scholarly journals Results of experiments on vanadium extraction out of Kusinsky deposit titanium-magnetite ores enrichment wastes

2019 ◽  
Vol 75 (5) ◽  
pp. 617-622
Author(s):  
E. S. Makhotkina ◽  
M. V. Shubina
Keyword(s):  
Sodium Chloride ◽  
Negative Impact ◽  
Raw Materials ◽  
Ore Deposits ◽  
Materials Analysis ◽  
Magnetite Ore ◽  
Vanadium Extraction ◽  
Extraction Degree ◽  
Leaching Solution ◽  
Titanium Magnetite

The actuality of exhausted of titanium-magnetite ore deposits wastes is stipulated not only by necessity of their negative impact on environmental elimination, but also by a possibility of application of these wastes as vanadium-containing raw materials. Analysis of existing technological processes for vanadium extraction accomplished. A possibility of vanadium extraction out of Kusinsky deposit titanium-magnetite ore tails studied. Results of experiments on vanadium extraction as soluble vanadates by leaching from the samples after roasting with soda ash, sodium sulfate, calcium oxide, and sodium chloride in various mass ratios presented. It was determined, that additives of sodium chloride and sodium carbonate are the most effective reagents for roasting of this type of vanadium raw materials. A significant effect of titanium-magnetite ore tails chemical composition on the vanadium extraction degree revealed: with an increase content from 0.15% to 0.53% in the ore tails vanadium, the extraction degree increases to 74.8%. When using the sodium chloride reaction additive, it is possible to leach in only one stage using sulfuric acid. Increasing the sodium chloride amount in the roasting mixture leads to a significant increase in the vanadium extraction degree in the leaching solution.

Investigation of Hydrometallurgical Processing of Titanomagnetite Ore Enrichment Waste

2020 ◽  
Vol 299 ◽  
pp. 1115-1120
Author(s):  
E.S. Makhotkina ◽  
M.V. Shubina ◽  
I.G. Shubin
Keyword(s):  
Sodium Chloride ◽  
Negative Impact ◽  
Raw Materials ◽  
Mineralogical Composition ◽  
Point Of View ◽  
Raw Material ◽  
Magnetite Ore ◽  
Hydrometallurgical Processing ◽  
Vanadium Extraction ◽  
Extraction Degree

In the article the negative impact of titano-magnetite ore enrichment waste on the environment and the possibility of its use as vanadium-containing raw materials are overviewed. The chemical and mineralogical composition features of various samples of the Kusinsky deposit titanomagnetite ore tails are presented. Different combinations of their roasting processes (with and without salt additives, with oxides, carbonates, or their compositions) and leaching processes (with water or acid) during hydrometallurgical processing were analyzed.The experiment results on the extraction of vanadium in the form of soluble vanadates from the titanomagnetite ore tails by leaching from samples subjected to roasting with soda ash, sodium sulfate, calcium oxide, and sodium chloride in various mass ratios are presented. The significant influence of ore sample chemical composition on the vanadium extraction degree was revealed. It was revealed that for this type of vanadium raw material additives of sodium chloride and sodium carbonate are most preferable from the vanadium extraction degree point of view.

Industrial, Ecological and Resource-Efficient Aspects of Vanadium Production and Use of Technogenic Vanadium Sources

2017 ◽  
Vol 265 ◽  
pp. 994-998 ◽  
Author(s):  
E.S. Makhotkina ◽  
M.V. Shubina
Keyword(s):  
Raw Materials ◽  
Steel Slag ◽  
Steel Production ◽  
Raw Material ◽  
Hydrometallurgical Processing ◽  
Material Sources ◽  
Vanadium Extraction ◽  
Extraction Degree ◽  
The Cost ◽  
New Applications

The causes of the global vanadium consumption increase are described and new applications of this metal are given in the article. The main natural sources of vanadium are titanomagnetite, which is a strategic mineral raw material. The current volumes of vanadium extraction from natural raw materials do not match the demand of the market. Therefore there is an urgent need for recycling of secondary and technogenic sources. Partially the basic existing technologies processing vanadium-containing waste are reviewed. The effect of these wastes on the environment and human health is analyzed. The importance of vanadium steel slag recycling for the ecological state of industrial regions, resource-efficiency in expanding the raw material sources of vanadium and reducing the cost of steel production in general is shown. The results of studies on the extraction of vanadium in the form of soluble vanadate of metallurgical vanadium slag using hydrometallurgical processing are demonstrated. The analysis of the received values of the vanadium extraction degree was conducted. The influence of various factors on the completeness of extraction was examined. A significant influence on the vanadium extraction degree of slag chemical composition, the ratio of slag and alkaline additives in the charge, conditions of roasting and leaching was revealed.

Innovative Biohydrometallurgical Approaches in the EU Project FAME

2017 ◽  
Vol 262 ◽  
pp. 307-310
Author(s):  
Susan Reichel ◽  
Mirko Martin ◽  
Christopher G. Bryan ◽  
Cristina Vila ◽  
António Fiúza ◽  
...  
Keyword(s):  
Raw Materials ◽  
Heap Leaching ◽  
Ore Deposits ◽  
Low Grade ◽  
Processing Technologies ◽  
Critical Elements ◽  
Processing Strategies ◽  
Leaching Solution ◽  
Sulfide Concentrates ◽  
Eu Project

The FAME (Flexible and Mobile Economic Processing Technologies) project targets the development of flexible and economic processing technologies for small and low-grade European ore deposits with complex mineralogy, targeting greisen, skarn and pegmatite ores. Amongst the valuable elements to be recovered are W, Sn, Li and minor constituents like In, Ge, Ga, Nb or Ta. To improve the processing of by-product sulfides to recover critical elements like In or Ga and to develop innovative processing strategies for raw materials, biohydrometallurgical technologies are investigated. There are different approaches in FAME for the biohydrometallurgical recovery of valuable metals from low grade ores: 1) the extraction of Li from zinnwaldite and lepidolite, 2) the heap leaching of low grade sulfide ore unsuitable for conventional processing to recover Zn and In, and 3) the bioleaching of sulfide concentrates in a two-stage tank process for recovery of Zn and Cu. So far the most promising results were achieved for heap-leaching of low-grade Zn-In ores achieving 7.4 ppm In in the leaching solution and for Li extraction (28%) from zinnwaldite.

Organic chemical devulcanization of rubber vulcanizates in supercritical carbon dioxide and associated less eco-unfriendly approaches: A review

2021 ◽  
pp. 0734242X2110085
Author(s):  
Jabulani I Gumede ◽  
Buyiswa G Hlangothi ◽  
Chris D Woolard ◽  
Shanganyane P Hlangothi
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Negative Impact ◽  
Raw Materials ◽  
Chemical Components ◽  
Organic Chemical ◽  
Attractive Alternative ◽  
Special Focus ◽  
Waste Tyres ◽  
Supercritical Carbon

There is a growing need to recover raw materials from waste due to increasing environmental concerns and the widely adopted transition to circular economy. For waste tyres, it is necessary to continuously develop methods and processes that can devulcanize rubber vulcanizates into rubber products with qualities and properties that can closely match those of the virgin rubber. Currently, the most common, due to its efficiency and perceived eco-friendliness in recovering raw rubber from waste rubbers, such as tyres, is devulcanization in supercritical carbon dioxide (scCO2) using commercial and typical devulcanizing agents. The scCO2 has been generally accepted as an attractive alternative to the traditional liquid-based devulcanization media because of the resultant devulcanized rubber has relatively better quality than other processes. For instance, when scCO2 is employed to recover rubber from waste tyres (e.g. truck tyres) and the recovered rubber is blended with virgin natural rubber (NR) in various compositions, the curing and mechanical properties of the blends closely match those of virgin NR. The atmospheric toxicity and cost of the commonly used devulcanization materials like chemical agents, oils and solvents have enabled a shift towards utilization of greener (mainly organic) and readily available devulcanization chemical components. This literature review paper discusses the approaches, which have less negative impact on the environment, in chemical devulcanization of rubber vulcanizates. A special focus has been on thermo-chemical devulcanization of waste tyres in scCO2 using common organic devulcanizing agents.

scholarly journals Potential Benefits and Constraints of Development of Critical Raw Materials’ Production in the EU: Analysis of Selected Case Studies

Resources ◽  
2021 ◽  
Vol 10 (7) ◽  
pp. 67
Author(s):  
Katarzyna Guzik ◽  
Krzysztof Galos ◽  
Alicja Kot-Niewiadomska ◽  
Toni Eerola ◽  
Pasi Eilu ◽  
...  
Keyword(s):  
Case Studies ◽  
Social Acceptance ◽  
Raw Materials ◽  
Local Level ◽  
Ore Deposits ◽  
Abandoned Mines ◽  
Social Constraints ◽  
Cost And Benefit Analysis ◽  
The Eu ◽  
Critical Raw Materials

Major benefits and constraints related to mineral extraction within the EU have been identified on the examples of selected critical raw materials’ deposits. Analyzed case studies include the following ore deposits: Myszków Mo-W-Cu (Poland), Juomasuo Au-Co (Finland), S. Pedro das Águias W-Sn (Portugal), Penouta Nb-Ta-Sn (Spain), Norra Kärr REEs (Sweden) and Trælen graphite (Norway). They represent different stages of development, from the early/grassroot exploration stage, through advanced exploration and active mining, up to reopening of abandoned mines, and refer to different problems and constraints related to the possibility of exploitation commencement. The multi-criteria analysis of the cases has included geological and economic factors as well as environmental, land use, social acceptance and infrastructure factors. These factors, in terms of cost and benefit analysis, have been considered at three levels: local, country and EU levels. The analyzed cases indicated the major obstacles that occur in different stages of deposit development and need to be overcome in order to enable a new deposit exploitation commencement. These are environmental (Juomasuo and Myszków), spatial (Juomasuo) as well as social constraints (Norra Kärr, Juomasuo). In the analyzed cases, the most important constraints related to future deposit extraction occur primarily at a local level, while some important benefits are identified mainly at the country and the EU levels. These major benefits are related to securing long-term supplies for the national industries and strategically important EU industry sectors.

scholarly journals Production of Microfibrillated Cellulose from Fast-Growing Poplar and Olive Tree Pruning by Physical Pretreatment

2021 ◽  
Vol 11 (14) ◽  
pp. 6445
Author(s):  
David Ibarra ◽  
Raquel Martín-Sampedro ◽  
Bernd Wicklein ◽  
Úrsula Fillat ◽  
María E. Eugenio
Keyword(s):  
Negative Impact ◽  
Raw Materials ◽  
Olive Tree ◽  
Barrier Properties ◽  
Microfibrillated Cellulose ◽  
Mechanical Resistance ◽  
Fast Growing ◽  
Wide Range ◽  
Pfi Refining ◽  
Tree Pruning

Motivated by the negative impact of fossil fuel consumption on the environment, the need arises to produce materials and energy from renewable sources. Cellulose, the main biopolymer on Earth, plays a key role in this context, serving as a platform for the development of biofuels, chemicals and novel materials. Among the latter, micro- and nanocellulose have been receiving increasing attention in the last few years. Their many attractive properties, i.e., thermal stability, high mechanical resistance, barrier properties, lightweight, optical transparency and ease of chemical modification, allow their use in a wide range of applications, such as paper or polymer reinforcement, packaging, construction, membranes, bioplastics, bioengineering, optics and electronics. In view of the increasing demand for traditional wood pulp (e.g., obtained from eucalypt, birch, pine, spruce) for micro/nanocellulose production, dedicated crops and agricultural residues can be interesting as raw materials for this purpose. This work aims at achieving microfibrillated cellulose production from fast-growing poplar and olive tree pruning using physical pretreatment (PFI refining) before the microfibrillation stage. Both raw materials yielded microfibrillated cellulose with similar properties to that obtained from a commercial industrial eucalypt pulp, producing films with high mechanical properties and low wettability. According to these properties, different applications for cellulose microfibers suspensions and films are discussed.

scholarly journals New Circular Challenges in the Development of Take-Away Food Packaging in the COVID-19 Period

Energies ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4705
Author(s):  
Ewa Kochańska ◽  
Rafał M. Łukasik ◽  
Maciej Dzikuć
Keyword(s):  
Social Transformation ◽  
Food Packaging ◽  
New Technologies ◽  
Negative Impact ◽  
Raw Materials ◽  
Distribution Channels ◽  
Low Carbon ◽  
Industrial Transformation ◽  
Specific Distribution ◽  
Food Market

The COVID-19 pandemic has set new challenges for the HoReCa industry. Lockdowns have coincided with and strongly impacted the industrial transformation processes that have been taking place for a decade. Among the most important HoReCa transition processes are those related to the rapid growth of the delivery-food market and ordering meals via internet platforms. The new delivery-food market requires not only the development of specific distribution channels, but also the introduction of appropriate, very specific food packaging. Food packaging and its functionality are defined by the administrative requirements and standards applicable to materials that have contact with food and principally through the prism of the ecological disaster caused by enormous amounts of plastic waste, mainly attributed to the food packaging. To meet environmental and administrative requirements, new technologies to produce food packaging materials are emerging, ensuring product functionality, low environmental impact, biodegradability, and potential for composting of the final product. However, predominantly, the obtained product should keep the nutritional value of food and protect it against changes in color or shape. Current social transformation has a significant impact on the food packaging sector, on one hand creating a new lifestyle for society all over the world, and on the other, a growing awareness of the negative impact of humans on the environment and increasing responsibility for the planet. The COVID-19 pandemic has highlighted the need to develop a circular economy based on the paradigm of shortening distribution channels, using local raw materials, limiting the consumption of raw materials, energy, water, and above all, minimizing waste production throughout the life cycle of products, all of which are in line with the idea of low-carbon development.

scholarly journals A Systematic Review on the Application of Machine Learning in Exploiting Mineralogical Data in Mining and Mineral Industry

Minerals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 816
Author(s):  
Mohammad Jooshaki ◽  
Alona Nad ◽  
Simon Michaux
Keyword(s):  
Machine Learning ◽  
Systematic Review ◽  
Raw Materials ◽  
Relevant Literature ◽  
Geological Structure ◽  
Subject Area ◽  
Ore Deposits ◽  
Machine Learning Algorithms ◽  
Global Demand ◽  
Ore Grade

Machine learning is a subcategory of artificial intelligence, which aims to make computers capable of solving complex problems without being explicitly programmed. Availability of large datasets, development of effective algorithms, and access to the powerful computers have resulted in the unprecedented success of machine learning in recent years. This powerful tool has been employed in a plethora of science and engineering domains including mining and minerals industry. Considering the ever-increasing global demand for raw materials, complexities of the geological structure of ore deposits, and decreasing ore grade, high-quality and extensive mineralogical information is required. Comprehensive analyses of such invaluable information call for advanced and powerful techniques including machine learning. This paper presents a systematic review of the efforts that have been dedicated to the development of machine learning-based solutions for better utilizing mineralogical data in mining and mineral studies. To that end, we investigate the main reasons behind the superiority of machine learning in the relevant literature, machine learning algorithms that have been deployed, input data, concerned outputs, as well as the general trends in the subject area.

Selective Leaching Nickel from the Pre-Reduced Limonitic Laterite Ore at Atmospheric Pressure

2012 ◽  
Vol 560-561 ◽  
pp. 494-498
Author(s):  
Yong Feng Chang ◽  
Chuan Lin Fan ◽  
Bin Chuan Li ◽  
Xiu Jing Zhai ◽  
Ting An Zhang
Keyword(s):  
Atmospheric Pressure ◽  
Ph Value ◽  
Test Results ◽  
Selective Leaching ◽  
Nickel Extraction ◽  
Extraction Degree ◽  
Leaching Solution ◽  
Novel Method ◽  
Leaching Condition ◽  
Laterite Ore

In this paper a novel method for selective leaching nickel from pre-reduced laterite ore at atmospheric pressure was reported. The reduced calcine was leached in thin acid liquor to liberate the nickel and iron together firstly. By properly controlling the leaching condition, the leached iron ion could hydrolyze as goethite precipitate and regenerate the acid consumed in the leaching procedure. Finally, the nickel is selectively extracted into the leaching solution. The main factors in the leaching process, such as reduction degree of the laterite ore, acidity of the leaching solution were investigated as influence on the nickel extraction. The test results showed that selectively leaching of nickel could be achieved with an extraction degree up to 90% by reducing most of the iron in the lateritic ore to wuestite and controlling the pH value of the leaching solution below 2.5.

scholarly journals Impact of Sodium Hexametaphosphate on the Flotation of Ultrafine Magnesite from Dolomite-Rich Desliming Tailings

Minerals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 499
Author(s):  
Duong Huu Hoang ◽  
Doreen Ebert ◽  
Robert Möckel ◽  
Martin Rudolph
Keyword(s):  
Ultrafine Particles ◽  
Raw Materials ◽  
Low Cost ◽  
Froth Flotation ◽  
Open Circuit ◽  
Ore Deposits ◽  
Sodium Hexametaphosphate ◽  
Low Grade ◽  
Low Contrast ◽  
The Impact

The depletion of ore deposits, the increasing demand for raw materials, the need to process low-grade, complex and finely disseminated ores, and the reprocessing of tailings are challenges especially for froth flotation separation technologies. Even though they are capable of handling relatively fine grain sizes, the flotation separation of very fine and ultrafine particles faces many problems still. Further, the flotation of low-contrast semi-soluble salt-type minerals with very similar surface properties, many complex interactions between minerals, reagents and dissolved species often result in poor selectivity. This study investigates the flotation beneficiation of ultrafine magnesite rich in dolomite from desliming, currently reported to the tailings. The paper especially focuses on the impact of the depressant sodium hexametaphosphate (SHMP) on the following: (i) the froth properties using dynamic froth analysis (DFA), (ii) the separation between magnesite and dolomite/calcite, and (iii) its effect on the entrainment. As a depressant/dispersant, SHMP has a beneficial impact on the flotation separation between magnesite and dolomite. However, there is a trade-off between grade and recovery, and as well as the dewatering process which needs to be considered. When the SHMP increases from 200 g/t to 700 g/t, the magnesite grade increases from 67% to 77%, while recovery decreases massively, from 80% to 40%. The open circuit with four cleaning stages obtained a concentrate assaying 77.5% magnesite at a recovery of 45.5%. The dolomite content in the concentrate is about 20%, where 80% of dolomite was removed and importantly 98% of the quartz was removed, with only 0.3% of the quartz in the final concentrate. Furthermore, the application of 1-hydroxyethylene-1,1-diphosphonic acid (HEDP) as a more environmentally friendly and low-cost alternative to SHMP is presented and discussed. Using only 350 g/t of HEDP can achieve a similar grade (76.3%), like 700 g/t of SHMP (76.9%), while obtaining a 17% higher magnesite recovery as compared to 700 g/t of SHMP. Interestingly, the proportion of hydrophilic quartz minerals ending up in the concentrate is lower for HEDP, with only 1.9% quartz at a recovery of 21.5% compared to the 2.7% of quartz at a recovery of 24.9% when using SHMP. The paper contributes in general to understanding the complexity of the depressant responses in froth flotation.

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