Mechanical properties of cellulose-based electro-active paper

Author(s):  
J Kim ◽  
W Jung ◽  
C H Jo ◽  
J Shelton ◽  
W Craft

Mechanical properties of cellulose-based electro-active paper (EAPap) are characterized in this work. Cellulose-based EAPap has been studied as a potential actuator concept, as a result of its low actuation voltage, lightweight, low power consumption, biodegradability and low cost. EAPap is made from cellulose paper, coated with thin electrically conducting electrodes. This EAPap shows a reversible and reproducible bending movement as well as a longitudinal displacement under electric field excitation. However, the EAPap is a complex anisotropic material, which has not been extensively characterized. It is important to have extended property data for EAPap so that the actuator performance can be optimized, and this requires additional material testing. Our material test results show that EAPap has two distinct elastic constants. The initial Young's modulus of EAPap is in the range of 4–9 GPa, which is higher than other polymer materials. This modulus is also orientation dependent, which may be associated with the piezoelectricity of the EAPap materials. Another important property is that the dynamically induced mechanical strains of these materials exhibit linear creep behaviour as confirmed by constant stress and low frequency cyclic loading tests. From scanning electron microscope investigations, cellulose EAPap exhibits a layered, anisotropic cellulose macromolecular structure that exhibits both elastic and plastic deformations, as well as substantial temperature and humidity dependence.

2020 ◽  
Vol 2020 ◽  
pp. 1-9
Author(s):  
O. J. Gbadeyan ◽  
S. Adali ◽  
G. Bright ◽  
B. Sithole ◽  
S. Onwubu

The possibility of obtaining calcium carbonate nanoparticles from Achatina fulica shell through mechanochemical synthesis to be used as a modifying filler for polymer materials has been studied. The process of obtaining calcium carbonate nanopowders includes two stages: dry and wet milling processes. At the first stage, the collected shell was dry milled and undergone mechanical sieving to ≤50 μm. The shell particles were wet milled afterward with four different solvents (water, methanol, ethylene glycol, and ethanol) and washed using the decantation method. The particle size and shape were investigated on transmission electron microscopy, and twenty-three particle counts were examined using an iTEM image analyzer. Significantly, nanoparticle sizes ranging from 11.56 to 180.06 nm of calcium carbonate was achieved after the dry and wet milling processes. The size particles collected vary with the different solvents used, and calcium carbonate synthesis with ethanol offered the smallest organic particle size with the average size ranging within 13.48-42.90 nm. The effect of the solvent on the chemical characteristics such as the functional group, elemental composition, and carbonate ion of calcium carbonate nanopowders obtained from Achatina fulica shell was investigated. The chemical characterization was analyzed using Fourier transform infrared (FTIR) and a scanning electron microscope (SEM) equipped with an energy-dispersive spectroscope (EDX). The effect of milling procedures on the mechanical properties such as tensile strength, stiffness, and hardness of prepared nanocomposites was also determined. This technique has shown that calcium carbonate nanoparticles can be produced at low cost, with low agglomeration, uniformity of crystal morphology, and structure from Achatina fulica shell. It also proved that the solvents used for milling have no adverse effect on the chemical properties of the nano-CaCO3 produced. The loading of calcium carbonate nanoparticles, wet milled with different solvents, exhibited different mechanical properties, and nanocomposites filled with methanol-milled nano-CaCO3 offered superior mechanical properties.


2018 ◽  
Vol 162 ◽  
pp. 02016 ◽  
Author(s):  
Harith Zaki ◽  
Iqbal Gorgis ◽  
Shakir Salih

This paper studies the uses, of waste paper as an additional material in concrete mixes. Papercrete is a term as the name seems, to imply a mixture of paper and concrete. It is a new, composite material using waste paper, as a partial addition of Portland cement, and is a sustainable, building material due to, reduced amount of waste paper being put to use. It gains, latent strength due to presence of hydrogen bonds in microstructure of paper. Papercrete has been, reported to be a low cost alternative, building construction, material and has, good sound absorption, and thermal insulation; to be a lightweight and fire-resistant material. The percent of waste paper used (after treating) namely (5%, 10%, 15% and 20%) by weight of cement to explore the mechanical properties of the mixes (compressive strength, splitting tensile strength, flexural strength, density), as compared with references mixes, it was found that fresh properties affected significantly by increasing the waste paper content. The compressive strength, splitting tensile strength, flexural strength and density got decreased with increase in the percentage of paper.


2020 ◽  
Vol 67 (2) ◽  
pp. 115-120
Author(s):  
Raisa A. Alekhina ◽  
Victoriya E. Slavkina ◽  
Yuliya A. Lopatina

The article presents options for recycling polymers. The use of biodegradable materials is promising. This is a special class of polymers that can decompose under aerobic or anaerobic conditions under the action of microorganisms or enzymes forming natural products such as carbon dioxide, nitrogen, water, biomass, and inorganic salts. (Research purpose) The research purpose is in reviewing biodegradable materials that can be used for the manufacture of products used in agriculture. (Materials and methods) The study are based on open information sources containing information about biodegradable materials. Research methods are collecting, studying and comparative analysis of information. (Results and discussion) The article presents the advantages and disadvantages of biodegradable materials, mechanical properties of the main groups of biodegradable polymers. The article provides a summary list of agricultural products that can be made from biodegradable polymer materials. It was found that products from the general group are widely used in agriculture. Authors have found that products from a special group can only be made from biodegradable polymers with a controlled decomposition period in the soil, their use contributes to increasing the productivity of crops. (Conclusions) It was found that biodegradable polymer materials, along with environmental safety, have mechanical properties that allow them producing products that do not carry significant loads during operation. We have shown that the creation of responsible products (machine parts) from biodegradable polymers requires an increase in their strength properties, which is achievable by creating composites based on them. It was found that the technological complexity of their manufacture and high cost are the limiting factors for the widespread use of biodegradable polymers at this stage.


2014 ◽  
Vol 606 ◽  
pp. 253-256 ◽  
Author(s):  
Martin Ovsik ◽  
Petr Kratky ◽  
David Manas ◽  
Miroslav Manas ◽  
Michal Stanek ◽  
...  

This article deals with the influence of different doses of Beta radiation to the structure and mico-mechanical properties of Low-density polyethylene (LDPE). Hard surface layers of polymer materials, especially LDPE, can be formed by radiation cross-linking by β radiation with doses of 33, 66 and 99 kGy. Material properties created by β radiation are measured by micro-hardness test using the DSI method (Depth Sensing Indentation). Individual radiation doses caused structural and micro-mechanical changes which have a significant effect on the final properties of the LDPE tested. The highest values of micro-mechanical properties were reached at radiation dose of 66 and 99 kGy, when the micro-hardness values increased by about 21%. The changes were examined and confirmed by X-ray diffraction.


Polymers ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1369
Author(s):  
Sanjeev Kumar ◽  
Lalta Prasad ◽  
Vinay Kumar Patel ◽  
Virendra Kumar ◽  
Anil Kumar ◽  
...  

In recent times, demand for light weight and high strength materials fabricated from natural fibres has increased tremendously. The use of natural fibres has rapidly increased due to their high availability, low density, and renewable capability over synthetic fibre. Natural leaf fibres are easy to extract from the plant (retting process is easy), which offers high stiffness, less energy consumption, less health risk, environment friendly, and better insulation property than the synthetic fibre-based composite. Natural leaf fibre composites have low machining wear with low cost and excellent performance in engineering applications, and hence established as superior reinforcing materials compared to other plant fibres. In this review, the physical and mechanical properties of different natural leaf fibre-based composites are addressed. The influences of fibre loading and fibre length on mechanical properties are discussed for different matrices-based composite materials. The surface modifications of natural fibre also play a crucial role in improving physical and mechanical properties regarding composite materials due to improved fibre/matrix adhesion. Additionally, the present review also deals with the effect of silane-treated leaf fibre-reinforced thermoset composite, which play an important role in enhancing the mechanical and physical properties of the composites.


Polymers ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 2205
Author(s):  
Han Liang ◽  
Jun Han ◽  
Chen Cao ◽  
Shuangwen Ma

Thin spray-on liner (TSL) is a surface protection technology used by spraying a polymer film, which is widely used for mine airtightness and waterproofing. A reinforcing TSL can replace steel mesh, which is a new method for roadway support. This paper reviews the development of a reinforcing TSL. Considering the deterioration of geological conditions in deep underground mining and the demand for reinforcing automation, two kinds of polymeric reinforcing TSL (RPTSL) materials are developed. The mechanical characteristics of the new TSL materials are studied experimentally. Results show that the average compressive strength, tensile strength, cohesion, and internal friction angle of the two TSL materials are 52 and 32 MPa, 12 and 8 MPa, 6.2 and 17.2 MPa, and 33.6° and 25.9°, respectively. The bonding strength between the two materials and coal is greater than the tensile strength of coal itself, and the mechanical properties of the material for comparison are lower than those of both materials. Based on the TSL support mechanism, we examine the application of the two TSL materials to the mining environment and compare the mechanical properties of polymer materials and cement-based materials. The advantages of polymer materials include versatile mechanical properties, good adhesion, and high early strength. This study provides a new support material to replace steel mesh for roadway surface support, which satisfies the needs of different surface support designs under complex geological conditions, and promotes the automation of roadway support.


Polymers ◽  
2021 ◽  
Vol 13 (16) ◽  
pp. 2588
Author(s):  
Mansuri M. Tosif ◽  
Agnieszka Najda ◽  
Aarti Bains ◽  
Grażyna Zawiślak ◽  
Grzegorz Maj ◽  
...  

In recent years, scientists have focused on research to replace petroleum-based components plastics, in an eco-friendly and cost-effective manner, with plant-derived biopolymers offering suitable mechanical properties. Moreover, due to high environmental pollution, global warming, and the foreseen shortage of oil supplies, the quest for the formulation of biobased, non-toxic, biocompatible, and biodegradable polymer films is still emerging. Several biopolymers from varied natural resources such as starch, cellulose, gums, agar, milk, cereal, and legume proteins have been used as eco-friendly packaging materials for the substitute of non-biodegradable petroleum-based plastic-based packaging materials. Among all biopolymers, starch is an edible carbohydrate complex, composed of a linear polymer, amylose, and amylopectin. They have usually been considered as a favorite choice of material for food packaging applications due to their excellent forming ability, low cost, and environmental compatibility. Although the film prepared from bio-polymer materials improves the shelf life of commodities by protecting them against interior and exterior factors, suitable barrier properties are impossible to attain with single polymeric packaging material. Therefore, the properties of edible films can be modified based on the hydrophobic–hydrophilic qualities of biomolecules. Certain chemical modifications of starch have been performed; however, the chemical residues may impart toxicity in the food commodity. Therefore, in such cases, several plant-derived polymeric combinations could be used as an effective binary blend of the polymer to improve the mechanical and barrier properties of packaging film. Recently, scientists have shown their great interest in underutilized plant-derived mucilage to synthesize biodegradable packaging material with desirable properties. Mucilage has a great potential to produce a stable polymeric network that confines starch granules that delay the release of amylose, improving the mechanical property of films. Therefore, the proposed review article is emphasized on the utilization of a blend of source and plant-derived mucilage for the synthesis of biodegradable packaging film. Herein, the synthesis process, characterization, mechanical properties, functional properties, and application of starch and mucilage-based film are discussed in detail.


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