scholarly journals Model of deformation growth dynamics during filled polymer materials mechanical tests under cable production conditions

Author(s):  
Vladimir Zolotarev ◽  
Oksana Golik ◽  
Eugene Moskvitin ◽  
Mykola Zykоv ◽  
Alina Shurupova ◽  
...  

With the introduction into highly filled halogen-free plastics production, the mechanical strength of which in operation directly depends on the flame retardant content and application technology, it becomes important to control the cable sheath mechanical characteristics in a fireproof design. Polymeric materials and their compositions are viscoelastic materials for which the mechanical properties depend on the stress time. The results of estimating the deformation samples rate elongation from the uniaxial stretching time at different dilution rates of the clamps in the mechanical characteristics determining process for halogen-free cable plastics in regulatory tests under production conditions are presented. It is shown that the inner and outer layers of the halogen-free plastic cable sheath have significantly different values of the plasticity normative parameter: differences evidence in the polymer structure in the inner and outer layers of the sheath due to the forced deformation process during extrusion, which is forced polymer structure orientation. Elongation relative deformation experimental dependences δL(t) of the samples on the uniaxial stretching time at different clamps dilution speeds are given, which illustrate confirmed by a large data array the dependencies shape reproducibility δL(t) for different in structure similar filled halogen-free polymers. The strain rate dependence model on tensile time as the sum of instantaneous-elastic, viscoelastic and instantaneous-plastic (irreversible) is proposed: dε/dt = λпр exp ( – t/λпр) + {∫ λ1 exp(–τ/λ1).exp[–(t–τ)/λ2]dτ]}/Δt. The appropriate parameter estimates of the named samples deformation components obtained by approximating the experimental data by the proposed model are given. The proposed model, firstly, explains the presence characteristic relative deformation maximum (t = tm) as a two interdependent deformation processes superposition with different aftermath λ. Secondly, it allows to specify the requirements for testing: with increasing the clamps dilution speed, the maximum time tm decreases significantly, respectively, the higher the clamps dilution speed, the smaller interval time Δt between a successive sample control section length measurements. This conclusion was experimentally confirmed for a specific material at a speed of 250 mm/min

2020 ◽  
Vol 67 (2) ◽  
pp. 115-120
Author(s):  
Raisa A. Alekhina ◽  
Victoriya E. Slavkina ◽  
Yuliya A. Lopatina

The article presents options for recycling polymers. The use of biodegradable materials is promising. This is a special class of polymers that can decompose under aerobic or anaerobic conditions under the action of microorganisms or enzymes forming natural products such as carbon dioxide, nitrogen, water, biomass, and inorganic salts. (Research purpose) The research purpose is in reviewing biodegradable materials that can be used for the manufacture of products used in agriculture. (Materials and methods) The study are based on open information sources containing information about biodegradable materials. Research methods are collecting, studying and comparative analysis of information. (Results and discussion) The article presents the advantages and disadvantages of biodegradable materials, mechanical properties of the main groups of biodegradable polymers. The article provides a summary list of agricultural products that can be made from biodegradable polymer materials. It was found that products from the general group are widely used in agriculture. Authors have found that products from a special group can only be made from biodegradable polymers with a controlled decomposition period in the soil, their use contributes to increasing the productivity of crops. (Conclusions) It was found that biodegradable polymer materials, along with environmental safety, have mechanical properties that allow them producing products that do not carry significant loads during operation. We have shown that the creation of responsible products (machine parts) from biodegradable polymers requires an increase in their strength properties, which is achievable by creating composites based on them. It was found that the technological complexity of their manufacture and high cost are the limiting factors for the widespread use of biodegradable polymers at this stage.


2001 ◽  
Vol 79 (7) ◽  
pp. 1093-1100 ◽  
Author(s):  
Almeria Natansohn ◽  
Paul Rochon

The well-known trans–cis–trans photoisomerization of azobenzenes produces at least three different kinds of motion in the polymer materials to which the azobenzenes are bound. The first is a photoinduced motion of the azobenzene groups only, and they can align in a selected position with respect to the light polarization. The second is a macroscopic motion of huge amounts of polymeric material, producing surface deformation, and the third is a reorganization of smectic domains in liquid crystalline polymers. These motions and their consequences are briefly discussed in relation to the polymer structure and some possible photonic applications are mentioned.Key words: photoinduced orientation, azobenzene polymers, surface gratings, photonics, thermochromism, photochromism, photorefractivity, photoinduced chirality and switching.


2021 ◽  
Vol 7 (1) ◽  
pp. 9
Author(s):  
Cansu Esen ◽  
Baris Kumru

As a metal-free polymeric semiconductor with an absorption in the visible range, carbon nitride has numerous advantages for photo-based applications spanning hydrogen evolution, CO2 reduction, ion transport, organic synthesis and organic dye degradation. The combination of g-C3N4 and polymer networks grants mutual benefit for both platforms, as networks are upgraded with photoactivity or formed by photoinitiation, and g-C3N4 is integrated into novel applications. In the present contribution, some of the recently published projects regarding g-C3N4 and polymeric materials will be highlighted. In the first study, organodispersible g-C3N4 were incorporated into a highly commercialized porous resin called poly(styrene-co-divinylbenzene) through suspension photopolymerization, and performances of resulting beads were investigated as recyclable photocatalysts. In the other study, g-C3N4 nanosheets were embedded in porous hydrogel networks, and so-formed hydrogels with photoactivity were transformed either into a ‘hydrophobic hydrogel’ or pore-patched materials via secondary network introduction, where both processes were accomplished via visible light. Since g-C3N4 is an organic semiconductor exhibiting sufficient charge separation under visible light illumination, a novel method for the oxidative photopolymerization of EDOT was successfully accomplished. As a result of the absence of dissolved anions during polymerization, so-formed neutral PEDOT is a highly viscous liquid that can be processed and post-doped easily, and grants facile coating processes.


2018 ◽  
Vol 55 (4) ◽  
pp. 524-530
Author(s):  
Marinela Marinescu ◽  
Larisa Butu ◽  
Claudia Borda ◽  
Delicia Arsene ◽  
Mihai Butu

This study presents research regarding the calculation of the mechanical characteristics of composite polymeric materials. By using LabVIEW� software a virtual instrument was created used for monitoring in real time the process of cross-linking the composite polymeric materials. The experiments were realized based on composite materials containing epoxy/fiberglass resin of different topologies. By means of the virtual instrument and of a sensor created based on the mechanical impedance analysis, implanted in the composite material, it was determined the G shearing module of the composite material at different temperatures.


Metaphysics ◽  
2020 ◽  
pp. 89-101
Author(s):  
V. F Panov ◽  
A. E Boyarshinov ◽  
A. V Klyuev ◽  
S. A Kurapov

The paper presents the latest results of the effect of SVM generators on melts of metals and polymeric materials, as well as the effect on metals during heat treatment. Shown is a block diagram of an installation for SVM material processing. Made an attempt to theoretically substantiate the use of SVM generators in metallurgy based on relational physics, quantum theory, and real relativity.


2021 ◽  
Vol 7 (1) ◽  
pp. 31-40
Author(s):  
T. Radzievskaya ◽  
N. Ivanov ◽  
S. Tarasov

The article presents the development prospects of planar optical waveguides for high-speed data transmission systems optoelectronic buses by polymer materials. The advantages and disadvantages of using non-specialized polymeric materials for general use are revealed. The polymer planar optical waveguides fabrication technologies are proposed. The main losses types in planar optical waveguides, the reasons for their occurrence, as well as approaches to their reduction are determined. Using the example of PDMS polymer and soft lithography technology, the technological process critical stages of polymer planar optical waveguides production are noted, which contribute to an scattering losses increase. For each stage, algorithms are proposed to prevent an scattering losses increase. These algorithms were implemented in practice in the manufacture of layouts of polymer planar optical waveguides of the optical-electronic data transmission bus.


Author(s):  
Lacramioara Balan ◽  
Rajesh Paleti

Traditional crash databases that record police-reported injury severity data are prone to misclassification errors. Ignoring these errors in discrete ordered response models used for analyzing injury severity can lead to biased and inconsistent parameter estimates. In this study, a mixed generalized ordered response (MGOR) model that quantifies misclassification rates in the injury severity variable and adjusts the bias in parameter estimates associated with misclassification was developed. The proposed model does this by considering the observed injury severity outcome as a realization from a discrete random variable that depends on true latent injury severity that is unobservable to the analyst. The model was used to analyze misclassification rates in police-reported injury severity in the 2014 General Estimates System (GES) data. The model found that only 68.23% and 62.75% of possible and non-incapacitating injuries were correctly recorded in the GES data. Moreover, comparative analysis with the MGOR model that ignores misclassification not only has lower data fit but also considerable bias in both the parameter and elasticity estimates. The model developed in this study can be used to analyze misclassification errors in ordinal response variables in other empirical contexts.


2019 ◽  
Author(s):  
Leili Tapak ◽  
Omid Hamidi ◽  
Majid Sadeghifar ◽  
Hassan Doosti ◽  
Ghobad Moradi

Abstract Objectives Zero-inflated proportion or rate data nested in clusters due to the sampling structure can be found in many disciplines. Sometimes, the rate response may not be observed for some study units because of some limitations (false negative) like failure in recording data and the zeros are observed instead of the actual value of the rate/proportions (low incidence). In this study, we proposed a multilevel zero-inflated censored Beta regression model that can address zero-inflation rate data with low incidence.Methods We assumed that the random effects are independent and normally distributed. The performance of the proposed approach was evaluated by application on a three level real data set and a simulation study. We applied the proposed model to analyze brucellosis diagnosis rate data and investigate the effects of climatic and geographical position. For comparison, we also applied the standard zero-inflated censored Beta regression model that does not account for correlation.Results Results showed the proposed model performed better than zero-inflated censored Beta based on AIC criterion. Height (p-value <0.0001), temperature (p-value <0.0001) and precipitation (p-value = 0.0006) significantly affected brucellosis rates. While, precipitation in ZICBETA model was not statistically significant (p-value =0.385). Simulation study also showed that the estimations obtained by maximum likelihood approach had reasonable in terms of mean square error.Conclusions The results showed that the proposed method can capture the correlations in the real data set and yields accurate parameter estimates.


Polymers ◽  
2020 ◽  
Vol 12 (5) ◽  
pp. 1142 ◽  
Author(s):  
Phuong Nguyen-Tri ◽  
Payman Ghassemi ◽  
Pascal Carriere ◽  
Sonil Nanda ◽  
Aymen Amine Assadi ◽  
...  

Atomic force microscopy (AFM) has been extensively used for the nanoscale characterization of polymeric materials. The coupling of AFM with infrared spectroscope (AFM-IR) provides another advantage to the chemical analyses and thus helps to shed light upon the study of polymers. This paper reviews some recent progress in the application of AFM and AFM-IR in polymer science. We describe the principle of AFM-IR and the recent improvements to enhance its resolution. We also discuss the latest progress in the use of AFM-IR as a super-resolution correlated scanned-probe infrared spectroscopy for the chemical characterization of polymer materials dealing with polymer composites, polymer blends, multilayers, and biopolymers. To highlight the advantages of AFM-IR, we report several results in studying the crystallization of both miscible and immiscible blends as well as polymer aging. Finally, we demonstrate how this novel technique can be used to determine phase separation, spherulitic structure, and crystallization mechanisms at nanoscales, which has never been achieved before. The review also discusses future trends in the use of AFM-IR in polymer materials, especially in polymer thin film investigation.


2019 ◽  
Vol 10 (16) ◽  
pp. 1993-1997 ◽  
Author(s):  
Sanjib Banerjee ◽  
Bhausaheb V. Tawade ◽  
Bruno Améduri

Effective use of Diels–Alder chemistry led to the development of thermally amendable and self-healing polymeric materials based on a copolymer of cyclopenta-1,3-dien-1-ylmethyl 2-(trifluoromethyl)acrylate (MAF-Furan) and 2,2,2-trifluoroethyl α-fluoroacrylate (FATRIFE).


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