scholarly journals Medical Peat Waste Upcycling to Carbonized Solid Fuel in the Torrefaction Process

Energies ◽  
2021 ◽  
Vol 14 (19) ◽  
pp. 6053
Author(s):  
Kacper Świechowski ◽  
Małgorzata Leśniak ◽  
Andrzej Białowiec
Keyword(s):  
Solid Fuel ◽  
Waste Incineration ◽  
Reaction Rates ◽  
Scanning Calorimetry ◽  
Exponential Factor ◽  
Heating Value ◽  
High Heating Value ◽  
Theoretical Mass ◽  
Main Decomposition ◽  
Local Law

Peat is the main type of peloid used in Polish cosmetic/healing spa facilities. Depending on treatment and origin, peat waste can be contaminated microbiologically, and as a result, it must be incinerated in medical waste incineration plants without energy recovery (local law). Such a situation leads to peat waste management costs increase. Therefore, in this work, we checked the possibility of peat waste upcycling to carbonized solid fuel (CSF) using torrefaction. Torrefaction is a thermal treatment process that removes microbiological contamination and improves the fuel properties of peat waste. In this work, the torrefaction conditions (temperature and time) on CSF quality were tested. Parallelly, peat decomposition kinetics using TGA and torrefaction kinetics with lifetime prediction using macro-TGA were determined. Furthermore, torrefaction theoretical mass and energy balance were determined. The results were compared with reference material (wood), and as a result, obtained data can be used to adjust currently used wood torrefaction technologies for peat torrefaction. The results show that torrefaction improves the high heating value of peat waste from 19.0 to 21.3 MJ × kg−1, peat main decomposition takes place at 200–550 °C following second reaction order (n = 2), with an activation energy of 33.34 kJ × mol−1, and pre-exponential factor of 4.40 × 10−1 s−1. Moreover, differential scanning calorimetry analysis revealed that peat torrefaction required slightly more energy than wood torrefaction, and macro-TGA showed that peat torrefaction has lower torrefaction constant reaction rates (k) than wood 1.05 × 10−5–3.15 × 10−5 vs. 1.43 × 10−5–7.25 × 10−5 s−1.

Producing a high heating value and weather resistant solid fuel via briquetting of blended wood residues and thermoplastics

Fuel ◽  
2021 ◽  
Vol 283 ◽  
pp. 119263
Author(s):  
Bing Song ◽  
Martin Cooke-Willis ◽  
Beatrix Theobald ◽  
Peter Hall
Keyword(s):  
Solid Fuel ◽  
Heating Value ◽  
High Heating Value ◽  
Wood Residues ◽  
High Heating

scholarly journals Densification and Combustion of Cherry Stones

Energies ◽  
2019 ◽  
Vol 12 (16) ◽  
pp. 3042 ◽  
Author(s):  
Magdalena Dołżyńska ◽  
Sławomir Obidziński ◽  
Małgorzata Kowczyk-Sadowy ◽  
Małgorzata Krasowska
Keyword(s):  
Solid Fuel ◽  
Exhaust Gas ◽  
Power Demand ◽  
Wood Pellets ◽  
Heating Value ◽  
Agglomeration Process ◽  
High Heating Value ◽  
High Heating ◽  
Fuel Mixtures ◽  
Power Installations

The aim of the presented research was to determine the suitability of cherry stones as a solid fuel. Mixtures of cherry stones with the addition of 10%, 15%, and 20% rye bran as a binder were subjected to the pressure agglomeration process in a rotary matrix working system (170, 220, and 270 rpm). The density of pellets, their kinetic durability, and power demand of the granulator’s device for each mix were determined. The highest quality was characterized by pellets containing 20% rye bran, which were combusted in a 25 kW boiler with a retort grate. The concentration of CO, CO2, NO, SO2, HCl, and O2 in the exhaust gas was tested. On the basis of the results of combustion, high heating value (HHV), low heating value (LHV), and elemental analysis, it was found that pellets from cherry stones with the addition of rye bran can serve as a substitute for wood pellets in low-power installations.

scholarly journals Potential of Biochar Derived from Agricultural Residues for Sustainable Management

2021 ◽  
Vol 13 (15) ◽  
pp. 8147
Author(s):  
Sasiwimol Khawkomol ◽  
Rattikan Neamchan ◽  
Thunchanok Thongsamer ◽  
Soydoa Vinitnantharat ◽  
Boonma Panpradit ◽  
...  
Keyword(s):  
Chemical Properties ◽  
Agricultural Residues ◽  
Hydroxyl Groups ◽  
Asian Countries ◽  
Heating Value ◽  
Coconut Husk ◽  
High Heating Value ◽  
Horizontal Drum ◽  
Physical And Chemical ◽  
And Chemical Properties

A horizontal drum kiln is a traditional method widely used in Southeast Asian countries for producing biochar. An understanding of temperature conditions in the kiln and its influence on biochar properties is crucial for identifying suitable biochar applications. In this study, four agricultural residues (corncob, coconut husk, coconut shell, and rice straw) were used for drum kiln biochar production. The agricultural residues were turned into biochar within 100–200 min, depending on their structures. The suitability of biochar for briquette fuels was analyzed using proximate, ultimate, and elemental analysis. The biochar’s physical and chemical properties were characterized via bulk density, iodine number, pHpzc, SEM, and FTIR measurements. All biochars had low O/C and H/C ratios and negative charge from both carbonyl and hydroxyl groups. Coconut husk and shell biochar had desirable properties such as high heating value and a high amount of surface functional groups which can interact with nutrients in soil. These biochars are thus suitable for use for a variety of purposes including as biofuels, adsorbents, and as soil amendments.

scholarly journals Biochar and Energy Production: Valorizing Swine Manure through Coupling Co-Digestion and Pyrolysis

2020 ◽  
Vol 6 (2) ◽  
pp. 43 ◽  
Author(s):  
Rubén González ◽  
Judith González ◽  
José G. Rosas ◽  
Richard Smith ◽  
Xiomar Gómez
Keyword(s):  
Anaerobic Digestion ◽  
Waste Treatment ◽  
Wide Spectrum ◽  
Swine Manure ◽  
Solid Content ◽  
Electricity Production ◽  
Plant Design ◽  
Heating Value ◽  
High Heating Value ◽  
Bio Oil

Anaerobic digestion is an established technological option for the treatment of agricultural residues and livestock wastes beneficially producing renewable energy and digestate as biofertilizer. This technology also has significant potential for becoming an essential component of biorefineries for valorizing lignocellulosic biomass due to its great versatility in assimilating a wide spectrum of carbonaceous materials. The integration of anaerobic digestion and pyrolysis of its digestates for enhanced waste treatment was studied. A theoretical analysis was performed for three scenarios based on the thermal needs of the process: The treatment of swine manure (scenario 1), co-digestion with crop wastes (scenario 2), and addition of residual glycerine (scenario 3). The selected plant design basis was to produce biochar and electricity via combined heat and power units. For electricity production, the best performing scenario was scenario 3 (producing three times more electricity than scenario 1), with scenario 2 resulting in the highest production of biochar (double the biochar production and 1.7 times more electricity than scenario 1), but being highly penalized by the great thermal demand associated with digestate dewatering. Sensitivity analysis was performed using a central composite design, predominantly to evaluate the bio-oil yield and its high heating value, as well as digestate dewatering. Results demonstrated the effect of these parameters on electricity production and on the global thermal demand of the plant. The main significant factor was the solid content attained in the dewatering process, which excessively penalized the global process for values lower than 25% TS.

scholarly journals Prediction of regional agro-industrial wastes characteristics by thermogravimetric analysis to obtain bioenergy using thermal process

2018 ◽  
Vol 37 (1) ◽  
pp. 544-557 ◽  
Author(s):  
Alejandra Saffe ◽  
Anabel Fernandez ◽  
Germán Mazza ◽  
Rosa Rodriguez
Keyword(s):  
Thermogravimetric Analysis ◽  
Analysis Data ◽  
Proximate Analysis ◽  
Industrial Wastes ◽  
Heating Value ◽  
Application Range ◽  
High Heating Value ◽  
One Step ◽  
Standard Techniques

The use of energy from biomass is becoming more common worldwide. This energy source has several benefits that promote its acceptance; it is bio-renewable, non-toxic and biodegradable. To predict its behavior as a fuel during thermal treatment, its characterization is necessary. The experimental determination of ultimate analysis data requires special instrumentation, while proximate analysis data can be obtained easily by using common equipment but, the required time is high. In this work, a methodology is applied based on thermogravimetric analysis, curves deconvolution and empirical correlations for characterizing different regional agro-industrial wastes to determine the high heating value, the contents of moisture, volatiles matter, fixed carbon, ash, carbon, hydrogen, oxygen, lignin, cellulose and hemicellulose. The obtained results are similar to those using standard techniques, showing the accuracy of proposed method and its wide application range. This methodology allows to determine the main parameters required for industrial operation in only in one step, saving time.

scholarly journals Assessment of Renewable Alternatives to Coal, Based on Their High Heating Value and Global Warming Potential

2021 ◽  
pp. 19-23
Author(s):  
V. Dhivakhar ◽  
Maju Varghese ◽  
Keerthi M. S. ◽  
S. Kaviya
Keyword(s):  
Global Warming ◽  
Global Warming Potential ◽  
Power Plants ◽  
Thermal Power ◽  
Thermal Power Plants ◽  
Major Contributor ◽  
Heating Value ◽  
High Heating Value ◽  
Green House Gas ◽  
High Heating

About 40% of the Global Electricity produced is fuelled by coal. Although Coal has various advantages like good High Heating Value, easy availability etc., it also has various disadvantages. Green House Gas Released from Coal Thermal Power Plants is the single major contributor to Global warming. Coal is also nonrenewable. Hence it is important to analyze the viability of potential alternatives and reduce the usage of coal. In this assessment, various potential replacements of coal have been analyzed based on their High heating value (HHV) and their Global Warming Potential. The Global warming Potential (GWP) of the assessed fuels have been calculated by the Respiratory Quotient (RQ) Factor method. Hence a direct comparison between Coal and other replacements based on their HHV and GWP has been performed.

scholarly journals Potensi Penerapan Energi Terbarukan Sebagai Upaya Mewujudkan Kemandirian Desa: Studi Kasus Desa Lendang Nangka Lombok Timur

2021 ◽  
Vol 13 (1) ◽  
pp. 1-10
Author(s):  
Shafwan Amrullah
Keyword(s):  
Air Flow ◽  
Heating Value ◽  
High Heating Value ◽  
High Heating

Desa saat ini didorong menjadi desa mandiri, baik dalam bidang energi maupun ekonomi dengan mengimplementasikan energi terbarukan untuk meningkatkan kemandirian energi sebagai salah satu langkah meningkatkan ekonomi masyarakat. Penelitian ini bertujuan untuk menganalisis potensi penggunaan energi terbarukan seperti Pembangkit Listrik Tenaga Bayu (PLTB), Pembangkit Listrik Tenaga Surya (PLTS), Pembangkit Listrik Tenaga Air (PLTA), dan Konversi Energi Gasifikasi di desa Lendang Nangka, Kabupaten Lombok Timur. Penelitian dilakukan dengan pengumpulan data baik dari BMKG dan pengujian secara langsung menggunakan alat Air Flow Anemometer GM8902 untuk mengetahui kecepatan angin dan DIGITAL TECHNOMETER LX-1010B untuk mengetahui intensitas cahaya matahari. Selain itu dilakukan wawancara kepada pengusaha kecil dan menengah untuk mengetahui penggunaan energi dalam menyokong proses produksinya. Hasil dari penelitian menunjukkan bahwa potensi PLTB yang dapat diemplementasikan adalah PLTB sekala kecil dengan daya sekitar 23,4-632,88 kWh/turbin. Untuk potensi PLTS menghasilkan daya sebesar 410-566 kWh per meter persegi panel surya. Untuk potensi PLTA, turbin yang cocok adalah turbin ukuran kecil dengan potensi daya sekitar 0,3024-2,2194 kWh. Sedangkan untuk potensi penggunaan converter energi jenis gasifikasi dapat dilakukan untuk mengurangi penggunaan bahan bakar tidak terbarukan sekaligus menghemat biaya porduksi. Sebab, nilai High Heating Value gas sintetik yang dihasilkan 1,7 kali lebih besar daripada pembakaran langsung dengan kayu.

scholarly journals Hydrothermal Carbonization Brewer’s Spent Grains with the Focus on Improving the Degradation of the Feedstock

Energies ◽  
2018 ◽  
Vol 11 (11) ◽  
pp. 3226 ◽  
Author(s):  
Pablo Arauzo ◽  
Maciej Olszewski ◽  
Andrea Kruse
Keyword(s):  
Water Content ◽  
Liquid Product ◽  
Reaction Times ◽  
Hydrothermal Carbonization ◽  
Heating Value ◽  
High Heating Value ◽  
Acid Addition ◽  
Spent Grains ◽  
Different Temperatures ◽  
Higher Temperature

Hydrochar is a very interesting product from agricultural and food production residues. Unfortunately, severe conditions for complete conversion of lignocellulosic biomass is necessary, especially compared to the conversion of sugar compounds. The goal of this work is to improve the conversion of internal carbohydrates by application of a two-steps process, by acid addition and slightly higher water content. A set of experiments at different temperatures (180, 200, and 220 °C), reaction times (2 and 4 h), and moisture contents (80% and 90%) was performed to characterize the solid (high heating value (HHV), elemental) and liquid product phase. Afterwards, acid addition for a catalyzed hydrolysis reaction during hydrothermal carbonization (HTC) and a two-steps reaction (180 and 220 °C) were tested. As expected, a higher temperature leads to higher C content of the hydrochar and a higher fixed carbon (FC) content. The same effect was found with the addition of acids at lower temperatures. In the two-steps reaction, a primary hydrolysis step increases the conversion of internal carbohydrates. Higher water content has no significant effect, except for increasing the solubility of ash components.

scholarly journals Estimation of fuel potential of faecal sludge in a water scarce city, a case study of Jaipur Urban, India

2020 ◽  
Vol 15 (2) ◽  
pp. 506-514
Author(s):  
Niharika Sharma ◽  
Sagar Gupta ◽  
Anil Dutt Vyas
Keyword(s):  
Heating Value ◽  
High Heating Value ◽  
Rural And Urban ◽  
Urban Level ◽  
Water Scarce ◽  
Sanitation Systems ◽  
The City ◽  
Different Sources ◽  
Faecal Sludge

Abstract Non-sewer sanitation systems are widely implemented for treatment and management of faecal sludge (FS) and septage in developing nations. India became an open defecation free (ODF) country in 2019, with more than 90 million toilets at rural and urban level constructed to achieve this ODF status. Government of India also initiated a faecal sludge and septage management (FSSM) policy in 2017. This paper highlights the policy vision for the state of Rajasthan and predicts options for a safely managed sanitation system through exploring the fuel potential of faecal sludge generated in the city. The intended study is an attempt to valorize faecal sludge into a marketable product through determining the heat capacity of dried faecal sludge from different sources such as pit toilets, septic tanks etc. In the present work in urban Jaipur, which is already a water scarce city, various onsite sanitation systems were targeted to collect FS samples from different locations. It was observed that the FS generated has a high heating value of 13.96 MJ/kg, with total solids ranges from 7 to 9%. For a pragmatic resource recovery option, the experimental data observed is validated with a literature review.

scholarly journals Curing Kinetic Parameters of Epoxy Composite Reinforced with Mallow Fibers

Materials ◽  
2019 ◽  
Vol 12 (23) ◽  
pp. 3939 ◽  
Author(s):  
Lucio Fabio Cassiano Nascimento ◽  
Fernanda Santos da Luz ◽  
Ulisses Oliveira Costa ◽  
Fábio de Oliveira Braga ◽  
Édio Pereira Lima Júnior ◽  
...  
Keyword(s):  
Kinetic Parameters ◽  
Industrial Process ◽  
Diglycidyl Ether ◽  
Response Surfaces ◽  
Heating Rates ◽  
Scanning Calorimetry ◽  
Exponential Factor ◽  
Curing Kinetic ◽  
Technological Tool

Knowledge about the curing behavior of a thermosetting resin and its composites includes the determination of kinetic parameters and constitutes an important scientific and technological tool for industrial process optimization. In the present work, the differential scanning calorimetry (DSC) technique was used to determine several curing parameters for pure epoxy and its composite reinforced with 20 vol % mallow fibers. Analyses were performed with heating rates of 5, 7.5, and 10 °C/min, as per the ASTM E698 standard. The kinetic related parameters, that is, activation energy (E), Avrami’s pre-exponential factor (Z), and mean time to reach 50% cure (t½), were obtained for the materials, at temperatures ranging from 25 to 100 °C. Response surfaces based on the mathematical relationship between reaction time, transformed fraction, and temperature were provided for optimization purposes. The results showed that the average curing time used for the production of diglycidyl ether of bisphenol A/triethylenetetramine (DGEBA/TETA) epoxy systems or their composites reinforced with natural mallow fibers can be considerably reduced as the temperature is increased up to a certain limit.

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