Research on High-Temperature Volatilization Characteristics of V2O5 during Direct Alloying of Smelting Vanadium Steel

2012 ◽  
Vol 557-559 ◽  
pp. 182-186
Author(s):  
Wei Xiang Wang ◽  
Zheng Liang Xue ◽  
Sheng Qiang Song ◽  
Ping Li ◽  
Zhi Chao Chen ◽  
...  
Keyword(s):  
High Temperature ◽  
Mass Ratio ◽  
Direct Alloying

This paper mainly researches the volatile phenomenon of V2O5 at high-temperature and the appropriate additions to depress volatilization of V2O5 effectively during direct alloying with V2O5 to smelting vanadium steel. It shows that the volatilization loss of V2O5 is 4.34% when V2O5 is heated to 1600°C for 10 minutes. The reductant ferrosilicon and additives CaO can depress the volatilization of V2O5 effectively. The volatilization loss of V2O5 decreases to 1.55% at 1600°C when the mass ratio of ferrosilicon to V2O5 is 1:1. CaO can react with V2O5 to form calcium vanadate to decrease the activity of V2O5. The volatilization loss of V2O5 decreases to 1.82% with adding 48.0% CaO in the V2O5–CaO system at 1600°C. The volatilization loss of V2O5 with adding more than 30% CaO can decrease to 0.48% when keeping the mass ratio of ferrosilicon to V2O5 is 1:1.

Effect of Roasting Temperature on High Temperature Sintering Process of Different Mass Ratio of CaCO3/ SiO2

2012 ◽  
Vol 454 ◽  
pp. 21-25
Author(s):  
Ying Gao ◽  
Yue Xin Han ◽  
Wenbo Li ◽  
Jie Liu
Keyword(s):  
High Temperature ◽  
Calcium Carbonate ◽  
Initial Temperature ◽  
Sintering Process ◽  
Mass Ratio ◽  
Remarkable Effect ◽  
Synthetic Product ◽  
Roasting Temperature

Roasting temperature is a significant factor for synthesis of wollastonite by high-temperature roasting. In this paper, experiments were carried out at various temperatures by using quartz and nanometer calcium carbonate mixed in different ratios. The synthetic products under the condition of different roasting temperatures and initial temperatures were characterized by means of XRD. The results indicated that initial temperature had a remarkable effect on the synthetic product during calcination at 1300°C for 2 h when nanometer calcium carbonate and quartz were mixed in such ratios as 2.3:1 and 4:1 by weight.

Research on Smelting Vanadium Steel by Silicothermic Reduction Direct Alloying with V2O5

2012 ◽  
Vol 476-478 ◽  
pp. 164-169
Author(s):  
Wei Xiang Wang ◽  
Zheng Liang Xue ◽  
Sheng Qiang Song ◽  
Ping Li ◽  
Zhi Chao Chen
Keyword(s):  
High Temperature ◽  
Thermodynamic Analysis ◽  
Induction Furnace ◽  
Tube Furnace ◽  
Vacuum Induction Furnace ◽  
Medium Frequency ◽  
Carbon Tube ◽  
Silicothermic Reduction ◽  
Direct Alloying

The basic thermodynamic analysis of silicothermic reduction during direct alloying to smelting vanadium steel with V2O5 was discussed in this paper. The high-temperature carbon tube furnace and medium frequency vacuum induction furnace were used to study the phase compositions of the reduction products and the change law of the yield of vanadium when V2O5 was reduced by ferrosilicon. The research shows that the main phases of the silicothermic reduction products were VSi2、FeVO4 and Ca2SiO4 under the condition of using CaO to restrain the volatile of V2O5. Yield of vanadium was gradually improved with the increase of ferrosilicon during the direct alloying. The yield of vanadium in the steel is as high as 95.25% when the addition of ferrosilicon is 35%.

PREPARATION OF C60 BY DETONATION A MIXTURE OF TRINITROTOLUENE AND GRAPHITE

2012 ◽  
Vol 27 (01) ◽  
pp. 1350004
Author(s):  
XIANFENG WEI ◽  
YONG HAN ◽  
LIU LIU ◽  
XINPING LONG
Keyword(s):  
High Pressure ◽  
High Performance Liquid Chromatography ◽  
Liquid Chromatography ◽  
High Temperature ◽  
High Performance ◽  
Extreme Conditions ◽  
Detonation Pressure ◽  
Detonation Synthesis ◽  
Mass Ratio ◽  
Detonation Products

To explore the practicability of C 60 synthesis under extreme conditions (high pressure and high temperature), trinitrotoluene (TNT), trinitramine (RDX) and graphite mixtures of different proportions were detonated in a vacuum container, and the detonation products were collected for detecting. The results of mass spectroscopy, high performance liquid chromatography showed significant signals of C 60, which proved that C 60 could be synthesized by detonating the mixture of TNT and graphite (in 6:4 and 7:3 mass ratio, respectively), the detonation pressure and temperature were calculated around 13 GPa and 2000 K, respectively. Both experiment results and theoretical analysis showed the importance of detonation pressure and cooling temperature in detonation synthesis of C 60.

Coal and Wood Chips Co-Pyrolysis Study

2014 ◽  
Vol 960-961 ◽  
pp. 422-426
Author(s):  
Qi Min Wang ◽  
Hao Wang ◽  
Jia Hao ◽  
Shuo Guo
Keyword(s):  
Renewable Energy ◽  
High Temperature ◽  
Environmental Pollution ◽  
Wood Chips ◽  
Mass Ratio ◽  
Pyrolysis Process ◽  
Biomass Utilization ◽  
Rational Use ◽  
Pyrolysis Reaction ◽  
Energy Shortage

As a clean, renewable energy, rational use of biomss can effectively solve the problem of energy shortage and environmental pollution. Co-combustion and Co-gasification of biomass and coal are important ways of biomass utilization. Co-pyrolysis reaction is one of the most important processes in the co-combustion and co-gasification. In order to study the different mix ways of coal and wood chips affections on the co-pyrolysis process, TGA was used to study the co-pyrolysis characters of wood chips and coal mixed by different methods with mass ratio 1:1. it is founded out that there is certain interaction between wood chips and coal by the comparison of TGA curves and calculation curves. There is promoting affection at the high temperature if wood chips and coal had been mixed up. There is inhibiting affection if wood chips and coal are tiering distributed.

Study on a High-Temperature Delayed Cross-Linked Acid

2012 ◽  
Vol 624 ◽  
pp. 252-255 ◽  
Author(s):  
Xiao Zhao ◽  
Qi Song ◽  
Hai Lin ◽  
Yan Ling Wang ◽  
Zeng Bao Wang ◽  
...  
Keyword(s):  
Lactic Acid ◽  
High Temperature ◽  
Reaction Time ◽  
Influencing Factors ◽  
Reaction Temperature ◽  
Zirconium Oxychloride ◽  
Cross Linking ◽  
Acid System ◽  
Mass Ratio ◽  
Reaction Conditions

A retarded zirconium cross-linking agent ECA-1 was prepared by using zirconium oxychloride, lactic acid， xylitol, and so on, then we got a high-temperature delayed cross-linking acid with cross-linking agent ECA-1 added to EVA-180 gelling acid, cross-linked acid performance and its influencing factors were discussed in details, such as reaction conditions of crosslinker, concentrations of crosslinker and thickener, and so on. The results showed that the obtained cross-linked acid had good temperature-tolerate and shear-tolerate properties when the mass ratio of zirconium oxychloride, lactic acid and xylitol is 1:1.25:0.0208 , the reaction temperature is 50~55°C, the reaction time is 4 hours, the delayed cross-linking time of acid system can be adjusted by changing the dosage of crosslinker and thickener.

scholarly journals Construction of an n-Body Potential for Revealing the Atomic Mechanism for Direct Alloying of Immiscible Tungsten and Copper

Materials ◽  
2021 ◽  
Vol 14 (20) ◽  
pp. 5988
Author(s):  
Tao Zeng ◽  
Fei Li ◽  
Yuan Huang
Keyword(s):  
High Temperature ◽  
Interatomic Potential ◽  
Diffusion Mechanism ◽  
Critical Role ◽  
Experimental Studies ◽  
Md Simulations ◽  
Interatomic Potentials ◽  
Direct Alloying ◽  
Materials Used ◽  
Body Potential

W-Cu laminated composites are critical materials used to construct nuclear fusion reactors, and it is very important to obtain direct alloying between W and Cu at the W/Cu interfaces of the composites. Our previous experimental studies showed that it is possible to overcome the immiscibility between W and Cu and obtain direct alloying when the alloying temperature is close to the melting point of Cu. Because the W-Cu interatomic potentials published thus far cannot accurately reproduce the alloying behaviors of immiscible W and Cu, an interatomic potential suitable for the W-Cu system has been constructed in the present study. Based on this potential, direct alloying between W and Cu at high temperature has been verified, and the corresponding diffusion mechanism has been studied, through molecular dynamics (MD) simulations. The results indicate that the formation of an amorphous Cu layer at the W/Cu interface plays a critical role in alloying because it allows Cu atoms to diffuse into W. The simulation results for direct alloying between W and Cu can be verified by experimental results and transmission electron microscopy observations. This indicates that the constructed W-Cu potential can correctly model the high-temperature performance of the W-Cu system and the diffusion mechanism of direct alloying between W and Cu.

scholarly journals Fundamental Investigations on the High-Temperature Corrosion of Spinel-Forming Alumina Castables by Steel Slags

2022 ◽  
Vol 12 (2) ◽  
pp. 704
Author(s):  
Jakub Ramult ◽  
Klaudia Wiśniewska-Tobiasz ◽  
Ryszard Prorok ◽  
Dominika Madej
Keyword(s):  
High Temperature ◽  
Liquid Phase ◽  
Corrosion Test ◽  
Steel Slag ◽  
High Temperature Corrosion ◽  
Mass Ratio ◽  
Narrow Temperature Range ◽  
Coating Method ◽  
Alumina Castables ◽  
Static Corrosion

This study investigated the effect of the CaO/SiO2 mass ratio of steel slag on the corrosion behavior of spinel-forming alumina-based castables with a content of MgO (3–7 wt.%). Equiweight mixtures of castables and slags were calculated by FactSage, observed by HMTA, fired at 1350 °C, and investigated by XRD. From these results, we conclude that the presence of SiO2-rich phases accelerates the growth of the liquid phase in a narrow temperature range for the tested samples, which accelerates the degradation of castables. The static corrosion test was conducted by means of the coating method at 1450 °C. The corrosion index (IC) in the regions of castables affected by slags was calculated. Phases and phase distributions were evaluated by SEM-EDS. From these results, we conclude that for the slag with the lowest mass ratio of CaO/SiO2 (1.1), the reaction zone occurs only below the slag-refractory interface, which indicates the aggressive character of this slag.

The Synthesis from α-SiO2 and Graphite System to Coesite under High Temperature High Pressure

2014 ◽  
Vol 1051 ◽  
pp. 299-302
Author(s):  
De Jun Wang ◽  
Run Ru Liu ◽  
Leng Jing ◽  
Xin Yu Bai
Keyword(s):  
High Pressure ◽  
High Temperature ◽  
Carbon Content ◽  
Powder Mixture ◽  
Mechanical Milling ◽  
Graphite Powder ◽  
High Energy ◽  
Mass Ratio ◽  
Synthesis Conditions ◽  
High Temperature High Pressure

Taking α-quartz of different mass ratio mixed with graphite powder mixture as the initial materials, using the method of combining high-energy mechanical milling with high pressure and high temperature , this work inspected the influences of carbon content on the synthesis conditions of coesite. The experimental products were measured by XRD, TEM, and Raman. The results showed that the existence of carbon can obviously inhibit the formation of coesite, and the higher carbon content of initial materials the higher pressure on forming coesite is needed.

scholarly journals Effect of MgO Content on the Viscosity, Foaming Life, and Bonding in Liquid and Liquid/Solid CaO-SiO2-MgO-5Al2O3-30FeO Slags

Metals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 249
Author(s):  
Yu-En Chang ◽  
Chi-Ming Lin ◽  
Jyun-Ming Shen ◽  
Wei-Ti Chang ◽  
Weite Wu
Keyword(s):  
High Temperature ◽  
Magnesium Oxide ◽  
Network Structure ◽  
Environmental Conditions ◽  
Liquid Slag ◽  
Slag System ◽  
Solid Particles ◽  
Basicity Constant ◽  
Mass Ratio ◽  
Factsage Software

The CaO-SiO2-MgO-5Al2O3-30FeO five (oxide) components slag system was studied by varying the magnesium oxide (MgO) content (5.7–13.6 wt.%.% MgO) and keeping the basicity constant). The data were analyzed using the FactSage software. It was observed that the liquid network structure and precipitation of solid particles had an impact on high-temperature viscosity and foaming life. Under the same basicity (mass ratio CaO/SiO2 = 1.5) and at a temperature of 1500 °C, the MgO content was varied as 5.7 wt.%, 7.4 wt.%, 9.6 wt.%, 11.5 wt.%, and 13.6 wt.% in A0~A5. The solid fractions of different samples were estimated with FactSage software and found to be A0–A2 (0 wt.%), A3 (2.77 wt.%), A4 (6.92 wt.%), A5 (11.7 wt.%). The viscosities of A0–A5 measured at 1500 ·C were 22, 47, 40, 76, 363, and 1088 mPa×s, respectively, and the foaming life was 2.0 min, 7.7 min, 6.2 min, 13.4 min, 16.8 min, and 18.0 min, respectively. It was found that A5 exhibits the best effective foaming life under these environmental conditions because it can ex-hibit a double foaming effect formed by the precipitation of solid particles. The Si-O-Si network in liquid slag also contributed to foaming life, when there was only liquid slag bonding in the slag, the effective foaming life was 7.7 min. In the absence of these factors, the foaming life was only 2 min.

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