scholarly journals Changes in Phenolics during Cooking Extrusion: A Review

Foods ◽  
2021 ◽  
Vol 10 (9) ◽  
pp. 2100
Author(s):  
Evžen Šárka ◽  
Marcela Sluková ◽  
Svatopluk Henke
Keyword(s):  
Raw Materials ◽  
Protein Complexes ◽  
Extrusion Process ◽  
Antinutritional Factors ◽  
Total Phenolic ◽  
Technological Parameters ◽  
Chemical Changes ◽  
Oxidation Reduction ◽  
Input Material ◽  
Twin Screw

In this paper, significant attention is paid to the retention of phenolics in extrudates and their health effects. Due to the large number of recent articles devoted to total phenolic content (TPC) of input mixtures and extrudates, the technological changes are only presented for basic raw materials and the originating extrudates, and only the composites identified has having the highest amounts of TPC are referred to. The paper is also devoted to the changes in individual phenolics during extrusion (phenolic acids, flavonoids, flavonols, proanthocyanidins, flavanones, flavones, isoflavons, and 3-deoxyanthocyanidins). These changes are related to the choice or raw materials, the configuration of the extruder, and the setting the technological parameters. The results found in this study, presented in the form of tables, also indicate whether a single-screw or twin-screw extruder was used for the experiments. To design an extrusion process, other physico-chemical changes in the input material must also be taken into account, such as gelatinization of starch; denaturation of protein and formation of starch, lipids, and protein complexes; formation of soluble dietary fiber; destruction of antinutritional factors and contaminating microorganisms; and lipid oxidation reduction. The chemical changes also include starch depolymerization, the Maillard reaction, and decomposition of vitamins.

scholarly journals Total Phenolic Content and Antimicrobial Activity of Different Lithuanian Propolis Solutions

2013 ◽  
Vol 2013 ◽  
pp. 1-5 ◽  
Author(s):  
Kristina Ramanauskienė ◽  
Asta Marija Inkėnienė ◽  
Vilma Petrikaitė ◽  
Vitalis Briedis
Keyword(s):  
Antimicrobial Activity ◽  
Phenolic Compounds ◽  
Propylene Glycol ◽  
Reduction Reaction ◽  
Total Phenolic ◽  
Technological Parameters ◽  
Oxidation Reduction ◽  
Alkaline Conditions ◽  
Oxidation Reduction Reaction

The manufacture of ethanol-free propolis solutions offers a broader application. A few trials with Lithuanian propolis have been conducted. The aims of the study are to manufacture propolis water and water-free solutions and evaluate the quality and antimicrobial activity of these solutions. The studied solutions containing 2.5%, 5%, and 10% propolis are prepared. As solvents, purified water, 70% v/v ethanol, 96.3% v/v ethanol, propylene glycol, and their systems were used. Determination of total levels of phenolic compounds (FAE mg/g) is based on colour oxidation-reduction reaction using Folin-Ciocalteu reagent under alkaline conditions and performed at 765 nm wavelength using UV spectrophotometer. The highest content of phenolic compounds was determined in solutions containing 10% propolis extracts, and the lowest amounts in 2.5% propolis extracts. The water extracted the lowest amount of phenolic compounds from crude propolis, ethanol extracted the highest amount, and propylene glycol ranked the middle position. It is determined that technological parameters (stirring, temperature) contribute to content of phenolic compounds. During microbiological study, MICs were determined. The studies showed that water extracted propolis solutions and solvents mixture did not inhibit the growth of the studied microorganisms, and propolis solutions in propylene glycol were found to have antimicrobial activity.

scholarly journals Valorization of Greenhouse Horticulture Waste from a Biorefinery Perspective

Foods ◽  
2021 ◽  
Vol 10 (4) ◽  
pp. 814
Author(s):  
Antonio D. Moreno ◽  
Aleta Duque ◽  
Alberto González ◽  
Ignacio Ballesteros ◽  
María José Negro
Keyword(s):  
Enzymatic Hydrolysis ◽  
Raw Materials ◽  
Reactive Extrusion ◽  
Extrusion Process ◽  
Alkali Concentration ◽  
Hydrolysis Process ◽  
Twin Screw ◽  
Greenhouse Horticulture ◽  
Extrusion Technology ◽  
Sugar Source

Greenhouse cultivation and harvesting generate considerable amounts of organic waste, including vegetal waste from plants and discarded products. This study evaluated the residues derived from tomato cultivation practices in Almería (Spain) as sugar-rich raw materials for biorefineries. First, lignocellulose-based residues were subjected to an alkali-catalyzed extrusion process in a twin-screw extruder (100 °C and 6–12% (w/w) NaOH) to assess maximum sugar recovery during the subsequent enzymatic hydrolysis step. A high saccharification yield was reached when using an alkali concentration of 12% (w/w), releasing up to 81% of the initial glucan. Second, the discarded tomato residue was crushed and centrifuged to collect both the juice and the pulp fractions. The juice contained 39.4 g of sugars per 100 g of dry culled tomato, while the pulp yielded an extra 9.1 g of sugars per 100 g of dry culled tomato after an enzymatic hydrolysis process. The results presented herein show the potential of using horticulture waste as an attractive sugar source for biorefineries, including lignocellulose-based residues when effective fractionation processes, such as reactive extrusion technology, are available.

scholarly journals IMPROVEMENT OF EXTRUDER WORKING PROCESS WITH TERMOVACUAL EFFECT

2019 ◽  
Vol 4 (2) ◽  
pp. 84-89
Author(s):  
Анатолий Курочкин ◽  
Anatolii A Kurochkin
Keyword(s):  
Flow Rate ◽  
Vacuum Chamber ◽  
Raw Materials ◽  
Volumetric Flow Rate ◽  
Extrusion Process ◽  
Technological Parameters ◽  
Working Process ◽  
Thermal Vacuum ◽  
Working Volume ◽  
Vacuum Effect

The research aim is a theoretical substantiation of the increase in the efficiency of extrudate dehydration due to the supply of air into the vacuum chamber of a modernized extruder with a thermal vacuum working process. On the basis of modern study of the implementation of the thermodynamic process in the interaction of three different air flows in a limited volume of the vacuum chamber of the extruder, one possible way of increasing the efficiency of the finished product dehydration was theoretically justified. In the previously proposed constructive-technological scheme of the extruder, the insufficiently intensive dehydration of the finished product leaving the die of the ma-chine is associated with a relatively low air flow rate at the surface of the cooling extruder. These speed limits the transfer rate of the liquid removed from the extruder by means of wet steam, which is withdrawn from the vacuum chamber of the extruder into a vacuum balloon and condenses. In a modernized extruder, the effect of thermal vac-uum effect is proposed to be enhanced by means of a metered supply of air into the working volume of the extrud-er’s vacuum chamber. The conducted research allowed obtaining analytical expressions with the help of which it is possible to determine the volumetric flow rate of air injected into the vacuum chamber of the machine and to deter-mine its effect on the main structural and technological parameters of the system that ensures the thermal vacuum effect of the extrusion process. The relationship between the coefficient taking into account the influence of the thermal vacuum effect in an autogenous extruder on other significant technical and technological parameters of the machine is shown. The results obtained can be useful and considered in the course of subsequent theoretical stud-ies of extruders with a vacuum chamber and will allow on their basis increasing the efficiency of the machines per-forming the thermal vacuum extrusion of raw materials of plant origin.

scholarly journals Study on Reinforced Modification of Polylactic Acid by New Hyperbranched Polyamide

2021 ◽  
Author(s):  
Jianjian Sun ◽  
Yansong Huang ◽  
Yu juan Jin ◽  
Lu Wang ◽  
Huafeng Tian
Keyword(s):  
Polylactic Acid ◽  
Raw Materials ◽  
Extrusion Process ◽  
Injection Molding Process ◽  
Molding Process ◽  
Twin Screw ◽  
Chemical Crosslinks ◽  
One Step ◽  
The Impact ◽  
Hyperbranched Polyamide

Abstract In order to achieve enhanced physical performance of polylactic acid (PLA), the hyperbranched polyamide (HBPA) was synthesized by "one-step" as raw materials, and added as a modifier to the PLA matrix. The HBPA/PLA blend was prepared through the twin screw extrusion process and the injection molding process. The results showed that, compared with pure PLA, the tensile strength of HBPA/PLA blends increased by 41.8% while the elongation at break and the impact strength basically unchanged. The addition of HBPA does not affect the glass transition temperature (Tg) and crystallization of PLA significantly, but can improve the thermal deformation temperature of PLA. HBPA acted as a nucleant for PLA during iso-temperature crystallization. HBPA could form hydrogen bonds and chemical crosslinks with PLA, thus exhibits excellent reinforcing effect for PLA.

scholarly journals Mathematical modeling of the oil extrusion process with pre-grinding of raw materials in a twin-screw extruder

10.5219/1436 ◽  
2020 ◽  
Vol 14 ◽  
pp. 937-944
Author(s):  
Mikhailo Mushtruk ◽  
Maxim Gudzenko ◽  
Igor Palamarchuk ◽  
Volodymyr Vasyliv ◽  
Natalia Slobodyanyuk ◽  
...  
Keyword(s):  
Raw Materials ◽  
Extrusion Process ◽  
High Energy ◽  
Raw Material ◽  
Twin Screw Extruder ◽  
Pressure Force ◽  
Screw Extruder ◽  
Energy Parameters ◽  
Twin Screw ◽  
Power And Energy

The extrusion process of oil-containing raw materials using a twin-screw extruder is becoming increasingly common in food technology. The problem of high energy costs for the implementation of this process is solved by reducing the resistance of the process mass due to the preliminary grinding of raw materials. The classical theory of extrusion is based mainly on the use of theoretical solutions of mathematical models of processes, which are simplified and allow determining integral parameters using coefficients, the preparation of which for the calculation of the corresponding processes and equipment is a rather complicated and approximate procedure. Mathematical modelling of the movement of the technological medium at the individual stages of the processing of raw materials allows us to determine the analytical dependences for the power and energy parameters of the system and to carry out their effective technical and economic evaluation. Using the methods of mathematical analysis and data processing in the MathCAD software environment, graphical dependences of the power and energy parameters of the research technical system were obtained. By increasing the density of the oil-containing raw materials, which is extruded in the research extruder by 40.5% the pressure force increases by 41%, that is, there is an almost proportional relationship between the pressure force and the density of the processed raw material. With an increase in the angular velocity of the drive shaft ω more than 8 rad.s-1, the pressure force in the research process increases sharply. With an increase in the density of raw materials, it is grinded before extrusion by 40%, the power consumption for the grinding process increases by 2.8 times for the recommended operating mode. Energy losses for pressing completely grinded raw materials are reduced by 2.52 times.

A possibility of using nickel concentrate, obtained as a result of hydrometallurgical enrichment of manganese-containing raw materials, at steel alloying

2020 ◽  
Vol 76 (7) ◽  
pp. 709-715
Author(s):  
O. Yu. Kichigina
Keyword(s):  
Raw Materials ◽  
Experimental Studies ◽  
Selective Extraction ◽  
Technological Parameters ◽  
Nickel Iron ◽  
Nickel Recovery ◽  
Nickel Concentrate ◽  
Steel Alloying ◽  
High Degree ◽  
Comprehensive Processing

At production of stainless steel expensive alloying elements, containing nickel, are used. To decrease the steel cost, substitution of nickel during steel alloying process by its oxides is an actual task. Results of analysis of thermodynamic and experimental studies of nickel reducing from its oxide presented, as well as methods of nickel oxide obtaining at manganese bearing complex raw materials enrichment and practice of its application during steel alloying. Technology of comprehensive processing of complex manganese-containing raw materials considered, including leaching and selective extraction out of the solution valuable components: manganese, nickel, iron, cobalt and copper. Based on theoretical and experiment studies, a possibility of substitution of metal nickel by concentrates, obtained as a result of hydrometallurgical enrichment, was confirmed. Optimal technological parameters, ensuring high degree of nickel recovery out of the initial raw materials were determined. It was established, that for direct steel alloying it is reasonable to add into the charge pellets, consisting of nickel concentrate and coke fines, that enables to reach the through nickel recovery at a level of 90%. The proposed method of alloying steel by nickel gives a possibility to decrease considerably steel cost at the expense of application of nickel concentrate, obtained out of tails of hydrometallurgical enrichment of manganese-bearing raw materials, which is much cheaper comparing with the metal nickel.

scholarly journals Apple Pomace as a Source of Bioactive Polyphenol Compounds in Gluten-Free Breads

Antioxidants ◽  
2021 ◽  
Vol 10 (5) ◽  
pp. 807
Author(s):  
Dorota Gumul ◽  
Rafał Ziobro ◽  
Jarosław Korus ◽  
Marek Kruczek
Keyword(s):  
Raw Materials ◽  
Apple Pomace ◽  
Total Phenolic ◽  
Gluten Free ◽  
Bioactive Substances ◽  
Free Products ◽  
Total Polyphenol ◽  
Polyphenol Compounds ◽  
High Oxidative Stress ◽  
Vegetables And Fruits

Gluten-free products based on starch and hydrocolloids are deficient in nutrients and do not contain pro-health substances. Therefore, they should be enriched in raw materials naturally rich in antioxidants, especially if they are intended for celiac patients, prone to high oxidative stress. Apart from the traditionally used pseudo-cereals, seeds, vegetables and fruits, innovative substrates such as the by-product (especially in Poland) dry apple pomace could be applied. The study material consisted of gluten-free bread enriched with apple pomace. The content of individual polyphenols, the content of total polyphenol and flavonoids, and also the antioxidant potential of the bread were determined by the UPLC-PDA-MS/MS methods. It was observed that apple pomace was a natural concentrate of bioactive substances from the group of polyphenols. In summary, gluten-free bread with 5% content of apple pomace showed the highest organoleptic scores and contained high levels of phenolic compounds. The values of total phenolic content, and the amounts of flavonoids, phenolic acids and phloridzin in this bread were 2.5, 8, 4 and 21 times higher in comparison to control.

scholarly journals Manufacture of all-wood sawdust-based particle board using ionic liquid-facilitated fusion process

2021 ◽  
Vol 55 (2) ◽  
pp. 331-349
Author(s):  
Hannes Orelma ◽  
Atsushi Tanaka ◽  
Maija Vuoriluoto ◽  
Alexey Khakalo ◽  
Antti Korpela
Keyword(s):  
Tensile Strength ◽  
Ionic Liquid ◽  
Raw Materials ◽  
Weight Ratio ◽  
Fusion Process ◽  
The Novel ◽  
Particle Board ◽  
Microscopy Technique ◽  
Twin Screw ◽  
Fusion Approach

AbstractTraditional particle board can generate harmful indoor air emissions due to the volatile resin-based compounds present. This study investigated the preparation of sawdust particle board using the novel ionic liquid based fusion approach with [EMIM]OAc. The dissolution parameters were investigated using the thermal optical microscopy technique. The particle board sheets were prepared by hot pressing sawdust in the presence of ionic liquid (IL) ([EMIM]OAc) and subsequently purifying the fusion sawdust matrix from the IL with methanol. The fusion process of the sawdust particles was analysed with SEM and mechanical testing. The raw materials and the produced materials were investigated with elemental analysis, FTIR, and 13C-SS-NMR. IL fusion of the sawdust required a temperature above 150 °C, similar to the glass transition temperature (tg) of lignin. At lower temperatures, strong particle fusion was not obtained. It was observed that the sawdust/IL weight ratio was an important parameter of the fusion process, and a 1:3 weight ratio resulted in the strongest particle boards with a tensile strength of up to 10 MPa, similar to commercial particle boards. The particle fusion process was also studied with a twin-screw extruder. The extrusion enhanced the fusion of the sawdust particles by increasing dissolution of the sawdust particles, which was subsequently seen in elevated tensile strength (20 MPa). The study provides a practical view of how sawdust-based particle board can be manufactured using ionic liquid-based fusion.

Definition of a JA-2 Equivalent Propellant to be Produced by Continuous Solventless Extrusion

2013 ◽  
Vol 80 (3) ◽  
Author(s):  
Thelma G. Manning ◽  
Joseph Leone ◽  
Martijn Zebregs ◽  
Dinesh R. Ramlal ◽  
Chris A. van Driel
Keyword(s):  
Extrusion Process ◽  
Continuous Manufacturing ◽  
Twin Screw Extrusion ◽  
Extrusion Processing ◽  
Roll Mill ◽  
Screw Extrusion ◽  
Twin Screw ◽  
Ballistic Properties ◽  
Definition Of ◽  
Double Base

In order to eliminate residual solvents in ammunition and to reduce the emissions of volatile organic compounds to the atmosphere, the U.S. Army ARDEC has teamed with TNO in developing a new process for the production of solventless propellant for tank ammunition. To reduce the costs of solventless propellants production, shear roll mill and continuous extrusion processing was investigated. As described in this paper JA-2 a double base propellant cannot be processed without solvent by the extrusion process. An alternative JA-2 equivalent propellant was defined. The aim of this work is to demonstrate the manufacturing of this propellant by solventless continuous twin screw extrusion processing while maintaining gun performance characteristics of conventional JA-2 propellant. This is elucidated by explicitly researching the relationship between interior ballistic properties of the gun propellant and utilizing a continuous manufacturing process. Processing conditions were established, and the propellant was manufactured accordingly. The extruded propellant has the desired properties, which resulted in a comparable gun performance as the conventional JA-2 propellant.

Effect of different extrusion methods on physicochemical properties and qualities of noodles based on rice flour

2021 ◽  
pp. 108201322110692
Author(s):  
Nispa Seetapan ◽  
Bootsrapa Leelawat ◽  
Nattawut Limparyoon ◽  
Rattana Yooberg
Keyword(s):  
Moisture Content ◽  
Rice Flour ◽  
Extrusion Process ◽  
Scanning Electron Micrographs ◽  
Twin Screw Extruder ◽  
Capillary Rheometer ◽  
Screw Extruder ◽  
Scanning Calorimetry ◽  
Twin Screw ◽  
Thermomechanical Processes

Rice noodles have been manufactured in the food industry using different extrusion methods, such as traditional and modern extrusions, which affect the noodle structure and qualities. Therefore, the effects of the extrusion process on qualities of rice noodles using the same blend of rice flour and crosslinked starch were evaluated. In this study, a capillary rheometer was used as an alternative approach to simulate the traditional extrusion method in which the noodles are obtained by continuously pressing the pregelatinized noodle dough through a die. For modern extrusion, a twin-screw extruder was employed to obtain the noodles in a one-step process. The optimal range of moisture content used in the formulation was studied. Upon cooking, the noodles showed a decrease in cooking time and cooking loss with increasing moisture content in the formulation. All cooked noodles showed comparable tensile strength, but those extruded by a twin-screw extruder had substantially greater elongation. Scanning electron micrographs revealed that the noodles prepared using the extruder had a denser starch matrix, while those obtained from a capillary rheometer showed the aggregation of starch fragments relevant to the existence of starch gelatinization endotherm from differential scanning calorimetry. This indicated that the extrusion process using the twin-screw extruder provided a more uniform starch transformation, i.e., more starch granule disruption and gelatinization, thus giving the noodles a more coherent structure and better extensibility after cooking. The obtained results suggested that different thermomechanical processes used in the noodle industry gave the extruded rice noodles different qualities respective to their different microstructures.

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