Thermal Transport Network Model for High-Porosity Materials: Application to Nanoporous Aerogels

Author(s):  
Brian R. Smith ◽  
Peter D. Beutler ◽  
Cristina H. Amon

Nanoporous thin films have received attention in the microelectronics field for their application as next-generation low-k inner-layer dielectric (ILD) materials due dielectric constants approaching 1.4. In addition, emerging applications as thermal insulation for microsystems aim to exploit the materials’ unique thermal properties in sensor and component products. However, its thermal properties can vary greatly depending on fabrication processes and material morphology. In addition, a variety of transport phenomena are present and delineation among them is difficult. In this work, we examine heat transport in aerogel, one of the most common embodiments of nanoporous materials, to identify the main modes of energy transport. We employ a modified diffusion-limited cluster aggregation (DLCA) technique to simulate aerogel’s highly porous, amorphous solid structure. Network models then simulate heat transport through the structure to extract effective thermal conductivity. The models are verified by comparing calculated bulk data to published aerogel literature. Preliminary models yield thermal conductivity on the order of 0.010 W/m*K, which is consistent with published data for aerogel films. These values vary inversely with porosity of the aerogel following an inverse power law often used to fit aerogel experimental data. This methodology is most useful for examining the sensitivity of thermal conductivity to salient structural features such as porosity, pore size distribution, solid thermal properties, average branch width, and sub-continuum phenomena. The results of this study can be used as a predictive tool in optimizing aerogel fabrication process to yield morphologies that best-suit the requirements of the application.

2014 ◽  
Vol 982 ◽  
pp. 100-103 ◽  
Author(s):  
Dana Koňáková ◽  
Monika Čáchová ◽  
Eva Vejmelková ◽  
Martin Keppert ◽  
Robert Černý

This article deals with thermal properties of selected kinds of timber. Wood, generally, is one of often used natural materials in building structures. For our research, woods were selected according to frequency of utilization in civil engineering branch. Four different timbers were chosen, and experimental determinations of their properties were performed. Basic physical properties as well as thermal properties belong among studied characteristics. From achieved results, it is obvious, that the bulk density of studied wood ranges between 373 kg m-3 and 649 kg m-3, the open porosity differ by 13%. Regarding thermal properties, values of the thermal conductivity as well as the specific heat capacity are influenced mainly by the open porosity and moisture content. The thermal conductivity in dry state varies by about 31% while in the case of the specific heat capacity the difference is about 19%. Obtained date will be used in the mathematical analysis of heat transport in building structures.


1997 ◽  
Vol 77 (4) ◽  
pp. 643-648 ◽  
Author(s):  
A. Laurén

Thermal conductivity was measured with thermal probes in undisturbed mor samples subjected to water desorption and sorption. The volumetric water content was determined simultaneously with time domain reflectometry. The thermal conductivity increased from 0.06 to 0.24 W m−1 K−1, when the water content increased from 0.10 to 0.40 m3 m−3. There was little spatial variation in the mor layer. The results were similar to those found in the literature for peat and humus materials. The thermal conductivity of the mor layer could be predicted with the de Vries model with good accuracy if the humus and air particles were assumed to be of lamellae shape and latent heat transport in air-filled pores was neglected. Key words: humus, thermal probe, thermal properties, time domain reflectometry


2014 ◽  
Vol 935 ◽  
pp. 172-175 ◽  
Author(s):  
Eravan Serri ◽  
M. Zailan Suleiman ◽  
M. Azree Othuman Mydin

Oil Palm Shell (OPS) are one of low thermal conductivity course aggregate for lightweight concrete. This paper report on all thermal properties parameter, thermal conductivity, specific heat and thermal diffusivity. Tree mixes of OPS of air dry density 1733 to 1811 kg/m3 and oven dry density 1502 to 1632 kg/m3 were prepaid and tested for thermal properties and compared with normal concrete using crushed granite as control and conventional materials. Raw shape with air density 1733 kg/m3 showed the lowest thermal properties with thermal conductivity, specific heat and thermal diffusivity of 0.59 W/mK, 1.352 MJ/m3K and 0.4414 mm2/s, respectively. All OPS mix can be consider as semi structure insulation material as per the RILEM classification which is thermal conductivity lower than 0.75 W/mK. High porosity content in concrete created act as an insulation characteristic and showed OPS have good potential as green insulation materials.


2019 ◽  
Vol 13 (3) ◽  
pp. 5513-5527
Author(s):  
J. W. Tee ◽  
S. H. Hamdan ◽  
W. W. F. Chong

Fundamental understanding of piston ring-pack lubrication is essential in reducing engine friction. This is because a substantial portion of engine frictional losses come from piston-ring assembly. Hence, this study investigates the tribological impact of different piston ring profiles towards engine in-cylinder friction. Mathematical models are derived from Reynolds equation by using Reynolds’ boundary conditions to generate the contact pressure distribution along the complete piston ring-pack/liner conjunction. The predicted minimum film thickness is then used to predict the friction generated between the piston ring-pack and the engine cylinder liner. The engine in-cylinder friction is predicted using Greenwood and Williamson’s rough surface contact model. The model considers both the boundary friction and the viscous friction components. These mathematical models are integrated to simulate the total engine in-cylinder friction originating from the studied piston ring-pack for a complete engine cycle. The predicted minimum film thickness and frictional properties from the current models are shown to correlate reasonably with the published data. Hence, the proposed mathematical approach prepares a simplistic platform in predicting frictional losses of piston ring-pack/liner conjunction, allowing for an improved fundamental understanding of the parasitic losses in an internal combustion engine.


Author(s):  
Messiha Saad ◽  
Darryl Baker ◽  
Rhys Reaves

Thermal properties of materials such as specific heat, thermal diffusivity, and thermal conductivity are very important in the engineering design process and analysis of aerospace vehicles as well as space systems. These properties are also important in power generation, transportation, and energy storage devices including fuel cells and solar cells. Thermal conductivity plays a critical role in the performance of materials in high temperature applications. Thermal conductivity is the property that determines the working temperature levels of the material, and it is an important parameter in problems involving heat transfer and thermal structures. The objective of this research is to develop thermal properties data base for carbon-carbon and graphitized carbon-carbon composite materials. The carbon-carbon composites tested were produced by the Resin Transfer Molding (RTM) process using T300 2-D carbon fabric and Primaset PT-30 cyanate ester. The graphitized carbon-carbon composite was heat treated to 2500°C. The flash method was used to measure the thermal diffusivity of the materials; this method is based on America Society for Testing and Materials, ASTM E1461 standard. In addition, the differential scanning calorimeter was used in accordance with the ASTM E1269 standard to determine the specific heat. The thermal conductivity was determined using the measured values of their thermal diffusivity, specific heat, and the density of the materials.


Materials ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3241
Author(s):  
Krzysztof Powała ◽  
Andrzej Obraniak ◽  
Dariusz Heim

The implemented new legal regulations regarding thermal comfort, the energy performance of residential buildings, and proecological requirements require the design of new building materials, the use of which will improve the thermal efficiency of newly built and renovated buildings. Therefore, many companies producing building materials strive to improve the properties of their products by reducing the weight of the materials, increasing their mechanical properties, and improving their insulating properties. Currently, there are solutions in phase-change materials (PCM) production technology, such as microencapsulation, but its application on a large scale is extremely costly. This paper presents a solution to the abovementioned problem through the creation and testing of a composite, i.e., a new mixture of gypsum, paraffin, and polymer, which can be used in the production of plasterboard. The presented solution uses a material (PCM) which improves the thermal properties of the composite by taking advantage of the phase-change phenomenon. The study analyzes the influence of polymer content in the total mass of a composite in relation to its thermal conductivity, volumetric heat capacity, and diffusivity. Based on the results contained in this article, the best solution appears to be a mixture with 0.1% polymer content. It is definitely visible in the tests which use drying, hardening time, and paraffin absorption. It differs slightly from the best result in the thermal conductivity test, while it is comparable in terms of volumetric heat capacity and differs slightly from the best result in the thermal diffusivity test.


Energies ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 4158
Author(s):  
Haiyan Yu ◽  
Haochun Zhang ◽  
Heming Wang ◽  
Dong Zhang

Currently, there are few studies on the influence of microscale thermal radiation on the equivalent thermal conductivity of microscale porous metal. Therefore, this paper calculated the equivalent thermal conductivity of high-porosity periodic cubic silver frame structures with cell size from 100 nm to 100 µm by using the microscale radiation method. Then, the media radiation characteristics, absorptivity, reflectivity and transmissivity were discussed to explain the phenomenon of the radiative thermal conductivity changes. Furthermore, combined with spectral radiation properties at the different cross-sections and wavelength, the radiative transmission mechanism inside high-porosity periodic cubic frame silver structures was obtained. The results showed that the smaller the cell size, the greater radiative contribution in total equivalent thermal conductivity. Periodic cubic silver frames fluctuate more in the visible band and have better thermal radiation modulation properties in the near infrared band, which is formed by the Surface Plasmon Polariton and Magnetic Polaritons resonance jointly. This work provides design guidance for the application of this kind of periodic microporous metal in the field of thermal utilization and management.


Energies ◽  
2020 ◽  
Vol 13 (11) ◽  
pp. 2918
Author(s):  
Liang Zhang ◽  
Songhe Geng ◽  
Jun Kang ◽  
Jiahao Chao ◽  
Linchao Yang ◽  
...  

Self-circulation wellbore is a new technique for geothermal development in hot dry rocks (HDR), which uses a U-shape channel composed of tubing and casing as the heat exchanger. In this study, a self-circulation wellbore in HDR on a laboratory scale was built, and a serial of experiments were conducted to investigate the heat exchange law and the influencing factors on the heat mining rate of the wellbore. A similarity analysis was also made to estimate the heat-mining capacity of the wellbore on a field scale. The experimental results show that the large thermal conductivity and heat capacity of granite with high temperature can contribute to a large heat-mining rate. A high injection rate can cause a high convective heat transfer coefficient in wellbore, while a balance is needed between the heat mining rate and the outlet temperature. An inner tubing with low thermal conductivity can significantly reduce the heat loss to the casing annulus. The similarity analysis indicates that a heat mining rate of 1.25 MW can be reached when using a 2000 m long horizontal well section in a 150 °C HDR reservoir with a circulation rate of 602.8 m3/day. This result is well corresponding to the published data.


1998 ◽  
Vol 120 (4) ◽  
pp. 1064-1071 ◽  
Author(s):  
J. M. Ha ◽  
G. P. Peterson

The original analytical model for predicting the maximum heat transport capacity in micro heat pipes, as developed by Cotter, has been re-evaluated in light of the currently available experimental data. As is the case for most models, the original model assumed a fixed evaporator region and while it yields trends that are consistent with the experimental results, it significantly overpredicts the maximum heat transport capacity. In an effort to provide a more accurate predictive tool, a semi-empirical correlation has been developed. This modified model incorporates the effects of the temporal intrusion of the evaporating region into the adiabatic section of the heat pipe, which occurs as the heat pipe approaches dryout conditions. In so doing, the current model provides a more realistic picture of the actual physical situation. In addition to incorporating these effects, Cotter’s original expression for the liquid flow shape factor has been modified. These modifications are then incorporated into the original model and the results compared with the available experimental data. The results of this comparison indicate that the new semiempirical model significantly improves the correlation between the experimental and predicted results and more accurately represents the actual physical behavior of these devices.


2014 ◽  
Vol 722 ◽  
pp. 25-29 ◽  
Author(s):  
Q.L. Che ◽  
X.K. Chen ◽  
Y.Q. Ji ◽  
Y.W. Li ◽  
L.X. Wang ◽  
...  

The carbide forming is proposed to improve interfacial bonding between diamond particles and copper-matrix for diamond/copper composites. The volume fraction of diamond and minor titanium are optimized. The microstructures, thermal properties, interface reaction production and its effect of minor titanium on the properties of the composites are investigated. The results show that the bonding force and thermal conductivity of the diamond/Cu-Ti alloys composites is much weaker and lower than that of the coated-diamond/Cu. the thermal conductivity of coated-60 vol. % diamond/Cu composites is 618 W/m K which is 80 % of the theoretical prediction value. The high thermal conductivity has been achieved by forming the titanium carbide at diamond/copper interface to gain a good interface.


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