Calibration of atmospheric hydrogen measurements

Abstract. Interest in atmospheric hydrogen (H2) has been growing in recent years with the prospect of H2 being a potential alternative to fossil fuels as an energy carrier. This has intensified research for a quantitative understanding of the atmospheric hydrogen cycle and its total budget, including the expansion of the global atmospheric measurement network. However, inconsistencies in published observational data constitute a major limitation in exploring such data sets. The discrepancies can be mainly attributed to difficulties in the calibration of the measurements. In this study various factors that may interfere with accurate quantification of atmospheric H2 were investigated including drifts of standard gases in high pressure cylinders. As an experimental basis a procedure to generate precise mixtures of H2 within the atmospheric concentration range was established. Application of this method has enabled a thorough linearity characterization of the commonly used GC-HgO reduction detector. We discovered that the detector response was sensitive to the composition of the matrix gas. Addressing these systematic errors, an accurate calibration scale has been generated defined by thirteen standards with dry air mole fractions ranging from 139–1226 nmol mol−1. The new scale has been accepted as the official World Meteorological Organisation's (WMO) Global Atmospheric Watch (GAW) H2 mole fraction scale.

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Calibration of atmospheric hydrogen measurements

Atmospheric Measurement Techniques ◽

10.5194/amt-4-509-2011 ◽

2011 ◽

Vol 4 (3) ◽

pp. 509-521 ◽

Cited By ~ 32

Author(s):

A. Jordan ◽

B. Steinberg

Keyword(s):

Fossil Fuels ◽

Detector Response ◽

Data Sets ◽

Atmospheric Concentration ◽

The Matrix ◽

Quantitative Understanding ◽

Potential Alternative ◽

Hydrogen Cycle ◽

Accurate Quantification

Abstract. Interest in atmospheric hydrogen (H2) has been growing in recent years with the prospect of H2 being a potential alternative to fossil fuels as an energy carrier. This has intensified research for a quantitative understanding of the atmospheric hydrogen cycle and its total budget, including the expansion of the global atmospheric measurement network. However, inconsistencies in published observational data constitute a major limitation in exploring such data sets. The discrepancies can be mainly attributed to difficulties in the calibration of the measurements. In this study various factors that may interfere with accurate quantification of atmospheric H2 were investigated including drifts of standard gases in high pressure cylinders. As an experimental basis a procedure to generate precise mixtures of H2 within the atmospheric concentration range was established. Application of this method has enabled a thorough linearity characterization of the commonly used GC-HgO reduction detector. We discovered that the detector response was sensitive to the composition of the matrix gas. Addressing these systematic errors, a new calibration scale has been generated defined by thirteen standards with dry air mole fractions ranging from 139–1226 nmol mol−1. This new scale has been accepted as the official World Meteorological Organisation's (WMO) Global Atmospheric Watch (GAW) H2 mole fraction scale.

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Characterization of Lignin Compounds at the Molecular Level: Mass Spectrometry Analysis and Raw Data Processing

Molecules ◽

10.3390/molecules26010178 ◽

2021 ◽

Vol 26 (1) ◽

pp. 178

Author(s):

Ruochun Zhang ◽

Yulin Qi ◽

Chao Ma ◽

Jinfeng Ge ◽

Qiaozhuan Hu ◽

...

Keyword(s):

Mass Spectrometry ◽

Fossil Fuels ◽

Molecular Level ◽

Mass Spectrometry Analysis ◽

Terrestrial Organic Matter ◽

Spectrometry Analysis ◽

Analysis Strategies ◽

Chemical Pulping ◽

Potential Alternative

Lignin is the second most abundant natural biopolymer, which is a potential alternative to conventional fossil fuels. It is also a promising material for the recovery of valuable chemicals such as aromatic compounds as well as an important biomarker for terrestrial organic matter. Lignin is currently produced in large quantities as a by-product of chemical pulping and cellulosic ethanol processes. Consequently, analytical methods are required to assess the content of valuable chemicals contained in these complex lignin wastes. This review is devoted to the application of mass spectrometry, including data analysis strategies, for the elemental and structural elucidation of lignin products. We describe and critically evaluate how these methods have contributed to progress and trends in the utilization of lignin in chemical synthesis, materials, energy, and geochemistry.

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TEM characterization of reaction zone in a SiC fiber-reinforced titanium alloy

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100105758 ◽

1988 ◽

Vol 46 ◽

pp. 738-739

Author(s):

G. Das ◽

R. E. Omlor

Keyword(s):

Titanium Alloys ◽

Reaction Zone ◽

Carbon Layer ◽

Fiber Reinforced ◽

Reaction Products ◽

Sic Fibers ◽

Sic Fiber ◽

The Matrix ◽

Immense Potential

Fiber reinforced titanium alloys hold immense potential for applications in the aerospace industry. However, chemical reaction between the fibers and the titanium alloys at fabrication temperatures leads to the formation of brittle reaction products which limits their development. In the present study, coated SiC fibers have been used to evaluate the effects of surface coating on the reaction zone in the SiC/IMI829 system.IMI829 (Ti-5.5A1-3.5Sn-3.0Zr-0.3Mo-1Nb-0.3Si), a near alpha alloy, in the form of PREP powder (-35 mesh), was used a茸 the matrix. CVD grown AVCO SCS-6 SiC fibers were used as discontinuous reinforcements. These fibers of 142μm diameter contained an overlayer with high Si/C ratio on top of an amorphous carbon layer, the thickness of the coating being ∽ 1μm. SCS-6 fibers, broken into ∽ 2mm lengths, were mixed with IMI829 powder (representing < 0.1vol%) and the mixture was consolidated by HIP'ing at 871°C/0. 28GPa/4h.

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Characterization of the Structure, Mechanical Properties and Erosive Resistance of the Laser Cladded Inconel 625-Based Coatings Reinforced by TiC Particles

Materials ◽

10.3390/ma14092225 ◽

2021 ◽

Vol 14 (9) ◽

pp. 2225

Author(s):

Aleksandra Kotarska ◽

Tomasz Poloczek ◽

Damian Janicki

Keyword(s):

Laser Cladding ◽

Inconel 625 ◽

Matrix Composites ◽

Erosion Rates ◽

Laser Cladding Process ◽

Composition Variation ◽

The Matrix ◽

Reinforcing Material ◽

Inconel 625 Superalloy

The article presents research in the field of laser cladding of metal-matrix composite (MMC) coatings. Nickel-based superalloys show attractive properties including high tensile strength, fatigue resistance, high-temperature corrosion resistance and toughness, which makes them widely used in the industry. Due to the insufficient wear resistance of nickel-based superalloys, many scientists are investigating the possibility of producing nickel-based superalloys matrix composites. For this study, the powder mixtures of Inconel 625 superalloy with 10, 20 and 40 vol.% of TiC particles were used to produce MMC coatings by laser cladding. The titanium carbides were chosen as reinforcing material due to high thermal stability and hardness. The multi-run coatings were tested using penetrant testing, macroscopic and microscopic observations, microhardness measurements and solid particle erosive test according to ASTM G76-04 standard. The TiC particles partially dissolved in the structure during the laser cladding process, which resulted in titanium and carbon enrichment of the matrix and the occurrence of precipitates formation in the structure. The process parameters and coatings chemical composition variation had an influence on coatings average hardness and erosion rates.

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Mechanical characterization of LM25 alloy matrix composite reinforced with boron carbide

Journal of Composite Materials ◽

10.1177/00219983211005513 ◽

2021 ◽

pp. 002199832110055

Author(s):

Zeeshan Ahmad ◽

Sabah Khan

Keyword(s):

Tensile Strength ◽

Boron Carbide ◽

Mechanical Characterization ◽

Stir Casting ◽

Surface Mapping ◽

Alloy Matrix ◽

Casting Technique ◽

The Matrix ◽

Carbide Particles

Alumnium alloy LM 25 based composites reinforced with boron carbide at different weight fractions of 4%, 8%, and 12% were fabricated by stir casting technique. The microstructures and morphology of the fabricated composites were studied by scanning electron microscopy and energy dispersive spectroscopy. Elemental mapping of all fabricated composites were done to demonstrate the elements present in the matrix and fabricated composites. The results of microstructural analyses reveal homogenous dispersion of reinforcement particles in the matrix with some little amount of clustering found in composites reinforced with 12% wt. of boron carbide. The mechanical characterization is done for both alloy LM 25 and all fabricated composites based on hardness and tensile strength. The hardness increased from 13.6% to 21.31% and tensile strength 6.4% to 22.8% as reinforcement percentage of boron carbide particles increased from 0% to 12% wt. A fractured surface mapping was also done for all composites.

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SiLiF Neutron Counters to Monitor Nuclear Materials in the MICADO Project

Sensors ◽

10.3390/s21082630 ◽

2021 ◽

Vol 21 (8) ◽

pp. 2630

Author(s):

Luigi Cosentino ◽

Quentin Ducasse ◽

Martina Giuffrida ◽

Sergio Lo Meo ◽

Fabio Longhitano ◽

...

Keyword(s):

Radioactive Waste ◽

Detector Response ◽

Nuclear Materials ◽

Spent Fuel ◽

Neutron Detectors ◽

Intermediate Level Radioactive Waste ◽

Eu Project ◽

Interim Storage ◽

Waste Drums

In the framework of the MICADO (Measurement and Instrumentation for Cleaning And Decommissioning Operations) European Union (EU) project, aimed at the full digitization of low- and intermediate-level radioactive waste management, a set of 32 solid state thermal neutron detectors named SiLiF has been built and characterized. MICADO encompasses a complete active and passive characterization of the radwaste drums with neutrons and gamma rays, followed by a longer-term monitoring phase. The SiLiF detectors are suitable for the monitoring of nuclear materials and can be used around radioactive waste drums possibly containing small quantities of actinides, as well as around spent fuel casks in interim storage or during transportation. Suitable polyethylene moderators can be exploited to better shape the detector response to the expected neutron spectrum, according to Monte Carlo simulations that were performed. These detectors were extensively tested with an AmBe neutron source, and the results show a quite uniform and reproducible behavior.

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Characterization of a new natural fiber extracted from Corypha taliera fruit

Scientific Reports ◽

10.1038/s41598-021-87128-8 ◽

2021 ◽

Vol 11 (1) ◽

Author(s):

Taslima Ahmed Tamanna ◽

Shah Alimuzzaman Belal ◽

Mohammad Abul Hasan Shibly ◽

Ayub Nabi Khan

Keyword(s):

Tensile Strength ◽

Natural Fiber ◽

Natural Fibers ◽

Morphological Characteristics ◽

Synthetic Fiber ◽

X Ray Diffraction ◽

Reinforced Composite ◽

Potential Alternative

AbstractThis study deals with the determination of new natural fibers extracted from the Corypha taliera fruit (CTF) and its characteristics were reported for the potential alternative of harmful synthetic fiber. The physical, chemical, mechanical, thermal, and morphological characteristics were investigated for CTF fibers. X-ray diffraction and chemical composition characterization ensured a higher amount of cellulose (55.1 wt%) content and crystallinity (62.5%) in the CTF fiber. The FTIR analysis ensured the different functional groups of cellulose, hemicellulose, and lignin present in the fiber. The Scherrer’s equation was used to determine crystallite size 1.45 nm. The mean diameter, specific density, and linear density of the CTF fiber were found (average) 131 μm, 0.86 g/cc, and 43 Tex, respectively. The maximum tensile strength was obtained 53.55 MPa for GL 20 mm and Young’s modulus 572.21 MPa for GL 30 mm. The required energy at break was recorded during the tensile strength experiment from the tensile strength tester and the average values for GL 20 mm and GL 30 mm are 0.05381 J and 0.08968 J, respectively. The thermal analysis ensured the thermal sustainability of CTF fiber up to 230 °C. Entirely the aforementioned outcomes ensured that the new CTF fiber is the expected reinforcement to the fiber-reinforced composite materials.

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Possible Pitfalls in the Analysis of Minerals and Loose Materials by Portable XRF, and How to Overcome Them

Minerals ◽

10.3390/min11010033 ◽

2020 ◽

Vol 11 (1) ◽

pp. 33

Author(s):

Valérie Laperche ◽

Bruno Lemière

Keyword(s):

Fluorescence Spectroscopy ◽

Laboratory Data ◽

Data Sets ◽

Light Elements ◽

Portable Xrf ◽

X Ray ◽

Protective Films ◽

The Matrix ◽

Valuable Complement ◽

Physical Effects

Portable X-ray fluorescence spectroscopy is now widely used in almost any field of geoscience. Handheld XRF analysers are easy to use, and results are available in almost real time anywhere. However, the results do not always match laboratory analyses, and this may deter users. Rather than analytical issues, the bias often results from sample preparation differences. Instrument setup and analysis conditions need to be fully understood to avoid reporting erroneous results. The technique’s limitations must be kept in mind. We describe a number of issues and potential pitfalls observed from our experience and described in the literature. This includes the analytical mode and parameters; protective films; sample geometry and density, especially for light elements; analytical interferences between elements; physical effects of the matrix and sample condition, and more. Nevertheless, portable X-ray fluorescence spectroscopy (pXRF) results gathered with sufficient care by experienced users are both precise and reliable, if not fully accurate, and they can constitute robust data sets. Rather than being a substitute for laboratory analyses, pXRF measurements are a valuable complement to those. pXRF improves the quality and relevance of laboratory data sets.

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Reliability Assessment of a Multi-State HVDC System by Combining Markov and Matrix-Based Methods

Energies ◽

10.3390/en14113097 ◽

2021 ◽

Vol 14 (11) ◽

pp. 3097

Author(s):

Roberto Benato ◽

Antonio Chiarelli ◽

Sebastian Dambone Sessa

Keyword(s):

Current System ◽

Estimation Method ◽

Reliability Estimation ◽

Voltage Source ◽

Voltage Source Converter ◽

Hvdc System ◽

Critical Elements ◽

The Matrix ◽

The Impact

The purpose of this paper is to highlight that, in order to assess the availability of different HVDC cable transmission systems, a more detailed characterization of the cable management significantly affects the availability estimation since the cable represents one of the most critical elements of such systems. The analyzed case study consists of a multi-terminal direct current system based on both line commutated converter and voltage source converter technologies in different configurations, whose availability is computed for different transmitted power capacities. For these analyses, the matrix-based reliability estimation method is exploited together with the Monte Carlo approach and the Markov state space one. This paper shows how reliability analysis requires a deep knowledge of the real installation conditions. The impact of these conditions on the reliability evaluation and the involved benefits are also presented.

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Characterization of Mmp37p, aSaccharomyces cerevisiaeMitochondrial Matrix Protein with a Role in Mitochondrial Protein Import

Molecular Biology of the Cell ◽

10.1091/mbc.e06-04-0366 ◽

2006 ◽

Vol 17 (9) ◽

pp. 4051-4062 ◽

Cited By ~ 47

Author(s):

Michelle R. Gallas ◽

Mary K. Dienhart ◽

Rosemary A. Stuart ◽

Roy M. Long

Keyword(s):

Matrix Protein ◽

Protein Import ◽

Mitochondrial Protein ◽

Temperature Sensitive ◽

Inner Membrane ◽

Mitochondrial Inner Membrane ◽

Close Proximity ◽

The Matrix ◽

Targeting Signal

Many mitochondrial proteins are encoded by nuclear genes and after translation in the cytoplasm are imported via translocases in the outer and inner membranes, the TOM and TIM complexes, respectively. Here, we report the characterization of the mitochondrial protein, Mmp37p (YGR046w) and demonstrate its involvement in the process of protein import into mitochondria. Haploid cells deleted of MMP37 are viable but display a temperature-sensitive growth phenotype and are inviable in the absence of mitochondrial DNA. Mmp37p is located in the mitochondrial matrix where it is peripherally associated with the inner membrane. We show that Mmp37p has a role in the translocation of proteins across the mitochondrial inner membrane via the TIM23-PAM complex and further demonstrate that substrates containing a tightly folded domain in close proximity to their mitochondrial targeting sequences display a particular dependency on Mmp37p for mitochondrial import. Prior unfolding of the preprotein, or extension of the region between the targeting signal and the tightly folded domain, relieves their dependency for Mmp37p. Furthermore, evidence is presented to show that Mmp37 may affect the assembly state of the TIM23 complex. On the basis of these findings, we hypothesize that the presence of Mmp37p enhances the early stages of the TIM23 matrix import pathway to ensure engagement of incoming preproteins with the mtHsp70p/PAM complex, a step that is necessary to drive the unfolding and complete translocation of the preprotein into the matrix.

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