Effect of Two-Step Treatments on Interfacial and Mechanical Properties of Sugarcane Rind Fiber/Natural Latex Biodegradable Composites

2014 ◽  
Vol 789 ◽  
pp. 106-111 ◽  
Author(s):  
Shi Yan Chen ◽  
Shi Yan Chen ◽  
Hai Xia Xin ◽  
Hua Ping Wang
Keyword(s):  
Mechanical Properties ◽  
Interfacial Adhesion ◽  
Fiber Surface ◽  
Treatment Method ◽  
Elongation At Break ◽  
Chemical Treatments ◽  
Biodegradable Composites ◽  
One Step ◽  
Treated Fiber ◽  
Reinforcing Filler

Sugarcane rind fiber/natural latex biodegradable composites were prepared by compounding natural latex with sugarcane rind fiber as reinforcing filler. We selected three chemical solvents, including sodium hydroxide (NaOH), silane (KH550) and acrylic acid (AA), and used one-step or two-step treatment method to improve the interfacial adhesion between sugarcane rind fiber and natural latex matrix. Fourier Transform Infrared spectroscopy (FTIR) was used to characterize the chemical composition change at the sugarcane rind fiber surface structure by the chemical treatments. Scanning Electron Microscopy (SEM) results showed that the interfacial adhesion and dispersion of the composites based on two-step treated fiber were improved. The mechanical properties of these biodegradable composites were evaluated, which showed an increase of the tensile strength and elongation at break of the composites based on two-step treated fiber compared to those based on untreated fiber.

Recycling of Bagasse as an Agricultural Waste and its Effect as Filler on Some Mechanical and Physical Properties of SBR Composites

2021 ◽  
Vol 36 (5) ◽  
pp. 586-595
Author(s):  
E. S. A. Khalaf
Keyword(s):  
Mechanical Properties ◽  
Interfacial Adhesion ◽  
Agricultural Waste ◽  
Optimum Concentration ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Elongation At Break ◽  
Mechanical And Physical Properties ◽  
Styrene Butadiene ◽  
Reinforcing Filler

Abstract In the present study, a series of mixes based on different concentrations of carbon black (CB) as a reinforcing filler and sugarcane bagasse as supplementary filler, were investigated to examine their effects on the mechanical properties of styrene butadiene rubber (SBR) composites. To this end, the first group of mixes deals with the effect of different concentrations of CB ranging from 0 to 80 phr at fixed bagasse concentration of 25 phr. The second group of mixes involves the addition of bagasse with concentrations varying from 10 to 50 phr at 10 intervals with fixed CB concentration of 40 phr. The sizes of the employed ground bagasse powder (GBP) in all prepared formulations ranged from 20 to 180 μm. In addition, 2.5 phr of maleic anhydride (MA) was added to enhance the interfacial adhesion between SBR and agricultural waste fillers (i. e. bagasse). Tensile strength, elongation at break, modulus at 100% elongation, resilience, hardness (Shore A), abrasion and degree of swelling of the rubber vulcanizates were studied. The prepared samples were also analyzed by scanning electron microscopy (SEM) to show the distribution of fiber and the occurrence of fiber-matrix adhesion. The optimum concentration of bagasse to be used simultaneously with CB in SBR composites was found to be 30 phr. Overall, it was found from the obtained results that the addition of GBP up to 50 phr is feasible without impairing the mechanical properties of SBR vulcanizates.

scholarly journals Effects of Chemical Modification on the Mechanical Properties of Calotropis Gigantea Fiber-reinforced Phenol Formaldehyde Biocomposites

2020 ◽  
Vol 26 (3) ◽  
pp. 295-299
Author(s):  
Sekar SANJEEVI ◽  
Athijayamani AYYANAR ◽  
Ramanathan KALIMUTHU ◽  
Sidhardhan SUSAIYAPPAN
Keyword(s):  
Mechanical Properties ◽  
Chemical Modification ◽  
Phenol Formaldehyde ◽  
Fiber Composites ◽  
Fiber Content ◽  
The Other ◽  
Fiber Reinforced ◽  
Calotropis Gigantea ◽  
Chemical Treatments ◽  
Treated Fiber

In this paper, the effects of three different chemical treatments on the mechanical properties of Phenol Formaldehyde (PF) composites reinforced with the Calotropis Gigantea Fibers (CGFs) were investigated based on the fiber content of the fibers. Composites were prepared by the untreated and treated fibers using the hand lay up technique and their mechanical properties were evaluated and compared. The results revealed that the composites show the greater mechanical properties at 40 wt.% for the untreated condition. Composites prepared with alkali treated fibers show the better mechanical properties as compared with the other treated fiber composites.

Effect of Ashes as Biomass in Silica Filled Natural Rubber

2017 ◽  
Vol 735 ◽  
pp. 153-157
Author(s):  
Wasinee Pinpat ◽  
Wirunya Keawwattana ◽  
Siree Tangbunsuk
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Natural Rubber ◽  
Rice Husk Ash ◽  
Silica Content ◽  
Elongation At Break ◽  
Compression Set ◽  
Cure Time ◽  
Oil Palm Ash ◽  
Reinforcing Filler

Silica has been used as reinforcing filler in natural rubber for a period of time as it results in excellent properties for NR vulcanizes. Rice husk ash (RHA), bagasse ash (BA), and oil palm ash (OPA) obtained from agricultural wastes are mainly composed of silica in the percentage of 80.00%, 57.33%, and 40.20% by weight, respectively. The effect of these fillers on cure characteristics and mechanical properties of natural rubber materials at fixed silica content at 35 parts per hundred of rubber (phr) were investigated. The results indicated that ashes showed greater cure time compared to that of the silica. The incorporation of ashes into natural rubber gradually improved compression set but significantly decreased tensile strength, elongation at break, and resilience. Moreover, young's modulus increased, while hardness showed no significant change with the addition of ashes. Overall results indicated that ashes could be used as cheaper fillers for natural rubber materials where improved mechanical properties were not critical.

The effect of simultaneous fiber surface treatment and matrix modification on mechanical properties of unidirectional ultra-high molecular weight polyethylene fiber/epoxy/nanoclay nanocomposites

2018 ◽  
Vol 52 (21) ◽  
pp. 2961-2972 ◽  
Author(s):  
Mohammad Mohammadalipour ◽  
Mahmood Masoomi ◽  
Mojtaba Ahmadi ◽  
Zahra Kazemi
Keyword(s):  
Mechanical Properties ◽  
Molecular Weight ◽  
Tensile Strength ◽  
High Molecular Weight ◽  
Glycidyl Methacrylate ◽  
Interfacial Adhesion ◽  
Fiber Surface ◽  
Cohesive Failure ◽  
Polyethylene Fiber ◽  
Ultra High Molecular Weight

Nonpolar structure of ultra-high molecular weight polyethylene fiber leads to a weak interfacial adhesion in ultra-high molecular weight polyethylene fiber reinforced epoxy composite. Herein, synchronized fiber and matrix modifications were utilized so as to improve the interfacial adhesion, resulting in promoting mechanical properties of these composites. For this purpose, the surface of ultra-high molecular weight polyethylene fiber was chemically treated with glycidyl methacrylate and the epoxy resin was modified through incorporation of different contents of nanoclay. The mechanical properties results showed that individual modification, either fiber or matrix, can just lead to improvements around 36.74% and 10.54% in tensile strength as well as 14.28% and 4.27% in tensile modulus, respectively. However, the ultimate outcome of the study revealed that much higher improvement can be achieved in synergistic attitude. The highest enhancement around 48.31% and 26.76% in tensile strength and modulus were seen for the sample containing glycidyl methacrylate-treated ultra-high molecular weight polyethylene fibers as reinforcement and nano epoxy modified with 1 wt.% of nanoclay. Such observation could be attributed to the mechanical interlocking and chemical reaction which were arising from incorporation of nanoclay in matrix and chemical treatment of fiber surface, correspondingly. In this regard, fiber roughness and chemical bonds formed between treated fiber and modified matrix play a key role in improving interfacial adhesion. Moreover, the fractured surface of such composites studied by scanning electron microscope confirmed the mechanical results and showed that much more matrix was adhered to the fiber surface after treatment, indicating cohesive failure.

scholarly journals Mechanical and Hydrothermal Aging Behaviour of Polyhydroxybutyrate-Co-Valerate (PHBV) Composites Reinforced by Natural Fibres

Molecules ◽  
2019 ◽  
Vol 24 (19) ◽  
pp. 3538 ◽  
Author(s):  
Karolina Mazur ◽  
Stanisław Kuciel
Keyword(s):  
Mechanical Properties ◽  
Young’S Modulus ◽  
Interfacial Adhesion ◽  
Saline Solution ◽  
Young's Modulus ◽  
Morphological Aspect ◽  
Reinforced Composites ◽  
Wood Fibers ◽  
Hydrothermal Aging ◽  
Biodegradable Composites

Biodegradable composites based on poly (3-hydroxybutyrate-co-3-hydroxyvalerate), reinforced with 7.5% or 15% by weight of wood fibers (WF) or basalt fibers (BF) were fabricated by injection molding. BF reinforced composites showed improvement in all properties, whereas WF composites showed an increase in Young’s modulus values, but a drop in strength and impact properties. When compared with the unmodified polymer, composites with 15% by weight of BF showed an increase of 74% in Young’s modulus and 41% in impact strength. Furthermore, the experimentally measured values of Young’s modulus were compared with values obtained in various theoretical micromechanical models. The Haplin-Kardas model was found to be in near approximation to the experimental data. The morphological aspect of the biocomposites was studied using scanning electron microscopy to obtain the distribution and interfacial adhesion of the fibers. Additionally, biodegradation tests of the biocomposites were performed in saline solution at 40 °C by studying the weight loss and mechanical properties. It was observed that the presence of fibers affects the rate of water absorption and the highest rate was seen for composites with 15% by weight of WF. This is dependent on the nature of the fiber. After both the first and second weeks mechanical properties decreased slightly about 10%.

EFFECT OF SURFACE TREATMENT ON THE PROPERTIES OF WOOL FABRIC

2007 ◽  
Vol 14 (04) ◽  
pp. 559-563 ◽  
Author(s):  
C. W. KAN ◽  
C. W. M. YUEN ◽  
C. K. CHAN ◽  
M. P. LAU
Keyword(s):  
Mechanical Properties ◽  
Thermal Properties ◽  
Fiber Surface ◽  
Air Permeability ◽  
Wool Fiber ◽  
Wool Fabric ◽  
Physical Treatment ◽  
Temperature Plasma ◽  
Technical Problems ◽  
Chemical Treatments

Wool fiber is commonly used in textile industry, however, it has some technical problems which affect the quality and performance of the finished products such as felting shrinkage, handle, lustre, pilling, and dyeability. These problems may be attributed mainly in the presence of wool scales on the fiber surface. Recently, chemical treatments such as oxidation and reduction are the commonly used descaling methods in the industry. However, as a result of the pollution caused by various chemical treatments, physical treatment such as low temperature plasma (LTP) treatment has been introduced recently because it is similarly capable of achieving a comparable descaling effect. Most of the discussions on the applications of LTP treatment on wool fiber were focused on applying this technique for improving the surface wettability and shrink resistance. Meanwhile, little discussion has been made on the mechanical properties, thermal properties, and the air permeability. In this paper, wool fabric was treated with LTP treatment with the use of a non-polymerizing gas, namely oxygen. After the LTP treatment, the fabrics low-stress mechanical properties, air permeability, and thermal properties were evaluated and discussed.

Composites of Poly(lactic Acid) with Rice Straw Fibers Modified by Poly(butyl Acrylate)

2011 ◽  
Vol 675-677 ◽  
pp. 357-360
Author(s):  
Li Jun Qin ◽  
Jian Hui Qiu ◽  
Ming Zhu Liu ◽  
Sheng Long Ding ◽  
Liang Shao ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Lactic Acid ◽  
Rice Straw ◽  
Butyl Acrylate ◽  
Interfacial Adhesion ◽  
Suspension Polymerization ◽  
Water Solution ◽  
Poly Lactic Acid ◽  
Biodegradable Composites

The modified rice straw fibers (MRSF) were prepared by suspension polymerization technique of butyl acrylate (BA) monomer and rice straw fibers (RSF) in water solution. FTIR test indicated that PBA was coated and absorbed on RSF.The biodegradable composites were prepared with the MRSF and poly(lactic acid) (PLA) by HAAKE rheometer. Mechanical properties showed that the tensile strength of PLA/MRSF composites were (W (%) =7.98%) increased by 6 MPa compared with blank sample. The possible reason was that the good interfacial adhesion between PLA and MRSF, which was demonstrated by SEM.

PLA-Based Biodegradable Copolyester Nanocomposites: Preparation, Characterization and Mechanical Properties

2011 ◽  
Vol 380 ◽  
pp. 290-293
Author(s):  
Bing Tao Wang ◽  
Ping Zhang ◽  
De Gao
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Lactic Acid ◽  
Interfacial Adhesion ◽  
Polyhedral Oligomeric Silsesquioxanes ◽  
Elongation At Break ◽  
Butylene Terephthalate ◽  
The Matrix ◽  
Different Characteristics

In situ melt copolycondensation was proposed to prepare biodegradable copolyester nanocomposites based on degradable components poly(L-lactic acid) (PLA), rigid segments poly(butylene terephthalate) (PBT), and nanoparticles polyhedral oligomeric silsesquioxanes (POSS). The morphologies and dispersions of two POSS nanoparticles (POSS-NH2 and POSS-PEG) in the copolyester PLABT matrix and their effects on the mechanical properties were investigated. The results demonstrated that the morphologies and dispersions of POSS-NH2 and POSS-PEG showed quite different characteristics. POSS-PEG took better dispersion in the PLABT, while POSS-NH2 had poor dispersions and formed crystalline microaggregates. Due to the good dispersion and strong interfacial adhesion of POSS-PEG with the matrix, the tensile strength and Young’s modulus were greatly improved from 6.4 and 9.6 MPa for neat PLABT up to 11.2 and 70.7 MPa for PLABT/POSS-PEG nanocomposite. Moreover, the incorporation of POSS-PEG could impart macromolecular chains good flexibility and improve the mobility of the chains, so the the elongation at break of PLABT/POSS-PEG nanocomposite dramatically increased from 190 to 350 % compared with neat PLABT.

Isocyanate Modification of Wood Fiber in Enhancing the Performance of its Composites with High Density Polyethylene

2012 ◽  
Vol 3 (2) ◽  
pp. 43-60 ◽  
Author(s):  
Fereshteh Arjmand ◽  
Mohammad Barmar ◽  
Mehdi Barikani
Keyword(s):  
Mechanical Properties ◽  
Interfacial Adhesion ◽  
Moisture Absorption ◽  
Wood Fiber ◽  
Cetyl Alcohol ◽  
Toluene Diisocyanate ◽  
Coupling Agents ◽  
Ftir Analysis ◽  
Moisture Uptake ◽  
Chemical Treatments

This study is focused on the modification of wood fiber by using a reactive diisocyanate (toluene diisocyanate, TDI) linker to couple wood fiber with cetyl alcohol and the investigation of its effects on mechanical properties of wood fiber–HDPE composites. The reaction of TDI with wood fiber and then cetyl alcohol resulted in the formation of new urethane bonds assessed by FTIR analysis. Therefore, TDI ended cetyl alcohol was used as a coupling agent in the preparation of wood fiber/ HDPE composite. The outcomes showed that the addition of such coupling agents resulted in greater reinforcement of composites, as indicated by the improvement in mechanical properties. Tensile strength of prepared composites increased by almost 64%, whereas 47% increase in flexural strength and 113% increase in impact properties was observed. However, the moisture absorption of the composites decreased by about 43%. All chemically treated composites showed lower moisture uptake than the untreated composites. This may be due to chemical treatment of wood fiber which reduces its hydrophilicity. These chemical treatments promote interfacial adhesion of fiber and HDPE matrix. Furthermore, scanning electron microscopy (SEM) revealed the improved morphology of the fractured surfaces of composites.

scholarly journals Effect of Superheated Steam Treatment on the Mechanical Properties and Dimensional Stability of PALF/PLA Biocomposite

Polymers ◽  
2019 ◽  
Vol 11 (3) ◽  
pp. 482 ◽  
Author(s):  
Ahmed Challabi ◽  
Buong Chieng ◽  
Nor Ibrahim ◽  
Hidayah Ariffin ◽  
Norhazlin Zainuddin
Keyword(s):  
Mechanical Properties ◽  
Dimensional Stability ◽  
Interfacial Adhesion ◽  
Superheated Steam ◽  
Weight Ratio ◽  
Xrd Analysis ◽  
Treatment Method ◽  
Sem Analysis ◽  
Steam Treatment ◽  
Different Temperatures

The effectiveness of superheated steam (SHS) as an alternative, eco-friendly treatment method to modify the surface of pineapple leaf fiber (PALF) for biocomposite applications was investigated. The aim of this treatment was to improve the interfacial adhesion between the fiber and the polymer. The treatment was carried out in an SHS oven for different temperatures (190–230 °C) and times (30–120 min). Biocomposites fabricated from SHS-treated PALFs and polylactic acid (PLA) at a weight ratio of 30:70 were prepared via melt-blending techniques. The mechanical properties, dimensional stability, scanning electron microscopy (SEM), and X-ray diffraction (XRD) for the biocomposites were evaluated. Results showed that treatment at temperature of 220 °C for 60 min gave the optimum tensile properties compared to other treatment temperatures. The tensile, flexural, and impact properties as well as the dimensional stability of the biocomposites were enhanced by the presence of SHS-treated PALF. The SEM analysis showed improvement in the interfacial adhesion between PLA and SHS-treated PALF. XRD analysis showed an increase in the crystallinity with the addition of SHS-PALF. The results suggest that SHS can be used as an environmentally friendly treatment method for the modification of PALF in biocomposite production.

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