scholarly journals AN EFFECTIVE BIOSORBENT DERIVED N EFFECTIVE BIOSORBENT DERIVED FROM PRODUCTION WASTE ROM PRODUCTION WASTE FOR WATER TREATMENT: STUDYING OR WATER TREATMENT: STUDYING THE ADSORPTION OF SYNTHETIC DYES HE ADSORPTION OF SYNTHETIC DYES

2021 ◽  
Vol 17 (6) ◽  
pp. 83-96
Author(s):  
Dmytro Yelatonsev ◽  
Anatoliy Mukhachev ◽  
Olena Ivanyuk
Keyword(s):  
Water Treatment ◽  
Food Waste ◽  
Raw Materials ◽  
Polymeric Materials ◽  
Production Waste ◽  
Nature Management ◽  
Eosin Y ◽  
Synthetic Dyes ◽  
Alizarin Red ◽  
Plant Materials

Introduction. Eco-friendly disposal of food waste, in particular, nutshells and fruit kernels, is an important issue to ensure sustainable nature management. These secondary raw materials are the source of valuable polymeric materials, cellulose and lignin.Problem Statement. IGiven the capacity of the food industry in Ukraine and the amount of waste produced, the development of technologies for processing lignin-cellulose biomass is an important research and practical issue.Purpose. The purpose of this research is to study the adsorption properties of chemically modified biosorbent based on plant materials concerning synthetic dyes of different types and classes; to assess the feasibility of biosorbent production and efficiency of its application in water treatment.Materials and Methods. Lignocellulose sorbent (LCS) has been synthesized from non-wood raw materials by chemical modification with the use of phosphoric acid with the addition of urea in an aqueous media. The Fourier transform infrared and standard methods of plant raw material analysis have been used to determine the physicochemical characteristics of LCS. The adsorption of anionic (methyl orange, alizarin red S, eosin Y), cationic (methylene blue, neutral red), and nonionic (aniline yellow) dyes on LCS from aqueous solution has been studied in the batch mode.Results. The adsorption capacity of LCS towards cationic dyes (47.0–53.3 mg/g) is higher than that of anionic (22.2–36.9 mg/g) and nonionic (4.7 mg/g) ones. The adsorption kinetics have been adequately described by a pseudo-second-order equation. Adsorption of all classes of dyes on LCS is thermodynamically feasible, spontaneous, and endothermic process. The liquid by-product of LCS production contains 15% nitrogen and 10% phosphorus, so it may be used as a fertilizer. Conclusions. The proposed method for processing food waste provides obtaining effective sorbent and liquid NP-fertilizer. LCS removes both cationic and anionic pollutants from water, so it may be considered a promisingbiosorbent for water purification.

Fruit and berry raw materials is a promising source of food ingredients for flour confectionery.

2020 ◽  
Vol 29 (11) ◽  
pp. 45-49
Author(s):  
L.N. Fedyanina ◽  
◽  
E.S. Smertina ◽  
V.A. Lyakh ◽  
A.E. Elizarova ◽  
...  
Keyword(s):  
Dietary Fiber ◽  
Scientific Literature ◽  
Consumer Demand ◽  
Raw Materials ◽  
Plant Materials ◽  
Food Ingredients ◽  
Promising Source

The article considers the problem of improving the range of confectionery from the standpoint of use plant materials of satisfaction by consumer demand in dieteticpreventive foods. The analysis of domestic and foreign scientific literature on promising directions of improving the range of dietetic-preventive confectionery is given. It is noted that in the recipes for flour confectionery introduced from non-traditional raw materials containing dietary fiber.

scholarly journals Research and application progress of lignin-based composite membrane

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Youjing Li ◽  
Fen Li ◽  
Ying Yang ◽  
Baocai Ge ◽  
Fanzhu Meng
Keyword(s):  
Environmental Pollution ◽  
Raw Materials ◽  
Waste Product ◽  
Functional Materials ◽  
Polymeric Materials ◽  
Composite Membranes ◽  
Organic Polymer ◽  
Future Research ◽  
Sustainable Resources ◽  
New Perspective

Abstract In view of the serious environmental pollution, which is the greatest problem the world is facing, and the continuous consumption of raw materials, it is imminent to search for green and sustainable resources. Lignin is an organic polymer that exists widely in nature, and if it can be transformed from traditional low-value waste product with low range of applications to functional materials with high application prospects, it can be of great significance to alleviate environmental pollution and shortage of fossil resources. One of the functional applications of lignin involves its use to fabricate composite with other polymeric materials, which can then be used to prepare membrane materials. This review summarizes the recent research and application progress of combining lignin with polypropylene, polyvinyl alcohol, starch, cellulose, chitosan, and other polymeric materials to prepare composite membranes; and summarizes the future development direction of lignin-based composite membranes. We hope this review may provide a new perspective to the understanding of lignin-based composite membranes and a useful reference for future research.

scholarly journals Emergence of Polymeric Material Utilising Sustainable Radiation Curable Palm Oil-Based Products for Advanced Technology Applications

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1865
Author(s):  
Rida Tajau ◽  
Rosiah Rohani ◽  
Mohd Sofian Alias ◽  
Nurul Huda Mudri ◽  
Khairul Azhar Abdul Halim ◽  
...  
Keyword(s):  
Palm Oil ◽  
Raw Materials ◽  
Raft Polymerization ◽  
Polymeric Materials ◽  
Fine Tuning ◽  
Advanced Technology ◽  
Radiation Processing ◽  
Radiation Mechanisms ◽  
Processing Technologies ◽  
Technology Applications

In countries that are rich with oil palm, the use of palm oil to produce bio-based acrylates and polyol can be the most eminent raw materials used for developing new and advanced natural polymeric materials involving radiation technique, like coating resins, nanoparticles, scaffold, nanocomposites, and lithography for different branches of the industry. The presence of hydrocarbon chains, carbon double bonds, and ester bonds in palm oil allows it to open up the possibility of fine-tuning its unique structures in the development of novel materials. Cross-linking, reversible addition-fragmentation chain transfer (RAFT), polymerization, grafting, and degradation are among the radiation mechanisms triggered by gamma, electron beam, ultraviolet, or laser irradiation sources. These radiation techniques are widely used in the development of polymeric materials because they are considered as the most versatile, inexpensive, easy, and effective methods. Therefore, this review summarized and emphasized on several recent studies that have reported on emerging radiation processing technologies for the production of radiation curable palm oil-based polymeric materials with a promising future in certain industries and biomedical applications. This review also discusses the rich potential of biopolymeric materials for advanced technology applications.

scholarly journals Recent Advances in Fabrication of Non-Isocyanate Polyurethane-Based Composite Materials

Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3497
Author(s):  
Piotr Stachak ◽  
Izabela Łukaszewska ◽  
Edyta Hebda ◽  
Krzysztof Pielichowski
Keyword(s):  
Raw Materials ◽  
Synthesis Method ◽  
Polymeric Materials ◽  
Original Research ◽  
Significant Group ◽  
Oh Groups ◽  
New Class ◽  
Hazardous Chemical ◽  
Wide Range

Polyurethanes (PUs) are a significant group of polymeric materials that, due to their outstanding mechanical, chemical, and physical properties, are used in a wide range of applications. Conventionally, PUs are obtained in polyaddition reactions between diisocyanates and polyols. Due to the toxicity of isocyanate raw materials and their synthesis method utilizing phosgene, new cleaner synthetic routes for polyurethanes without using isocyanates have attracted increasing attention in recent years. Among different attempts to replace the conventional process, polyaddition of cyclic carbonates (CCs) and polyfunctional amines seems to be the most promising way to obtain non-isocyanate polyurethanes (NIPUs) or, more precisely, polyhydroxyurethanes (PHUs), while primary and secondary –OH groups are being formed alongside urethane linkages. Such an approach eliminates hazardous chemical compounds from the synthesis and leads to the fabrication of polymeric materials with unique and tunable properties. The main advantages include better chemical, mechanical, and thermal resistance, and the process itself is invulnerable to moisture, which is an essential technological feature. NIPUs can be modified via copolymerization or used as matrices to fabricate polymer composites with different additives, similar to their conventional counterparts. Hence, non-isocyanate polyurethanes are a new class of environmentally friendly polymeric materials. Many papers on the matter above have been published, including both original research and extensive reviews. However, they do not provide collected information on NIPU composites fabrication and processing. Hence, this review describes the latest progress in non-isocyanate polyurethane synthesis, modification, and finally processing. While focusing primarily on the carbonate/amine route, methods of obtaining NIPU are described, and their properties are presented. Ways of incorporating various compounds into NIPU matrices are characterized by the role of PHU materials in copolymeric materials or as an additive. Finally, diverse processing methods of non-isocyanate polyurethanes are presented, including electrospinning or 3D printing.

Carbon Dioxide as a Carbon Resource – Recent Trends and Perspectives

2012 ◽  
Vol 67 (10) ◽  
pp. 961-975 ◽  
Author(s):  
Markus Hölscher ◽  
Christoph Gürtler ◽  
Wilhelm Keim ◽  
Thomas E. Müller ◽  
Martina Peters ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Raw Materials ◽  
Low Cost ◽  
Polymeric Materials ◽  
Short Review ◽  
Chemical Research ◽  
Bond Forming ◽  
Bulk Chemicals ◽  
High Thermodynamic Stability ◽  
Recent Trends

With the growing perception of industrialized societies that fossil raw materials are limited resources, academic chemical research and chemical industry have started to introduce novel catalytic technologies which aim at the development of economically competitive processes relying much more strongly on the use of alternative carbon feedstocks. Great interest is given world-wide to carbon dioxide (CO2) as it is part of the global carbon cycle, nontoxic, easily available in sufficient quantities anywhere in the industrialized world, and can be managed technically with ease, and at low cost. In principle carbon dioxide can be used to generate a large variety of synthetic products ranging from bulk chemicals like methanol and formic acid, through polymeric materials, to fine chemicals like aromatic acids useful in the pharmaceutical industry. Owing to the high thermodynamic stability of CO2, the energy constraints of chemical reactions have to be carefully analyzed to select promising processes. Furthermore, the high kinetic barriers for incorporation of CO2 into C-H or C-C bond forming reactions require that any novel transformation of CO2 must inevitably be associated with a novel catalytic technology. This short review comprises a selection of the most recent academic and industrial research developments mainly with regard to innovations in CO2 chemistry in the field of homogeneous catalysis and processes.

scholarly journals The Safety Assessment of Toxic Metals in Commonly Used Herbs, Spices, Tea, and Coffee in Poland

2021 ◽  
Vol 18 (11) ◽  
pp. 5779
Author(s):  
Grażyna Kowalska
Keyword(s):  
Heavy Metals ◽  
Environmental Protection Agency ◽  
Inductively Coupled Plasma ◽  
Raw Materials ◽  
Hazard Quotient ◽  
World Health Organisation ◽  
World Health ◽  
Target Hazard Quotient ◽  
Plant Materials

The presented study was aimed at the determination of the level of contamination with heavy metals (Cd, Pb, As, and Hg) in 240 samples of plant materials, i.e., herbal raw materials, spices, tea, and coffee. Moreover, a probabilistic risk assessment (noncarcinogenic and carcinogenic risks) was estimated by models including target hazard quotient (THQ) and cancer risk (CR). The samples were subjected to microwave mineralisation with the use of HNO3 (65%), while the determination of the content of the elements was performed with the use of inductively coupled plasma mass spectrometer (ICP–MS) and a mercury analyser. The element which was characterised by the highest level of accumulation in the analysed samples was lead (from 0.010 to 5.680 mg/kg). Among the heavy metals under analysis, the lowest concentration was noted in the case of mercury (from 0.005 to 0.030 mg/kg). A notably higher level of contamination with heavy metals was noted in the analysed samples of herbs and spices (0.005–5.680 mg/kg), compared to samples of tea and coffee (0.005–0.791 mg/kg). According to the guidelines of the World Health Organisation (WHO) concerning the limits of contamination of samples of herbal raw materials with heavy metals, lead levels exceeding the limits were only noted in 24 samples of herbs (18%). In all of the analysed samples of spices, tea, and coffee, no instances of exceeded limits were noted for any of the analysed heavy metals. The values of TTHQmax (in relation to the consumption of the analysed products) were as follows: up to 4.23 × 10−2 for spices, up to 2.51 × 10−1 for herbs, up to 4.03 × 10−2 for China tea, and up to 1.25 × 10−1 for roasted coffee beans. As the value of THQ ≤1, there is no probability of the appearance of undesirable effects related to the consumption of the analysed group of raw materials and products of plant origin. The CR value for As (max. value) was 1.29 × 10−5, which is lower than the maximum acceptable level of 1 × 10−4 suggested by United States Environmental Protection Agency (USEPA).

Investigation of changes in physical and mechanical parameters of biodegradable polymer films during composting

2021 ◽  
pp. 40-43
Author(s):  
Дмитрий Михайлович Мяленко
Keyword(s):  
Lactic Acid ◽  
Environmental Protection ◽  
Biodegradable Polymer ◽  
Polymeric Materials ◽  
Mechanical Parameters ◽  
Ecological Situation ◽  
Plant Materials ◽  
Foreign Countries ◽  
Hydrolysis Of ◽  
Aliphatic Biopolymer

Вопросы защиты окружающей среды и улучшения экологической обстановки приобретают глобальный характер. Количество производимых в России и зарубежных странах синтетических полимерных материалов постоянно увеличивается, что заставляет задуматься о подходах к разработке современных биоразлагаемых полимерных материалов из полностью возобновляемого растительного сырья. Один из таких материалов - это линейный алифатический биополимер, полученный путем гидролиза молочной кислоты: полилактид (PLA). В данной статье представлены результаты исследований способности к биоразложению полимерных материалов на основе PLA при их компостировании в течение 3 мес. The issues of environmental protection and improvement of the ecological situation are becoming global in nature. The number of synthetic polymeric materials produced from Russia and foreign countries is constantly increasing, which makes us think about approaches to the development of modern biodegradable polymeric materials from completely renewable plant materials. One such material is a linear aliphatic biopolymer made by hydrolysis of lactic acid: polylactide (PLA). This article presents the results of studies on the biodegradability of PLA-based polymeric materials when composted for 3 months.

scholarly journals SOLUTION OF THE FUNDAMENTAL TASKS OF DEEP PROCESSING OF PLANT WASTE IN THE RESHETNEV SI-BERIAN STATE UNIVERSITY OF SCIENCE AND TECHNOLOGY

2020 ◽  
pp. 303-308
Author(s):  
Edkham Shukriyevich Akbulatov ◽  
Aleksey Viktorovich Lyubyashkin ◽  
Tat'yana Vasil'yevna Ryazanova ◽  
Yuriy Davydovich Alashkevich ◽  
Elena Vladimirovna Isaeva ◽  
...  
Keyword(s):  
Raw Materials ◽  
Science And Technology ◽  
Scientific Activity ◽  
Chemical Technology ◽  
State University ◽  
Highly Qualified ◽  
Plant Materials ◽  
Plant Raw Materials ◽  
Introductory Article ◽  
Business Structures

A special issue of the journal "Chemistry of Plant Raw Materials" published on the 65th anniversary of the department "Chemical Technology of Wood and Biotechnology", the 90th anniversary of the Siberian State Technological University and the 60th anniversary of the Siberian State Aerospace University. The combination of the two largest and socio-economically significant universities ensured the creation in 2016 of the Reshetnev Siberian State University of science and technology. This is the first supporting university in Eastern Siberia, providing training for highly qualified specialists in more than 100 programs for the forestry, woodworking and chemical industries, aviation and space industry, mechanical engineering, scientific and financial organizations, international and Russian business structures, and the media. The introductory article presents a brief historical excursion, the main directions and prospects of scientific activity of the department “Chemical technology of wood and biotechnology”. They are related to solving the problem of deep complex processing of plant materials with the involvement of modern biological and chemical technologies.

scholarly journals Pengendalian Persediaan Bahan Baku Nalco Water Treatment Dengan Menggunakan Metode Lot Sizing

2019 ◽  
Vol 2 (2) ◽  
pp. 80
Author(s):  
Masad Hariyadi ◽  
Boy Isma Putra
Keyword(s):  
Water Treatment ◽  
Raw Materials ◽  
Unit Cost ◽  
Exponential Smoothing ◽  
Raw Material ◽  
Economic Order Quantity ◽  
Economic Order ◽  
Order Quantity ◽  
Double Exponential ◽  
Double Exponential Smoothing

The limited supply of Nalco raw materials from producers has become a problem for PT ABC, this has led to the control of raw material inventory at PT ABC not including good management, because in the management of raw materials the company still records inventory with manual systems and in ordering raw materials only based on estimates. From the results of the study, the forecasting method used is the Double Exponential Smoothing Holt's, Brown, and Holt Winters Additive Algorithm methods, from the three methods that are most suitable is the Double Exponential Smoothing Brown method with the smallest Mean Square Error of 256.2. Calculation of Sizing Lot by using Economic Order Quantity method, Least Unit Cost method, and Silver Meal method, of the three methods the most optimal is the Economic Order Quantity method because it has the lowest cost of Rp. 12,651,145. The calculation of Safety Stock gets 17 Pail results. and for Reorder Points for Nalco Water Treatment raw material, which is 29 Pail.

scholarly journals PRODUCTION OF EXTRACTS FROM VEGETABLE RAW MATERIALS BY CARBON DIOXIDE

2020 ◽  
Vol 14 (1) ◽  
Author(s):  
K. Gafurov ◽  
B. Muhammadiev ◽  
Sh. Mirzaeva ◽  
F. Kuldosheva
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Co2 ◽  
Raw Materials ◽  
Maximum Yield ◽  
Volumetric Flow Rate ◽  
Extraction Process ◽  
Raw Material ◽  
Critical Conditions ◽  
Plant Materials ◽  
Laboratory Setup

The unique properties of supercritical carbon dioxide as a solvent are widely used for extraction. In supercritical media, the dissolution of molecules of various chemical nature is possible. The purpose of this investigation was to study the extraction process and obtain extracts from valuable regional plant materials by applying CO2 extraction under pre- and supercritical conditions. The objects of research were: ground seeds of melon, pumpkin and licorice roots, as well as mint leaves, mulberry and jida flowers. For extraction, a laboratory setup was used that allows extraction when the CO2 is supplied by a high-pressure plunger pump in the sub- and supercritical state using a heat pump. The pressure range is 3-15 MPa, temperatures 295–330 K, and the volumetric flow rate above the critical CO2 is 800–900 g. Experiments with ground seeds of melon and pumpkin showed that as a result of 4 sequentially performed extraction cycles on a single load with supercritical CO2 parameters ( 315–330 K; 3–7.5 MPa) the decrease in the mass of melon seeds was 90 g (pumpkins 80 g). During the total extraction time (2.5 hours), 20 kg of CO2 were pumped through the reactor (25 l at 290 K and 6.8 MPa), while the average oil content in the extract was 4 g per 1 kg of CO2 (3.0 g per 1 l of SС-CO2) In experiments with jida flowers, the maximum amount of solid extractable substance (2% by weight of the raw material) was obtained at a temperature in the extractor of 308 K and a pressure of 7.5 MPa. Upon extraction under critical conditions in collection 2, the liquid phase was absent; only a yellow-green paste was released in it. According to the results of experiments with mint leaves, the maximum yield of a greenish liquid was observed at T = 315 K and P = 4 MPa., Mulberry - at T = 306 K and P = 6.0 MPa. The results of the extraction of oils and extracts from ground seeds of melon, pumpkin and licorice roots, as well as mint leaves, mulberries and jida flowers confirm that the maximum yield of the extracted substance is achieved with supercritical CO2 parameters in the extractor (310 K, 7.5 MPa). When liquid CO2 is extracted (300 K and 6-8 MPa), up to 2% of a yellow substance is extracted, which does not differ in appearance from a supercritical extract.

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