Swelling, Tensile and Thermal Behaviors of Citric Acid Crosslinked Tapioca Starch/Cellulose Biocomposite Films

2020 ◽  
Vol 1010 ◽  
pp. 514-519
Author(s):  
Salleh Morgan Noor Zulaika ◽  
Hui Lin Ong ◽  
Firuz Zainuddin
Keyword(s):  
Tensile Strength ◽  
Lemon Juice ◽  
Cellulose Content ◽  
Scanning Calorimetry ◽  
Lime Juice ◽  
Tapioca Starch ◽  
Biocomposite Films ◽  
Key Lime ◽  
Biocomposite Film ◽  
Strength Result

The biocomposite films were prepared using a solution casting method and allowed to dry in the oven of 50°C. The cellulose used in this research was extracted from the rice straw. The biocomposite films firstly were prepared without crosslinker with various cellulose content; 0.2g, 0.4g, 0.6g, 0.8g, and 1.0g wt%. Based on the tensile strength result, 0.6g of cellulose is an optimum amount to prepare the biocomposite films with various amounts of crosslinker; 1g, 2g, 3g, 4g, and 5g. The tapioca starch/cellulose biocomposite films crosslinked with lemon juices have higher tensile strength (16MPa) and lower in swelling percentage (3.32%) compared to the biocomposite films crosslinked with key lime juice (5.44%). The thermal behavior was studied based on the Differential Scanning Calorimetry test shows the biocomposite film that highly crosslinked needs higher energy during their phase change. The energy liberated in the tapioca starch/cellulose biocomposite film with key lime juice as crosslinker is 201.6 J/g while that of biocomposite film with lemon juice as crosslinker is 383.0 J/g.

scholarly journals Tensile Strength and Moisture Resistance Properties of Biocomposite Films Based on Polyvinyl Alcohol (PVA) with Cellulose as Reinforcement from Durian Peel Fibers

2021 ◽  
Vol 302 ◽  
pp. 02001
Author(s):  
Melbi Mahardika ◽  
Mochamad Asrofi ◽  
Devita Amelia ◽  
Edi Syafri ◽  
Sanjay Mavinkere Rangappa ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Polyvinyl Alcohol ◽  
Cellulose Fibers ◽  
Moisture Resistance ◽  
Solution Casting ◽  
Casting Method ◽  
Elongation At Break ◽  
Biocomposite Films ◽  
Solution Casting Method ◽  
Biocomposite Film

Polyvinyl Alcohol (PVA) based biocomposite film with cellulose was successfully fabricated by the solution casting method. The cellulose fibers were obtained by extraction of durian peel using alkalization and bleaching treatments. These treated cellulose fibers were used for the fabrication of PVA-based biocomposites. The durian peel cellulose fibers were varied by 2%, 4%, 6%, and 8% in the PVA matrix. Tensile test and moisture resistance of biocomposites were evaluated. The 6% addition of cellulose fibers in biocomposites increases the tensile strength up to 54% (37 MPa) than pure PVA film (24 MPa). Conversely, it reduces the elongation at break of the biocomposite film. Meanwhile, the moisture resistance properties of the biocomposites increased with the addition of cellulose fibers. The tensile strength and moisture resistance of biocomposites have been increased due to the homogeneous dispersion of the cellulose fibers and PVA matrix. These biocomposites able to reduce the environmental impacts by utilizing residual lignocellulosic biomass.

scholarly journals Electrical and Mechanical Properties of Sugarcane Bagasse Pyrolyzed Biochar Reinforced Polyvinyl Alcohol Biocomposite Films

2021 ◽  
Vol 5 (9) ◽  
pp. 249
Author(s):  
Kawsar Ahmed ◽  
Mahbub Hasan ◽  
Julfikar Haider
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Polyvinyl Alcohol ◽  
Sugarcane Bagasse ◽  
Electrical Conductance ◽  
Biocomposite Films ◽  
Thermochemical Processing ◽  
Biocomposite Film ◽  
Experimental Findings ◽  
A Minor

Biochar obtained from the oxygen-deficient thermochemical processing of organic wastes is considered to be an effective reinforcing agent in biocomposite development. In the present research, biocomposite film was prepared using sugarcane bagasse pyrolyzed biochar and polyvinyl alcohol (PVA), and its electrical and mechanical properties were assessed. The biocomposite films were produced by varying content (5 wt.%, 8 wt.% and 12 wt.%) of the biochar produced at 400 °C, 600 °C, 800 °C and 1000 °C and characterized using X-Ray diffraction, scanning electron microscope, Fourier transform infrared spectroscopy. The experimental findings revealed that biochar produced at a higher pyrolyzing temperature could significantly improve the electrical conductance of the biocomposite film. A maximum electrical conductance of 7.67 × 10−2 S was observed for 12 wt.% addition of biochar produced at 1000 °C. A trend of improvement in the electrical properties of the biocomposite films suggested a threshold wt.% of the biochar needed to make a continuous conductive network across the biocomposite film. Rapid degradation of tensile strength was observed with an increasing level of biochar dosage. The lowest tensile strength 3.12 MPa was recorded for the film with 12 wt.% of biochar produced at 800 °C. Pyrolyzing temperature showed a minor impact on the mechanical strength of the biocomposite. The prepared biocomposites could be used as an electrically conductive layer in electronic devices.

Analysis of Sound Reduction and Strong Drag Composite Concrete Fibers Gedebok Banana Results Delignification with Sodium Hydroxide Solvent (Naoh)

2018 ◽  
Vol 6 (02) ◽  
pp. 105-120
Author(s):  
Muhammad Rouf Suprayogi ◽  
Annisa Mufida ◽  
Edwin Azwar
Keyword(s):  
Tensile Strength ◽  
Compressive Strength ◽  
Lignin Content ◽  
Sound Intensity ◽  
Cellulose Fiber ◽  
Cellulose Content ◽  
Cellulose Powder ◽  
Drying Method ◽  
Normal Concrete ◽  
Sound Reduction

In composite science, desirable materials that are lighter but have the power and quality that can match or even exceed the material that has been there before. The purpose of this study was to investigate the effect of cellulose fiber addition from banana gedebok to tensile strength, compressive strength and damping of concrete composite sound. To achieve this objective, mixing of cellulose fibers with K-275 quality concrete mix with variation of 0% and 5% substitution in which the cellulose is varied in powder and wicker form. Delignification of lignin content from banana gedebok was done by soaking and drying method without any variation and yielding powder having cellulose content of 13,0388%, hemicellulose 18,2796% and lignin 0,6684%. This study produces concrete composites that have a tensile strength and a compressive strength lower than that of normal concrete. Normally reinforced concrete tensile strength value 94.5 kg / cm2, 71.4 kg / cm2 cellulose powder concrete and 90.3 kg / cm2 cellulose woven concrete. Normal concrete compressive strength value 334,22 kg / cm2, cellulose powder concrete 215,7 kg / cm2, and cellulose webbing concrete 157,98 kg / cm2. As for the power damping sound of cellulose webbing concrete has the highest damping power compared to other concrete with the absorbed sound intensity that is 52-68 dB

Effect of Microcrystalline Cellulose from Banana Stem Fiber on Mechanical Properties and Crystallinity of PLA Composite Films

2011 ◽  
Vol 695 ◽  
pp. 170-173 ◽  
Author(s):  
Voravadee Suchaiya ◽  
Duangdao Aht-Ong
Keyword(s):  
Tensile Strength ◽  
Young’S Modulus ◽  
Microcrystalline Cellulose ◽  
Young's Modulus ◽  
Agricultural Waste ◽  
Composite Films ◽  
Sem Image ◽  
Biocomposite Films ◽  
Twin Screw ◽  
Banana Stem

This work focused on the preparation of the biocomposite films of polylactic acid (PLA) reinforced with microcrystalline cellulose (MCC) prepared from agricultural waste, banana stem fiber, and commercial microcrystalline cellulose, Avicel PH 101. Banana stem microcrystalline cellulose (BS MCC) was prepared by three steps, delignification, bleaching, and acid hydrolysis. PLA and two types of MCC were processed using twin screw extruder and fabricated into film by a compression molding. The mechanical and crystalline behaviors of the biocomopsite films were investigated as a function of type and amount of MCC. The tensile strength and Young’s modulus of PLA composites were increased when concentration of MCC increased. Particularly, banana stem (BS MCC) can enhance tensile strength and Young’s modulus of PLA composites than the commercial MCC (Avicel PH 101) because BS MCC had better dispersion in PLA matrix than Avicel PH 101. This result was confirmed by SEM image of fractured surface of PLA composites. In addition, XRD patterns of BS MCC/PLA composites exhibited higher crystalline peak than that of Avicel PH 101/PLA composites

scholarly journals Recycling Waste Cotton Cloths for the Isolation of Cellulose Nanocrystals: A Sustainable Approach

Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 626
Author(s):  
Siti Hajar Mohamed ◽  
Md. Sohrab Hossain ◽  
Mohamad Haafiz Mohamad Kassim ◽  
Mardiana Idayu Ahmad ◽  
Fatehah Mohd Omar ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Cellulose Nanocrystals ◽  
Value Added ◽  
Crystallinity Index ◽  
Attenuated Total Reflection ◽  
Cellulose Content ◽  
Scanning Calorimetry ◽  
Good Thermal Stability ◽  
Alkaline Pulping ◽  
Hydrolysis Of Cellulose

There is an interest in the sustainable utilization of waste cotton cloths because of their enormous volume of generation and high cellulose content. Waste cotton cloths generated are disposed of in a landfill, which causes environmental pollution and leads to the waste of useful resources. In the present study, cellulose nanocrystals (CNCs) were isolated from waste cotton cloths collected from a landfill. The waste cotton cloths collected from the landfill were sterilized and cleaned using supercritical CO2 (scCO2) technology. The cellulose was extracted from scCO2-treated waste cotton cloths using alkaline pulping and bleaching processes. Subsequently, the CNCs were isolated using the H2SO4 hydrolysis of cellulose. The isolated CNCs were analyzed to determine the morphological, chemical, thermal, and physical properties with various analytical methods, including attenuated total reflection-Fourier transform-infrared spectroscopy (ATR-FTIR), field-emission scanning electron microscopy (FE-SEM), energy-filtered transmission electron microscopy (EF-TEM), X-ray diffraction (XRD), thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). The results showed that the isolated CNCs had a needle-like structure with a length and diameter of 10–30 and 2–6 nm, respectively, and an aspect ratio of 5–15, respectively. Additionally, the isolated CNCs had a high crystallinity index with a good thermal stability. The findings of the present study revealed the potential of recycling waste cotton cloths to produce a value-added product.

scholarly journals Dynamic Single-Fiber Pull-Out of Polypropylene Fibers Produced with Different Mechanical and Surface Properties for Concrete Reinforcement

Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 722
Author(s):  
Enrico Wölfel ◽  
Harald Brünig ◽  
Iurie Curosu ◽  
Viktor Mechtcherine ◽  
Christina Scheffler
Keyword(s):  
Tensile Strength ◽  
Dynamic Loading ◽  
Melt Spinning ◽  
Structural Changes ◽  
High Surface ◽  
Single Fiber ◽  
Scanning Calorimetry ◽  
Matrix Interaction ◽  
Pull Out ◽  
Fiber Matrix

In strain-hardening cement-based composites (SHCC), polypropylene (PP) fibers are often used to provide ductility through micro crack-bridging, in particular when subjected to high loading rates. For the purposeful material design of SHCC, fundamental research is required to understand the failure mechanisms depending on the mechanical properties of the fibers and the fiber–matrix interaction. Hence, PP fibers with diameters between 10 and 30 µm, differing tensile strength levels and Young’s moduli, but also circular and trilobal cross-sections were produced using melt-spinning equipment. The structural changes induced by the drawing parameters during the spinning process and surface modification by sizing were assessed in single-fiber tensile experiments and differential scanning calorimetry (DSC) of the fiber material. Scanning electron microscopy (SEM), atomic force microscopy (AFM) and contact angle measurements were applied to determine the topographical and wetting properties of the fiber surface. The fiber–matrix interaction under quasi-static and dynamic loading was studied in single-fiber pull-out experiments (SFPO). The main findings of microscale characterization showed that increased fiber tensile strength in combination with enhanced mechanical interlocking caused by high surface roughness led to improved energy absorption under dynamic loading. Further enhancement could be observed in the change from a circular to a trilobal fiber cross-section.

scholarly journals DESIGN, OPTIMIZATION AND EVALUATION OF CETRIZINE DIHYDROCHLORIDE FAST DISSOLVING FILMS EMPLOYING STARCH TARTRATE–A NOVEL SUPERDISINTEGRANT

2019 ◽  
pp. 75-86
Author(s):  
R. SANTOSH KUMAR ◽  
ANNU KUMARI ◽  
B. KUSUMA LATHA ◽  
PRUDHVI RAJ
Keyword(s):  
Tensile Strength ◽  
Drug Dissolution ◽  
In Vitro Dissolution ◽  
Content Uniformity ◽  
Scanning Calorimetry ◽  
Disintegration Time ◽  
Folding Endurance ◽  
Contour Plots ◽  
The Individual

Objective: The aim of the current research is optimization, preparation and evaluation of starch tartrate (novel super disintegrant) and preparation of fast dissolving oral films of cetirizine dihydrochloride by employing starch tartrate. Methods: To check the drug excipient compatibility studies of the selected drug (Cetrizine dihydrochloride) and the prepared excipient i. e starch tartrate, different studies like FTIR (Fourier-transform infrared spectroscopy), DSC (Differential scanning calorimetry) and thin-layer chromatography (TLC) were carried out to find out whether there is any interaction between cetirizine dihydrochloride and starch tartrate. The solvent casting method was used for the preparation of fast dissolving films. The prepared films were then evaluated for thickness, folding endurance, content uniformity, tensile strength, percent elongation, in vitro disintegration time and in-vitro dissolution studies. Response surface plots and contour plots were also plotted to know the individual and combined effect of starch tartrate (A), croscarmellose sodium (B) and crospovidone (C) on disintegration time and drug dissolution efficiency in 10 min (dependent variables). Results: Films of all the formulations are of good quality, smooth and elegant by appearance. Drug content (100±5%), thickness (0.059 mm to 0.061 mm), the weight of films varies from 51.33 to 58.06 mg, folding endurance (52 to 67 times), tensile strength (10.25 to 12.08 N/mm2). Fast dissolving films were found to disintegrate between 34 to 69 sec. Percent dissolved in 5 min were found to be more in F1 formulation which confirms that starch tartrate was effective at 1%. Conclusion: From the research conducted, it was proved that starch tartrate can be used in the formulation of fast dissolving films of cetirizine dihydrochloride. The disintegration time of the films was increased with increase in concentration of super disintegrant.

scholarly journals Effect of rare earth oxide CeO2 on the anodic bonding performance of PEG-based MEMS encapsulation materials

2021 ◽  
Vol 13 (3) ◽  
pp. 168781402110077
Author(s):  
Chao Du ◽  
Cuirong Liu ◽  
Xu Yin ◽  
Haocheng Zhao
Keyword(s):  
Tensile Strength ◽  
Rare Earth ◽  
Rare Earth Oxide ◽  
Solid Polymer Electrolytes ◽  
Anodic Bonding ◽  
Solid Polymer ◽  
Bonding Layer ◽  
Scanning Calorimetry ◽  
Ion Migration ◽  
Bonding Performance

Herein, we synthesized a new polyethylene glycol (PEG)-based solid polymer electrolyte containing a rare earth oxide, CeO2, using mechanical metallurgy to prepare an encapsulation bonding material for MEMS. The effects of CeO2 content (0–15 wt.%) on the anodic bonding properties of the composites were investigated. Samples were analyzed and characterized by alternating current impedance spectroscopy, X-ray diffraction, scanning electron microscopy, differential scanning calorimetry, tensile strength tests, and anodic bonding experiments. CeO2 reduced the crystallinity of the material, promoted ion migration, increased the conductivity, increased the peak current of the bonding process, and increased the tensile strength. The maximum bonding efficiency and optimal bonding layer were obtained at 8 wt% CeO2. This study expands the applications of solid polymer electrolytes as encapsulation bonding materials.

scholarly journals Infrared Radiation Favorably Influences the Quality Characteristics of Key Lime Juice

2021 ◽  
Vol 11 (6) ◽  
pp. 2842 ◽  
Author(s):  
Ammar B. Altemimi ◽  
Asaad R. S. Al-Hilphy ◽  
Tarek Gamal Abedelmaksoud ◽  
Salam A. Aboud ◽  
Laxmikant S. Badwaik ◽  
...  
Keyword(s):  
Infrared Radiation ◽  
Heat Exposure ◽  
Titratable Acidity ◽  
Pectin Methylesterase ◽  
Physicochemical Characteristics ◽  
Conventional Heating ◽  
Lime Juice ◽  
Significant Difference ◽  
Key Lime ◽  
And Control

The effect of infrared radiation (IR) on the physicochemical characteristics, pectin methylesterase activity (PME), hydroxymethylfurfural (HMF) content, microbiological activity, color, and sensory aspects on black lime juice was studied. IR was compared to conventional thermal heating (CTH) in batch infrared extraction pasteurizer, designed to allow both infrared and conventional heating. IR resulted in a reduction in pH and Brix values and a mild increase in titratable acidity, as compared to CTH and control. After 60 days at 5 °C, the ascorbic acid percentage was decreased by 24.90%, 29.75%, and 58.31% in the control, IR and CTH, respectively. The total amount of phenols in juice treated with IR was higher as compared to CTH and control, while there was a significant decrease in the antioxidant activity. The statistical analysis reflected significantly low (p < 0.05) activity of PME for IR samples as compared to CTH and control. The amount of Hydroxymethylfurfural (HMF) in all juice samples steadily increased during the storage at 5 °C in 60 days. The microbial content of control was 3.85 log cfu/mL after 60 days at 5 °C, while it was 2.1 log cfu/mL for IR which reflected a significant difference between the IR, CTH, and control samples. Additionally, color and sensory analysis of IR treated sample when compared to control, reflected similar attributes. Overall, IR was found to be an excellent substitute for the preservation of black lime juice as a rapid pasteurization technique with less heat exposure; wherein the nutrition and health benefits of the juice could be maintained for a minimum period of 60 days.

Influence of Polypropylene Fiber in Strength of Foamed Concrete

2012 ◽  
Vol 488-489 ◽  
pp. 253-257 ◽  
Author(s):  
Josef Hadipramana ◽  
Abdul Aziz Abdul Samad ◽  
Zi Jun Zhao ◽  
Noridah Mohammad ◽  
W. Wirdawati
Keyword(s):  
Tensile Strength ◽  
Mechanical Test ◽  
Polypropylene Fiber ◽  
High Density ◽  
Splitting Tensile Strength ◽  
Normal Concrete ◽  
Wide Range ◽  
Foamed Concrete ◽  
Strength Result ◽  
And Behavior

Foamed concrete is material that can be used in wide range of constructions and produced in high density. This investigation examined effect of chopped Polypropylene Fiber (PF) that mixed into admixture concerning strength of foamed concrete high density. Mechanical test were performed to measure effect of PF on improving compressive and splitting tensile strength. Result indicate that PF significantly improving compressive strength and behavior of PF where drawn into foamed concrete similarly with normal concrete. The fibrillated PF has been occurred and reduced the micro crack of matrix and prevented propagation crack growth. The presence of PF improved splitting tensile strength was not significantly. Influence of porous of foamed concrete is considered. Scanning Electron Microscope (SEM) exhibits condition microstructure of foamed concrete reinforced PF that alter microstructure, especially interfacial bonding due to PF presence.

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