scholarly journals Potential Bio-Fuel from Refinery Waste through Anaerobic Digestion

2022 ◽  
Vol 12 (1) ◽  
pp. 68
Author(s):  
Sophia Nawaz Gishkori ◽  
Ghulam Abbas ◽  
Aqeel Ahmad Shah ◽  
Sajjad Ur Rahman ◽  
Muhammad Salman Haider ◽  
...  
Keyword(s):  
Elemental Analysis ◽  
Calorific Value ◽  
Volatile Matter ◽  
Proximate Analysis ◽  
Oil Refinery ◽  
Degradation Behavior ◽  
Heating Value ◽  
Percentage Composition ◽  
Thermogravimetric Analyzer ◽  
Thermal Degradation Behavior

In this study we report biofuel potential in waste cake obtained from oil refinery. The sample was analyzed for its calorific value using auto bomb calorimeter (LECO AC-500), proximate analysis using Thermogravimetric analyzer (LECO 701) and elemental analysis using CHNS analyzer (LECO Tru-Spec). The elemental analysis of dry waste cake vs wet cake depicted the percentage composition of carbon (49.8%, 40.8%), hydrogen (7.9%, 6.0%), nitrogen (2.8%, 1.9%), Sulphur (1.9%, 0.5%) and oxygen content (37.6%, 40.4%). As for as the thermal degradation behavior of dry and wet cake in TGA is concerned, higher moisture contents (68.50%) found in wet cake and lower in dry cake (40.1%). Whereas the volatile matter in dry cake (30.9%) and low volatile in wet cake (14.3%). Similarly, %age of ash become high in dry cake (17.3%) and low in wet cake (5.11%). The results reflected that higher heating value of dry waste cake is higher (22.5 MJ/kg) than wet waste cake (20.5 MJ/kg) and commonly used sugarcane bagasse (17.88 MJ/kg).

Evaluasi Prediksi Higher Heating Value (HHV) Biomassa Berdasarkan Analisis Proksimat

2020 ◽  
Vol 4 (1) ◽  
pp. 1-7
Author(s):  
Made Dirgantara ◽  
Karelius Karelius ◽  
Marselin Devi Ariyanti, Sry Ayu K. Tamba
Keyword(s):  
Renewable Energy ◽  
Natural Gas ◽  
Key Words ◽  
Critical Analysis ◽  
Fossil Fuels ◽  
Calorific Value ◽  
Proximate Analysis ◽  
Heating Value ◽  
Bomb Calorimeter ◽  
Hhv Prediction

Abstrak – Biomassa merupakan salah satu energi terbarukan yang sangat mudah ditemui, ramah lingkungan dan cukup ekonomis. Keberadaan biomassa dapat dimaanfaatkan sebagai pengganti bahan bakar fosil, baik itu minyak bumi, gas alam maupun batu bara. Analisi diperlukan sebagai dasar biomassa sebagai energi seperti proksimat dan kalor. Analisis terpenting untuk menilai biomassa sebagai bahan bakar adalah nilai kalori atau higher heating value (HHV). HHV secara eksperimen diukur menggunakan bomb calorimeter, namun pengukuran ini kurang efektif, karena memerlukan waktu serta biaya yang tinggi. Penelitian mengenai prediksi HHV berdasarkan analisis proksimat telah dilakukan sehingga dapat mempermudah dan menghemat biaya yang diperlukan peneliti. Dalam makalah ini dibahas evaluasi persamaan untuk memprediksi HHV berdasarkan analisis proksimat pada biomassa berdasarkan data dari penelitian sebelumnya. Prediksi nilai HHV menggunakan lima persamaan yang dievaluasi dengan 25 data proksimat biomassa dari penelitian sebelumnya, kemudian dibandingkan berdasarkan nilai error untuk mendapatkan prediksi terbaik. Hasil analisis menunjukan, persamaan A terbaik di 7 biomassa, B di 6 biomassa, C di 6 biomassa, D di 5 biomassa dan E di 1 biomassa.Kata kunci: bahan bakar, biomassa, higher heating value, nilai error, proksimat  Abstract – Biomass is a renewable energy that is very easy to find, environmentally friendly, and quite economical. The existence of biomass can be used as a substitute for fossil fuels, both oil, natural gas, and coal. Analyzes are needed as a basis for biomass as energy such as proximate and heat. The most critical analysis to assess biomass as fuel is the calorific value or higher heating value (HHV). HHV is experimentally measured using a bomb calorimeter, but this measurement is less effective because it requires time and high costs. Research on the prediction of HHV based on proximate analysis has been carried out so that it can simplify and save costs needed by researchers. In this paper, the evaluation of equations is discussed to predict HHV based on proximate analysis on biomass-based on data from previous studies. HHV prediction values using five equations were evaluated with 25 proximate biomass data from previous studies, then compared based on error value to get the best predictions. The analysis shows that Equation A predicts best in 7 biomass, B in 6 biomass, C in 6 biomass, D in 5 biomass, and E in 1 biomass. Key words: fuel, biomass, higher heating value, error value, proximate 

scholarly journals Characteristics of Woody Cutting Waste Briquette with Paper Waste Pulp as Binder

2020 ◽  
Vol 190 ◽  
pp. 00030
Author(s):  
Qurrotin Ayunina Maulida Okta Arifianti ◽  
Azmi Alvian Gabriel ◽  
Syarif Hidayatulloh ◽  
Kuntum Khoiro Ummatin
Keyword(s):  
Moisture Content ◽  
Ignition Time ◽  
Combustion Process ◽  
Calorific Value ◽  
Volatile Matter ◽  
Proximate Analysis ◽  
Hydraulic Press ◽  
Combustion Characteristic ◽  
Paper Waste ◽  
Iron Mold

The current research aimed to increase the calorific value of woody cutting waste briquette with paper waste pulp as binder. There were three different binder variation used in this study, they are 5 %, 10 %, and 15 %. To create a briquette, a cylindrical iron mold with diameter of 3.5 cm and height of 3 cm and a hydraulic press with 2 t power were applied. The physical characteristics of the combination woody waste briquette and paper waste pulp, such as moisture content, ash content, volatile matter and carbon fix were examined using proximate analysis. The calorific value of briquetted fuel was tested by bomb calorimeter. The combustion test was performed to determine the combustion characteristic of briquettes, for example initial ignition time, temperature distribution, and combustion process duration. The general result shows that the calorific value of briquette stood in the range of 4 876 kCal kg–1 to 4 993 kCal kg–1. The maximum moisture content of briquette was 5.32 %. The longest burning time was 105 min.

scholarly journals Studies on Thermal Degradation Behavior of Siliceous Agriculture Waste (Rice Husk, Wheat Husk and Bagasse)

2015 ◽  
Vol 17 (3) ◽  
pp. 47-51 ◽  
Author(s):  
Syed H. Javed ◽  
Umair Aslam ◽  
Mohsin Kazmi ◽  
Masooma Rustam ◽  
Sheema Riaz ◽  
...  
Keyword(s):  
Thermal Degradation ◽  
Rice Husk ◽  
Acid Treatment ◽  
Proximate Analysis ◽  
Degradation Behavior ◽  
Agriculture Waste ◽  
Pure Silica ◽  
Thermal Degradation Behavior ◽  
Residual Weight ◽  
Wheat Husk

Abstract Various siliceous agriculture waste (SAW) such as rice husk, wheat husk and bagasse have been investigated to study their thermal degradation behavior using Thermogravimetric Analyzer (TGA) technique. The focus of this research is to conduct TGA of raw and acid treated (20% HCl & 1M H2SO4) SAW at heating rate 10°C/min in the atmosphere of nitrogen. The results were analyzed on the basis of thermograms and it was inferred that 24 hours soaking with 20% HCl prior to thermal degradation enhanced the percent weight loss. The process also improved the percentage of residual weight of SAW indicating the extraction of amorphous silica with increased purity. The effect of acid treatment was verified by determining chemical composition of SAW samples before and after soaking with 20% HCl. Proximate analysis, thermal degradation temperature ranges and percentage of residual weight at 800°C for each of rice husk, wheat husk and bagasse were also quantified to observe the thermal degradation behavior. XRF analysis was performed to observe the effect of acid treatment for extraction of pure silica.

Fuel Property of Pyrolytic-Oil from Para Rubber De-Oiled Seed Residue

2015 ◽  
Vol 781 ◽  
pp. 643-646
Author(s):  
Tanakorn Unpinit ◽  
Mallika Thabuot
Keyword(s):  
Maximum Yield ◽  
Degradation Behavior ◽  
Fuel Property ◽  
Heating Value ◽  
Bio Oil ◽  
Thermal Degradation Behavior ◽  
Clay Catalyst ◽  
Pyrolytic Oil ◽  
Loss Characteristic ◽  
Major Hydrocarbon

In this report, bio-oil was produced from the pyrolysis of Para Rubber de-oiled seed residue mixing with clay catalyst of 5-20%wt. under 400 to 600°C. Pyrolytic oil was determined for the thermal weight loss characteristic, heating value, structural and physical properties. Results showed the yield of pyrolytic oil increased with the increasing catalyst percentage, maximum yield of 24.59%wt. was revealed from the pyrolysis at 550°C. Using clay catalyst of 5%wt. at 400°C gave bio-oil with the highest heating value up to 49.17 MJ/kg. While pyrolytic oil which obtained from the mixture of de-oiled seed residue and 10%wt. clay at 400°C showed the thermal degradation behavior in the range of diesel and gasoline. All pyrolytic oils produced in this study have the major hydrocarbon structure of C-H stretching as investigated by FTIR. However, this product should be upgraded to get better properties closed to the commercial fuel.

Geochemical Characteristics and Comprehensive Utilization of the Main Coal Seams in Wubu Mining Area, Northern Shaanxi Province

2013 ◽  
Vol 734-737 ◽  
pp. 755-758
Author(s):  
Zhi Xue Li ◽  
Ming Pei Li ◽  
Long Yi Shao
Keyword(s):  
Elemental Analysis ◽  
Chemical Properties ◽  
Calorific Value ◽  
Mining Area ◽  
Proximate Analysis ◽  
Shaanxi Province ◽  
Coal Seams ◽  
Comprehensive Utilization ◽  
Coal Analysis ◽  
Northern Shaanxi

Use a variety of coal analysis methods on the Wubu mining area main coal seams S1 and T1 in proximate analysis, elemental analysis, and technologic property analysis, the results show that the main coal seams is a kind of medium ash, medium volatile coal, especially low-medium sulfur, high calorific value coal. They have a good chemical properties and technologic properties, and can be used for coking, civilian, steam coal.

scholarly journals PENGARUH SUHU DAN KONSENTRASI PEREKAT TERHADAP KARAKTERISTIK BRIKET BIOARANG BERBAHAN BAKU TANDAN KOSONG KELAPA SAWIT DENGAN PROSES PIROLISIS

Konversi ◽  
2015 ◽  
Vol 4 (2) ◽  
pp. 16
Author(s):  
Yuli Ristianingsih ◽  
Ayuning Ulfa ◽  
Rachmi Syafitri K.S
Keyword(s):  
Solid Waste ◽  
Palm Oil ◽  
Calorific Value ◽  
Volatile Matter ◽  
Ash Content ◽  
Crude Palm Oil ◽  
Fixed Carbon ◽  
Heating Value ◽  
Empty Fruit Bunches ◽  
Rate Of Combustion

Abstrak-Tandan Kosong Kelapa Sawit merupakan limbah padat hasil produksi Crude Palm Oil (CPO). Setiap 1(satu) ton tandan buah segar dihasilkan 23% limbah padat. Limbah padat ini dapat di konversi menjadi bahan bakar pengganti minyak yaitu briket. Briket bioarang adalah bahan bakar padat yang dapat digunakan sebagai bahan bakar alternatif pengganti bahan bakar yang berasal dari fosil seperti minyak dan gas. Penelitian ini bertujuan untuk mengetahui pengaruh suhu pirolisis terhadap yield bioarang yang dihasilkan dan mengetahui pengaruh konsentrasi perekat kanji (5% w/w, 10% w/w, 15% w/w) terhadap karakteristik briket hasil penelitian (kadar air, volatile matter, kadar abu, fixed carbon, nilai kalor dan laju pembakaran). Penelitian dilakukan dengan metode pirolisis yaitu proses pembakaran bahan baku dalam reaktor pirolisis dengan menggunakan suhu yang tinggi dan tanpa atau dengan sedikit oksigen. Pirolisis dilakukan selama 2,5 jam dengan variasi suhu yaitu 350°C, 400°C, 450°C dan 500°C. Arang yang dihasilkan dicampur dengan perekat sesuai variasi dan dicetak menjadi briket. Briket kemudian dianalisa kadar air, kadar abu, kadar karbon, kadar zat terbang, nilai kalor dan laju pembakaran. Briket dengan yield tertinggi terdapat pada suhu 350°C sebesar 51,53% dan yield terendah pada suhu 500°C sebesar 26,03%. Briket hasil penelitian ini telah memenuhi standar mutu briket sebagai bahan bakar dilihat dari nilai kalor. Komposisi optimal antara perekat kanji dan arang TKKS hasil pirolisis yaitu pada 5%:95% yang menghasilkan nilai kalor terbesar yaitu 6748,15kal/g.  Kata kunci : Briket Bioarang, Pirolisis, Tandan Kosong Kelapa Sawit                Abstract-Palm Oil Empty Fruit Bunches are solid waste from Crude Palm Oil (CPO industry). For 1 ton of fresh fruit bunches produced 23% of solid waste. This solid waste can be converted into alternative energy that called briquettes. Briquettes are solid fuel that can be used as an alternative fuel replacement for fossil fuels such as oil and gas. This study aims to determine the effect of temperature on the yield generated briquettes and the effect of stach adhesive concentration (5, 10 and 15% wt) to briquettes characteristics (moisture content, volatile matter, ash content, fixed carbon, calorific value and the rate of combustion). In this reseacrh, two kilograms of palm oil empty fruit bunches was burned using pyrolisis reactor at different temperatur (350, 400, 450 and 5000C) for 2.5 hour. Charcoal produced was mixed with an adhesive in accordance variations and molded into briquettes. Briquettes then analyzed the water content, ash content, carbon content, volatile matter content, heating value and rate of combustion. The maximum yield of briquettes which was obtained in this research is 51.53% at temperature 3500C and the lowest yield at temperature of 500 ° C by 26.03%. Briquettes results of this study have met the quality standards of fuel briquettes as seen from the heating value. Optimal adhesive composition between starch and charcoal TKKS is 5%: 95% that generates highest calorific value about 6748.15kal/ g. Keywords: Briquette Bioarang, Pyrolysis, oil palm empty bunches

scholarly journals PYROLYSIS OF ALANG – ALANG (IMPERATA CILINDRICA) AS BIOENERGY SOURCE IN BANTEN PROVINCE INDONESIA

2019 ◽  
Vol 3 (1) ◽  
pp. 60-78
Author(s):  
Fitriyah Fitriyah ◽  
Syarif Hidayat ◽  
Muhammad S. Abu Bakar ◽  
Neeranuch Phusunti
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Thermogravimetric Analysis ◽  
Elemental Analysis ◽  
Fixed Bed ◽  
Compositional Analysis ◽  
Calorific Value ◽  
Proximate Analysis ◽  
Gas Chromatography Mass Spectrometry ◽  
Bio Oil

Bahan bakar fosil sumber energi memiliki keterbatasan dan tidak terbarukan, penggunaan bahan bakar fosil secara terus menerus mengakibatkan krisis energy dan lingkungan. Rumput liar pada saat ini memiliki potensi untuk dikembangkan sebagai generasi kedua biomasa. Hal ini memiliki keuntungan seperti tumbuh dengan cepat, mudah tumbuh, perawatan yang minimal, dapat tumbuh pada lahan kritis dan tersedia dalam jumlah yang banyak. Dalam upaya mengembangkan generasi kedua biomasa, penelitian ini secara sistematis memberikan perspektif ekologi dan teknologi proses dalam mengembangkan bioenergi dari alang – alang di Provinsi Banten. Pada penelitian ini karakterisasi alang – alang dilakukan untuk menentukan sifat – sifat dan potensi bioenergy. Sedangkan fixed bed pirolisis dilakukan untuk mengidentifikasi potensi produksi bio-oil dari proses pirolisis. Sementara analisis karakterisasi bio-oil dilakukan untuk melihat potensi chemical building block sebagai sumber energi. Analisis sifat kimia dan fisika alang – alang dilakukan melalui thermogravimetric analysis, proximate analysis, elemental analysis, compositional analysis, calorific value. Sedangkan analisis potensi bio-oil di lakukan melalui Gas Chromatography–Mass Spectrometry (GC-MS). Dari hasil karakterisasi mengindikasikan bahwa alang – alang memiliki nilai kalori 18,05 MJ/kg, dengan ash konten yang rendah, dan tinggi kandungan volatile. Analisis dengan GC/MS menunjukan komponen utama dalam bio-oil dikelompokan ke dalam furan, ketone, phenol dan anhydrosugar yang merupakan platform yang dapat dikonversi menjadi sumber energi. Fixed bed pyrolysis atau fixed bed pirolisis alang – alang menunjukan, bahwa yield bio-oil meningkat sebagaimana peningkatan temperatur dan puncaknya pada suhu 500 0C dengan persentase 37,91%. Kata Kunci: Alang - alang, Pirolisis, GC/MS, Thermogravimetric analysis, Bioenergi   ABSTRACT Fossil fuel as a source of energy have limitation and are non-renewable. Continuous utilisation of fossil fuels as energy source can lead to energy crisis and environmental impact. Perennials grasses (alang – alang) are currently being developed as a suitable second-generation biofuel feedstock. It has advantages such as rapid growth rate, easy to grow, minimal maintenance and utilise marginal land without competing with food supply. Taking into account of the various challenges attributed to the transformation of second-generation biomass for energy production, this work systematically looks at the ecological perspective and the availability for bioenergy production from alang – alang in Banten Province. Biomass characterisation is carried out to determine the properties and bioenergy potential. Fixed bed pyrolysis study was conducted to predict the potential production of bio-oil from the pyrolysis process. GC/MS study is conducted to identify the potential building blocks of value-added chemicals from alang – alang. The physicochemical properties of feedstock was thoroughly evaluated using thermogravimetric analysis, proximate analysis, elemental analysis, compositional analysis, calorific value. The analysis of the potential of bio-oil was carried out through GC / MS. Characterisation results indicate that alang - alang has a calorific value of 18.39 MJ/kg, with low ash content and high percentage of volatile matter. Analysis from Gas Chromatography–Mass Spectrometry (GC-MS) showed that majority of the chemical groups in the bio-oil contained furan, ketone, phenol and anhydro-sugars. Phenolic and furanic were found as major compounds in bio oil. Phenolic, furanic, ketonic and anhydrosugars are promising renewable platform compounds derived from pyrolysis of alang – alang. The compounds can be further converted to chemicals or fuels. The fixed-bed pyrolysis of alang - alang showed that the yield of bio-oil increases as the temperature increases and peaks at 500°C with 38.79%. Keywords: Alang - alang, Pyrolysis, GC/MS, Thermogravimetric analysis, Bioenergy

scholarly journals Experimental and Theoretical Fuel Property Comparison of Four Different Waste Biomass with A Commercial Counterpart

2021 ◽  
Author(s):  
Mustafa Kaan Baltacıoğlu ◽  
Mustafa Tunahan Başar ◽  
Hüseyin Turan Arat ◽  
Yasin Erdoğan
Keyword(s):  
Calorific Value ◽  
Orange Peel ◽  
Volatile Matter ◽  
Waste Biomass ◽  
Heating Value ◽  
Moisture Contents ◽  
Accredited Laboratory ◽  
Pomegranate Seed ◽  
Pomegranate Seeds ◽  
Pellet Form

Abstract This study focuses on determining the fuel properties of apple pulp, pomegranate seeds, pomegranate peel and orange peel wastes and converting them into pellet fuel. Within the scope of the study, the organic wastes were dried, ruined into small pieces and then pressed to take the pellet form. Moisture content, ash content, volatile matter determination, fixed carbon content, total sulfur content, hydrogen content, lower heating value and higher heating value were analyzed as solid fuel characterization process. Experiments were carried out in an internationally accredited laboratory in accordance with ASTM and TS EN ISO/IEC 17025 Standards. Considering the results, it was determined that the pellet obtained from fully dry state pomegranate seed had a calorific value of 4244 kcal/kg, whereas the commercial pellet was 4759 kcal/kg under the same conditions. On the other hand, the moisture contents of the commercial pellet and pomegranate seed sample were 5.42% and 1.83%, respectively. The drying process was one of the costliest stages of pellet production. The low moisture contents can reduce the production cost and shorten the time.

scholarly journals Physiochemical Properties of Cotton Stalk Biomass from Aricultural Residues

2015 ◽  
Vol 10 (1) ◽  
pp. 343-349 ◽  
Author(s):  
Dobariya Umesh ◽  
P Sarsavadiya ◽  
Krishna Vaja ◽  
Khardiwar Mahadeo
Keyword(s):  
Calorific Value ◽  
Volatile Matter ◽  
Proximate Analysis ◽  
Agricultural Residues ◽  
Ash Content ◽  
Cotton Stalk ◽  
Fixed Carbon ◽  
Physiochemical Properties ◽  
Feed Stock ◽  
Energy Conversion Process

The study was undertaken to investigate the properties of cotton stalk fuel from the agricultural residues. The whole cotton stalk plant is converted into shredded material with the help of cotton stalk shredder. The capacity of cotton stalk shredder machine is 218 kg/h. The proximate analysis of the shredded cotton stalk in terms of bulk density 34.92 kg / m3 moisture content 13.63 %, volatile matter 74.52 %, ash content (4.95 %, fixed carbon 20.53 % and calorific value of cotton stalk biomass (3827 cal/g) respectively. were showed that agricultural residues are the most potential and their quantitative availability, Since the aim by using shredded cotton stalk as feed stock for energy conversion process of the developed gasifier.

scholarly journals The Investigation of Mercury Contents in Polish Coal Samples

2013 ◽  
Vol 39 (2) ◽  
pp. 141-150 ◽  
Author(s):  
Michał Wichliński ◽  
Rafał Kobyłecki ◽  
Zbigniew Bis
Keyword(s):  
Electricity Generation ◽  
Volatile Matter ◽  
Proximate Analysis ◽  
Mercury Content ◽  
Hard Coal ◽  
Fixed Carbon ◽  
Heating Value ◽  
High Heating Value ◽  
Enrichment Process

Abstract This paper presents the results of the investigation associated with the determination of mercury content in Polish hard coal and lignite samples. Those coals are major fuels used for electricity generation in Poland. The results indicated that the average content of mercury in the coal samples was roughly about 100 ng/g. Apart from the determination of the mercury contents a detailed ultimate and proximate analysis of the coal samples was also carried out. The relationships between the mercury content and ash, as well as fixed carbon, volatile matter, sulfur, and high heating value of the coal samples were also established. Furthermore, the effect of coal enrichment was also investigated, and it was found that the enrichment process enabled the removal of up to 75% of the coal mercury from the samples.

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