Formulation and Study of an Environmentally Friendly Microemulsion-Based Drilling Fluid (O/W) with Pine Oil

This work has developed and evaluated a microemulsion-based drilling fluid formulation with characteristics to be applied in oil wells. The microemulsion was formulated with a solution of water/glycerol, pine oil, and Tween 80, a nonionic and biodegradable surfactant. The physical and chemical properties of the drilling fluid obtained in this work were investigated through rheology and filtration analysis, solids content, aging, lubricity, toxicity, and thermal degradation. A non-toxic microemulsion-based drilling fluid oil-in-water (O/W) with high lubricity (0.07638) and thermal stability was obtained with suitable viscosity, gel strength and low fluid loss (4.0 mL), low solids content (6%), stability in a wide range of salinity conditions, and the possibility of high water content (above 85% in mass fraction). The fluid presented a pseudoplastic behavior, and statistically significant Herschel–Bulkley parameters were obtained.

Plant Tannins and Essential Oils Have an Additive Deterrent Effect on Diet Choice by Kangaroos

Tannins and essential oils are well recognised as antiherbivore compounds. We investigated the relative effectiveness of the polyphenol, tannin, and the essential oils, 1,8-cineole and pine oil, as feeding deterrents against western grey kangaroos. Both groups of secondary metabolites are naturally abundant in many Australian plants. These three metabolite groups were incorporated separately or together into standard pellets for presentation to kangaroos, and their behaviour (sequence of food choice and feeding time) and amounts consumed were observed. The control (with no secondary metabolites) was much preferred. There was a sharp reduction in the ingestion of pellets containing tannins, 1,8-cineole or pine oil. Combinations of the metabolites resulted in almost no consumption. In association with tannin, pellets containing either 1,8-cineole or pine oil were as effective deterrents as both combined. There was a strong correlation between time spent feeding on the different diets and the amount of food consumed, although the rate of intake was markedly slower when secondary metabolites were present. Behavioural observations showed that the amount of food ingested is initially guided by the presence/absence of essential oils, apparently detected by smell, and later by the presence/absence of tannins, by taste. Both groups of secondary metabolites work in concert by stimulating different senses that minimise herbivory by marsupials, such as the western grey kangaroo, and help to explain their abundance in the Australian flora.

Effect of Floor Cleaner Combination of Alcohol Ethoxylate-Sodium Lauryl Ether Sulfate and Combination of Carbol-Pine Oil on Ascaris lumbricoides Eggs

Disinfectants are chemical agents used in disinfection in liquid form or solution form and are well-known as microbicidal, fungicidal, and virucidal but still unknown as parasiticidal, especially the effect to A. lumbricoides. In Indonesia, the prevalence of ascariasis is about 30,4% and still high. Ascariasis is caused by A. lumbricoides helminth that human swallows in egg form. Ascaris lumbricoides egg's characteristics are hydrophobic and sticky, making it easy to stick on the floor, household, and skin. This research aims to find the difference between the combination of the effects of Alcohol Ethoxylate-Sodium Lauryl Ether Sulfate and the combination of Carbol-Pine Oil to A. lumbricoides eggshell and larva development as prevention and to break the life cycle chain of A. lumbricoides. The research results showed no effects from Alcohol Ethoxylate- Sodium Lauryl Ether Sulfate combination and Carbol-Pine Oil combination to A. lumbricoides eggshell and embryo development. Keywords: Disinfectants, ascariasis, concentration, eggshell, larva development.

Testing of Pine Oil and Glycerol Ketal as Components of B10 Fuel Blend

The aim of the present work was to the preparation of biodiesel from sunflower oil and ethanol by the transesterification reaction in the presence of the KOH. The conversion was 88% at using a 1:3 molar ratio of oil to alcohol at 75°C. Important fuel physical properties of B10 blend with (or without) oxygenated additivities by the ASTM standards had been investigated. Based on the obtained results is noted that the fuel blend B10 with (or without) additivities has greater potentials for diesel engines than, B100 and fossil diesel.

Comparative Analyses of Glyphosate Alternative Weed Management Strategies on Plant Coverage, Soil and Soil Biota

Glyphosate-based foliar spray herbicides are the most common method for urban weed control due to their broad-spectrum and efficacy for burndown applications. As interest in glyphosate alternatives has increased in recent years, this project assessed the efficacy of the following non-glyphosate-based alternative weed management strategies: glufosinate, imazapyr, MCPA + dicamba, prodiamine, pine oil, clove oil, nonanoic acid, acetic acid + hydrochloric acid and steam against untreated (negative) controls and glyphosate-treated sites. Across all four seasonal treatments (winter, spring, summer and autumn), glyphosate and glufosinate reduced weed coverage (>65% after 4 and 12 weeks); imazapyr reduced weed coverage by >80% after 12 weeks; and steam reduced weed coverage by >80% after 4 weeks, and after 12 weeks showed to reduce weed coverage by >20% after the second application. The MCPA + dicamba, prodiamine, pine oil, clove oil, nonanoic acid and acetic acid + hydrochloric acid treatments had mixed impacts on weed coverage. Minimal alterations to soil physicochemical properties were observed across the two sites for all treatments. Assessment of impacts the different weed management strategies had on arthropod and microbial relative abundance showed minimal alterations; with only steam observed to reduce relative microbial abundance. Glufosinate, imazapyr and steam may be considered alternatives to glyphosate for reducing weed coverage but may not be as effective or have undesirable off-target effects. Overall, glyphosate provided the most consistent weed reduction at both sites over 12 weeks, without any recorded negative off-target or soil biota impacts.

Laboratory and Field Trials to Identify Sustainable Chemical Control Strategies for Trioza erytreae in European Citrus Orchards

Trioza erytreae (Del Guercio) is one of the psyllid insect vectors of the causal agents of huanglongbing. This paper proposes an assessment of the effectiveness of several pesticides with and without a pine oil-based organic adjuvant, in order to contain the spread and population of this pest and reduce the side effects on the Tamarixia dryi parasitoid. Five insecticides and their combinations with pine oil were sprayed against T. erytreae on citrus trees under semi-field and field conditions. The effect of the same treatments was assessed on T. dryi under laboratory conditions. All insecticides, except for acetamiprid, increased their effectiveness when combined with pine oil under both conditions. Cyantraniliprole, dimethoate, and their respective combinations with the organic adjuvant showed the highest efficacies against T. erytreae. Under laboratory conditions, dimethoate reported the most negative effect on T. dryi activity whereas cyantraniliprole and its combination with pine oil yielded a low toxicity effect on this parasitoid. Our results recommend the development of an integrated control approach for citrus growers based on an insecticide rotation program, preventing the emergence of pest resistance to one substance. In this sense, other insecticides, such as lambda-cyhalothrin with pine oil adjuvant or acetamiprid, could be considered.

Authenticity control of pine sylvestris essential oil by chiral gas chromatographic analysis of α-pinene

Numerous terpenes present in essential oils (EOs) display one or more chiral centers. Within the same genus the enantiomeric ratio of these compounds can be different. Thus, the determination of enantiomers is a valuable tool to evaluate authenticity and quality of EOs. In here, the terpene profile of primary and commercial pine EOs was analyzed by conventional and chiral gas chromatography coupled to a flame ionization detector. The enantiomeric excess of ( ±)-α-pinene was determined and significant differences between primary and commercially available EOs were observed. Primary EOs of Pinus sylvestris L. showed a positive enantiomeric excess of (+)-α-pinene whereas commercial EOs labeled as P. sylvestris L. exhibited an enantiomeric excess of (−)-α-pinene. Thus, chiral analysis provides useful information on the authenticity of pine EOs and allows to uncover possible mislabeling, the use of the wrong herbal substance and sources of adulteration in pine oil.

The Influences of NP100 Surfactant and Pine-Oil Concentrations on Filtrate Volume and Filter-Cake Thickness of Microemulsion-Based Drilling Fluids (O/W)

In this work, nonionic surfactant NP100 and pine oil influences on the filtrate volume (FV) and the filter-cake thickness (thkns) of microemulsified drilling fluids were studied. A ternary phase diagram was obtained to define the microemulsion region, where a 2k factorial design was used with the addition of four center points and axial points. Twelve microemulsion points were defined and used later in the formulation of the investigated drilling fluids. The results showed that the increase in the surfactant and pine oil’s concentration increased FV and thkns, withthe oil phase being the most influential component in the filtrate volume and the surfactant being the most influential in the filter-cake thickness. Statistically significant models were obtained. The optimal concentrations were determined for the lowest FV and thkns; 45% of surfactant and 5% of pine oil for the filtrate volume (1.3 mL), and 45% of surfactant and 15% of pine oil for the filter-cake thickness (0.64 mm).

Performance Characteristics of Pine Oil Mixed Diesel Fueled Single Cylinder Four Stroke Diesel Engine

In this study, biodiesel from the stem of Pinus roxburghii was prepared by steam distillation process. Consequently, the physical and thermal properties of pine biodiesel (P100), and 20 % pine-biodiesel and 80 % diesel (P20) were tested on American Society for Testing and Materials (ASTM) standards. The test results confirmed that the thermophysical properties of pine biodiesel and its blend were suitable for the fuel in diesel engine without any modification in the test engine. Eventually, the engine performance and combustion parameters were evaluated for pine-biodiesel blend for 5 % biodiesel and 95 % diesel (P5), 10 % biodiesel and 90 % diesel (P10), 15 % biodiesel and 85 % diesel (P15) and P20, and compared with diesel on Kirloskar Single Cylinder Compression Ignition Engine for a compression ratio of 15:1. In the midst of those in different blends evaluated, P15 showed the better brake specific fuel consumption (BSFC) i.e 18.75 % lower than diesel fuel particularly up to 50 % of the engine load. However, at higher load, decrease rate in BSFC of P15 fuel is lower than engine load up to 50 %. Similarly, brake thermal efficiency (BTE) of P15 increases to 13.5% mainly on 50 % loading condition of the engine. At above, increment rate of BTE of pine oil biodiesel compared to diesel decreases. The brake power (BP) and brake mean effective pressure (BMEP) of P15 also found nearer to diesel. However, the BP of P15 found higher compared to diesel in all loading conditions. Thus, from the experimental investigations, P15 blend of pine oil biodiesel was found to be amenable for its use in compression ignition (CI) engine without any modification, as the BTE and SFC were found to better and, BP, indicated power (IP) and BMEP were also found nearer to diesel fuel.

Evaluation of the Influence of 1,4-Dioxane and Exhaust Gas Recirculation on the Performance and Emission Values of a Diesel Engine Fuelled With Low Viscous Biofuel Blend

The world greatly relies on the usage of liquid fuels for its energy needs, especially in the transportation sector, which is very high in developing countries. In countries like India, diesel fuel is mainly used for all its transportation requirements (considering its higher efficiency), leading to higher pollution. Many kinds of research works are conducted to find a replacement for diesel fuel. In which biodiesel is considered to be a potential replacement for diesel. However, the challenges like higher viscosity, lower calorific value, higher NOx emission stands as a huge barrier. To overcome this, this study proposes using a low viscous biofuel, which has a higher calorific value close to diesel. To reduce NOx emission, the exhaust gas recirculation (EGR) technique is used in this study. A single-cylinder, constant speed, water-cooled stationary engine setup is used for this study. 20% of pine oil is blended with diesel, and 10ml of 1,4, dioxane additive is added. These blends are tested in the engine for different load conditions (0, 25, 50, 75 and 100%) with and without 10% EGR. The results showed that pine oil usage negatively affected the performance characters but significantly reduced CO, HC, and Smoke emissions (15.94, 17.04 and 2.47% respectively). The 10ml of 1,4, dioxane further enhanced this reduction (32.61, 28.15 and 4.36% respectively). The 10% EGR usage negatively affected both performance and emission characters, but it reduced NOx emissions significantly (11.53%). This study provides an integrated way to overcome the challenges seen in biodiesel usage with a low viscous biofuel and exhaust gas recirculation technique.