scholarly journals Development of soapstock processing technology to ensure waste-free and safe production

2021 ◽  
Vol 6 (10 (114)) ◽  
pp. 23-29
Author(s):  
Viktoriia Kalyna ◽  
Vitalii Koshulko ◽  
Olha Ilinska ◽  
Natalia Tverdokhliebova ◽  
Oksana Tolstousova ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Fatty Acid ◽  
Sulfuric Acid ◽  
Sodium Chloride ◽  
Acid Solution ◽  
Mass Fraction ◽  
Sodium Hydroxide Solution ◽  
Salting Out ◽  
Acid Yield ◽  
Total Fat

Soapstock is a large-tonnage waste of the oil and fat industry, the disposal of which is environmentally hazardous. Processing of soapstock into industrially valuable products, in particular, fatty acids, is promising. The method for producing fatty acids, which consists in sequential saponification of soapstock with sodium hydroxide solution, salting out with sodium chloride and decomposition with sulfuric acid solution has been investigated. The feature of this work is the study of the effect of salting out conditions of saponified soapstock on the yield and neutralization number of fatty acids. As an experimental sample, sunflower soapstock was used, the indicators of which correspond to DSTU 5033 (CAS 68952-95-4): mass fraction of total fat – 67.3 %, fatty acids – 61.8 %, neutral fat – 5.5 %. Soapstock was subjected to preliminary saponification under the following conditions: duration 85 min., concentration of sodium hydroxide solution 45 %. After that, the saponified mass was subjected to salting out. The obtained core soap was decomposed with the sulfuric acid solution under the following conditions: temperature 90 °C, duration 40 min. Rational salting out conditions were determined: duration (80 min.) and sodium chloride concentration (16%). Under these conditions, the fatty acid yield is 95.0 %, the neutralization number is 194.8 mg KOH/g. The resulting fatty acids comply with DSTU 4860 (CAS 61788-66-7): the mass fraction of moisture and volatiles is 0.85 %, the mass fraction of total fat is 98.9 %, cleavage depth is 94.2 % oleic acid. This method of soapstock processing increases the fatty acid yield by 3.5 % compared to the method with saponification and decomposition, by 20.3 % compared to the method of soapstock decomposition with sulfuric acid. At the same time, the neutralization number increases by 4.1 % and 8.2 %, respectively. The improved method for fatty acids producing from soapstock provides high- quality fatty acids with increased yield.

scholarly journals Rational conditions of fatty acids obtaining by soapstock treatment with sulfuric acid

2021 ◽  
Vol 4 (6(112)) ◽  
pp. 6-13
Author(s):  
Natalia Sytnik ◽  
Ekaterina Kunitsia ◽  
Viktoria Mazaeva ◽  
Viktoriia Kalyna ◽  
Andrii Chernukha ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Fatty Acid ◽  
Sulfuric Acid ◽  
Sunflower Oil ◽  
Mass Fraction ◽  
Reaction Medium ◽  
First Grade ◽  
Acid Yield ◽  
Oil Refineries ◽  
Total Fat

As a result of alkaline neutralization of oils, a significant amount of soapstock is formed, the utilization of which creates an environmental and economic problem. The production of fatty acids from soapstock using sulfuric acid decomposition is investigated in this work. The peculiarity of the work is the determination of regression dependences of the yield and neutralization number of fatty acids on the soapstock processing conditions: temperature and duration. Soapstock obtained after neutralization of sunflower oil was used as raw material. Soapstock indicators: mass fraction of moisture – 15.4 %, total fat – 71.9 %, fatty acids – 64.5 %, neutral fat – 7.4 %. Rational conditions of soapstock processing are determined: temperature (90–95) °С, duration 40 min. Under these conditions, the fatty acid yield is 79.0 %, the neutralization number is 180.0 mg KOH/g. Quality indicators of the obtained fatty acids: mass fraction of moisture and volatile substances – 1.8 %, mass fraction of total fat – 97.0 %, cleavage depth – 64.5 % of oleic acid, the presence of mineral acids – no. Fatty acids correspond to fatty acids of the first grade according to DSTU 4860 (CAS 61788-66-7). An increase in the temperature and duration of soapstock contact with sulfuric acid increases the yield and neutralization number of fatty acids. This is due to a decrease in the viscosity of the reaction medium, an increase in the depth of cleavage of soapstock soaps with sulfuric acid, an increase in the intensity and duration of mass transfer. The developed rational conditions allow obtaining fatty acids from soapstock, which correspond in composition to fatty acids from refined deodorized sunflower oil. The results allow solving a number of economic and environmental problems associated with soapstock utilization and can be implemented in oil refineries and fatty acid production

scholarly journals Technology development of fatty acids obtaining from soapstok using saponification

2021 ◽  
Vol 5 (6 (113)) ◽  
pp. 16-23
Author(s):  
Natalia Sytnik ◽  
Ekaterina Kunitsia ◽  
Viktoriia Kalyna ◽  
Olena Petukhova ◽  
Kostiantyn Ostapov ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Sulfuric Acid ◽  
Sodium Hydroxide ◽  
Mass Fraction ◽  
Sodium Hydroxide Solution ◽  
First Grade ◽  
Oil Refining ◽  
Two Stage ◽  
Hydroxide Solution ◽  
Total Fat

The processing of oil refining waste is essential from economic and environmental points of view. An important issue is the processing of soapstock to extract fatty acids, which are raw materials for various industries. The two-stage method of fatty acids obtaining from soapstock using saponification with sodium hydroxide solution and decomposition with sulfuric acid is investigated. The peculiarity of the work is the study of the influence of soapstock saponification conditions on the key efficiency indicators of fatty acid extraction: yield and neutralization number. A sample of soapstock was obtained as a result of alkaline neutralization of sunflower oil. Soapstock quality corresponds to DSTU 5033 (CAS 68952-95-4): mass fraction of total fat – 68.5 %, fatty acids – 62.6 %, neutral fat – 5.9 %. Rational saponification conditions were determined: duration (85 min.) and concentration of sodium hydroxide solution (45 %). After saponification, the soapstock was subjected to decomposition with sulfuric acid under the following conditions: temperature 90 °C, duration 40 min. Under the rational saponification conditions, the yield of fatty acids (91.8 %) and the neutralization number (187.1 mg KOH/g) were determined. The obtained fatty acids correspond to the first-grade fatty acids according to DSTU 4860 (CAS 61788-66-7). Acid indicators: mass fraction of moisture and volatile substances – 1.5 %, mass fraction of total fat – 98.0 %, cleavage depth – 69.2 % oleic acid. The use of the soapstock saponification stage before decomposition leads to an improvement in the quality indicators and an increase in the neutralization number of fatty acids by 4 %, yield – by 16.2 %. The results of the study make it possible to produce fatty acids from soapstock by two-stage technology with high yield and neutralization number

scholarly journals Trends in total fat and fatty acid intakes and chronic health conditions in Korean adults over 2007–2015

2019 ◽  
Vol 22 (8) ◽  
pp. 1341-1350 ◽  
Author(s):  
SuJin Song ◽  
Jae Eun Shim ◽  
Won O Song
Keyword(s):  
Fatty Acids ◽  
Fatty Acid ◽  
National Level ◽  
Age Groups ◽  
Chronic Health Conditions ◽  
Health Conditions ◽  
Chronic Health ◽  
Korean Adults ◽  
Distribution Ranges ◽  
Total Fat

AbstractObjectiveTo investigate trends in total fat and fatty acid intakes and chronic health conditions among Korean adults over nine years between 2007 and 2015.DesignCross-sectional, observational study using a stratified, multistage probability sampling design at a national level. Intakes of total fat and fatty acids were estimated from 24 h dietary recalls by sex and age groups. Trends of total fat and fatty acid intakes were determined by multiple linear regression after adjusting for covariates. Trends in age-standardized prevalence of obesity, hypercholesterolaemia and hypertriacylglycerolaemia were examined by sex.SettingKorea.ParticipantsPopulation data of 47749 healthy adults (aged ≥19 years) derived from the Korea National Health and Nutrition Examination Survey between 2007 and 2015.ResultsOver the survey period, daily intakes of energy and total, saturated, monounsaturated, polyunsaturated, n-3 and n-6 fats (grams and percentage of energy (%E)) increased steadily. In all sex and age groups, significant increases were seen in SFA intake from 9·9 g (4·7 %E) to 12·0 g (5·3 %E) and in MUFA intake from 9·9 g (4·6 %E) to 13·3 g (5·8 %E). The prevalence of hypercholesterolaemia increased from 10·7 to 17·9 % over the same period.ConclusionsIn Korean adults, total fat, SFA and other fatty acids have been increasing along with the prevalence of hypercholesterolaemia. This information can help set adequate macronutrient and fatty acid distribution ranges in developing population-specific preventive strategies against diet-related illness.

scholarly journals Impact assessment of the TFA regulation on fatty acid composition of foods in Hungary

2020 ◽  
Vol 30 (Supplement_5) ◽  
Author(s):  
A Varga ◽  
E Sarkadi Nagy ◽  
L Zámbó ◽  
É Illés ◽  
M Bakacs ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Fatty Acid ◽  
Trans Fatty Acids ◽  
Saturated Fat ◽  
Portion Size ◽  
World Health ◽  
Food Sources ◽  
Increased Risk ◽  
Total Fat ◽  
The Impact

Abstract Trans fatty acids are formed during the industrial processing of food, and are proven to be harmful for the human body. They have been associated with increased risk of cardiovascular disease, abdominal obesity, diabetes, and certain types of cancer. Decree 71/2013. (XI. 20.) of the Ministry of Human Capacities, which has been in force since 2014, defines the highest permitted amount of trans fats in food products placed on the market in Hungary. The impact of the decree on the industrially produced trans fatty acids (iTFA) availability and population intake was assessed in 2017. Results demonstrated that iTFA were replaced by other fatty acids due to the legislation. In 2019, we investigated food groups which had high measured TFA content before the regulation entered into force and compared the total fat and fatty acid profiles to the same brand or similar products being on the market afterwards. In collaboration with the World Health Organization, this was the first assessment to determine to which extent manufacturers increased saturated fat (SFA) content of foodstuffs to reduce iTFA content. In those product groups, which were identified as significant food sources of iTFA before introducing the regulation (biscuits, coffee creamers and flavorings, sweets, bakery products, confectionary, wafers, margarines) we found no significant changes in the total fat content, while in most foodstuffs the average proportion of SFA was higher after reformulation, as iTFA were mainly substituted with SFA in 61% of the products, with cis-MUFA in 25% and cis-PUFA in 14% of the products, respectively. Evidence from this analysis supports concerns that eliminating iTFA in certain foodstuffs leads to unwanted substitution with saturated fat, hence reducing the possible health benefits. Given the high SFA intake and the unfavourable cardiovascular statistics in Hungary, the consumption frequency and portion size control of these products are advised. Key messages Monitoring the changes of food composition is important in order to evaluate the effect of the regulation. Manufacturers should be encouraged to reduce the SFA content to a technologically feasible level.

scholarly journals Polyunsaturated fatty acid concentrations in human hindmilk are stable throughout 12-months of lactation and provide a sustained intake to the infant during exclusive breastfeeding: an Italian study

2000 ◽  
Vol 84 (1) ◽  
pp. 103-109 ◽  
Author(s):  
Franca Marangoni ◽  
Carlo Agostoni ◽  
Anna M. Lammard ◽  
Marcello Giovannini ◽  
Claudio Galli ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Fatty Acid Composition ◽  
Fatty Acid ◽  
Polyunsaturated Fatty Acids ◽  
Human Milk ◽  
Acid Composition ◽  
Saturated Fatty Acids ◽  
Total Fat ◽  
Extended Lactation ◽  
Long Chain

While a wealth of data on the fatty acid composition of mature human milk has been published, limited information is available on the quantities of individual fatty acids supplied to the suckling infant with maternal milk, through the whole first year of life. Our aim was to qualitatively and quantitatively evaluate the fatty acid composition of human milk from Italian mothers, throughout extended lactation with particular emphasis on the long-chain polyunsaturated fatty acids. We have thus measured the total fat content and the concentrations of major fatty acids by quantitative GLC in pooled breast hindmilk collected from all feedings over 24 h at colostrum, 1, 3, 6, 9 and 12 months in ten mothers recruited after delivery of full-term infants. Total saturated fatty acids progressively increase and total monounsaturated progressively decrease as percentage levels, while among long-chain polyunsaturated fatty acids, percentages of arachidonic acid and docosahexaenoic acid decrease from colostrum up to the third month. Hindmilk total lipids (mg/dl) rise more than twofold up to 3 months, and then remain stable. The amounts (mg/dl) of linoleic acid and α-linolenic acid progressively increase, following the trend of total fat, while arachidonic and docosahexaenoic concentrations (mg/dl) remain stable throughout the whole nursing period. Assessment of the intakes per kg body weight shows different trends for the individual major long-chain polyunsaturated fatty acids supplied to the infant from hindmilk during exclusive breast-feeding (3 months). This information may be useful for the evaluation of infant intakes during extended lactation.

scholarly journals The Dietary Total-Fat Content Affects the In Vivo Circulating C15:0 and C17:0 Fatty Acid Levels Independently

Nutrients ◽  
2018 ◽  
Vol 10 (11) ◽  
pp. 1646 ◽  
Author(s):  
Benjamin Jenkins ◽  
Manar Aoun ◽  
Christine Feillet-Coudray ◽  
Charles Coudray ◽  
Martin Ronis ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Fatty Acid ◽  
Fat Content ◽  
Dietary Biomarkers ◽  
Dietary Fatty Acid Composition ◽  
Fat Consumption ◽  
Total Fat ◽  
Complex Influence ◽  
Fatty Acid Compositions

Pentadecanoic acid (C15:0) and heptadecanoic acid (C17:0) have been described as dietary biomarkers of dairy-fat consumption, with varying degrees of reliability between studies. It remains unclear how the total amount of dietary fat, representing one of the main confounding factors in these biomarker investigations, affects C15:0 and C17:0 circulating concentrations independent of their relative intake. Additionally, it is not clear how changes in the dietary total-fat affects other fatty acids in circulation. Through two dietary studies with different total-fat levels but maintaining identical fatty acid compositions, we were able to see how the dietary total-fat affects the fatty acids in circulation. We saw that there was a statistically significant, proportionate, and robust decrease in the endogenous C15:0 levels with an increase in dietary total-fat. However, there was no significant change in the circulating C17:0 concentrations as the total-fat increased. To conclude, the dietary total-fat content and fat-type have a very complex influence on the relative compositions of circulating fatty acids, which are independent of the actual dietary fatty acid composition. Knowing how to manipulate circulating C15:0 and C17:0 concentrations is far-reaching in nutritional/pathological research as they highlight a dietary route to attenuate the development of metabolic disease (both by reducing risk and improving prognosis).

scholarly journals Associations of the SCD1 gene SNP with fatty acids composition of Holstein cows

2020 ◽  
Vol 27 ◽  
pp. 00060
Author(s):  
Natalia Yu. Safina ◽  
Shamil K. Shakirov ◽  
Rustam Kh. Ravilov ◽  
Gazimzyan S. Sharafutdinov
Keyword(s):  
Fatty Acids ◽  
Fatty Acid Composition ◽  
Fatty Acid ◽  
Acid Composition ◽  
Milk Fat ◽  
Mass Fraction ◽  
Holstein Cows ◽  
Allelic Polymorphism ◽  
Milk Fatty Acid ◽  
Significant Difference

The research presents the findings of DNA testing of allelic polymorphism by the PCR-RFLP method of the SCD1 gene and the relationship of genotypes with the milk fatty acid composition of Holstein cows of Tatarstan population. The research was conducted among 172 Holstein cows at the Integrated Agricultural Production Centre “Stud farm named after Lenin” in Atninsky district of the Republic of Tatarstan in 2017–2018. All genotypes of the SCD1 gene were identified through the research. The milk yield test showed that the maximum content of the mass fraction of fat was in animals with the TT genotype. The significant difference between the content of the mass fraction of fat in milk in individuals by the locus of the SCD1-Fsp4H I gene was: TT to CC – 0.32 % (p < 0.05) and TT to TC – 0.40 % (p < 0.01). The results of chromatography indicate the balance of the milk fatty acid composition of cows with the TT genotype and, as a consequence, its positive effect on the human body. Cows with a homozygous TT genotype are characterized by the optimum ratio of fatty acids in milk fat. The maximum value of the oxygen desaturation index is also observed in animals with the TT genotype by the SCD1 gene.

scholarly journals Fatty acid composition including trans isomers of Serbian biscuits

2011 ◽  
Vol 65 (2) ◽  
pp. 139-146 ◽  
Author(s):  
Snezana Kravic ◽  
Zvonimir Suturovic ◽  
Jaroslava Svarc-Gajic ◽  
Zorica Stojanovic ◽  
Mira Pucarevic ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Fatty Acid Composition ◽  
Fatty Acid ◽  
Acid Composition ◽  
Lipid Fraction ◽  
Fats And Oils ◽  
Total Fatty Acids ◽  
The Mean ◽  
Total Fat

An experimental study was carried out with the aim of evaluating the quality of the lipid fraction of Serbian biscuits. Total fat contents of the biscuit samples ranged between 10.2% and 24.5%. The saturated, cis-monounsaturated and cis-polyunsaturated fatty acid contents were within the ranges of 18.585.6%, 10.649.9% and 2.713.3% of total fatty acids, respectively. The content of trans fatty acids (TFA) ranged from 0.0% to 42.5% and the mean was 10.2%. In a total of 34 investigated samples, 10 of them were found to be trans - free, 8 contained low level of TFA (under 2%), 4 samples contained between 2 and 10% of TFA, while 12 samples contained very high amounts of TFA (12.042.5%). The results obtained showed a considerable variability in fatty acid composition of biscuits which indicated that different types of fats and oils were used for production of biscuits in Serbia.

scholarly journals Production of fatty acids inRalstonia eutrophaH16 by engineeringβ-oxidation and carbon storage

PeerJ ◽  
2015 ◽  
Vol 3 ◽  
pp. e1468 ◽  
Author(s):  
Janice S. Chen ◽  
Brendan Colón ◽  
Brendon Dusel ◽  
Marika Ziesack ◽  
Jeffrey C. Way ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Fatty Acid ◽  
Chain Length ◽  
Acid Production ◽  
Ralstonia Eutropha ◽  
Fatty Acid Production ◽  
Acid Yield ◽  
Medium Chain ◽  
Medium Chain Length ◽  
Coa Ligase

Ralstonia eutrophaH16 is a facultatively autotrophic hydrogen-oxidizing bacterium capable of producing polyhydroxybutyrate (PHB)-based bioplastics. As PHB’s physical properties may be improved by incorporation of medium-chain-length fatty acids (MCFAs), and MCFAs are valuable on their own as fuel and chemical intermediates, we engineeredR. eutrophafor MCFA production. Expression ofUcFatB2, a medium-chain-length-specific acyl-ACP thioesterase, resulted in production of 14 mg/L laurate in wild-typeR. eutropha. Total fatty acid production (22 mg/L) could be increased up to 2.5-fold by knocking out PHB synthesis, a major sink for acetyl-CoA, or by knocking out the acyl-CoA ligasefadD3, an entry point for fatty acids intoβ-oxidation. As ΔfadD3mutants still consumed laurate, and because theR. eutrophagenome is predicted to encode over 50 acyl-CoA ligases, we employed RNA-Seq to identify acyl-CoA ligases upregulated during growth on laurate. Knockouts of the three most highly upregulated acyl-CoA ligases increased fatty acid yield significantly, with one strain (ΔA2794) producing up to 62 mg/L free fatty acid. This study demonstrates that homologousβ-oxidation systems can be rationally engineered to enhance fatty acid production, a strategy that may be employed to increase yield for a range of fuels, chemicals, and PHB derivatives inR. eutropha.

scholarly journals Fatty acid composition of commercially important fish from Brazil

1993 ◽  
Vol 50 (3) ◽  
pp. 478-483 ◽  
Author(s):  
L.E. Gutierrez ◽  
R.C.M. da Silva
Keyword(s):  
Fatty Acids ◽  
Fatty Acid Composition ◽  
Oleic Acid ◽  
Fatty Acid ◽  
Freshwater Fish ◽  
Acid Composition ◽  
Marine Fish ◽  
Commercially Important ◽  
Total Fat ◽  
Important Fish

Total fat and fatty acid composition of seven fresh-water and nine marine fish commercially important in Brazil were determined. Palmitic acid was the predominant saturated fatty acid in both freshwater and marine fish. In the fat from freshwater fish the total C-16 fatty acids were higher than in marine fish. Oleic acid was the most abundant monounsaturated fatty acid and it was found in higher levels in freshwater fish. The data revealed that most freshwater fish from Brazil examined were a poor source of eicosapentaenoic (20:5) and docosahexaenoic (22:6) acids. Of the marine fish analysed, only sardine and manjuba could be recommended as a good sources of n-3 fatty acids.

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