scholarly journals Characterization and Thermal Behavior Study of Biomass from Invasive Acacia mangium Species in Brunei Preceding Thermochemical Conversion

2021 ◽  
Vol 13 (9) ◽  
pp. 5249
Author(s):  
Ashfaq Ahmed ◽  
Muhammad S. Abu Bakar ◽  
Abdul Razzaq ◽  
Syarif Hidayat ◽  
Farrukh Jamil ◽  
...  
Keyword(s):  
Native Species ◽  
Acacia Mangium ◽  
Proximate Analysis ◽  
Yield Potential ◽  
Thermochemical Conversion ◽  
Cellulose Decomposition ◽  
Brunei Darussalam ◽  
Behavior Study ◽  
Bio Oil ◽  
Moisture Basis

Acacia mangium is a widely grown tree species across the forests in Brunei Darussalam, posing a threat to the existence of some native species in Brunei Darussalam. These species produce large quantities of lignocellulosic biomass from the tree parts comprising the phyllodes, trunk, bark, twigs, pods, and branches. This study examined the thermochemical characteristics and pyrolytic conversion behavior of these tree parts to assess the possibility of valorization to yield bioenergy. Proximate, ultimate, heating value, and Fourier Transform Infrared Spectroscopy (FTIR) analyses were performed to assess the thermochemical characterization, while thermogravimetric analysis was conducted to examine the pyrolytic degradation behavior. Proximate analysis revealed a moisture content, volatile, fixed carbon, and ash contents of 7.88–11.65 wt.%, 69.82–74.85 wt.%, 14.47–18.31 wt.%, and 1.41–2.69 wt.%, respectively. The heating values of the samples were reported in a range of 19.51–21.58 MJ/kg on a dry moisture basis, with a carbon content in the range of 45.50–50.65 wt.%. The FTIR analysis confirmed the heterogeneous nature of the biomass samples with the presence of multiple functional groups. The pyrolytic thermal degradation of the samples occurred in three major stages from the removal of moisture and light extractives, hemicellulose and cellulose decomposition, and lignin decomposition. The bio-oil yield potential from the biomass samples was reported in the range of 40 to 58 wt. %, highlighting the potential of Acacia mangium biomass for the pyrolysis process.

scholarly journals Acacia Holosericea: An Invasive Species for Bio-char, Bio-oil, and Biogas Production

2019 ◽  
Vol 6 (2) ◽  
pp. 33 ◽  
Author(s):  
Md Sumon Reza ◽  
Ashfaq Ahmed ◽  
Wahyu Caesarendra ◽  
Muhammad S. Abu Bakar ◽  
Shahriar Shams ◽  
...  
Keyword(s):  
Moisture Content ◽  
Heating Rate ◽  
Invasive Plant ◽  
Biogas Production ◽  
Proximate Analysis ◽  
High Hydrogen ◽  
Heating Value ◽  
Brunei Darussalam ◽  
Bio Oil ◽  
Acacia Holosericea

To evaluate the possibilities for biofuel and bioenergy production Acacia Holosericea, which is an invasive plant available in Brunei Darussalam, was investigated. Proximate analysis of Acacia Holosericea shows that the moisture content, volatile matters, fixed carbon, and ash contents were 9.56%, 65.12%, 21.21%, and 3.91%, respectively. Ultimate analysis shows carbon, hydrogen, and nitrogen as 44.03%, 5.67%, and 0.25%, respectively. The thermogravimetric analysis (TGA) results have shown that maximum weight loss occurred for this biomass at 357 °C for pyrolysis and 287 °C for combustion conditions. Low moisture content (<10%), high hydrogen content, and higher heating value (about 18.13 MJ/kg) makes this species a potential biomass. The production of bio-char, bio-oil, and biogas from Acacia Holosericea was found 34.45%, 32.56%, 33.09% for 500 °C with a heating rate 5 °C/min and 25.81%, 37.61%, 36.58% with a heating rate 10 °C/min, respectively, in this research. From Fourier transform infrared (FTIR) spectroscopy it was shown that a strong C–H, C–O, and C=C bond exists in the bio-char of the sample.

scholarly journals Characterizations of Biomasses for Subsequent Thermochemical Conversion: A Comparative Study of Pine Sawdust and Acacia Tortilis

Processes ◽  
2020 ◽  
Vol 8 (5) ◽  
pp. 546
Author(s):  
Gratitude Charis ◽  
Gwiranai Danha ◽  
Edison Muzenda
Keyword(s):  
Calorific Value ◽  
Proximate Analysis ◽  
Thermochemical Conversion ◽  
Infrared Spectrometry ◽  
Acacia Tortilis ◽  
Pine Sawdust ◽  
Bio Oil ◽  
Bulk Energy ◽  
Compressed Wood

The bioenergy production potential from biomasses is dependent on their characteristics. This study characterized pine sawdust samples from Zimbabwe and acacia tortilis samples from Botswana using conventional and spectrometry techniques. The ultimate analysis results for pine were 45.76% carbon (C), 5.54% hydrogen (H), 0.039% nitrogen (N), 0% sulphur (S) and 48.66% oxygen (O) and, for acacia, were 41.47% C, 5.15% H, 1.23% N, 0% S and 52.15% O. Due to the low N and S in the biomasses, they promise to provide cleaner energy than fossil-based sources. Proximate analysis results, on a dry basis, for acacia were 3.90% ash, 15.59% fixed carbon and 76.51% volatiles matter and 0.83%, 20% and 79.16%, respectively, for pine. A calorific value of 17.57 MJ/kg was obtained for pine, compared with 17.27 MJ/kg for acacia, suggesting they are good thermochemical feedstocks. Acacia’s bulk energy density is five times that of pine, making it excellent for compressed wood applications. Though the ash content in acacia was much higher than in pine, it fell below the fouling and slagging limit of 6%. In pyrolysis, however, high ash contents lead to reduced yields or the quality of bio-oil through catalytic reactions. Fourier transform infrared spectrometry indicated the presence of multiple functional groups, as expected for a biomass and its derivatives.

Thermogravimetric devolatisation behavior of agricultural residue for generation of syngas

2021 ◽  
pp. 1-17
Author(s):  
Praveen Kumar ◽  
P.M.V. Subbarao ◽  
L.D. Kala ◽  
V.K. Vijay
Keyword(s):  
Activation Energy ◽  
Pearl Millet ◽  
Proximate Analysis ◽  
Thermochemical Conversion ◽  
Degradation Behavior ◽  
Ozawa Method ◽  
Thermogravimetric Method ◽  
Agricultural Residue ◽  
Tg Analysis ◽  
Tg And Dtg

Abstract The thermal degradation characteristics of eucalyptus, pearl millet cob, and corncob were investigated using non-isothermal thermogravimetric method. This investigation was performed with the objective of carrying out thermochemical conversion for obtaining syngas. TG and DTG analysis were carried out to understand thermal devolatisation behavior and estimation of various thermophysical properties of the biomasses. The degradation behavior was analysed in the light of lignocellulosic composition that was found to have definitive influence on degradation outcomes. TG analysis has been utilized to obtain proximate analysis of biomass. Activation energy using Flynn-Wall-Ozawa method have been estimated and found to be 201, 150 and 68 kJ mol−1 for eucalyptus, pearl millet cob, and corncob respectively. The TG analysis and activation energy together indicated that corncob is easiest for thermochemical conversion amongst the three biomasses. The TG curve also confirms the same.

Evaluation of Polymer Compatibility with Bio-oil Produced from Thermochemical Conversion of Biomass

2015 ◽  
Vol 29 (12) ◽  
pp. 7993-7997 ◽  
Author(s):  
Martin R. Haverly ◽  
Lysle E. Whitmer ◽  
Robert C. Brown
Keyword(s):  
Thermochemical Conversion ◽  
Bio Oil ◽  
Polymer Compatibility

scholarly journals GROWTH AND YIELD OF Shorea parvifolia PLANTED UNDER AKASIA PLANTS IN KAPUAS, CENTRAL KALIMANTAN

2016 ◽  
Vol 7 (3) ◽  
pp. S48-S49
Author(s):  
Wahyudi .
Keyword(s):  
Native Species ◽  
Research Result ◽  
Volume Growth ◽  
Acacia Mangium ◽  
Average Diameter ◽  
Growth And Yield ◽  
Central Kalimantan ◽  
Enrichment Planting ◽  
The Moment ◽  
Silvicultural System

Shorea parvifolia is the native species of Kalimantan and has a high commercial value. This research was aimed to analysis the growth and yield of meranti planted under Acacia mangium stands, as enrichment planting on the TPTI silvicultural system.  The research was conducted at Kapuas District, Central Kalimantan Province. Type of soil at the site is ultisol with 2 606 mm/year of precipitation average.  Initially, Acacia mangium planted with space namely 3 x 3 m at 1993. After two years, seedlings of Shorea parvifolia were planted among akasia plants with 1 111 tress/ha of density.  Thinning of akasia plants were conducted stage by stage, especially at the stunted plants or dead. The data were latest analyzed at 2014 or at the moment of 20 years old.  Research result showed that at the 1, 5, 10, 15, and 15 years old, life percentage of Shorea parvifolia are 94.8%, 78%, 66.4%, 57.5%, and 53% respectively. Average diameter of Shorea parvifolia at the same times are 1.27 cm, 6.13 cm, 12.8 cm, 19.86, and 27.46 cm respectively, and their average total height are 1.51 m, 5.27 m, 10.89 m, 17.18 m, and 24.41 m respectively. Volume growth of Shorea parvifolia at the same times namely 0.05 m3/ha , 3.97 m3/ha, 36.93 m3/ha, 145.44 m3/ha, and 303.62 m3/ha respectively.Key words: growth and yield, CAI, MAI, Shorea parvifolia.

scholarly journals Influence of Pyrolysis Temperature on Product Distribution and Characteristics of Anaerobic Sludge

Energies ◽  
2019 ◽  
Vol 13 (1) ◽  
pp. 79
Author(s):  
Muhammad Usman Hanif ◽  
Mohammed Zwawi ◽  
Sergio C. Capareda ◽  
Hamid Iqbal ◽  
Mohammed Algarni ◽  
...  
Keyword(s):  
Pyrolysis Temperature ◽  
Product Distribution ◽  
Biofuel Production ◽  
Thermochemical Conversion ◽  
Anaerobic Sludge ◽  
Cow Dung ◽  
High Heating Value ◽  
Bio Oil ◽  
Different Temperatures ◽  
Combustible Gases

Pyrolysis of anaerobically digested sludge can serve as an efficient biomass for biofuel production. Pyrolysis produces products like char, bio-oil, and combustible gases by thermochemical conversion process. It can be used for sludge treatment that decreases sludge disposal problems. Sludge produced from anaerobic co-digestion (microalgae, cow dung, and paper) waste has high carbon and hydrogen content. We investigated the candidacy of the anaerobic sludge having high heating value (HHV) of 20.53 MJ/kg as a reliable biomass for biofuels production. The process of pyrolysis was optimized with different temperatures (400, 500, and 600 °C) to produce high quantity and improved quality of the products, mainly bio-oil, char, and gas. The results revealed that with the increase in pyrolysis temperature the quantity of char decreased (81% to 55%), bio-oil increased (3% to 7%), and gas increased (2% to 5%). The HHV of char (19.2 MJ/kg), bio-oil (28.1 MJ/kg), and gas (18.1 MJ/kg) were predominantly affected by the amount of fixed carbon, hydrocarbons, and volatile substance, respectively. The study confirmed that the anaerobic sludge is a promising biomass for biofuel production and pyrolysis is an efficient method for its safe disposal.

scholarly journals Karakteristik dan Potensi Produksi Pati Varietas Sagu Bestari [Characteristics and Starch Production Potential of Sago Bestari Variety]

Buletin Palma ◽  
2020 ◽  
Vol 21 (1) ◽  
pp. 29
Author(s):  
Hengky Novarianto ◽  
Ismail Maskromo ◽  
Meity A Tulalo ◽  
Elsje T Tenda ◽  
Jeanette Kumaunang ◽  
...  
Keyword(s):  
Vitamin C ◽  
Morphological Characteristics ◽  
Proximate Analysis ◽  
Leaf Length ◽  
Yield Potential ◽  
High Yield ◽  
Observation Data ◽  
Sago Starch ◽  
Production Potential ◽  
Starch Production

<p>Sago development requires plant material as superior seedlings for rehabilitation and replanting. Until 2016 two superior sago varieties were released, namely Molat sago varieties from Maluku in 2011 and Selatpanjang Meranti sago varieties from the Meranti Islands Regency, Riau in 2013. Indragiri Hilir Regency, Riau Province is one of the areas of natural sago growth, and producing sago starch . This district has the opportunity to develop sago palms as a potential and regional producer. In connection with that, a research has been conducted which aims to find out and obtain superior sago species from Indragiri Hilir Regency, from 2015 to 2017. The research method was conducted by observing the sago population with high yield potential. For the observation, 10 sample trees every year were selected in each location/village in Gaung Anak Serka District, Indragiri Hilir Regency, Riau Province. Data observations were carried out on the morphological characteristics of sago and suckers, sago starch production potential, and proximate analysis. Observation data were analyzed for diversity, standard deviation and coefficient of variance. Morphological observations and production of Bestari sago starch obtained an average leaf length of 8.00 m, diameter of the diameter of bottom stem 47.37 cm, circumference of the bottom stem 148.52 cm, the number of leaf scars on the leaf-free stem 53.23 scars, the number leaves on the crown 16.98 strands, the distance of leaf scar 12.42 cm, the length of the petiole 231.00 cm, the width of the petiole 9.25 cm, the thickness of the petiole 3.93 cm, the length of the rachis 660.33 cm, the length of the leaflets 155.59 cm, leaflets width 9.39 cm, and dry starch yield 254.94 kg per palm. Proximate analysis results on Bestari sago starch obtained an average water content of 13.00%, ash content of 0.60%, fat content of 0.83%, protein content of 0.84%, crude fiber content of 0.29%, and carbohydrate content was 84.34%, with 350 calories, Vitamin C 0.96 mg/100 gr sago starch, and total sugar around 1.43%. Hoping that sago Bestari variety will become the suckers resources for sago development in Indragiri Hilir Region, Riau Province and other region of Indonesia.</p><p> </p><p><strong>ABSTRAK </strong></p><p>Pengembangan sagu membutuhkan bahan tanaman sebagai bibit unggul untuk rehabilitasi dan penanaman kembali. Sampai tahun 2016 telah dilepas dua varietas sagu unggul, yaitu varietas sagu Molat asal Maluku tahun 2011 dan varietas sagu Selatpanjang Meranti asal Kabupaten Kepulauan Meranti, Riau tahun 2013. Kabupaten Indragiri Hilir, Provinsi Riau adalah salah satu daerah pertumbuhan sagu alami dan penghasil pati sagu. Kabupaten ini memiliki peluang untuk dikembangkan tanaman sagu sebagai potensi dan penghasilan daerah. Sehubungan dengan itu, maka telah dilakukan penelitian yang bertujuan untuk mengetahui dan mendapatkan jenis sagu unggul asal Kabupaten Indragiri Hilir, sejak tahun 2015 sampai tahun 2017. Metode penelitian dilakukan dengan observasi terhadap populasi sagu potensi hasil tinggi. Untuk pengamatan telah dipilih sebanyak 10 pohon contoh setiap tahun di setiap lokasi/Desa di Kecamatan Gaung Anak Serka, Kabupaten Indragiri Hilir, Provinsi Riau. Pengamatan data dilakukan terhadap karakteristik morfologi tanaman sagu dan anakan, potensi produksi pati sagu, dan analisis proksimat. Data pengamatan dianalisis keragaman, simpangan baku dan koefisien keragamannya. Hasil pengamatan morfologi dan produksi pati sagu Bestari diperoleh rata-rata panjang bebas daun 8,00 m, diameter batang bawah 47,37 cm, lingkar batang bawah 148,52 cm, jumlah bekas pelepah daun pada batang bebas daun 53,23 buah, jumlah daun pada mahkota 16,98 helai, jarak antar pelepah 12,42 cm, panjang pelepah 231,00 cm,lebar pelepah 9,25 cm, tebal pelepah 3,93 cm, panjang daun 660,33 cm, panjang anak daun 155,59 cm, lebar anak daun 9,39 cm, dan produksi pati kering 254,94 kg per pohon. Hasil analisis proksimat pada pati sagu Bestari diperoleh rata-rata kadar air 13,00%, kadar abu 0,60%, kadar lemak 0,83%, kadar protein 0,84%, kandungan serat kasar 0,29%, dan kadar karbohidrat adalah 84,34%, dengan 350 kalori, Vitamin C 0,96 mg/100 gr pati sagu, dan total gula sekitar 1,43%. Diharapkan varietas sagu Bestari menjadi sumber benih untuk pengembangan sagu di Kabupaten Indragiri Hilir, Riau dan daerah Indonesia lainnya</p>

scholarly journals PYROLYSIS OF ALANG – ALANG (IMPERATA CILINDRICA) AS BIOENERGY SOURCE IN BANTEN PROVINCE INDONESIA

2019 ◽  
Vol 3 (1) ◽  
pp. 60-78
Author(s):  
Fitriyah Fitriyah ◽  
Syarif Hidayat ◽  
Muhammad S. Abu Bakar ◽  
Neeranuch Phusunti
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Thermogravimetric Analysis ◽  
Elemental Analysis ◽  
Fixed Bed ◽  
Compositional Analysis ◽  
Calorific Value ◽  
Proximate Analysis ◽  
Gas Chromatography Mass Spectrometry ◽  
Bio Oil

Bahan bakar fosil sumber energi memiliki keterbatasan dan tidak terbarukan, penggunaan bahan bakar fosil secara terus menerus mengakibatkan krisis energy dan lingkungan. Rumput liar pada saat ini memiliki potensi untuk dikembangkan sebagai generasi kedua biomasa. Hal ini memiliki keuntungan seperti tumbuh dengan cepat, mudah tumbuh, perawatan yang minimal, dapat tumbuh pada lahan kritis dan tersedia dalam jumlah yang banyak. Dalam upaya mengembangkan generasi kedua biomasa, penelitian ini secara sistematis memberikan perspektif ekologi dan teknologi proses dalam mengembangkan bioenergi dari alang – alang di Provinsi Banten. Pada penelitian ini karakterisasi alang – alang dilakukan untuk menentukan sifat – sifat dan potensi bioenergy. Sedangkan fixed bed pirolisis dilakukan untuk mengidentifikasi potensi produksi bio-oil dari proses pirolisis. Sementara analisis karakterisasi bio-oil dilakukan untuk melihat potensi chemical building block sebagai sumber energi. Analisis sifat kimia dan fisika alang – alang dilakukan melalui thermogravimetric analysis, proximate analysis, elemental analysis, compositional analysis, calorific value. Sedangkan analisis potensi bio-oil di lakukan melalui Gas Chromatography–Mass Spectrometry (GC-MS). Dari hasil karakterisasi mengindikasikan bahwa alang – alang memiliki nilai kalori 18,05 MJ/kg, dengan ash konten yang rendah, dan tinggi kandungan volatile. Analisis dengan GC/MS menunjukan komponen utama dalam bio-oil dikelompokan ke dalam furan, ketone, phenol dan anhydrosugar yang merupakan platform yang dapat dikonversi menjadi sumber energi. Fixed bed pyrolysis atau fixed bed pirolisis alang – alang menunjukan, bahwa yield bio-oil meningkat sebagaimana peningkatan temperatur dan puncaknya pada suhu 500 0C dengan persentase 37,91%. Kata Kunci: Alang - alang, Pirolisis, GC/MS, Thermogravimetric analysis, Bioenergi   ABSTRACT Fossil fuel as a source of energy have limitation and are non-renewable. Continuous utilisation of fossil fuels as energy source can lead to energy crisis and environmental impact. Perennials grasses (alang – alang) are currently being developed as a suitable second-generation biofuel feedstock. It has advantages such as rapid growth rate, easy to grow, minimal maintenance and utilise marginal land without competing with food supply. Taking into account of the various challenges attributed to the transformation of second-generation biomass for energy production, this work systematically looks at the ecological perspective and the availability for bioenergy production from alang – alang in Banten Province. Biomass characterisation is carried out to determine the properties and bioenergy potential. Fixed bed pyrolysis study was conducted to predict the potential production of bio-oil from the pyrolysis process. GC/MS study is conducted to identify the potential building blocks of value-added chemicals from alang – alang. The physicochemical properties of feedstock was thoroughly evaluated using thermogravimetric analysis, proximate analysis, elemental analysis, compositional analysis, calorific value. The analysis of the potential of bio-oil was carried out through GC / MS. Characterisation results indicate that alang - alang has a calorific value of 18.39 MJ/kg, with low ash content and high percentage of volatile matter. Analysis from Gas Chromatography–Mass Spectrometry (GC-MS) showed that majority of the chemical groups in the bio-oil contained furan, ketone, phenol and anhydro-sugars. Phenolic and furanic were found as major compounds in bio oil. Phenolic, furanic, ketonic and anhydrosugars are promising renewable platform compounds derived from pyrolysis of alang – alang. The compounds can be further converted to chemicals or fuels. The fixed-bed pyrolysis of alang - alang showed that the yield of bio-oil increases as the temperature increases and peaks at 500°C with 38.79%. Keywords: Alang - alang, Pyrolysis, GC/MS, Thermogravimetric analysis, Bioenergy

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