Hydrogen Generation Facilitates Sintering Atmospheres

2021 ◽  
Author(s):  
David Wolff
Keyword(s):  
Heat Conduction ◽  
Hydrogen Storage ◽  
Thermal Processing ◽  
Hydrogen Generation ◽  
Energy Content ◽  
High Energy ◽  
Pure Hydrogen ◽  
Post Processing ◽  
Hydrogen Supply ◽  
Processing Techniques

Abstract For annealing, brazing or sintering, furnace atmospheres help ensure that metals thermal processors obtain the results they need. Hydrogen-containing atmospheres are used to protect surfaces from oxidation, and to ensure satisfactory thermal processing results. Hydrogen-containing atmospheres make thermal processing more forgiving because the hydrogen improves heat conduction and actively cleans heated surfaces – reducing oxides and destroying surface impurities. For powder based fabrication such as P/M, MIM or binder-jet metal AM, the use of a hydrogen-containing thermal processing atmosphere ensures the highest possible density of the sintered parts without necessitating the use of post-processing techniques. Users of pure hydrogen or hydrogen-containing gas blend atmospheres often struggle with hydrogen supply options. Hydrogen storage may create compliance problems due to its flammability and high energy content. Hydrogen generation enables hydrogen use without hydrogen storage issues. Deployment of hydrogen generation can ease the addition of thermal processing atmospheres to new and existing processing facilities.

Hydrogen Generation in an Annular Micro-Reactor: an Experimental Investigation of Water Splitting Reaction Using Aluminum in Presence of Potassium Hydroxide

2018 ◽  
Vol 17 (2) ◽  
Author(s):  
Shyam P. Tekade ◽  
Diwakar Z. Shende ◽  
Kailas L. Wasewar
Keyword(s):  
Water Splitting ◽  
Potassium Hydroxide ◽  
Hydrogen Generation ◽  
Energy Content ◽  
Average Rate ◽  
High Energy ◽  
Low Flow ◽  
Flow Rates ◽  
Metal Aluminum ◽  
Micro Reactor

Abstract Hydrogen is one of the important non-conventional energy sources because of its high energy content and non-polluting nature of combustions. The water splitting reaction is one of the significant methods for hydrogen generation from non-fossil feeds. In the present paper, the hydrogen generation has been experimentally investigated with water splitting reaction using metal aluminum in presence of potassium hydroxide as an activator under flow conditions. The rate of hydrogen generation was reported in the annular micro- reactor of 1 mm annulus using various flow rates of aqueous 0.5 N KOH ranging from 1 ml/min to 10 ml/min. The complete conversion of aluminum was observed at all the flow rates of aqueous KOH. The hydrogen generation rate was observed to depend on the flow rate of liquid reactant flowing through the reactor. At 1 ml/min of 0.5 N KOH, hydrogen generates at an average rate of 3.36 ml/min which increases to 10.70 ml/min at 10 ml/min of aqueous KOH. The Shrinking Core Model was modified for predicting the controlling mechanism. The rate of hydrogen generation was observed to follow different controlling mechanisms on various time intervals at low flow rates of aqueous KOH. It was observed that chemical reaction controls the overall rate of hydrogen generation at higher flow rates of aqueous KOH.

Mg-based composites as effective materials for storage and generation of hydrogen for FC applications

2021 ◽  
pp. 53-80
Author(s):  
D. Korablev ◽  
◽  
A. Bezdorozhev ◽  
V. Yartys ◽  
J. Solonin ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
Hydrogen Generation ◽  
High Energy ◽  
High Energy Density ◽  
Hydrolysis Reaction ◽  
Preparation Technique ◽  
Power Sources ◽  
Safety Issues ◽  
Renewable Power ◽  
Physical And Chemical

Today, hydrogen is considered as an ideal choice for storing and carrying energy produced by renewable power sources since it is renewable, eco-friendly and has a high energy density. However, due to the low hydrogen storage capacity, high cost and safety issues of the conventional storage methods, several challenges need to be resolved to effectively use hydrogen in mobile applications. Solid-state hydrogen storage in atomic form in hydrides is a promising method of storage for this purpose, particularly because a double amount of hydrogen can be produced via hydrolysis reaction of chemically active hydrides. Among the metal hydrides, magnesium hydride (MgH2) is considered to be one of the most attractive candidates. However, the hydrolysis reaction is rapidly hindered by the passivation layer formed on the surface of MgH2. In order to improve MgH2 hydrolysis efficiency various approaches have been applied. This paper reviews recent progress on the modifications of MgH2-based materials by adding different type of additives, including metals, oxides, hydroxides, halides and surfactants. The introduced additives possess different catalytic properties due to their intrinsic physical and chemical characteristics, and therefore can strongly influence the hydrolysis reaction of MgH2. The most promising results were obtained for various salt additives showing that the reaction rate depends mostly on the additive type rather than on concentration. The effect of preparation technique on the hydrolysis of MgH2 – MgCl2 composites was studied in detail. The obtained results indicate that efficient hydrolysis performance can be achieved by ball milling of the freshly synthesized MgH2 with 5 wt.% MgCl2 and 1 wt.% TiC–2TiB2 additives. The combination of the applied approaches exhibited a notable synergistic effect on the hydrogen generation.

Some Unconventional Aero Gas Turbines Using Hydrogen Fuel

2002 ◽  
Author(s):  
Stefano Boggia ◽  
Anthony Jackson
Keyword(s):  
Gas Turbines ◽  
Energy Content ◽  
Renewable Energy Sources ◽  
High Energy ◽  
Aviation Fuel ◽  
Cycle Performance ◽  
Turbine Engines ◽  
Pure Hydrogen ◽  
Hydrogen Fuel ◽  
Reduction Of Co2

The use of hydrogen as an aviation fuel can be beneficial for the reduction of CO2 emissions, if renewable energy sources are used for hydrogen production. Pure hydrogen fuel produces no CO2 in flight. NOx emissions can be significantly lower for hydrogen fuelled combustors than for current kerosene fuelled combustors. Other advantages derive from the high energy content, which reduces the necessary fuel mass, and from the availability of a valuable heat sink, useful to improve cycle performance. The present paper (based on the EU Cryoplane Project) focuses on the use of hydrogen in aero gas turbine engines. It studies the differences in performance produced by of its cryogenic properties in unconventional cycles. Three novel concepts are applied to a turbofan aero engine; for each cycle the improvement in performance at take-off and cruise is presented. An estimation of the weight and size of the engine is then made.

scholarly journals Solid-State Hydrogen Storage within a Proton Battery and Its Performance Analysis with Different Catalyst Loadings

2019 ◽  
Vol 8 (9) ◽  
pp. 636-643
Keyword(s):  
Hydrogen Storage ◽  
Hydrogen Adsorption ◽  
Hydrogen Generation ◽  
Energy Content ◽  
Catalyst Loading ◽  
Ionic Form ◽  
Carbon Electrode ◽  
Potential Candidate ◽  
Desorption Process ◽  
Proton Battery

Hydrogen has already been identified as a potential candidate capable of replacing fossil fuels because of its immense energy content compared to conventional fuels. However, finding the safe, efficient generation and storage of hydrogen is a challenge. The present paper reports on hydrogen generation and its subsequent adsorption-desorption process in a proton battery with varied catalyst loading. The method of porous carbon electrode fabrication and experimentation is disclosed. The scanning electron microscopy (SEM) is employed to determine morphology characteristics of the fabricated electrodes that are integrated in a proton battery to study the process of hydrogen adsorption and desorption under the influence of varied catalytic loading. The comparison between catalytic loading of 1 mg/cm 2 and 2 mg/cm2 is analysed and reported. The hydrogen storage capacity of activated carbon electrode employed in a proton battery is obtained to be in the range of 0.4 to 0.5 wt. %. The obtained result proves the technical feasibility of a hydrogen generation and its subsequent adsorption in an ionic form within a proton battery. The obtained results contribute towards finding a sustainable alternative solution to fossil-based fuels for the global energy demand.

scholarly journals Reduction of the Heterocyclic Amines in Grilled Beef Patties through the Combination of Thermal Food Processing Techniques without Destroying the Grilling Quality Characteristics

Foods ◽  
2021 ◽  
Vol 10 (7) ◽  
pp. 1490
Author(s):  
Wei Wang ◽  
Lu Dong ◽  
Yan Zhang ◽  
Huaning Yu ◽  
Shuo Wang
Keyword(s):  
Microwave Heating ◽  
Food Processing ◽  
Thermal Processing ◽  
Superheated Steam ◽  
Quality Characteristics ◽  
Heterocyclic Amines ◽  
Thermal Processes ◽  
Beef Patties ◽  
Thermal Food Processing ◽  
Processing Techniques

In order to reduce the formation of heterocyclic amines in grilled beef patties without destroying their unique quality characteristics, the effects of different thermal processes, including charcoal grilling, infrared grilling, superheated steam roasting and microwave heating, on the production of heterocyclic amines in beef patties and grilling quality characteristics were systematically analyzed. The results showed that infrared grilling can significantly (p < 0.05) reduce the content of heterocyclic amines in grilled patties, and the combination of microwave heating or superheated steam roasting with infrared grilling could further reduce the content of heterocyclic amines, with a maximum reduction ratio of 44.48%. While subtle differences may exist in infrared grilled patties with/without superheated steam roasting or microwave heating, a slight change will not affect the overall quality characteristics of grilled patties. The combined thermal processing will not visually affect the color of the grilled patties. Correlation analysis and regression analysis showed that the reduction in heterocyclic amines caused by microwave heating and superheated steam roasting are related to the moisture content and lipid oxidation of grilled patties, respectively. Using combined thermal processes to reduce the formation of heterocyclic amines is advisable.

scholarly journals Post-Processing Techniques for the Improvement of Liposome Stability

Pharmaceutics ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1023
Author(s):  
Ji Young Yu ◽  
Piyanan Chuesiang ◽  
Gye Hwa Shin ◽  
Hyun Jin Park
Keyword(s):  
Freeze Drying ◽  
Protective Agent ◽  
Post Processing ◽  
Additional Process ◽  
Spray Freeze Drying ◽  
The Stability ◽  
Processing Techniques ◽  
The Impact ◽  
Self Aggregation ◽  
Liposome Stability

Liposomes have been utilized as a drug delivery system to increase the bioavailability of drugs and to control the rate of drug release at the target site of action. However, the occurrence of self-aggregation, coalescence, flocculation and the precipitation of aqueous liposomes during formulation or storage can cause degradation of the vesicle structure, leading to the decomposition of liposomes. To increase the stability of liposomes, post-processing techniques have been applied as an additional process to liposomes after formulation to remove water and generate dry liposome particles with a higher stability and greater accessibility for drug administration in comparison with aqueous liposomes. This review covers the effect of these techniques including freeze drying, spray drying and spray freeze drying on the stability, physicochemical properties and drug encapsulation efficiency of dry liposomes. The parameters affecting the properties of liposomes during the drying process are also highlighted in this review. In addition, the impact of using a protective agent to overcome such limitations of each process is thoroughly discussed through various studies.

scholarly journals Towards the Hydrogen Economy—A Review of the Parameters That Influence the Efficiency of Alkaline Water Electrolyzers

Energies ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 3193
Author(s):  
Ana L. Santos ◽  
Maria-João Cebola ◽  
Diogo M. F. Santos
Keyword(s):  
Energy Content ◽  
Water Electrolysis ◽  
High Energy ◽  
Operating Conditions ◽  
Energy Sources ◽  
Alkaline Water Electrolysis ◽  
Alkaline Water ◽  
New Energy ◽  
Recent Developments ◽  
Cell Components

Environmental issues make the quest for better and cleaner energy sources a priority. Worldwide, researchers and companies are continuously working on this matter, taking one of two approaches: either finding new energy sources or improving the efficiency of existing ones. Hydrogen is a well-known energy carrier due to its high energy content, but a somewhat elusive one for being a gas with low molecular weight. This review examines the current electrolysis processes for obtaining hydrogen, with an emphasis on alkaline water electrolysis. This process is far from being new, but research shows that there is still plenty of room for improvement. The efficiency of an electrolyzer mainly relates to the overpotential and resistances in the cell. This work shows that the path to better electrolyzer efficiency is through the optimization of the cell components and operating conditions. Following a brief introduction to the thermodynamics and kinetics of water electrolysis, the most recent developments on several parameters (e.g., electrocatalysts, electrolyte composition, separator, interelectrode distance) are highlighted.

scholarly journals Spectral Decomposition and Sound Source Localization of Highly Disturbed Flow through a Severe Arterial Stenosis

2021 ◽  
Vol 8 (3) ◽  
pp. 34
Author(s):  
Fardin Khalili ◽  
Peshala T. Gamage ◽  
Amirtahà Taebi ◽  
Mark E. Johnson ◽  
Randal B. Roberts ◽  
...  
Keyword(s):  
Spectral Decomposition ◽  
Pressure Fluctuations ◽  
Flow Analysis ◽  
High Energy ◽  
Arterial Stenosis ◽  
Epidermal Surface ◽  
Flow Through ◽  
Processing Techniques ◽  
Proper Orthogonal ◽  
Signal Processing Techniques

For the early detection of atherosclerosis, it is imperative to explore the capabilities of new, effective noninvasive diagnosis techniques to significantly reduce the associated treatment costs and mortality rates. In this study, a multifaceted comprehensive approach involving advanced computational fluid dynamics combined with signal processing techniques was exploited to investigate the highly turbulent fluctuating flow through arterial stenosis. The focus was on localizing high-energy mechano-acoustic source potential to transmit to the epidermal surface. The flow analysis results showed the existence of turbulent pressure fluctuations inside the stenosis and in the post-stenotic region. After analyzing the turbulent kinetic energy and pressure fluctuations on the flow centerline and the vessel wall, the point of maximum excitation in the flow was observed around two diameters downstream of the stenosis within the fluctuating zone. It was also found that the concentration of pressure fluctuation closer to the wall was higher inside the stenosis compared to the post-stenotic region. Additionally, the visualization of the most energetic proper orthogonal decomposition (POD) mode and spectral decomposition of the flow indicated that the break frequencies ranged from 80 to 220 Hz and were correlated to the eddies generated within these regions.

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