Preparation and study of low-resistance polyacrylonitrile nano membranes for gas filtration

2016 ◽  
Vol 87 (2) ◽  
pp. 208-215 ◽  
Author(s):  
Li-Hua Lou ◽  
Xiao-Hong Qin ◽  
Hongnan Zhang

In this paper, patterned nanofibrous membranes were fabricated for air filtration. Polyacrylonitrile was employed as the electrospinning material as its fluffy property and bulged bubble template served as collector to prepare the patterned membrane. With this special structure, the pressure drop significantly declined from 151.7 to 24.7 mmH2O, although the filtration efficiency of nanofiber membranes exhibited a slight decline from 99.94% to 96.33% compared to traditional electrospinning nanofibrous membranes. These sharp declines of the pressure drop while retaining the filtration efficiency imply that it could have more extensive applications.

2020 ◽  
pp. 152808372096141
Author(s):  
Chi Zou ◽  
Yunlong Shi ◽  
Xiaoming Qian

The glass fiber felt made through flame blowing process was characterized on morphology and its filtration performance. Fiber diameter has been measured through SEM and BET methods. Theoretical calculations on pressure drop and filtration efficiency were developed and compared with the experimental measurement. The discrepancy between the calculated results and measurement on filtration efficiency is derived from the presence of fine fiber (<0.5µm) in the glass fiber felt, which contributes to the actual high filtration efficiency in measurement. The multiple micro-layered structure in glass fiber felt, which improves the dust holding capacity and enables glass fiber felt as a depth filter. Glass fiber felt showed a longer duration of the slow increase region for pressure drop build-up comparing to other filter materials with lower averaged pressure drop through its filtration service life. Furthermore, quality factor calculation has been developed for prediction on the energy cost performance of the filters based on the pressure drop, separation efficiency and dust holding capacity.


2020 ◽  
pp. 152808372092377
Author(s):  
Bilal Zaarour ◽  
Hussen Tina ◽  
Lei Zhu ◽  
XiangYu Jin

Engineering the surface morphology of fibers has been attracting significant consideration in various areas and applications. In this study, polyvinylidene fluoride (PVDF) branched nanofibers with a diameter of less than 50 nm are electrospun directly at a low relative humidity by adding tetrabutylammonium chloride. The effects of the branched structure on the specific surface area and pore size distribution are investigated, and the filtration properties of the air filter based on branched nanofiber webs with different basis weights are studied. The results exhibit that the air filter based on PVDF branched nanofibers with the basis weight of 1 g/m2 has an outstanding filtration efficiency (99.999%) to 0.26 µm sodium chloride particles under the pressure drop of 126.17 Pa. We believe that this study can be used as a useful reference for the preparation of branched nanofibers through one-step electrospinning.


2017 ◽  
Vol 748 ◽  
pp. 423-427
Author(s):  
Jin Yu Zhao ◽  
Zhao Lin Liu ◽  
Ju Chuan Shan

Polyvinyl alcohol (PVA) nanofibrous membrances for effective air filtration were fabricated by electrospinning. Tunable fiber morphologies can be formed by facilely regulating the solution concentration and the applied voltage, and their effect on filtration performance of the PVA membrances were also investigeted. Results show that the PVA membrance exhibits high filtration efficiency of 97.1% and low pressure drop of 113 Pa when the PVA concentration is 8 wt% and the applied voltage is 15 kV with a tip-to-collector distance of 15 cm and a feed rate of 1 ml/h.


2018 ◽  
Vol 31 (4) ◽  
pp. 438-448 ◽  
Author(s):  
Bo Yi ◽  
Yuntao Zhao ◽  
Enling Tian ◽  
Jing Li ◽  
Yiwei Ren

Polyimide (PI) nanofiber membranes were successfully prepared from a PI/N-methyl-2-pyrrolidone (NMP) solution via electrospinning. This technique simply and facilely produced efficient high-performance PI fibers. The morphology, surface wettability, thermal stability, mechanical properties, and filtration performance of the as-prepared PI nanofiber membranes were characterized in detail. The membranes exhibited smooth and hydrophobic surfaces. The nanofibers were well distributed in the membranes with fiber diameters in the range of 140–400 nm. All the PI nanofiber membranes showed excellent thermostability, and their initial decomposition temperature ( Td) and heat resistance temperature ( THRI) exceeded 544.4°C and 198.8°C, respectively. The PI nanofiber membranes also possessed reasonable mechanical properties with a tensile strength and a Young’s modulus reaching 10.5 and 927.6 MPa, respectively. Regarding the filtration performance, the developed nanofiber membranes achieved the best filtration efficiency of 90.4%. Such electrospun PI nanofiber membranes can be a promising candidate for hot gas filtration.


Polymers ◽  
2021 ◽  
Vol 13 (19) ◽  
pp. 3257
Author(s):  
Fabrice N. H. Karabulut ◽  
Günther Höfler ◽  
Naveen Ashok Chand ◽  
Gareth W. Beckermann

Electrospun nanofibres can outperform their melt-blown counterparts in many applications, especially air filtration. The different filtration mechanisms of nanofibres are particularly important when it comes to the air filtration of viruses (such as COVID-19) and bacteria. In this work, we present an electrospun nanofibre filter media, FilterLayrTM by NanoLayr Ltd., containing poly(methyl methacrylate)/ethylene vinyl alcohol nanofibres. The outstanding uniformity of the nanofibres was indicated by the good correlation between pressure drop (ΔP) and areal weight with R2 values in the range of 0.82 to 0.98 across various test air velocities. By adjusting the nanofibre areal weight (basis weight), the nanofibre filter media was shown to meet the particle filtration efficiency and breathability requirements of the following internationally accepted facemask and respirator standards: N95 respirator facemask performance in accordance with NIOSH 42CFR84 (filtration efficiency of up to 98.10% at a pressure drop of 226 Pa and 290 Pa at 85 L·min−1 and 120 L·min−1, respectively), Level 2 surgical facemask performance in accordance with ASTM F2299 (filtration efficiency of up to 99.97% at 100 nm particle size and a pressure drop of 44 Pa at 8 L·min−1), and Level 2 filtration efficiency and Level 1 breathability for barrier face coverings in accordance with ASTM F3502 (filtration efficiency of up to 99.68% and a pressure drop of 133 Pa at 60 L·min−1), with Level 2 breathability being achievable at lower nanofibre areal weights.


2021 ◽  
pp. 152808372110610
Author(s):  
Shivendra Yadav ◽  
Dipayan Das

This article reports on development, characterization, and performance of liquid-treated nonwoven air filter media for automotive engine intake application. A polypropylene fiber-based needle-punched nonwoven fabric was prepared for treatment with four viscous liquids (glycerol, SAE 20W/50 engine oil, PEG 400, and deionized water) by liquid spraying technique. The filtration performance was evaluated in terms of initial and final gravimetric filtration efficiencies, fractional filtration efficiency, evolution of pressure drop, and dust holding capacity. The liquid-treated filter media registered higher gravimetric as well as fractional filtration efficiency and higher dust holding capacity as compared to the untreated ones. The initial and final gravimetric filtration efficiencies were found to be directly related to liquid add-on via a power law relationship. The liquid-treated filter media also exhibited higher fractional filtration efficiency than their untreated counterparts for all sizes of tested particles. Interestingly, the increase of fractional efficiency was more for smaller particles as compared to larger ones. This was explained quantitatively through single fiber efficiency due to adhesion. The viscosity of liquid was found to be a very crucial parameter as the dust deposition morphology was contingent to the flow of liquid onto the filter media. The stickiest liquid yielded highest filtration efficiencies, displayed slowest rise of pressure drop, and exhibited highest dust holding capacity.


Polymers ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 2494
Author(s):  
Dawei Li ◽  
Ying Shen ◽  
Lanlan Wang ◽  
Feng Liu ◽  
Bingyao Deng ◽  
...  

Electrospun polymer membranes were considered to be promising materials for fine particulate matter (PM) filtration. However, the poor mechanical properties of the electrospun membrane restricted their application for pressure-driven air filtration. Herein, strength-enhanced electrospun polyimide (PI) membranes were demonstrated via a synergistic approach. Solvent-vapor treatment was utilized to introduce extra bonding at the cross points of PI nanofiber, while SiO2 nanoparticles (SiO2 NPs) were used to reinforce the body of nanofibers. The mechanical strength and filtration performance of hybrid membranes could be regulated by adjusting the quantity of SiO2 NPs. The tensile strength of the pure PI membrane was increased by 33% via adding 1.5% SiO2 NPs, which was further promoted by 70% after solvent-vapor treatment. With a slight reduction in pressure drop (6.5%), the filtration efficiency was not greatly suppressed by welding the SiO2 NP hybrid PI nanofibers. Moreover, the welded composite filter showed high particulate (0.3–1.0 μm) filtration efficiency (up to nearly 100%) and stable pressure drop throughout the 20 tested filtration cycles.


Author(s):  
Maorui Hu ◽  
Yifei Wang ◽  
Zhifeng Yan ◽  
Guodong Zhao ◽  
Yixia Zhao ◽  
...  

Air pollution and public health incidents have become a serious global concern. Hierarchical nanofibrous membranes are taken as high-performance filters with advanced structure, but the reliable fabrication is still challenging....


2011 ◽  
Vol 236-238 ◽  
pp. 1885-1888
Author(s):  
Han Wang ◽  
Zuo Yi Yang ◽  
Jin Yong Liu ◽  
Gao Feng Zheng ◽  
Ling Min Chen

High filtration efficiency of nanofibrous membrane has been proved in air filtration area, but, in addition to filtration efficiency, pressure drop is another important characteristic of fibrous filter. Because pressure-drop is related to energy wastage of filtration, it’s necessary to study. While there are not enough studies dedicated to pressure-drop of nanofibrous membrane filters. Here, different thickness PVA nanofibrous membranes were made by electrospinning, and they deposited on cotton scaffolds to form nanofibrous filter samples. Through testing these samples, we found as thickness of nanofibrous membrane increased, pressure-drop rose almost linearly, while filtration efficiency presented a different change trend. When thickness of nanofibrous membrane reaching a point, filtration efficiency attained extreme limit, even if increasing thickness nanofibrous membrane, filtration efficiency only rose limitedly, but pressure-drop still increased rapidly. At the same time, we found despite the thickness of nanofibrous membrane was thinner than conventional fibrous filter, pressure-drop of nanofibrous filter was obviously higher than conventional fibrous filter. So it’s remarkable phenomena. Through theoretical analysis and simulation, the causation of high pressure-drop of nanofibrous filter was discussed and provided. Decreasing diameter of fiber caused resistance performance change. It’s necessary to carry on a further research.


Nanomaterials ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 1740 ◽  
Author(s):  
Ana Cláudia Canalli Bortolassi ◽  
Vádila Giovana Guerra ◽  
Mônica Lopes Aguiar ◽  
Laurence Soussan ◽  
David Cornu ◽  
...  

Often, solid matter is separated from particle-laden flow streams using electrospun filters due to their high specific surface area, good ability to capture aerial particulate matter, and low material costs. Moreover, electrospinning allows incorporating nanoparticles to improve the filter’s air filtration efficiency and bacterial removal. Therefore, a new, improved polyacrylonitrile (PAN) nanofibers membrane that could be used to remove air pollutants and also with antibacterial activity was developed. We engineered three different filters that are characterized by the different particles embedded in the PAN nanofibers: titanium dioxide (TiO2), zinc oxide (ZnO), and silver (Ag). Then, their filtration performance was assessed by quantifying the filtration of sodium chloride (NaCl) aerosol particles of 9 to 300 nm in diameter using a scanning mobility particle sizer. The TiO2_F filter displayed the smallest fiber diameter and the highest filtration efficiency (≈100%). Conversely, the Ag_F filter showed the highest quality factor (≈0.06 Pa−1) because of the lower air pressure drop. The resulting Ag_F nanofibers displayed a very good antibacterial activity using an Escherichia coli suspension (108 CFU/mL). Moreover, the quality factor of these membranes was higher than that of the commercially available nanofiber membrane for air filtration.


Sign in / Sign up

Export Citation Format

Share Document