scholarly journals Reuse of the Steel Mill Scale for Sustainable Industrial Applications

Proceedings ◽  
2020 ◽  
Vol 63 (1) ◽  
pp. 14
Author(s):  
Dana-Adriana Iluțiu-Varvara ◽  
Marius Tintelecan ◽  
Claudiu Aciu ◽  
Ioana-Monica Sas-Boca
Keyword(s):  
Chemical Elements ◽  
Industrial Applications ◽  
Raw Material ◽  
Future Research ◽  
Steel Mill ◽  
High Iron Content ◽  
Mill Scale ◽  
Iron Aluminum ◽  
Silica Alumina ◽  
Hematite Fe2o3

The purpose of our paper is to assess the reuse potential of the steel mill scale for sustainable industrial applications. We have presented the experimental procedures for chemical and mineralogical characterizations. According to the results of the elementary chemical analysis, the steel mill scale contains the following predominant chemical elements: iron, aluminum, silicon, and magnesium. Due to its high iron content, the steel mill scale can be reused as a source of raw material in the sustainable steelmaking industry. The mineralogical phases identified in the steel mill scale are: wüstite (FeO), hematite (Fe2O3), magnetite (Fe3O4), silica (quartz) (SiO2), magnesioferitte (MgFe2O4), and aluminum oxide (corundum) (Al2O3). Silica, alumina, and hematite are the main compounds of the cement and contribute to the formation of the: dicalcium silicate (2CaO·SiO2), tricalcium silicate (3CaO·SiO2), tricalcium aluminate (3CaO·Al2O3), and tetra—calcium aluminoferrite (4CaO·Al2O3·Fe2O3). The results of the paper are promising and encourage the future research for establishing the optimal percentage for the reuse of the steel mill scale in the composition of concrete.

scholarly journals Effect of Beneficiation on the Characterization of Getso Kaolin

Mining Revue ◽  
2021 ◽  
Vol 27 (4) ◽  
pp. 72-77
Author(s):  
Nurudeen Salahudeen ◽  
Ahmad A. Mukhtar
Keyword(s):  
Clay Minerals ◽  
Physicochemical Characterization ◽  
Chemical Characterization ◽  
Xrd Analysis ◽  
Industrial Applications ◽  
Raw Material ◽  
Mineralogical Characterization ◽  
X Ray ◽  
Silica Alumina

Abstract In their raw forms, clay minerals are found with a number of inherent impurities which make them unsuitable for most industrial applications. In order to overcome this problem and add value to clay minerals, beneficiation process is an indispensable solution. This study investigates effect of wet beneficiation process on the characteristics of a local clay mined from Getso village of Kano State, Nigeria. Mineralogical characterization of the clay was carried out using X-ray diffraction (XRD) analyzer. Chemical characterization of the clay was carried out using X-ray fluorescence analyzer. Physicochemical characterization of the clay was carried out using pH meter and density analysis conducted using density bottle. XRD analysis of Getso clay showed that the raw clay had 8 wt% kaolinite and 51% quartz. Wet beneficiation resulted into 53% improvement of the kaolinite content and 47% reduction of quartz impurity. The XRF analysis has shown that silica-alumina ratio of the raw Getso clay was 1.55 and this reduced to 1.49 after beneficiation. The physicochemical characterization of the clay has shown that Getso clay is neutral, the raw clay and beneficiated clay had average pH values of 7.5 and 7.3, respectively. Specific gravity values of the raw and beneficiated clay were 2.24 and 2.04, respectively. The beneficiation process had been effective as substantial increase in kaolinte content was observed and a reasonable decrese in the impurity contents was observed from the raw to the beneficiated clay. The Garnet content was completely reduced to zero while quartz, clinochlore and orthoclase were reduced by 24%, 9% and 13% respectively. The clay obtained after the beneficiation be serve as good raw material for production of whitewares, high grade ceramics in synthesis of zeolitic materials.

scholarly journals Polyelectrolyte Gels: A Unique Class of Soft Materials

Gels ◽  
2021 ◽  
Vol 7 (3) ◽  
pp. 102
Author(s):  
Ferenc Horkay
Keyword(s):  
Exchange Process ◽  
Interaction Strength ◽  
Soft Materials ◽  
Industrial Applications ◽  
Future Research ◽  
Swelling Kinetics ◽  
Polyelectrolyte Gels ◽  
Ion Exchange Process ◽  
Counter Ions ◽  
Kinetics Of

The objective of this article is to introduce the readers to the field of polyelectrolyte gels. These materials are common in living systems and have great importance in many biomedical and industrial applications. In the first part of this paper, we briefly review some characteristic properties of polymer gels with an emphasis on the unique features of this type of soft material. Unsolved problems and possible future research directions are highlighted. In the second part, we focus on the typical behavior of polyelectrolyte gels. Many biological materials (e.g., tissues) are charged (mainly anionic) polyelectrolyte gels. Examples are shown to illustrate the effect of counter-ions on the osmotic swelling behavior and the kinetics of the swelling of model polyelectrolyte gels. These systems exhibit a volume transition as the concentration of higher valence counter-ions is gradually increased in the equilibrium bath. A hierarchy is established in the interaction strength between the cations and charged polymer molecules according to the chemical group to which the ions belong. The swelling kinetics of sodium polyacrylate hydrogels is investigated in NaCl solutions and in solutions containing both NaCl and CaCl2. In the presence of higher valence counter-ions, the swelling/shrinking behavior of these gels is governed by the diffusion of free ions in the swollen network, the ion exchange process and the coexistence of swollen and collapsed states.

scholarly journals Wire Arc Additive Manufacturing: Review on Recent Findings and Challenges in Industrial Applications and Materials Characterization

Metals ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 939
Author(s):  
Mukti Chaturvedi ◽  
Elena Scutelnicu ◽  
Carmen Catalina Rusu ◽  
Luigi Renato Mistodie ◽  
Danut Mihailescu ◽  
...  
Keyword(s):  
Additive Manufacturing ◽  
Structural Integrity ◽  
Industrial Applications ◽  
Raw Material ◽  
Continuous Increase ◽  
Control Optimization ◽  
Modern Manufacturing ◽  
Directed Energy ◽  
Manufacturing Technologies ◽  
Wire Arc Additive Manufacturing

Wire arc additive manufacturing (WAAM) is a fusion manufacturing process in which the heat energy of an electric arc is employed for melting the electrodes and depositing material layers for wall formation or for simultaneously cladding two materials in order to form a composite structure. This directed energy deposition-arc (DED-arc) method is advantageous and efficient as it produces large parts with structural integrity due to the high deposition rates, reduced wastage of raw material, and low consumption of energy in comparison with the conventional joining processes and other additive manufacturing technologies. These features have resulted in a constant and continuous increase in interest in this modern manufacturing technique which demands further studies to promote new industrial applications. The high demand for WAAM in aerospace, automobile, nuclear, moulds, and dies industries demonstrates compatibility and reflects comprehensiveness. This paper presents a comprehensive review on the evolution, development, and state of the art of WAAM for non-ferrous materials. Key research observations and inferences from the literature reports regarding the WAAM applications, methods employed, process parameter control, optimization and process limitations, as well as mechanical and metallurgical behavior of materials have been analyzed and synthetically discussed in this paper. Information concerning constraints and enhancements of the wire arc additive manufacturing processes to be considered in terms of wider industrial applicability is also presented in the last part of this paper.

scholarly journals A Compact Review of Laser Welding Technologies for Amorphous Alloys

Metals ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 1690
Author(s):  
Jian Qiao ◽  
Peng Yu ◽  
Yanxiong Wu ◽  
Taixi Chen ◽  
Yixin Du ◽  
...  
Keyword(s):  
Amorphous Alloy ◽  
Laser Welding ◽  
Amorphous Alloys ◽  
High Energy ◽  
Industrial Applications ◽  
High Energy Density ◽  
Current Status ◽  
Future Research ◽  
Technological Parameters ◽  
Fast Heating

Amorphous alloys have emerged as important materials for precision machinery, energy conversion, information processing, and aerospace components. This is due to their unique structure and excellent properties, including superior strength, high elasticity, and excellent corrosion resistance, which have attracted the attention of many researchers. However, the size of the amorphous alloy components remains limited, which affects industrial applications. Significant developments in connection with this technology are urgently needed. Laser welding represents an efficient welding method that uses a laser beam with high energy-density for heating. Laser welding has gradually become a research hotspot as a joining method for amorphous alloys due to its fast heating and cooling rates. In this compact review, the current status of research into amorphous-alloy laser welding technology is discussed, the influence of technological parameters and other welding conditions on welding quality is analyzed, and an outlook on future research and development is provided. This paper can serve as a useful reference for both fundamental research and engineering applications in this field.

Analyses and evaluation of the main chemical components in different tobacco (Nicotiana tabacum L.) genotypes

2021 ◽  
Vol 72 (1) ◽  
pp. e389
Author(s):  
M. Camlica ◽  
G. Yaldiz
Keyword(s):  
Fatty Acid ◽  
Crude Oil ◽  
Sugar Content ◽  
Industrial Applications ◽  
Reducing Sugar ◽  
Raw Material ◽  
Chemical Components ◽  
Alternative Source ◽  
Nicotine Content ◽  
Tobacco Seeds

The nicotine, reducing sugar and ion contents from the threshing of tobacco can re-used from the industry. The crude oil and fatty oil compositions of tobacco seeds can be considered as an alternative source of raw material for biodiesel. In this study, the nicotine, reducing sugar content, crude oil, fatty acid composition and ion content were determined in 29 genotypes and 1 cultivar of tobacco. The genetic diversity was determined among the tobacco cultivar and genotypes base on examined properties. The nicotine content varied between 0.10-0.87%, reducing sugar ranged from 9.70-21.30%, crude oil varied between 24.33-47.00% and fatty acid compositions was found in the range of 77.94-100%. Linoleic (13.92-75.04%) and butyric (0.33-64.98%) acids were the major components. Overall, the BSR-5 (52.56 mg/g) and ESR-5 (44.58 mg/g) genotypes exhibited the highest potassium contents and ESR-7 (6.54 mg/g) and ESR-8 (1.28 mg/g) genotypes had the lowest chlorine contents. As a result of this study, the highest nicotine content, reducing sugar and crude oil of tobacco were found in ESR-4, ESR-11 and BSR-5 genotypes, respectively. The dendrogram analysis divided the tobacco into two main groups and most of the same origin genotypes fell into the same group. The results indicated that the different tobacco leaves and seeds can be evaluated as an alternative source in the industry as cigarettes, biodiesel and different industrial applications such as cosmetic, oil paints and varnishes based on their chemical properties.

scholarly journals Chemical Composition and Thermal Behavior of Kraft Lignins

Forests ◽  
2019 ◽  
Vol 10 (6) ◽  
pp. 483 ◽  
Author(s):  
Aleš Ház ◽  
Michal Jablonský ◽  
Igor Šurina ◽  
František Kačík ◽  
Tatiana Bubeníková ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Molecular Weight Distribution ◽  
Weight Distribution ◽  
Cost Effective ◽  
Activation Energies ◽  
Industrial Applications ◽  
Raw Material ◽  
Molecular Weight Determination ◽  
Two Samples ◽  
Process Measurements

Lignin has great potential for utilization as a green raw material or as an additive in various industrial applications, such as energy, valuable chemicals, or cost-effective materials. In this study, we assessed a commercial form of lignin isolated using LignoBoost technology (LB lignin) as well as three other types of lignin (two samples of non-wood lignins and one hardwood kraft lignin) isolated from the waste liquors produced during the pulping process. Measurements were taken for elemental analysis, methoxyl and ash content, higher heating values, thermogravimetric analysis, and molecular weight determination. We found that the elemental composition of the isolated lignins affected their thermal stability, activation energies, and higher heating values. The lignin samples examined showed varying amounts of functional groups, inorganic component compositions, and molecular weight distributions. Mean activation energies ranged from 93 to 281 kJ/mol. Lignins with bimodal molecular weight distribution were thermally decomposed in two stages, whereas the LB lignin showing a unimodal molecular weight distribution was decomposed in a single thermal stage. Based on its thermal properties, the LB lignin may find direct applications in biocomposites where a higher thermal resistance is required.

scholarly journals Kaolinite Claystone-Based Geopolymer Materials: Effect of Chemical Composition and Curing Conditions

Minerals ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 444 ◽  
Author(s):  
Pavlína Hájková
Keyword(s):  
Chemical Composition ◽  
Water Glass ◽  
Chemical Elements ◽  
Solidification Process ◽  
Ease Of Use ◽  
Raw Material ◽  
Curing Conditions ◽  
Low Viscosity ◽  
Lower Porosity ◽  
Curing Methods

This work describes the role of chemical composition and curing conditions in geopolymer strength, leachability of chemical elements and porosity. The study focuses on geopolymer material prepared from calcined kaolinite claystone, which is not studied frequently as a raw material for geopolymer production, although it has a high application potential as it is easily commercially available and allows preparation of geopolymers with low viscosity. The composition of geopolymers and their curing methods were selected considering their ease of use in the praxis. Therefore, the potassium water glass itself was used as alkali activator without any KOH or NaOH addition. Chemical composition was changed only by the density of water glass in the range of 1.2 to 1.6 g·cm−3. Geopolymers were cured at a temperature within the range of 5 °C–70 °C to speed up the solidification process as well as by microwave radiation. High compressive strengths were obtained for geopolymers with the highest densities of the water glass (1.5 and 1.6 g·cm−3) in dependence on various curing conditions. Higher strengths were achieved in the case of samples where the solidification was not accelerated. The samples cured at lower temperatures (5 °C) showed lower porosity compared to the other curing types. The lowest leachability of Si and alkalis was reached for the samples with water glass density 1.5 g·cm−3.

scholarly journals Red Mud-Based Polyaluminum Ferric Chloride Flocculant: Preparation, Characterization and Flocculation Performance

2021 ◽  
Author(s):  
Yong Cheng ◽  
Longjun Xu ◽  
Chenglun Liu ◽  
Zao Jiang ◽  
Qiyuan Zhang ◽  
...  
Keyword(s):  
Red Mud ◽  
High Efficiency ◽  
Low Cost ◽  
Oxygen Demand ◽  
Industrial Applications ◽  
Iron Chloride ◽  
Raw Material ◽  
Molar Ratio ◽  
Polymerization Temperature ◽  
Solution Ph

Abstract In this work, red mud was used as raw material to extract Al and Fe with hydrochloric acid. The high-efficiency polyaluminum iron chloride (PAFC) flocculant was prepared via adjusting the pH of the leaching solution, the molar ratio of aluminum and iron, and the polymerization temperature. The effect of synthesis and flocculation conditions on the flocculation performance of aged landfill leachate was investigated. The results confirmed that the PAFC prepared at the polymerization pH of 2.5, the Al/Fe molar ratio of 8, and the polymerization temperature of 70 °C had the optimum flocculation effect. The flocculation consequences of PAFC and commercial polyaluminum iron chloride flocculant (CPAFC) under different flocculation conditions were compared. The chemical oxygen demand (COD), UV254, chroma and settlement height of PAFC at flocculant concentration of 60 g/L and solution pH of 6 were 72.2%, 79.2%, 82.9% and 9.5 cm (within 90 min), respectively. PAFC has excellent flocculation performance and can be used as a simple, potentially low-cost wastewater treatment agent in industrial applications.

scholarly journals New Laboratory and Pilot Techniques Applied at Mintek in Aid of Furnace Containment System Designs

JOM ◽  
2021 ◽  
Author(s):  
Joalet Dalene Steenkamp ◽  
Kondwani Wesley Banda ◽  
Pieter Johannes Andries Bezuidenhout ◽  
Glen Michael Denton
Keyword(s):  
Pilot Scale ◽  
Industrial Applications ◽  
Raw Material ◽  
Design Philosophy ◽  
Dc Arc Furnace ◽  
Containment System ◽  
Furnace Technology ◽  
Dc Arc ◽  
System Designs ◽  
Selection Of

AbstractThe Pyrometallurgy Division at Mintek is known internationally for the development of applications of direct current (DC) arc furnace technology in smelting applications, more specifically in the smelting of primary resources, i.e., chromite, ilmenite, titanomagnetite, nickel laterite and ores containing precious group metals, and secondary resources, i.e., furnace slag or dust. From a furnace containment perspective, either an insulating or a conductive design philosophy can be applied, irrespective of the raw material being processed. In the initial stages of a project, desktop studies are typically conducted which include the selection of a furnace containment design philosophy, specific to the application. To lower the risk associated with incorrect selection of a design philosophy and/or furnace containment system components, it is prudent to conduct tests on laboratory and pilot scale and to transfer the knowledge gained to industrial applications. The paper presents examples of the laboratory and pilot techniques utilized.

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