Properties of epoxy-thiokol materials based on the products of the preliminary reaction of thioetherification

In order to improve the adhesive and physical-mechanical properties of epoxy-thiocol compositions cured without heat treatment, we propose to carry out the reaction of interaction between thiokol mercaptan groups and oxirane cycles of epoxy resin at an elevated temperature before introducing a curing agent, and then use the product of this thioetherification reaction for curing at room temperature. The temperature range of the thioetherification reaction (90–1800С) was determined by the method of differential scanning calorimetry. The optimal temperature (1600С) and duration of the preliminary thioetherification reaction (2 hours) were determined, which ensure the maximum level of adhesive strength and physical-mechanical properties. It was shown that composite materials based on the products of the thioetherification reaction significantly outperform analogs based on mechanical mixtures of epoxy resin and thiokol in terms of cohesive and adhesive strength, deformation capacity, fracture work and specific impact strength. The impact resistance and shear strength of adhesive joints are especially significantly increased during the curing of the compositions without external heat supply.

Download Full-text

The Effect of Multilevel Carbon Reinforcements on the Fire Performance, Conductivity, and Mechanical Properties of Epoxy Composites

Polymers ◽

10.3390/polym11020303 ◽

2019 ◽

Vol 11 (2) ◽

pp. 303 ◽

Cited By ~ 4

Author(s):

Andrea Toldy ◽

Gábor Szebényi ◽

Kolos Molnár ◽

Levente Tóth ◽

Balázs Magyar ◽

...

Keyword(s):

Mechanical Properties ◽

Thermal Conductivity ◽

Flame Retardant ◽

Epoxy Resin ◽

Impact Resistance ◽

Fire Performance ◽

Multiwalled Carbon ◽

Peak Heat Release Rate ◽

Flame Retarded ◽

The Impact

We studied the effect of a multilevel presence of carbon-based reinforcements—a combination of conventional load-bearing unidirectional carbon fiber (CF) with multiwalled carbon nanotubes (CNT) and conductive CNT-containing nonwoven carbon nanofabric (CNF(CNT))—on the fire performance, thermal conductivity, and mechanical properties of reference and flame-retarded epoxy resin (EP) composites. The inclusion of carbon fibers and flame retardant reduced the peak heat release rate (pHRR) of the epoxy resins. The extent to which the nanoreinforcements reduced the pHRR depended on their influence on thermal conductivity. Specifically, high thermal conductivity is advantageous at the early stages of degradation, but after ignition it may lead to more intensive degradation and a higher pHRR; especially in the reference samples without flame retardant. The lowest pHRR (130 kW/m2) and self-extinguishing V-0 UL-94 rating was achieved in the flame-retarded composite containing all three levels of carbon reinforcement (EP + CNF(CNT) + CNT + CF FR). The plasticizing effect of the liquid flame retardant impaired both the tensile and flexural properties; however, it significantly enhanced the impact resistance of the epoxy resin and its composites.

Download Full-text

INFLUENCE OF DILUENTS AND PLASTICIZERS ON THE PROPERTIES OF EPOXY-POLYSULFIDE COMPOSITES

Polymer journal ◽

10.15407/polymerj.43.03.172 ◽

2021 ◽

Vol 43 (3) ◽

pp. 172-179

Author(s):

K.M. SUKHYY ◽

◽

A.N. NOSOVA ◽

O.A. BELYANOVSKAYA ◽

I.V. SUKHA ◽

...

Keyword(s):

Epoxy Resin ◽

Adhesive Strength ◽

Elevated Temperatures ◽

Loss Modulus ◽

Glycidyl Ether ◽

Strengthening Effect ◽

Deformation Capacity ◽

Strength And Deformation ◽

Mechanical Mixtures ◽

Specific Impact

It was found that to increase the adhesive and physicomechanical properties of compositions based on epoxy resin and polysulfide rubber (thiokol), cured without heat treatment, it is necessary to carry out a preliminary thioetherification reaction (PRTE) due to the interaction of rubber mercaptan groups and oxirane cycles of epoxy resin at elevated temperatures and then use the product of this reaction to cure at room temperature. Composite materials based on the products of the thioetherification reaction significantly surpass analogs based on mechanical mixtures of epoxy resin and thiokol in terms of cohesive and adhesive strength, deformation capacity, fracture work, and specific impact strength. It is shown that the introduction of both diluents and plasticizers into the products of the preliminary thioetherification reaction of epoxy resins and polysulfide rubbers leads to an increase in the parameters of tensile strength and deformation capacity. The greatest strengthening effect is achieved with the use of oligoesteracrylate MGF-9 and glycidyl ether of diethylene glycol DEG-1, the smallest - with the introduction of the plasticizer EDOS. It was found that the introduction of plasticizers promotes some increase in the adhesive strength, but much less in comparison with the cohesive strength. In this case, the adhesion and cohesive characteristics change antibatically. It has been shown by dynamic mechanical spectrometry that the presence of diluents and plasticizers in epoxy-polysulfide composites leads to a decrease in the temperatures of the maximum values of the tangent of the angle of mechanical losses, loss modulus, the initial and final sections of the transition of the material from the glassy to the highly elastic state, as well as the density of the chemical network in the epoxy matrix.

Download Full-text

Effect of combined drink cans and steel fibers on the impact resistance and mechanical properties of concrete

JOURNAL OF MECHANICAL ENGINEERING AND SCIENCES ◽

10.15282/jmes.14.2.2020.15.0527 ◽

2020 ◽

Vol 14 (2) ◽

pp. 6734-6742

Author(s):

A. Syamsir ◽

S. M. Mubin ◽

N. M. Nor ◽

V. Anggraini ◽

S. Nagappan ◽

...

Keyword(s):

Mechanical Properties ◽

Tensile Strength ◽

Compressive Strength ◽

Reinforced Concrete ◽

Impact Resistance ◽

Fiber Reinforced Concrete ◽

Steel Fibers ◽

Fiber Reinforced ◽

Indirect Tensile ◽

The Impact

This study investigated the combine effect of 0.2 % drink cans and steel fibers with volume fractions of 0%, 0.5%, 1%, 1.5%, 2%, 2.5% and 3% to the mechanical properties and impact resistance of concrete. Hooked-end steel fiber with 30 mm and 0.75 mm length and diameter, respectively was selected for this study. The drinks cans fiber were twisted manually in order to increase friction between fiber and concrete. The results of the experiment showed that the combination of steel fibers and drink cans fibers improved the strength performance of concrete, especially the compressive strength, flexural strength and indirect tensile strength. The results of the experiment showed that the combination of steel fibers and drink cans fibers improved the compressive strength, flexural strength and indirect tensile strength by 2.3, 7, and 2 times as compare to batch 1, respectively. Moreover, the impact resistance of fiber reinforced concrete has increase by 7 times as compared to non-fiber concretes. Moreover, the impact resistance of fiber reinforced concrete consistently gave better results as compared to non-fiber concretes. The fiber reinforced concrete turned more ductile as the dosage of fibers was increased and ductility started to decrease slightly after optimum fiber dosage was reached. It was found that concrete with combination of 2% steel and 0.2% drink cans fibers showed the highest compressive, split tensile, flexural as well as impact strength.

Download Full-text

Effect of SWCNT-Tuball Paper on the Lightning Strike Protection of CFRPs and Their Selected Mechanical Properties

Materials ◽

10.3390/ma14113140 ◽

2021 ◽

Vol 14 (11) ◽

pp. 3140

Author(s):

Kamil Dydek ◽

Anna Boczkowska ◽

Rafał Kozera ◽

Paweł Durałek ◽

Łukasz Sarniak ◽

...

Keyword(s):

Mechanical Properties ◽

Carbon Nanotubes ◽

Electrical Conductivity ◽

Copper Foil ◽

Impact Resistance ◽

Mechanical Analysis ◽

Lightning Strike ◽

Single Wall Carbon Nanotubes ◽

Carbon Fibre Reinforced Polymer ◽

The Impact

The main aim of this work was the investigation of the possibility of replacing the heavy metallic meshes applied onto the composite structure in airplanes for lightning strike protection with a thin film of Tuball single-wall carbon nanotubes in the form of ultra-light, conductive paper. The Tuball paper studied contained 75 wt% or 90 wt% of carbon nanotubes and was applied on the top of carbon fibre reinforced polymer before fabrication of flat panels. First, the electrical conductivity, impact resistance and thermo-mechanical properties of modified laminates were measured and compared with the reference values. Then, flat panels with selected Tuball paper, expanded copper foil and reference panels were fabricated for lightning strike tests. The effectiveness of lightning strike protection was evaluated by using the ultrasonic phased-array technique. It was found that the introduction of Tuball paper on the laminates surface improved both the surface and the volume electrical conductivity by 8800% and 300%, respectively. The impact resistance was tested in two directions, perpendicular and parallel to the carbon fibres, and the values increased by 9.8% and 44%, respectively. The dynamic thermo-mechanical analysis showed higher stiffness and a slight increase in glass transition temperature of the modified laminates. Ultrasonic investigation after lightning strike tests showed that the effectiveness of Tuball paper is comparable to expanded copper foil.

Download Full-text

Effect of toughened polyamide-coated carbon fiber fabric on the mechanical performance and fracture toughness of CFRP

Journal of Composite Materials ◽

10.1177/0021998321999458 ◽

2021 ◽

pp. 002199832199945

Author(s):

Jong H Eun ◽

Bo K Choi ◽

Sun M Sung ◽

Min S Kim ◽

Joon S Lee

Keyword(s):

Mechanical Properties ◽

Fracture Toughness ◽

Photoelectron Spectroscopy ◽

Mechanical Performance ◽

Epoxy Composites ◽

Scanning Calorimetry ◽

Internal Damage ◽

Impact Tests ◽

Flexural Tests ◽

The Impact

In this study, carbon/epoxy composites were manufactured by coating with a polyamide at different weight percentages (5 wt.%, 10 wt.%, 15 wt.%, and 20 wt.%) to improve their impact resistance and fracture toughness. The chemical reaction between the polyamide and epoxy resin were examined by fourier transform infrared spectroscopy, differential scanning calorimetry and X-ray photoelectron spectroscopy. The mechanical properties and fracture toughness of the carbon/epoxy composites were analyzed. The mechanical properties of the carbon/epoxy composites, such as transverse flexural tests, longitudinal flexural tests, and impact tests, were investigated. After the impact tests, an ultrasonic C-scan was performed to reveal the internal damage area. The interlaminar fracture toughness of the carbon/epoxy composites was measured using a mode I test. The critical energy release rates were increased by 77% compared to the virgin carbon/epoxy composites. The surface morphology of the fractured surface was observed. The toughening mechanism of the carbon/epoxy composites was suggested based on the confirmed experimental data.

Download Full-text

Mechanical, Thermal and Rheological Properties of Polyethylene-Based Composites Filled with Micrometric Aluminum Powder

Materials ◽

10.3390/ma13051242 ◽

2020 ◽

Vol 13 (5) ◽

pp. 1242

Author(s):

Olga Mysiukiewicz ◽

Paulina Kosmela ◽

Mateusz Barczewski ◽

Aleksander Hejna

Keyword(s):

Mechanical Properties ◽

Melt Flow Index ◽

Tensile Tests ◽

Mechanical Analysis ◽

Flow Index ◽

Scanning Calorimetry ◽

Metal Composites ◽

Pre Treatment ◽

The Impact ◽

Properties Of Composites

Investigations related to polymer/metal composites are often limited to the analysis of the electrical and thermal conductivity of the materials. The presented study aims to analyze the impact of aluminum (Al) filler content (from 1 to 20 wt%) on the rarely investigated properties of composites based on the high-density polyethylene (HDPE) matrix. The crystalline structure, rheological (melt flow index and oscillatory rheometry), thermal (differential scanning calorimetry), as well as static (tensile tests, hardness, rebound resilience) and dynamic (dynamical mechanical analysis) mechanical properties of composites were investigated. The incorporation of 1 and 2 wt% of aluminum filler resulted in small enhancements of mechanical properties, while loadings of 5 and 10 wt% provided materials with a similar performance to neat HDPE. Such results were supported by the lack of disturbances in the rheological behavior of composites. The presented results indicate that a significant content of aluminum filler may be introduced into the HDPE matrix without additional pre-treatment and does not cause the deterioration of composites’ performance, which should be considered beneficial when engineering PE/metal composites.

Download Full-text

Residual Stresses in Intrinsic UD-CFRP-Steel-Laminates - Experimental Determination, Identification of Sources, Effects and Modification Approaches

Materials Science Forum ◽

10.4028/www.scientific.net/msf.825-826.369 ◽

2015 ◽

Vol 825-826 ◽

pp. 369-376 ◽

Cited By ~ 5

Author(s):

Robert Prussak ◽

Daniel Stefaniak ◽

Christian Hühne ◽

Michael Sinapius

Keyword(s):

Mechanical Properties ◽

Residual Stress ◽

Tensile Strength ◽

Epoxy Composite ◽

Thermal Residual Stress ◽

Fiber Metal Laminates ◽

Fiber Metal ◽

Impact Energies ◽

The Impact ◽

Specific Impact

This paper focuses on the reduction of process-related thermal residual stress in fiber metal laminates and its impact on the mechanical properties. Different modifications during fabrication of co-cure bonded steel/carbon epoxy composite hybrid structures were investigated. Specific examinations are conducted on UD-CFRP-Steel specimens, modifying temperature, pressure or using a thermal expansion clamp during manufacturing. The impact of these parameters is then measured on the deflection of asymmetrical specimens or due yield-strength measurements of symmetrical specimens. The tensile strength is recorded to investigate the effect of thermal residual stress on the mechanical properties. Impact tests are performed to determine the influence on resulting damage areas at specific impact energies. The experiments revealed that the investigated modifications during processing of UD-CFRP-Steel specimens can significantly lower the thermal residual stress and thereby improve the tensile strength.

Download Full-text

Effect of Secondary Carbon Nanofillers on the Electrical, Thermal, and Mechanical Properties of Conductive Hybrid Composites Based on Epoxy Resin and Graphite

Materials ◽

10.3390/ma14154169 ◽

2021 ◽

Vol 14 (15) ◽

pp. 4169

Author(s):

Marcel Zambrzycki ◽

Krystian Sokolowski ◽

Maciej Gubernat ◽

Aneta Fraczek-Szczypta

Keyword(s):

Mechanical Properties ◽

Specific Surface ◽

Epoxy Resin ◽

Surface Area ◽

Specific Surface Area ◽

Hybrid Composites ◽

Department Of Energy ◽

Carbon Nanofillers ◽

The Impact ◽

Secondary Carbon

In this work, we present a comparative study of the impact of secondary carbon nanofillers on the electrical and thermal conductivity, thermal stability, and mechanical properties of hybrid conductive polymer composites (CPC) based on high loadings of synthetic graphite and epoxy resin. Two different carbon nanofillers were chosen for the investigation—low-cost multi-layered graphene nanoplatelets (GN) and carbon black (CB), which were aimed at improving the overall performance of composites. The samples were obtained by a simple, inexpensive, and effective compression molding technique, and were investigated by the means of, i.a., scanning electron microscopy, Raman spectroscopy, electrical conductivity measurements, laser flash analysis, and thermogravimetry. The tests performed revealed that, due to the exceptional electronic transport properties of GN, its relatively low specific surface area, good aspect ratio, and nanometric sizes of particles, a notable improvement in the overall characteristics of the composites (best results for 4 wt % of GN; σ = 266.7 S cm−1; λ = 40.6 W mK−1; fl. strength = 40.1 MPa). In turn, the addition of CB resulted in a limited improvement in mechanical properties, and a deterioration in electrical and thermal properties, mainly due to the too high specific surface area of this nanofiller. The results obtained were compared with US Department of Energy recommendations regarding properties of materials for bipolar plates in fuel cells. As shown, the materials developed significantly exceed the recommended values of the majority of the most important parameters, indicating high potential application of the composites obtained.

Download Full-text

Phase Morphology, Thermal and Mechanical Properties of Compatibilized Nylon12/Natural Rubber Blends Using PS/MNR

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.844.53 ◽

2013 ◽

Vol 844 ◽

pp. 53-56

Author(s):

Saravalee Saengthaveep ◽

Sadhan C. Jana ◽

Rathanawan Magaraphan

Keyword(s):

Mechanical Properties ◽

Natural Rubber ◽

Moisture Absorption ◽

Rubber Particle ◽

Impact Resistance ◽

Phase Morphology ◽

Thermal And Mechanical Properties ◽

Binary Blend ◽

Polyamide 12 ◽

The Impact

To produce a tough material for application demanding high impact resistance and low moisture absorption, melt blending of Nylon12 (Polyamide 12, PA12) and natural rubber (NR) was carried out in a brabender plasticorder at 210 °C with rotor speed of 70 rpm in the presence of polystyrene/maleated natural rubber (PS/MNR) blend as a compatibilizer. The effect of compatibilizer content (1, 3, 5, 7 and 10 phr) on phase morphology, thermal, and mechanical properties of [Nylon12/NR]/[PS/MNR] blends was investigated by using SEM, DSC, and Izod impact tester, respectively. The result revealed that PS/MNR blend improved the compatibility of Nylon12/NR blends efficiently due to the presence of amide linkage at the interfaces from the reaction between the reactive groups of MNR and the NH2 end groups of Nylon12 during mixing. A fine phase morphology (good dispersion and small dispersed phase size of NR domains in Nylon12 matrix) of [Nylon12/NR]/[PS/MNR] blends was observed at the optimum compatibilizer content of 7 phr, relating to the improvement of mechanical property. The impact energy of [Nylon12/NR]/[PS/MNR] blends was 503 J/m higher than that of neat Nylon12 (115 J/m) and Nylon12/NR binary blend (241 J/m) due to the toughening effect of rubber and proper morphology. The melting temperature of all blends did not change obviously from thermal analysis. However, the presence of rubber particle obstructed the crystallization of Nylon12 phase, leading to the decreasing of %crystallinity from 93% to around 70%.

Download Full-text

Influence of Polyurea Composite Coating on Selected Mechanical Properties of AISI 304 Steel

Materials ◽

10.3390/ma12193137 ◽

2019 ◽

Vol 12 (19) ◽

pp. 3137 ◽

Cited By ~ 3

Author(s):

Monika Duda ◽

Joanna Pach ◽

Grzegorz Lesiuk

Keyword(s):

Mechanical Properties ◽

Epoxy Resin ◽

Composite Coating ◽

Composite Coatings ◽

Glass Fabric ◽

Coated Sample ◽

Hemp Fiber ◽

Aisi 304 ◽

Aisi 304 Steel ◽

The Impact

This paper contains experimental results of mechanical testing of the AISI 304 steel with composite coatings. The main goal was to investigate the impact of the applied polyurea composite coating on selected mechanical properties: Adhesion, impact resistance, static behavior, and, finally, fatigue lifetime of notched specimens. In the paper the following configurations of coatings were tested: EP (epoxy resin), EP_GF (epoxy resin + glass fabric), EP_GF_HF (epoxy resin + glass fabric hemp fiber), EP_PUA (epoxy resin + polyurea) resin, EP_GF_PUA (epoxy resin + glass fabric + polyurea) resin, and EP_GF_HF_PUA (epoxy resin + glass fabric + hemp fiber + polyurea) resin. The highest value of force required to break adhesive bonds was observed for the EP_PUA coating, the smallest for the single EP coating. A tendency of polyurea to increase the adhesion of the coating to the base was noticed. The largest area of delamination during the impact test was observed for the EP_GF_HF coating and the smallest for the EP-coated sample. In all tested samples, observed delamination damage during the pull-off test was located between the coating and the metallic base of the sample.

Download Full-text