GEOPOLYMER CONCRETE AT AMBIENT AND ELEVATED TEMPERATURES: RECENT DEVELOPMENTS AND CHALLENGES

2019 ◽  
Vol 2 (Special Issue on First SACEE'19) ◽  
pp. 113-128 ◽  
Author(s):  
Zhong Tao ◽  
Zhu Pan

Geopolymer concrete (GPC) is attracting increasing attention due to its potential to replace ordinary Portland cement (OPC) concrete to reduce the carbon dioxide emissions from cement production. Although extensive research has been conducted in this area since the 1970s, its applications in engineering practice are still very limited. This paper briefly reviews the recent developments of GPC and its properties at ambient and elevated temperatures. It was found that GPC generally exhibits comparative properties to OPC concrete at ambient temperature. In contrast, GPC often has better fire performance and superior durability. Therefore, GPC could be advantageously used to improve the fire performance and durability of buildings and infrastructure. While a lot of aluminosilicate raw materials (such as fly ash) are low cost, the prohibitive costs of laboratory grade activators (such as sodium hydroxide and sodium silicate) greatly limit the widespread application of GPC. Therefore, there is a need to develop low-cost geopolymer concrete. Meanwhile, a few other challenges should also be overcome, such as difficulties to achieve consistent properties and to control efflorescence of GPC. Further research is required at both material and structural levels to address these issues. Particularly, there is a need to develop relevant building codes to promote the use of GPC in practice.

Membranes ◽  
2019 ◽  
Vol 9 (9) ◽  
pp. 105 ◽  
Author(s):  
Amanmyrat Abdullayev ◽  
Maged Bekheet ◽  
Dorian Hanaor ◽  
Aleksander Gurlo

In water treatment applications, the use of ceramic membranes is associated with numerous advantages relative to polymer-based filtration systems. High-temperature stability, fouling resistance, and low maintenance requirements contribute to lower lifecycle costs in such systems. However, the high production costs of most commercially available ceramic membranes, stemming from raw materials and processing, are uneconomical for such systems in most water treatment applications. For this reason, there is a growing demand for new ceramic membranes based on low-cost raw materials and processes. The use of unrefined mineral feedstocks, clays, cement, sands, and ash as the basis for the fabrication of ceramic membranes offers a promising pathway towards the obtainment of effective filtration systems that can be economically implemented in large volumes. The design of effective ceramic filtration membranes based on low-cost raw materials and energy-efficient processes requires a balance of pore structure, mass flow, and robustness, all of which are highly dependent on the composition of materials used, the inclusion of various pore-forming and binding additives, and the thermal treatments to which membranes are subjected. In this review, we present recent developments in materials and processes for the fabrication of low-cost membranes from unrefined raw materials, including clays, zeolites, apatite, waste products, including fly ash and rice husk ash, and cement. We examine multiple aspects of materials design and address the challenges relating to their further development.


Author(s):  
Rena E. Mustafaeva

The work is devoted to the search for new effective modifying additives that allow to purposefully regulate the technological properties of rubber compounds and physical-mechanical properties of rubbers based on combinations of non-polar rubbers and at the same time being cheaper and more affordable than traditional products, in particular, with resorcinol-urotropin complex (modifier RU -1). It was proposed to use as a modifier of frame rubbers based on a combination of isoprene (SKI-3) and butadiene-styrene (SCS-30ARKM-15) rubbers, chlorinated atactic polypropylene (CHAPP). It is shown that when the RU-1 modifier is replaced with this compound, the conditional stresses and tensile strength, tearing resistance, rebound elasticity, fatigue resistance in the regime of constant deformation amplitude, heat resistance, resistance to thermal aging of rubbers, as well as the strength of rubber bonding with rubber Textile cord, including at elevated temperatures are observed. Comparison of the CHAPP for the effectiveness of the action in the carcass gum with the previously proposed oligoefirmetacrylate epichlorhydrine, from the point of view of the provided complex of properties, showed the advantage of chlorinated atactic polypropylene for a number of priority indicators. From the comparative analysis of the modifying activity of chlorinated atactic polypropylene and oligoether methacrylate epichlorohydrin, it follows that the vulcanizates of rubber compounds containing instead of RU-1 chlorinated atactic polypropylene CHAPP are characterized by more improved parameters of hardness in TM-2, elasticity by rebound, the strength of the rubber-cord connection. It is also revealed that the main advantage of the proposed modifier is the low cost of the modifier used, as well as the use of secondary raw materials for its production.Forcitation:Mustafayeva R.E. Technological aspects of production and research of polymers composite materials with increased strength. Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol. 2017. V. 60. N 10. P. 82-86


Author(s):  
Ourania Tsioulou ◽  
Andreas Lampropoulos ◽  
Kyriacos Neocleous ◽  
Nicholas Kyriakides ◽  
Thomaida Polydorou

<p>Concrete is one of the most commonly used construction materials. However, the main drawbacks in the use of concrete are related to the use of cement and subsequently the high percentage of carbon dioxide emissions. The use of cement substitutes is an area where there is a lot of ongoing research. Geopolymer concrete is a concrete in which cement is replaced by waste materials such as Pulverised Fuel Ash (PFA), or Ground Granulated Blast furnace Slag (GGBS). To activate the geopolymerisation, an alkali activator is used. The procedure, which is used for the production of a geopolymer concrete, is normally a two-part procedure: Preparation of the alkali activator one day before the mixing and mixing of the aluminosilicate sources (PFA, GGBS) with the activator. To make the production of geopolymers more user friendly it needs to be converted to one part procedure where water will be added in a readymade mix. In the published literature, there is research on one- part geopolymers, but there are limited studies on the use of demolition waste materials as substitution of PFA and GGBS in this type of materials. With the current study, different sources of raw materials focusing on demolition waste materials such as red bricks and reclaimed concrete, which are commonly used in construction worldwide, will be examined for the production of one- part geopolymer. The major aim of this research proposal is to develop an innovative sustainable one-part cement free geopolymer concrete. The new concrete is a “green” concrete where cement is replaced by waste materials. Construction demolition materials such as red bricks can be used as raw materials in the geopolymer matrix. This project will focus on the selection, characterisation and development of the appropriate processing of these red bricks so as they can be used as raw materials in the geopolymer matrix. Also, the development of one part mix where the new concrete will be ready for use by adding only water in it, is another aim of the proposed project.</p>


2019 ◽  
Vol 11 (2) ◽  
pp. 537 ◽  
Author(s):  
Ali Naqi ◽  
Jeong Jang

The cement industry is facing numerous challenges in the 21st century due to depleting natural fuel resources, shortage of raw materials, exponentially increasing cement demand and climate linked environmental concerns. Every tonne of ordinary Portland cement (OPC) produced releases an equivalent amount of carbon dioxide to the atmosphere. In this regard, cement manufactured from locally available minerals and industrial wastes that can be blended with OPC as substitute, or full replacement with novel clinkers to reduce the energy requirements is strongly desirable. Reduction in energy consumption and carbon emissions during cement manufacturing can be achieved by introducing alternative cements. The potential of alternative cements as a replacement of conventional OPC can only be fully realized through detailed investigation of binder properties with modern technologies. Seven prominent alternative cement types are considered in this study and their current position compared to OPC has been discussed. The study provides a comprehensive analysis of options for future cements, and an up-to-date summary of the different alternative fuels and binders that can be used in cement production to mitigate carbon dioxide emissions. In addition, the practicalities and benefits of producing the low-cost materials to meet the increasing cement demand are discussed.


Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1345
Author(s):  
Md. Saifur Rahman ◽  
Md. Saif Hasan ◽  
Ashis Sutradhar Nitai ◽  
Sunghyun Nam ◽  
Aneek Krishna Karmakar ◽  
...  

Carboxymethyl cellulose (CMC) is one of the most promising cellulose derivatives. Due to its characteristic surface properties, mechanical strength, tunable hydrophilicity, viscous properties, availability and abundance of raw materials, low-cost synthesis process, and likewise many contrasting aspects, it is now widely used in various advanced application fields, for example, food, paper, textile, and pharmaceutical industries, biomedical engineering, wastewater treatment, energy production, and storage energy production, and storage and so on. Many research articles have been reported on CMC, depending on their sources and application fields. Thus, a comprehensive and well-organized review is in great demand that can provide an up-to-date and in-depth review on CMC. Herein, this review aims to provide compact information of the synthesis to the advanced applications of this material in various fields. Finally, this article covers the insights of future CMC research that could guide researchers working in this prominent field.


2016 ◽  
Vol 10 (4s) ◽  
pp. 571-580 ◽  
Author(s):  
Paulina Kosmela ◽  
◽  
Lukasz Zedler ◽  
Krzysztof Formela ◽  
Jozef Haponiuk ◽  
...  

Diversity of the polyurethane (PU) foams applications cause that investigation of the relationships between their structure and properties is currently very popular topic among the many research institutions and companies. At the turn of the last years many scientific papers about PU foams and their composites were published. The one of the main trends in research in this field is related to the reduction of production costs of PU foams. This aim can be successfully achieved through the incorporation of raw materials of natural origin or the utilization of waste materials. This work reviews the progress and recent developments in area of PU foams containing low-cost and pro-ecological modifiers, such as crude glycerol, liquefied biomass, ground tire rubber, etc.


2020 ◽  
Vol 4 (1) ◽  
pp. 41-48
Author(s):  
Teodoro Astorga Amatosa ◽  
Michael E. Loretero

Bamboo is a lightweight and high-strength raw materials that encouraged researchers to investigate and explore, especially in the field of biocomposite and declared as one of the green-technology on the environment as fully accountable as eco-products. This research was to assess the technical feasibility of making single-layer experimental Medium-Density Particleboard panels from the bamboo waste of a three-year-old (Dendrocalamus asper). Waste materials were performed to produce composite materials using epoxy resin (C21H25C105) from a natural treatment by soaking with an average of pH 7.6 level of sea-water. Three different types of MDP produced, i.e., bamboo waste strip MDP (SMDP), bamboo waste chips MDP (CMDP) and bamboo waste mixed strip-chips MDP (MMDP) by following the same process. The experimental panels tested for their physical-mechanical properties according to the procedures defined by ASTM D1037-12. Conclusively, even the present study shows properties of MDP with higher and comparable to other composite materials; further research must be given better attention as potential substitute to be used as hardwood materials, especially in the production, design, and construction usage.


2019 ◽  
Author(s):  
Yu Wang ◽  
Nachuan Yang ◽  
Yi Shuai ◽  
Yunpeng Zhang ◽  
Kanghua Chen

Polymers ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 2237 ◽  
Author(s):  
P. R. Sarika ◽  
Paul Nancarrow ◽  
Abdulrahman Khansaheb ◽  
Taleb Ibrahim

Phenol–formaldehyde (PF) resin continues to dominate the resin industry more than 100 years after its first synthesis. Its versatile properties such as thermal stability, chemical resistance, fire resistance, and dimensional stability make it a suitable material for a wide range of applications. PF resins have been used in the wood industry as adhesives, in paints and coatings, and in the aerospace, construction, and building industries as composites and foams. Currently, petroleum is the key source of raw materials used in manufacturing PF resin. However, increasing environmental pollution and fossil fuel depletion have driven industries to seek sustainable alternatives to petroleum based raw materials. Over the past decade, researchers have replaced phenol and formaldehyde with sustainable materials such as lignin, tannin, cardanol, hydroxymethylfurfural, and glyoxal to produce bio-based PF resin. Several synthesis modifications are currently under investigation towards improving the properties of bio-based phenolic resin. This review discusses recent developments in the synthesis of PF resins, particularly those created from sustainable raw material substitutes, and modifications applied to the synthetic route in order to improve the mechanical properties.


2020 ◽  
Vol 18 (1) ◽  
pp. 1148-1166
Author(s):  
Ganjar Fadillah ◽  
Septian Perwira Yudha ◽  
Suresh Sagadevan ◽  
Is Fatimah ◽  
Oki Muraza

AbstractPhysical and chemical methods have been developed for water and wastewater treatments. Adsorption is an attractive method due to its simplicity and low cost, and it has been widely employed in industrial treatment. In advanced schemes, chemical oxidation and photocatalytic oxidation have been recognized as effective methods for wastewater-containing organic compounds. The use of magnetic iron oxide in these methods has received much attention. Magnetic iron oxide nanocomposite adsorbents have been recognized as favorable materials due to their stability, high adsorption capacities, and recoverability, compared to conventional sorbents. Magnetic iron oxide nanocomposites have also been reported to be effective in photocatalytic and chemical oxidation processes. The current review has presented recent developments in techniques using magnetic iron oxide nanocomposites for water treatment applications. The review highlights the synthesis method and compares modifications for adsorbent, photocatalytic oxidation, and chemical oxidation processes. Future prospects for the use of nanocomposites have been presented.


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