scholarly journals The influence of technological additives and peroxides on the properties of rubber mixtures based on ethylene propylene caoutchouc

2019 ◽  
Vol 60 (10) ◽  
pp. 81-87
Author(s):  
Nikolay F. Ushmarin ◽  
◽  
Lyudmila Yu. Tsareva ◽  
Ksenia A. Konnova ◽  
Maria V. Yakimova ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Tensile Elongation ◽  
Physical And Mechanical Properties ◽  
Physicomechanical Properties ◽  
Dicumyl Peroxide ◽  
Rubber Mixture ◽  
Elongation At Break ◽  
Ethylene Propylene ◽  
Aging In Air

The article investigates the influence of technological additives and peroxides on the properties of two rubber mixtures based on ethylene-propylene caoutchouc of marking SKEPT-40. The main properties were: rheometric (maximum and minimum torques; start, optimum and maximum vulcanization rates; maximum vulcanization rates), physical and mechanical (conditional tensile strength, elongation at break, hardness) and operational (changes in conditional strength at tensile, elongation at break and hardness after aging in air). The resistance of rubbers to the action of high temperatures by methods of differential thermal and thermogravimetric analysis was studied. As technological additives, MA-L22, Struktol WS180, Zincolet BB 222 and Struktol A89 were used. Vulcanizing agents were peroxides: Novoperox BP-40, Percodox BC-FF, Dicumyl Peroxide (DK), Chemanox PX1 and Dicumyl Peroxide DCP 99. The studies were carried out for two rubbers, one of which is intended for the manufacture of molded products, and the second rubber – for sealing profiles. It was shown that the technological additive Zincolet BB 222 increases the vulcanization rate of rubber mixture for molded products. All technological additives used have practically no effect on the conditional tensile strength and hardness vulcanizates of molded products, increasing their elongation at break. The smallest changes in the physical and mechanical properties are characterized by the vulcanizate, which contains the technological additive Zincolet BB 222. Technological additives practically do not affect the process of vulcanization of the rubber mixture and slightly affect the process of destruction of rubber during aging. Of the investigated technological additives Zincolet BB 222 is more conducive to improving the thermal properties of rubber. It has been established that Novoperox BP-40 and Chemanox PX1 peroxides increase the rate of vulcanization of the rubber mixture for sealing profiles. For vulcanizates of this rubber mixture, when Novoperox BP-40 and Chemanox PX1 is replaced with other peroxides, a decrease in the conditional tensile strength, hardness and an increase in the elongation at break are observed. With aging in air, changes in the physicomechanical properties of the vulcanizates of the rubber mixture variants containing Novoperox BP-40 and Chemanox PX1 are insignificant and close to each other.

Effect of Castor Oil Impregnation on the Physical and Mechanical Properties of Bacterial Cellulose

2012 ◽  
Vol 3 (1) ◽  
pp. 13-26
Author(s):  
Myrtha Karina ◽  
Lucia Indrarti ◽  
Rike Yudianti ◽  
Indriyati
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Bacterial Cellulose ◽  
Young’S Modulus ◽  
Castor Oil ◽  
Young's Modulus ◽  
Physical And Mechanical Properties ◽  
Scanning Electron Micrographs ◽  
Elongation At Break ◽  
Acetone Water

The effect of castor oil on the physical and mechanical properties of bacterial cellulose is described. Bacterial cellulose (BC) was impregnated with 0.5–2% (w/v) castor oil (CO) in acetone–water, providing BCCO films. Scanning electron micrographs revealed that the castor oil penetrated the pores of the bacterial cellulose, resulting in a smoother morphology and enhanced hydrophilicity. Castor oil caused a slight change in crystallinity indices and resulted in reduced tensile strength and Young's modulus but increased elongation at break. A significant reduction in tensile strength and Young's modulus was achieved in BCCO films with 2% castor oil, and there was an improvement in elongation at break and hydrophilicity. Impregnation with castor oil, a biodegradable and safe plasticiser, resulted in less rigid and more ductile composites.

Physical and mechanical properties of agar based edible film with glycerol plasticizer

2017 ◽  
Author(s):  
Arham Rusli
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Film Thickness ◽  
Food Packaging ◽  
Base Material ◽  
Physical And Mechanical Properties ◽  
Edible Film ◽  
Glycerol Concentration ◽  
Elongation At Break

Appropriate concentration of base material and plasticizer is required to obtain good physical and mechanical properties of edible film for food packaging and preservation functions. The aim of this study was to obtain the best combination of the base material and plasticizer in the manufacture of agar films based on physical and mechanical properties. Results showed that the physical and mechanical properties of the agar edible film were affected by the agar and glycerol concentrations. Increasing agar concentrations resulted in the increase in the film thickness, tensile strength (TS), and elongation at break (EAB), but decreased the filmsolubility. While increasing glycerol concentration tended to increase the film thickness and solubility, but decrease the TS of the film. The best concentration combination of agar and glycerol in this study was 3 and 10%, respectively.

scholarly journals The influence of functional ingredients on the physico-mechanical and operational properties of rubbers for water-oil-swelling sealing elements

2019 ◽  
Vol 57 (2) ◽  
pp. 68-73
Author(s):  
Evgeny N. Egorov ◽  
◽  
Nikolay F. Ushmarin ◽  
Sergey I. Sandalov ◽  
Ivan S. Spiridonov ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Oil And Gas ◽  
Physical And Mechanical Properties ◽  
Oil And Gas Industry ◽  
Weight Changes ◽  
Gas Industry ◽  
Elongation At Break ◽  
Functional Ingredients ◽  
Sealing Elements

The article investigated the effect of caoutchoucs, sevilen 11808-340, vulcanizing groups, fillers, plasticizers, ingredients of directional actions on the physical and mechanical properties (conditional tensile strength, elongation at break, hardness, rebound elasticity, tear resistance) and operational properties (changes of conditional tensile strength of rubbers after exposure to oil, weight changes after aging of rubbers in a solution of citric and hydrochloric acids, changes in the volume of rubbers after exposure to a mixture of oil and water) of two rubbers. These rubbers are developed for the manufacture of the outer and inner layers of water-oil-swellable sealing elements (WSOE) for the oil and gas industry. It has been established that rubber for the outer layer of WSOE based on butadiene-nitrile BNKS-18AMN, isoprene SKI-3 and butadiene CKD caoutchoucs, as well as rubber for the inner layer of UEN based on butadiene-nitrile BNKS-18AMN, butadiene methylstyrene SKMS-30ARK and butadiene CKD caoutchoucs possess the required physicomechanical and operational properties. It was shown that these rubbers containing a vulcanizing group sulfur + thiazole 2 MBS, sevilen 11808-340, a combination of carbon black T 900 with rosil 175, talc and chalk, petroleum resin “Sibplast”, vermiculite and igloprobivnoe cloth, are characterized by improved physical-mechanical and operational properties. These rubber can be recommended as the basis for the manufacture of outer and inner layers of water-oil-swelling sealing elements.

scholarly journals PENGARUH LIMBAH ABU PEMBAKARAN BIOMASSA KELAPA SAWIT TERHADAP SIFAT-SIFAT FISIKA DAN MEKANIK HIGH IMPACT POLYSTYRENE

2015 ◽  
Vol 4 (3) ◽  
pp. 23-28
Author(s):  
Fadhilla Asyri ◽  
Kartini Noor Hafni ◽  
A. Haris Simamora
Keyword(s):  
Electron Microscopy ◽  
Mechanical Properties ◽  
Scanning Electron Microscopy ◽  
Tensile Strength ◽  
Impact Strength ◽  
Specific Gravity ◽  
Physical And Mechanical Properties ◽  
High Impact ◽  
Elongation At Break ◽  
Scanning Electron

This study aims was to determine the effect of palm oil fuel ash (POFA) composite as filler on the physical and mechanical properties of high impact polystyrene (HIPS) composites. The research methodology included preparation of raw materials, treatment POFA (hydration process of POFA), mixing using tumbler and then extruder, molding composite specimens, and testing. The variables used were weight ratio of HIPS with 140 mesh POFA at 95/5; 92.5/7.5; 90/10. The composites were tested by Fourier Transform Infrared (FTIR), ash content, specific gravity, tensile strength, elongation at break, impact strength, hardness test, and Scanning Electron Microscopy (SEM). The results of FTIR characterization shows the formation of –OH bonding that was suspected as Si-OH or Si-hydrat. Results of physical and mechanical properties of the composites shows that increase of the filler composition in HIPS-POFA composites until the ratio of 90/10, increase the specific gravity to 7.2% of the original, tensile strength did not change significantly to 28.4 MPa, elongation at break decreased to 2.7%, impact strength decreased to 3.183 KJ/m2, and the hardness increased to 110.5, and Scanning Electron Microscopy (SEM) test show the transformation of POFA structure on treated POFA and intercalation between the matrix and POFA.

scholarly journals Physico-mechanical properties of cattle hide leather for working gloves with flame retardant addition

2020 ◽  
Vol 18 (2) ◽  
pp. 151
Author(s):  
Iwan Fajar Pahlawan ◽  
Gresy Griyanitasari
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Flame Retardant ◽  
Descriptive Analysis ◽  
Physical And Mechanical Properties ◽  
Metal Casting ◽  
Protective Equipment ◽  
Elongation At Break ◽  
Finishing Process ◽  
Casting Industry

<p class="MDPI17abstract"><strong>Objective: </strong>Indonesian<strong> </strong>metal casting industry<strong> </strong>is a labor-oriented industry which involves thermal application in the workplace. Thus, it is essential to protect the workers for any risks during their activity. Leather gloves, as personal protective equipment, need to be manufactured that can prevent the workers from burn injured.<strong> </strong>The study aimed to analyze the effect of flame retardant addition on finished leather’s physical and mechanical properties for a specific article, i.e. working gloves.</p><p class="MDPI17abstract"><strong>Methods: </strong>The research used pickled cattle hides and commercial flame retardant as main materials. The leather chemicals used in the process are those which is commonly used to manufacture working gloves leather article. The treatments involved the addition of commercial flame retardant in fatliquoring (2%, 4%, 6% w/w) and finishing process (100 parts, 200 parts, 300 parts). The effect of flame retardant addition on shrinkage percentage, thickness, rub fastness, tensile strength, and elongation at break, were evaluated. Descriptive analysis is applied to describe the properties of the resulted finished leather.</p><p class="MDPI17abstract"><strong>Results:</strong> The result shows that the addition of flame retardant in fatliquoring and finishing process indicates a variation in the leather’s physical-mechanical properties. The leather, manufactured with the addition of 4% (w/w) in fatliquoring, shrunk 7.65±1.42%, had tensile strength value at 520.48±13.79 kg/cm<sup>2</sup>, good rub fastness at dry and wet basis (5 and 4/5), elongation value at 52.9±4.09%, and thickness 0.87±0.02 mm.</p><p class="MDPI17abstract"><strong>Conclusions: </strong>it can be concluded that the use of 4% (w/w) flame retardant in fatliquoring is suggested to be the best formulation to produce working gloves leather.<strong></strong></p>

EFFECTS OF GRAFTED VINYL TRIETHOXY SILANE ON MOISTURE CROSSLINKED EPDM

2021 ◽  
Author(s):  
Zhengwei Lin ◽  
Haotian Zhao ◽  
Yanlu Chen ◽  
Jie Mao ◽  
Martin Hoch ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Fourier Transform ◽  
Mechanical Performance ◽  
Weight Ratio ◽  
Dicumyl Peroxide ◽  
Rubber Compound ◽  
Elongation At Break ◽  
Melt Grafting ◽  
Vinyl Triethoxysilane

ABSTRACT An EPDM terpolymer grafted with silane vinyl triethoxysilane (EPDM-g-VTES) was prepared by melt grafting, with dicumyl peroxide (DCP) as an initiator. Next, dibutyl tin dilaurate was added as a catalyst to promote moisture crosslinking of EPDM-g-VTES. By means of the rheological response of the rubber compound, Fourier transform infrared spectroscopy, and moving die rheometer, the VTES graft ratio and DCP partial crosslinking (pre-crosslinking) of EDPM-g-VTES were characterized to show the feasibility of moisture crosslinking. The mechanical properties of moisture crosslinked EPDM-g-VTES specimens were tested by universal material tester. The results showed that when the weight ratio of VTES to DCP was fixed at 15:1, the VTES graft ratio and DCP partial crosslinking of EDPM-g-VTES increased with the increase of VTES content. But the torque in the moisture crosslinking curve of EPDM-g-VTES increased significantly with the extension of crosslinking time, which proved that EPDM grafted with VTES was cured by moisture successfully. The tensile strength and elongation at break of EPDM-g-VTES were improved by moisture cure. Furthermore, the moisture cured specimen with 3 wt% VTES had the best mechanical performance.

Mechanical Properties of Poly(3-hydrobutyrate-co-hydroxyvalerate)/ Biodegradable Hyperbranched Poly(ester amide) Blends

2013 ◽  
Vol 745-746 ◽  
pp. 436-441
Author(s):  
Pei Liu ◽  
Long Chen ◽  
Jun Xu ◽  
Mei Fang Zhu ◽  
Zong Yi Qin
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Tensile Elongation ◽  
High Dispersion ◽  
Melt Blending ◽  
Elongation At Break ◽  
Biodegradable Composites ◽  
Hyperbranched Poly ◽  
Blending Method ◽  
Fracture Morphologies

Biodegradable composites were prepared by adding hyperbranched poly (ester amide) (HBPs) into poly (3-hydroxybutyrate-co-3-hydrovalerate) (PHBV) through melt blending method. It was found that the tensile strength and toughness of PHBV were simultaneously enhanced by the addition of HBPs. Compared with neat PHBV, the tensile strength of the composite increased about 23% from 20.96 to 25.87 MPa for the content of 2.5 wt.% HBPs, and more remarkable enhancement in tensile elongation at break can be achieved by about 88% for 5 wt.% HBPs. The influences of HBPs on crystallization, thermal and fracture morphologies of PHBV were further evaluated by using differential scanning calorimeter and scanning electron microscope, respectively. The decrease in the crystallinity of PHBV and high dispersion of the HBPs in PHBV matrix were observed, which should contribute to the improvement on the mechanical properties of PHBV.

Preparation and Properties of DCP-Crosslinked Biobased Polyamide

2013 ◽  
Vol 634-638 ◽  
pp. 1037-1043 ◽  
Author(s):  
Xiao Xue ◽  
Qing Xiu Jia ◽  
Guo Liang Zhao
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Infrared Spectroscopy ◽  
Cross Linking ◽  
Dicumyl Peroxide ◽  
Elongation At Break ◽  
Gel Content ◽  
Dose Ranging ◽  
The Cross ◽  
Higher Doses

In this work, a new bio-based hybrid polyamide (BDIS) was prepared and was cross-linked by dicumyl peroxide (DCP) with dose ranging from 1 to 7%. The state of cure was observed in vulcameter, and the vulcanization condition was determined subsequently. The cross-linking efficiency of BDIS/DCP blends was assessed using torque, gel content measurements and infrared spectroscopy (FTIR). DCP dose below 1% was not sufficient to reach gelation. Over 1%, the gel content increased with increasing DCP dose. The cross-linked BDIS films exhibited enhanced toughness and mechanical properties compared to precursors. Optimal mechanical properties were obtained with concentration of about 5 wt % DCP. At higher doses, the tensile strength and the elongation at break were decreased due to scission reactions.

scholarly journals Effect of Alumina Contents on the Physicomechanical Properties of Alumina (Al2O3) Reinforced Polyester Composites

2019 ◽  
Vol 2019 ◽  
pp. 1-9 ◽  
Author(s):  
Fahamsyah H. Latief ◽  
Achmad Chafidz ◽  
Harri Junaedi ◽  
Adel Alfozan ◽  
Rawaiz Khan
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Physical And Mechanical Properties ◽  
Physicomechanical Properties ◽  
Small Decrease ◽  
Alumina Particles ◽  
Alumina Composites ◽  
Polyester Composites ◽  
Experimental Density ◽  
Main Factor

Polyester-based composites filled with various contents of alumina (Al2O3) (i.e., 0, 1, 5, and 10 vol%) have been fabricated in this study. Physical and mechanical properties of the composites have also been analysed. The analysis results showed that the experimental density of the polyester/alumina composites was smaller than the theoretical density, which could be attributed to the formation of voids during preparation of the composites. Meanwhile, the tensile strength, stiffness, and hardness of the composites increased with increasing alumina content, while the strain-at-break of the composites decreased. It was observed that the composites containing 5 vol% of alumina had the best tensile strength, stiffness, and hardness. The uniform distribution and dispersion of alumina particles were likely responsible for the improvement of the mechanical properties. In other hand, small decrease in tensile strength, stiffness, and hardness of composite was found in the composites with 10 vol% of alumina. The formation of agglomerates and voids was believed to be the main factor for the decrease of the both properties.

Influence of Nano-Polyaniline Contents on Mechanical Properties of Crosslink Recycled Polypropylene Polyaniline

2015 ◽  
Vol 1125 ◽  
pp. 13-17 ◽  
Author(s):  
Muhamad Rasyidi Husin ◽  
Agus Arsad ◽  
Mohd Shaiful Zaidi Mat Desa ◽  
Mohd Faizal Abdul Rahman
Keyword(s):  
Electron Microscopy ◽  
Mechanical Properties ◽  
Scanning Electron Microscopy ◽  
Tensile Strength ◽  
Morphological Structure ◽  
Dicumyl Peroxide ◽  
Slight Improvement ◽  
Elongation At Break ◽  
Recycled Polypropylene ◽  
Scanning Electron

Crosslink of recycled polypropylene with polyaniline (rPP-PANI) have been prepared via ultrasound extrusion. The concentration of PANI used in the research was varied from 0 to 10 wt% and that of dicumyl peroxide (DCP) was fixed in 1 phr loading of PANI. To examine the morphological structure of the blends, fill emission scanning electron microscopy (FESEM) was conducted. The increasing loading of polyaniline (PANI) has promoted a slight improvement in both elastic modulus and tensile strength at 4 wt% and impact strength at 10 wt%. However elongation at break showed a decrease at all PANI loadings. The FESEM micrograph confirmed good dispersion of nano-PANI on rPP matrix to form crosslinking between rPP matrix and PANI.

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