scholarly journals Preparation and Characterization of Waterborne UV Lacquer Product Modified by Zinc Oxide with Flower Shape

Polymers ◽  
2020 ◽  
Vol 12 (3) ◽  
pp. 668 ◽  
Author(s):  
Yan Wu ◽  
Xinyu Wu ◽  
Feng Yang ◽  
Jiaoyou Ye
Keyword(s):  
Zinc Oxide ◽  
Stearic Acid ◽  
Erosion Resistance ◽  
Hydrophobic Surface ◽  
Zinc Stearate ◽  
Raw Material ◽  
Hydroxyl Group ◽  
Vapor Molecule ◽  
Poplar Wood ◽  
Acid Vapor

In this paper, the waterborne UV lacquer product (WUV) was used as the main raw material, zinc oxide (ZnO) was used as the additive, and the stearic acid as the surface modifier. According to the method of spraying coating on the surface of poplar wood (Populus tomentosa), a simple and efficient preparation method was carried out to generate a super-hydrophobic surface and enhance the erosion resistance of the coating. By testing, the contact angle (CA) of water on the coating surface can reach 158.4°. The microstructure and chemical composition of the surface of coatings were studied by scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FT-IR), and X-ray diffraction (XRD). The results showed that under acidic conditions, the non-polar long chain alkyl group of stearic acid vapor molecule reacted with the hydroxyl group in acetic acid, the metal ions of the ZnO were displaced to the stearic acid and generated globular zinc stearate (C36H70O4Zn). The hydrophobic groups –CH3 were grafted to the surface of zinc stearate (ZnSt2) particles and the micro/nano level of multistage flower zinc stearate coarse structure was successfully constructed on the surface of poplar wood, which endowed it with superhydrophobic properties. It is shown that the coating has good waterproof and erosion resistance.

Dispersion of Channel Gas Black in Rubber. Effect of Stearic Acid and Other So-called Dispersing Agents

1935 ◽  
Vol 8 (3) ◽  
pp. 470-482
Author(s):  
C. R. Park ◽  
V. N. Morris
Keyword(s):  
Zinc Oxide ◽  
Fatty Acid ◽  
Carbon Black ◽  
Stearic Acid ◽  
Convincing Evidence ◽  
Zinc Stearate ◽  
Surface Forces ◽  
Dispersing Agent ◽  
Principal Effect ◽  
Dispersing Agents

Abstract THE completeness of wetting of carbon black by rubber, the consequent state of dispersion of the black, and the effect of the surface forces in the development of reënforcement of the rubber have been the subjects of much deliberation and experimentation. Of special interest has been the effect of stearic acid upon the dispersing power of rubber for carbon black. On the basis of Green's observation (6) that the dispersion of zinc oxide which had previously flocculated in kerosene resulted in a pronounced softening of the mixture, Goodwin and Park (5) concluded that stearic acid has little effect upon the dispersion of carbon black in rubber. They pointed out that stearic acid has a slight softening action in uncured stock and in cured stock containing no zinc oxide, and that the addition of fatty acid to a stock containing no zinc oxide affects its physical properties adversely. Although they considered that these facts furnished slight indications of a dispersing effect by the stearic acid, these authors offered no convincing evidence of the dispersing effect of stearic acid on carbon black in rubber. For various reasons, including the fact that the plasticity of uncured black stocks is not materially affected by the presence of zinc stearate, Goodwin and Park also concluded that zinc stearate is not a dispersing agent for blacks. In fact, they postulated that the effect of zinc stearate, if any, is to decrease the wetting of the black by the medium and hence to cause flocculation. Since the combined addition of zinc oxide and stearic acid to a rubber-sulfur mix results in an improvement in properties, these investigators were finally led to the conclusion that the principal effect of these soap-forming agents in a carbon black stock is on the curing properties of the rubber itself rather than on the dispersion of the black.

scholarly journals A Superhydrophobic, Antibacterial, and Durable Surface of Poplar Wood

Nanomaterials ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1885
Author(s):  
Xinyu Wu ◽  
Feng Yang ◽  
Jian Gan ◽  
Zhangqian Kong ◽  
Yan Wu
Keyword(s):  
Stearic Acid ◽  
Antibacterial Properties ◽  
Alkali Resistance ◽  
Poplar Wood ◽  
X Ray Diffraction ◽  
X Ray ◽  
Different Temperatures ◽  
Acid And Alkali Resistance ◽  
The Stability

The silver particles were grown in situ on the surface of wood by the silver mirror method and modified with stearic acid to acquire a surface with superhydrophobic and antibacterial properties. Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and X-ray energy spectroscopy (XPS) were used to analyze the reaction mechanism of the modification process. Scanning electron microscopy (SEM) and contact angle tests were used to characterize the wettability and surface morphology. A coating with a micro rough structure was successfully constructed by the modification of stearic acid, which imparted superhydrophobicity and antibacterial activity to poplar wood. The stability tests were performed to discuss the stability of its hydrophobic performance. The results showed that it has good mechanical properties, acid and alkali resistance, and UV stability. The durability tests demonstrated that the coating has the function of water resistance and fouling resistance and can maintain the stability of its hydrophobic properties under different temperatures of heat treatment.

Optimization of steam pretreatment conditions for enzymatic hydrolysis of poplar wood

Holzforschung ◽  
2011 ◽  
Vol 65 (4) ◽  
Author(s):  
Fokko Schütt ◽  
Jürgen Puls ◽  
Bodo Saake
Keyword(s):  
Enzymatic Hydrolysis ◽  
Raw Material ◽  
Steam Pretreatment ◽  
Alkaline Extraction ◽  
Poplar Wood ◽  
Steam Refining ◽  
Severity Factor ◽  
Short Rotation ◽  
Pretreatment Conditions ◽  
Hydrolysis Of

Abstract Steam refining was investigated as a pretreatment for enzymatic hydrolysis of poplar wood from a short rotation plantation. The experiments were carried out without debarking to use an economically realistic raw material. Steam refining conditions were varied in the range of 3–30 min and 170–220°C, according to a factorial design created with the software JMP from SAS Institute Inc., Cary, NC, USA. Predicted steaming conditions for highest glucose and xylose yields after enzymatic hydrolysis were at 210°C and 15 min. Control tests under the optimized conditions verified the predicted results. Further pretreatments without bark showed that the enzymes were not significantly inhibited by the bark. The yield of glucose and xylose was 61.9% of theoretical for the experiments with the whole raw material, whereas the yield for the experiments without bark was 63.6%. Alkaline extraction of lignin from the fibers before enzymatic hydrolysis resulted in an increase of glucose yields from mild pretreated fibers and a decrease for severe pretreated fibers. The extracted lignin had a high content of xylose of up to 14% after very mild pretreatments. On the other hand, molecular weights of the extracted lignin increased substantially after pretreatments with a severity factor above 4. Hence, alkaline extraction of the lignin seems only attractive in a narrow range of steaming conditions.

scholarly journals A study to set-up a technological process for purification of Zinc scraps by using liquation method

2021 ◽  
Vol 8 (1) ◽  
pp. 36-43
Author(s):  
Ngoc Vuong Tran ◽  
Manh Hung Luong ◽  
Dinh Dang Nguyen
Keyword(s):  
Zinc Oxide ◽  
Raw Materials ◽  
Time Factors ◽  
Pilot Scale ◽  
Raw Material ◽  
Optimal Time ◽  
Fe Content ◽  
Technology Process ◽  
Zn Content ◽  
Set Up

Zinc scrap is a source of raw material for zinc oxide production. However, to qualify the requirement of raw material for zinc oxide (99.5%) production, refining this source is needed. Many methods are considered such as rectification, chemical method, etc., but difficult to apply on an industrial scale. This workfocused on the investigation of the influence of temperature and time factors for asessing the possibility of applying liquation method for the purification of impurities from scrap zinc.The experiment results show that the optimum temperature of liquation to remove Pb,Fe from zinc scrap is in the range of 440-450°C, the optimal time of the process is 8h for the pot with 8cm in height and 6cm in diameter (the quantity of raw zinc sample is about 2kg / batch), then we can obtain about 80% of zinc metal with an average Zn content of about 97, 0%, both Pb and Fe content decreased to a range from 0.35 to 0.4%, and 1.0 to 1.1%, respectively, which meet the requirement of raw materials for the production of high quanlity ZnO ( 99,5 %). Based on the parameters obtained on lab-scale, a trial on pilot scale of 250 kg / batch was conducted, The result confirms that the quality of the products meets the requirement of raw materials for production of high quality ZnO (99.5%) and a technology process for refining zinc scrap by the liquation was proposed.

scholarly journals Synthesis of Acid Polyols As a Feedstock to Produce Flexible Polyurethanes and Their Effect on the Income Level of Furniture Craftsmen

2019 ◽  
Vol 2 (1) ◽  
pp. 39
Author(s):  
Andi Budirohmi
Keyword(s):  
Fourier Transform ◽  
Fatty Acid ◽  
Raw Materials ◽  
Raw Material ◽  
Polymerization Process ◽  
Hydroxyl Group ◽  
Infra Red ◽  
Renewable Raw Material ◽  
Shoe Soles ◽  
Alternative Feedstock

Polyuretanes are widely used as elastomers, coatings, adhesivesand binders,interior and exterior cars, furniture,shoe soles, carpets, rigit and flexible foams, membrane materials as well as constuction materials .The production of polyurethanes is largely derived  from  polyols derived from petroleum . Howover, petroleum  is a non- renewable raw material . Thus it is necessary to look alternative feedstock  for the manufacture of polyol  as a polyurethane raw material. Synnthesis polyurethane by polymerization process  using  polyol volume based on polyol  oleat acid  polypropylenglycol ( PPG ) in order to know  whether fatty acid can be used  as raw materials  of polyurethane manufacture.From the result of the study. Based on Fourier Transform Infra  Red ( FTIR), showed,that the product  produced is polyol with obtained hydroxyl  group ( OH group )with hydroxylnumber is 129,81 mg KOH / g and 157,60 mg KOH / g sample of 70 

CARBON AND FUEL FROM RUBBER WASTE

2020 ◽  
pp. 103-108
Author(s):  
Gennadi I. Zhuravsky ◽  
Maksim I. Nitievski
Keyword(s):  
Zinc Oxide ◽  
Water Vapor ◽  
Raw Materials ◽  
Liquid Waste ◽  
Raw Material ◽  
High Grade ◽  
High Quality ◽  
Technical Carbon ◽  
Rubber Waste ◽  
Composite Mixture

The results of studies of thermolysis waste in the environment of overheated water vapor are presented. It is shown that as a result of fractionation from liquid waste thermolysis products, gasoline and diesel fuel fractions can be obtained. It is proposed to use a composite mixture of liquid and solid waste thermolysis products as raw materials for high-grade technical carbon. Studies have shown that high-grade technical carbon can be obtained as raw materials using a composite mixture of rubber waste thermolysis products as raw materials. The technological line of obtaining technical carbon from the products of thermolysis of worn tires is described. Analysis of the ash produced by the process of burning the composite mixture shows that it contains compounds of iron, zinc and silicon. Therefore, this ash is of interest as a high-quality raw material for the production of zinc oxide, as one of the main ingredients of rubber mixtures.

Effect of stearic acid coating on anti-oxidation property of Sn-Ag-Cu solder powder

2019 ◽  
Vol 31 (1) ◽  
pp. 68-74 ◽  
Author(s):  
Fen Peng ◽  
Wensheng Liu ◽  
Yufeng Huang ◽  
Siwei Tang ◽  
Chaoping Liang ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Liquid Phase ◽  
Stearic Acid ◽  
Photoelectron Spectroscopy ◽  
Hydroxyl Group ◽  
Phase Method ◽  
Layer By Layer ◽  
Content Type ◽  
Maximum Angle ◽  
Coated Powder

Purpose The purpose of this study is to develop a monolayer surface coating of stearic acid on Sn-Ag-Cu solder powder to limit oxidation. Design/methodology/approach Stearic acid was adsorbed onto Sn-Ag-Cu solder powder through liquid-phase adsorption. The isotherm of adsorption was measured and then the microstructure of coated powder was characterized by scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy and Fourier-transform infrared spectroscopy. Findings The adsorption isotherm of stearic acid on the powder was “H” type, which revealed the layer-by-layer adsorption on non-porous surface. When the concentration of solution was in the range of 0.001-0.006 mol/L, with an adsorption amount of 0.12 ± 0.1 mg/g, monolayer stearic acid covered the solder powder completely. Uniform and integrated self-assembled monolayer coating was formed through hydrogen bonds between the oxygen ions in surface lattice of Sn3.0Ag0.5Cu solder powder and the —O—H hydroxyl group of stearic acid. The maximum angle of stability of coated powder also reduced by 2.87° compared with that of non-coated powder. The increase rate of oxygen content of coated powder was much slower than that of non-coated powder when they were exposed to humid air. Originality/value As a result, oxidation of fine solder powder was effectively limited. Essentially, this method can also be applied to the coating of other types of solder powder and has reference significance to other coating by liquid-phase method.

Effect of Sulfur and Dicumyl Peroxide on Vulcanization of Natural Rubber with Tetramethylthiuram Disulfide and Zinc Oxide

1970 ◽  
Vol 43 (6) ◽  
pp. 1294-1310 ◽  
Author(s):  
S. P. Manik ◽  
S. Banerjee
Keyword(s):  
Zinc Oxide ◽  
Stearic Acid ◽  
Natural Rubber ◽  
Reaction Mechanisms ◽  
Elemental Sulfur ◽  
Initial Rate ◽  
Dicumyl Peroxide ◽  
Tetramethylthiuram Disulfide ◽  
Sulfur Vulcanization ◽  
Salient Features

Abstract The salient features of both non-elemental sulfur vulcanization by TMTD and elemental sulfur vulcanization promoted by TMTD both in presence and absence of ZnO and stearic acid have been studied. TMTD increases the rate of DCP decomposition and lowers the crosslinking maxima due to DCP depending on its concentration. However, with higher amounts of TMTD the initial rate of crosslinking is increased with the increased amount of TMTD, while crosslinking maxima are still lowered due to reversion. ZnO or ZnO-stearic acid, however, seems to alter the entire course of the reaction. Both the crosslink formation and TMTD decomposition are much higher in presence of ZnO or ZnO-stearic acid, but stearic acid seems to have no effect. The reaction mechanisms for TMTD accelerated sulfuration in absence and presence of ZnO have also been studied.

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