

Currently, drug delivery technologies for protein and peptide delivery mainly rely on biodegradable polymers. However, protein stability during release from these systems can be critical due to physical and chemical instabilities. Lipospheres are solid microparticles composed of fat core stabilized by phospholipids layer represent an alternative carrier for the delivery of highly challenging, labile and unstable  substances. This review highlights various aspects of lipospheres like physicochemical characteristics and stability for better clinical utility with a wider spectrum of proteins and peptides.


2020 ◽  
Vol 67 (2) ◽  
pp. 115-120
Author(s):  
Raisa A. Alekhina ◽  
Victoriya E. Slavkina ◽  
Yuliya A. Lopatina

The article presents options for recycling polymers. The use of biodegradable materials is promising. This is a special class of polymers that can decompose under aerobic or anaerobic conditions under the action of microorganisms or enzymes forming natural products such as carbon dioxide, nitrogen, water, biomass, and inorganic salts. (Research purpose) The research purpose is in reviewing biodegradable materials that can be used for the manufacture of products used in agriculture. (Materials and methods) The study are based on open information sources containing information about biodegradable materials. Research methods are collecting, studying and comparative analysis of information. (Results and discussion) The article presents the advantages and disadvantages of biodegradable materials, mechanical properties of the main groups of biodegradable polymers. The article provides a summary list of agricultural products that can be made from biodegradable polymer materials. It was found that products from the general group are widely used in agriculture. Authors have found that products from a special group can only be made from biodegradable polymers with a controlled decomposition period in the soil, their use contributes to increasing the productivity of crops. (Conclusions) It was found that biodegradable polymer materials, along with environmental safety, have mechanical properties that allow them producing products that do not carry significant loads during operation. We have shown that the creation of responsible products (machine parts) from biodegradable polymers requires an increase in their strength properties, which is achievable by creating composites based on them. It was found that the technological complexity of their manufacture and high cost are the limiting factors for the widespread use of biodegradable polymers at this stage.


Macromol ◽  
2021 ◽  
Vol 1 (3) ◽  
pp. 201-233
Author(s):  
Nina Maria Ainali ◽  
Dimitrios Kalaronis ◽  
Eleni Evgenidou ◽  
Dimitrios N. Bikiaris ◽  
Dimitra A. Lambropoulou

During the past two decades, immobilization of titanium dioxide (TiO2), a well-known photocatalyst, on several polymeric substrates has extensively gained ground since it limits the need of post-treatment separation stages. Taking into account the numerous substrates tested for supporting TiO2 photocatalysts, the use of biodegradable polymer seems a hopeful option owing to its considerable merits, including the flexible nature, low price, chemical inertness, mechanical stability and wide feasibility. The present review places its emphasis on recently published research articles (2011–2021) and exhibits the most innovative studies facilitating the eco-friendly biodegradable polymers to fabricate polymer-based photocatalysts, while the preparation details, photocatalytic performance and reuse of the TiO2/polymer photocatalysts is also debated. The biodegradable polymers examined herein comprise of chitosan (CS), cellulose, alginate, starch, poly(lactid acid) (PLA), polycaprolactone (PCL) and poly(lactide-co-glycolide) (PLGA), while an emphasis on the synthetical pathway (dip-coating, electrospinning, etc.) of the photocatalysts is provided.


Polymers ◽  
2021 ◽  
Vol 13 (3) ◽  
pp. 404
Author(s):  
Nur Sharmila Sharip ◽  
Hidayah Ariffin ◽  
Tengku Arisyah Tengku Yasim-Anuar ◽  
Yoshito Andou ◽  
Yuki Shirosaki ◽  
...  

The major hurdle in melt-processing of ultra-high molecular weight polyethylene (UHMWPE) nanocomposite lies on the high melt viscosity of the UHMWPE, which may contribute to poor dispersion and distribution of the nanofiller. In this study, UHMWPE/cellulose nanofiber (UHMWPE/CNF) bionanocomposites were prepared by two different blending methods: (i) melt blending at 150 °C in a triple screw kneading extruder, and (ii) non-melt blending by ethanol mixing at room temperature. Results showed that melt-processing of UHMWPE without CNF (MB-UHMWPE/0) exhibited an increment in yield strength and Young’s modulus by 15% and 25%, respectively, compared to the Neat-UHMWPE. Tensile strength was however reduced by almost half. Ethanol mixed sample without CNF (EM-UHMWPE/0) on the other hand showed slight decrement in all mechanical properties tested. At 0.5% CNF inclusion, the mechanical properties of melt-blended bionanocomposites (MB-UHMWPE/0.5) were improved as compared to Neat-UHMWPE. It was also found that the yield strength, elongation at break, Young’s modulus, toughness and crystallinity of MB-UHMWPE/0.5 were higher by 28%, 61%, 47%, 45% and 11%, respectively, as compared to the ethanol mixing sample (EM-UHMWPE/0.5). Despite the reduction in tensile strength of MB-UHMWPE/0.5, the value i.e., 28.4 ± 1.0 MPa surpassed the minimum requirement of standard specification for fabricated UHMWPE in surgical implant application. Overall, melt-blending processing is more suitable for the preparation of UHMWPE/CNF bionanocomposites as exhibited by their characteristics presented herein. A better mechanical interlocking between UHMWPE and CNF at high temperature mixing with kneading was evident through FE-SEM observation, explains the higher mechanical properties of MB-UHMWPE/0.5 as compared to EM-UHMWPE/0.5.


Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 659
Author(s):  
Iva Rezić ◽  
Mislav Majdak ◽  
Vanja Ljoljić Bilić ◽  
Ivan Pokrovac ◽  
Lela Martinaga ◽  
...  

In this work the in vitro antimicrobial activity of colloidal solutions of nine different commercially available nanoparticles were investigated against Staphylococcus aureus strains, both methicillin-sensitive (MSSA) and methicillin-resistant (MRSA). Research covered antimicrobial investigation of different metal and metal-oxide nanoparticles, including Ag 10 nm, Ag 40 nm, Al2O3 100 nm, Au 20 nm, Pt 4 nm, TiO2 100 nm, Y2O3 100 nm, ZnO 100 nm and ZrO2 100 nm nanoparticles. Such materials were foreseen to be applied as coatings on 3D-printed biodegradable polymers: i.e., catheters, disposable materials, hospital bedding items, disposable antimicrobial linings and bandages for chronic wounds. Therefore, the antimicrobial activity of the nanoparticles was determined by agar well diffusion assays and serial microdilution broth assays. In addition, the chromatographic characterization of elements present in trace amounts was performed as a method for tracing the nanoparticles. Moreover, the potential of preparing the rough surface of biodegradable polymers for coating with antimicrobial nanoparticles was tested by 3D-printing fused deposition methodology. The in vitro results have shown that particular nanoparticles provided powerful antimicrobial effects against MSSA and MRSA strains, and can be easily applied on different biopolymers.


2021 ◽  
Vol 416 ◽  
pp. 125763
Author(s):  
Loredana Manfra ◽  
Vincenzo Marengo ◽  
Giovanni Libralato ◽  
Maria Costantini ◽  
Francesca De Falco ◽  
...  

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