scholarly journals Thermal Barrier Stability and Wear Behavior of CVD Deposited Aluminide Coatings for MAR 247 Nickel Superalloy

Materials ◽  
2020 ◽  
Vol 13 (17) ◽  
pp. 3863
Author(s):  
Dominik Kukla ◽  
Mateusz Kopec ◽  
Zbigniew L. Kowalewski ◽  
Denis J. Politis ◽  
Stanisław Jóźwiak ◽  
...  
Keyword(s):  
Wear Resistance ◽  
Process Parameters ◽  
High Performance ◽  
Wear Behavior ◽  
Chemical Vapor ◽  
Scratch Test ◽  
Xrd Analysis ◽  
Nickel Superalloy ◽  
X Ray ◽  
Aluminide Coatings

In this paper, aluminide coatings of various thicknesses and microstructural uniformity obtained using chemical vapor deposition (CVD) were studied in detail. The optimized CVD process parameters of 1040 °C for 12 h in a protective hydrogen atmosphere enabled the production of high density and porosity-free aluminide coatings. These coatings were characterized by beneficial mechanical features including thermal stability, wear resistance and good adhesion strength to MAR 247 nickel superalloy substrate. The microstructure of the coating was characterized through scanning electron microscopy (SEM), X-ray energy dispersive spectroscopy (EDS) and X-ray diffraction (XRD) analysis. Mechanical properties and wear resistance of aluminide coatings were examined using microhardness, scratch test and standardized wear tests, respectively. Intermetallic phases from the Ni-Al system at specific thicknesses (20–30 µm), and the chemical and phase composition were successfully evaluated at optimized CVD process parameters. The optimization of the CVD process was verified to offer high performance coating properties including improved heat, adhesion and abrasion resistance.

EFFECT OF NITROGEN AMOUNT ON TRIBOLOGICAL BEHAVIOR OF PLASMA NITRIDED 31CrMoV9 STEEL

2019 ◽  
Vol 26 (07) ◽  
pp. 1850217 ◽  
Author(s):  
O. ÇOMAKLI ◽  
A. F. YETIM ◽  
B. KARACA ◽  
A. ÇELIK
Keyword(s):  
Wear Resistance ◽  
Tribological Behavior ◽  
Wear Behavior ◽  
Plasma Nitriding ◽  
Surface Hardness ◽  
Compound Layer ◽  
Gas Mixture ◽  
X Ray Diffraction ◽  
X Ray ◽  
Pin On Disk

The 31CrMoV9 steels were plasma nitrided under different gas mixture ratios to investigate an influence of nitrogen amount on wear behavior. The structure, mechanical and tribological behavior of untreated and nitrided 31CrMoV9 steels were analyzed with X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), microhardness device, 3D profilometer and pin-on-disk wear tester. The analysis outcomes displayed that the compound layer consists of nitride phases (Fe2N, Fe3N, Fe4N and CrN). Additionally, the thickness of the compound layers, surface hardness and roughness increased with increasing nitrogen amount in the gas mixture. The highest friction coefficient value was obtained at nitrogen amount of 50%, but the lowest value was seen at nitrogen amount of 6%. It was observed that wear resistance of 31CrMoV9 steel improved after plasma nitriding, and the best wear resistance was also obtained from plasma nitrided sample at the gas mixture of 94% H[Formula: see text]% N2.

Effect of Varying Wt% of TiC on Mechanical and Wear Properties of RZ5-TiC In-Situ Composite

2018 ◽  
Vol 8 (2) ◽  
pp. 45-56 ◽  
Author(s):  
Deepak Mehra ◽  
M.M. Mahapatra ◽  
S. P. Harsha
Keyword(s):  
Wear Resistance ◽  
Wear Behavior ◽  
Wear Test ◽  
X Ray Diffraction ◽  
Wear Properties ◽  
X Ray ◽  
Tic Particle ◽  
Mechanical And Microstructural Properties ◽  
Sliding Distance

The purpose of this article is to enhance the mechanical properties and wear resistance of the RZ5 alloy used in the aerospace application by adding TiC particles. The present study discusses processing of in-situ RZ5-TiC composite fabricated by self-propagating high temperature (S.H.S.) method and its wear behavior. The effects of TiC particle on mechanical and microstructural properties of the composite are studied. The wear test is performed by varying the sliding distance and applied load. The composite is characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). The results exhibited the properties like strength and hardness of RZ5-10wt%TiC composite has been increased considerably, while grain size is decreased as compared to the RZ5 alloy. The fractography indicated mixed mode (quasi-cleavage and ductile feature) failure of the composites. The wear results showed improvement in wear resistance of the composite. The FESEM showed dominate wear mechanisms are abrasion, ploughing grooves.

Comparative study of corrosion and corrosion-wear behavior of TiN and CrN coatings on UNS S17400 stainless steel

2018 ◽  
Vol 36 (4) ◽  
pp. 403-412 ◽  
Author(s):  
Hossein Olia ◽  
Reza Ebrahimi-Kahrizsangi ◽  
Fakhreddin Ashrafizadeh ◽  
Iman Ebrahimzadeh
Keyword(s):  
Stainless Steel ◽  
Wear Resistance ◽  
Physical Vapor Deposition ◽  
Wear Behavior ◽  
Open Circuit ◽  
Corrosion Wear ◽  
Nacl Solution ◽  
Compact Structure ◽  
X Ray ◽  
Electrochemical Tests

AbstractPhysical vapor deposition (PVD) multilayered coatings with titanium nitride and chromium nitride top layers were deposited on UNS S17400 alloy in an attempt to improve the corrosion and corrosion-wear resistance of this stainless steel in corrosive environments. The coatings were produced in an industrial chamber by cathodic arc PVD on heat-treated and mechanically polished stainless steel specimens. The microstructures of the substrates and coatings were characterized by X-ray diffraction and scanning electron microscope equipped with an energy-dispersive X-ray spectroscopy system. To evaluate the corrosion and corrosion-wear resistance, reciprocating-sliding tribometer and electrochemical tests were conducted in 3.5% NaCl solution. The results showed that nitride coatings possess, in general, better corrosion and corrosion-wear resistance compared with bare S17400 substrates. Specimens with CrN top coating revealed a typical compact structure and superior corrosion resistance compared with substrate and TiN top coating. However, the sliding motion damaged the surface with some microcracks on the coating, which act as the diffusion channels for NaCl solution; both TiN and CrN top coats experienced approximately similar behavior in corrosion-wear open-circuit potential testing.

EFFECT OF TiO2 PARTICLES ON MICRO-HARDNESS, CORROSION, WEAR AND FRICTION OF Ni–P–TiO2 COMPOSITE COATINGS AT DIFFERENT ANNEALING TEMPERATURES

2016 ◽  
Vol 23 (01) ◽  
pp. 1550082 ◽  
Author(s):  
PRASANNA GADHARI ◽  
PRASANTA SAHOO
Keyword(s):  
Wear Resistance ◽  
Corrosion Resistance ◽  
Composite Coatings ◽  
Corrosion Current ◽  
Xrd Analysis ◽  
Charge Transfer Resistance ◽  
Micro Hardness ◽  
Transfer Resistance ◽  
X Ray ◽  
Annealing Temperatures

The present study investigates the effect of titania particles on the micro-hardness, wear resistance, corrosion resistance and friction of electroless Ni–P–TiO2 composite coatings deposited on mild steel substrates at different annealing temperatures. The experimental results confirmed that the amount of TiO2 particles incorporated in the coatings increases with increase in the concentration of particles in the electroless bath. In presence of TiO2 particles, hardness, wear resistance and corrosion resistance of the coating improve significantly. At higher annealing temperature, wear resistance increases due to formation of hard Ni3P phase and incorporation of titania particles in the coated layer. Charge transfer resistance and corrosion current density of the coatings reduce with an increase in TiO2 particles, whereas corrosion potential increases. Microstructure changes and composition of the composite coating due to heat treatment are studied with the help of scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDXA) and X-ray diffraction (XRD) analysis.

scholarly journals Enhancement of the Wear Resistance and Microhardness of Aluminum Alloy by Nd:YaG Laser Treatment

2014 ◽  
Vol 2014 ◽  
pp. 1-5 ◽  
Author(s):  
Haitham T. Hussein ◽  
Abdulhadi Kadhim ◽  
Ahmed A. Al-Amiery ◽  
Abdul Amir H. Kadhum ◽  
Abu Bakar Mohamad
Keyword(s):  
Wear Resistance ◽  
Aluminum Alloy ◽  
Wear Rate ◽  
Laser Treatment ◽  
Vickers Hardness ◽  
Nd:Yag Laser ◽  
Wear Behavior ◽  
X Ray ◽  
Before And After ◽  
Hardness Values

Influence of laser treatment on mechanical properties, wear resistance, and Vickers hardness of aluminum alloy was studied. The specimens were treated by using Nd:YaG laser of energy 780 mj, wavelength 512 nm, and duration time 8 ns. The wear behavior of the specimens was studied for all specimens before and after treatment by Nd:YaG laser and the dry wear experiments were carried out by sing pinon-disc technique. The specimens were machined as a disk with diameter of 25 mm and circular groove in depth of 3 mm. All specimens were conducted by scanning electron microscopy (SEM), energy-dispersive X-ray florescence analysis (EDS), optical microscopy, and Vickers hardness. The results showed that the dry wear rate was decreased after laser hardening and increased Vickers hardness values by ratio of 2.4 : 1. The results showed that the values of wear rate for samples having circular grooves are less than samples without grooves after laser treatment.

scholarly journals Fabrication of ZnO/CNTs for Application in CO2 Sensor at Room Temperature

Nanomaterials ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 3087
Author(s):  
Rana Saad ◽  
Ahmed Gamal ◽  
Mohamed Zayed ◽  
Ashour M. Ahmed ◽  
Mohamed Shaban ◽  
...  
Keyword(s):  
Chemical Structure ◽  
Chemical Vapor ◽  
Xrd Analysis ◽  
Chemical Vapor Deposition Method ◽  
Spray Pyrolysis Method ◽  
X Ray Diffraction ◽  
Co2 Gas ◽  
X Ray ◽  
Co2 Sensor ◽  
Higher Sensitivity

Thin films of ZnO and ZnO/carbon nanotubes (CNTs) are prepared and used as CO2 gas sensors. The spray pyrolysis method was used to prepare both ZnO and ZnO/CNTs films, with CNTs first prepared using the chemical vapor deposition method (CVD). The chemical structure and optical analyses for all the prepared nanomaterials were performed using X-ray diffraction (XRD), Fourier transformer infrared spectroscopy (FTIR), and UV/Vis spectrophotometer devices, respectively. According to the XRD analysis, the crystal sizes of ZnO and ZnO/CNTs were approximately 50.4 and 65.2 nm, respectively. CNTs have average inner and outer diameters of about 3 and 13 nm respectively, according to the transmitted electron microscope (TEM), and a wall thickness of about 5 nm. The detection of CO2 is accomplished by passing varying rates of the gas from 30 to 150 sccm over the prepared thin-film electrodes. At 150 sccm, the sensitivities of ZnO and ZnO/CNTs sensors are 6.8% and 22.4%, respectively. The ZnO/CNTs sensor has a very stable sensitivity to CO2 gas for 21 days. Moreover, this sensor has a high selectivity to CO2 in comparison with other gases, in which the ZnO/CNTs sensor has a higher sensitivity to CO2 compared to H2 and C2H2.

Friction Induced Strengthening Mechanisms of Magnesia Partially Stabilized Zirconia

1987 ◽  
Vol 109 (3) ◽  
pp. 531-536 ◽  
Author(s):  
V. Aronov
Keyword(s):  
Wear Resistance ◽  
Phase Transformation ◽  
Plastic Strain ◽  
Wear Behavior ◽  
Xrd Analysis ◽  
Stabilized Zirconia ◽  
Near Surface ◽  
Partially Stabilized Zirconia ◽  
Wear Rates ◽  
Frictional Interface

Experimental investigation of the wear behavior of Magnesia Partially Stabilized Zirconia (Mg-PSZ) rubbed against itself showed that up to three orders of magnitude increase in the wear resistance can be achieved in a particular temperature range that depends on both the sliding speed and the ambient temperature. XRD analysis revealed that thermally induced phase transformation takes place on the frictional interface. Surface analysis show that wear rates at maximum wear resistance are controlled by the crack generation kinetics rather than by crack propagation kinetics. The plastic strain before fracture varies with temperature. The maximum plastic strain was observed at the temperature of maximum wear resistance. A phenomenological model is presented that provides an explanation for the wear temperature behavior of Mg-PSZ. The model is based on the following chain of events that takes place on the frictional interface: spatial overheating of the surface areas, phase transformation of the overheated areas, cooling, volume expansion, and development of a compressive stress field in the near surface volumes.

Crystalline Orientation of PbTiO3 Nanorods Grown by MOCVD Using ZnO Nanorods as a Template

2011 ◽  
Vol 1292 ◽  
Author(s):  
Hironori Fujisawa ◽  
Masaru Shimizu ◽  
Ryohei Kuri ◽  
Seiji Nakashima ◽  
Yasutoshi Kotaka ◽  
...  
Keyword(s):  
Vapor Deposition ◽  
Metalorganic Chemical Vapor Deposition ◽  
Zno Nanorods ◽  
Chemical Vapor ◽  
Piezoresponse Force Microscopy ◽  
Xrd Analysis ◽  
X Ray Diffraction ◽  
Crystalline Orientation ◽  
X Ray ◽  
Force Microscopy

ABSTRACTPbTiO3-covered ZnO nanorods were grown on Al2O3$\left({11\bar 20} \right)$ by metalorganic chemical vapor deposition (MOCVD), and their crystalline orientation was investigated by x-ray diffraction (XRD). Structural analysis by scanning electron microscopy and XRD revealed that the hexagonal ZnO nanorods had $\left\{ {10\bar 10} \right\}$-side facets. XRD analysis of PbTiO3 thin films on ZnO$\left({10\bar 10} \right)$/Al2O3$\left({10\bar 10} \right)$revealed that PbTiO3 was epitaxially grown on ZnO$\left({10\bar 10} \right)$, showing 6 variants of crystallites with the c-axis tilted either 27o or 69o from the surface normal to the ZnO$\left({10\bar 10} \right)$ plane. Effective piezoelectric coefficients calculated for the 27o and 69o-crystallites using piezoresponse force microscopy confirm that deformation of nanorods and nanotubes contributed to the large electrically-induced strain along the radial direction.

Tribological Testing and Modeling of Elastomeric Materials

2014 ◽  
Vol 604 ◽  
pp. 87-90
Author(s):  
Antti Vaajoki ◽  
Anssi Laukkanen ◽  
Richard Waudby ◽  
Päivi Kivikytö-Reponen ◽  
Kati Valtonen ◽  
...  
Keyword(s):  
Wear Resistance ◽  
Wear Behavior ◽  
Cost Effective ◽  
Scratch Test ◽  
Strain Rates ◽  
Scratch Testing ◽  
Abrasive Particles ◽  
Formidable Challenge ◽  
Elastomeric Materials ◽  
Repeated Impacts

In applications which experience repeated impacts by hard abrasive particles at high or moderate strain rates, elastomers are commonly used. The goal of the current work is to develop a methodology involving scratch testing and modeling which would be simple and cost effective for capturing the failure and wear behavior of elastomeric materials. The high failure strains as well as the extremely good wear resistance of elastomers make this task a formidable challenge. Modeling of a scratch test, however, seems to be promising in this regard.

Correlation of Process Parameters to Surface Integrity Responsible for Wear Resistance of HVOF Sprayed WC-Ni Coatings

2017 ◽  
Author(s):  
X. P. Zhu ◽  
P. C. Du ◽  
Y. Meng ◽  
M. K. Lei ◽  
D. M. Guo
Keyword(s):  
Fracture Toughness ◽  
Stainless Steel ◽  
Wear Resistance ◽  
Elastic Modulus ◽  
Process Parameters ◽  
Surface Integrity ◽  
High Performance ◽  
Surface Characteristics ◽  
Wear Performance ◽  
Final Performance

Surface integrity of high performance components has a profound influence on the final performance. Therefore, surface integrity is a key point for realizing high performance manufacturing by which manufacture processes and parameters can be pre-selected according to a required functional performance of components, i.e., solving inverse problem of manufacturing, as long as correlations could be established respectively for between processes and surface integrity, and between surface integrity and performance. However, in practice it is still difficult in correlating processes to performance through surface integrity, due to the material and geometry constraints hindering achievability of a desired surface integrity during conventional manufacturing as well as the complex influence of multiple surface integrity parameters on a final performance. In this study, thermally sprayed WC-10Ni coatings onto stainless steel using high velocity oxy-fuel (HVOF) spraying process are investigated to identify the surface integrity predominantly determining the water-lubricated wear performance of coated steel, and then to correlate it to process parameters. The controllable surface integrity facilitates identifying responsible surface integrity parameters for a required high performance, and subsequently deriving necessary process parameters for achieving the desired responsible surface integrity. Specifically, HVOF process parameters are adjusted by changing the oxygen-to-fuel (O/F) ratio to control thermal and mechanical processing loads, i.e. temperature of heated in-flight spraying powders and impact velocity of the molten splats onto stainless steel to form the coatings. Surface features including porosity and phase structure, and surface characteristics including hardness, elastic modulus, and fracture toughness were studied with respect to the wear performance. The porosity and WC phase composition of coatings are identified responsible for the wear performance, as two essential surface integrity parameters that in turn greatly affect the surface characteristics including coating hardness, elastic modulus and fracture toughness. Consequently, the process parameter O/F is feasibly correlated to wear resistance through the responsible surface integrity parameters, as elucidating the coating formation mechanism of influence of particle velocity and temperature on the coating porosity and WC decomposition.

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