scholarly journals An Equilibrator System to Measure Dissolved Oxygen and Its Isotopes

2013 ◽  
Vol 30 (2) ◽  
pp. 361-377 ◽  
Author(s):  
Lauren Elmegreen Rafelski ◽  
Bill Paplawsky ◽  
Ralph F. Keeling

Abstract An equilibrator is presented that is designed to have a sufficient equilibration time even for insoluble gases, and to minimize artifacts associated with not equilibrating to the total gas tension. A gas tension device was used to balance the pressure inside the equilibrator with the total gas tension. The equilibrator has an e-folding time of 7.36 ± 0.74 min for oxygen and oxygen isotopes, allowing changes on hourly time scales to be easily resolved. The equilibrator delivers “equilibrated” air at a flow rate of 3 mL min−1 to an isotope ratio mass spectrometer. The high gas sampling flow rate would allow the equilibrator to be interfaced with many potential devices, but further development may be required for use at sea. This system was tested at the Scripps Institution of Oceanography pier, in La Jolla, California. A mathematical model validated with performance tests was used to assess the sensitivity of the equilibrated air composition to headspace pressure and makeup gas composition. Parameters in this model can be quantified to establish corrections under different operating conditions. For typical observed values, under the operating conditions presented here, the uncertainty in the measurement due to the equilibrator system is 2.2 per mil for δ(O2/N2), 1.5 per mil for δ(O2/Ar), 0.059 per mil for δ18O, and 0.0030 per mil for Δ17O.

Author(s):  
Patrick Magee ◽  
Mark Tooley

The purpose of respiratory gas analysis during anaesthesia is to identify and measure the concentrations, on a breath by breath basis, of the individual gases and vapours in use. It may also be useful as a guide to cardiac function or to identify trace contaminant gases. Different techniques use different physicochemical properties of the gas or vapour. An understanding of the physical principle underlying each method is necessary in order to recognise the value and limitations of each. In terms of the device’s ability to respond on a breath by breath basis, there are two important components: the time taken for the gas to be sampled from the anaesthetic machine or breathing system, the delay time; then there is the time taken for the device to measure the gas concentration, the response time. This is depicted in Figure 16.1. Most of the delay occurs in the delay time or transit time and can be reduced either by analysing the gas sample close to the airway, or by using as short and thin a sampling tube and as high a sampling flow rate to the analyser as possible [Chan et al. 2003]; the sampling flow rate is usually of the order of 100 to 200 ml min−1. If minimal fresh gas flow rates are being used in a circle anaesthetic breathing system and the sampled gas is not returned to the breathing system, then a high gas sampling rate could represent a significant gas leak. Figure 16.1 shows a sigmoid curve of recorded gas concentration change in response to a square wave input change. The response of a gas analyser is often expressed as the time taken to produce a 90–95% response to a step or square wave input change. A square wave change in gas concentration can be produced by moving a gas sampling tube rapidly into and out of a gas stream, by bursting a small balloon within a sampling volume containing a gas sample, or by switching a shutter to a gas sample volume using a solenoid valve. An important part of the use of gas analysers is zeroing and calibration since they are all prone to drift in both zero and gain.


2020 ◽  
Vol 26 (3) ◽  
pp. 126-130
Author(s):  
Krasimir Kalev

AbstractA schematic diagram of a hydraulic drive system is provided to stabilize the speed of the working body by compensating for volumetric losses in the hydraulic motor. The diagram shows the inclusion of an originally developed self-adjusting choke whose flow rate in the inlet pressure change range tends to reverse - with increasing pressure the flow through it decreases. Dependent on the hydraulic characteristics of the hydraulic motor and the specific operating conditions.


Materials ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1546
Author(s):  
Árpád Imre-Lucaci ◽  
Melinda Fogarasi ◽  
Florica Imre-Lucaci ◽  
Szabolcs Fogarasi

This paper presents a novel approach for the recovery of lead from waste cathode-ray tube (CRT) glass by applying a combined chemical-electrochemical process which allows the simultaneous recovery of Pb from waste CRT glass and electrochemical regeneration of the leaching agent. The optimal operating conditions were identified based on the influence of leaching agent concentration, recirculation flow rate and current density on the main technical performance indicators. The experimental results demonstrate that the process is the most efficient at 0.6 M acetic acid concentration, flow rate of 45 mL/min and current density of 4 mA/cm2. The mass balance data corresponding to the recycling of 10 kg/h waste CRT glass in the identified optimal operating conditions was used for the environmental assessment of the process. The General Effect Indices (GEIs), obtained through the Biwer Heinzle method for the input and output streams of the process, indicate that the developed recovery process not only achieve a complete recovery of lead but it is eco-friendly as well.


2013 ◽  
Vol 67 (10) ◽  
pp. 2141-2147 ◽  
Author(s):  
Patrick Atheba ◽  
Patrick Drogui ◽  
Brahima Seyhi ◽  
Didier Robert

The present work evaluates the potential of the photocatalysis (PC) process for the degradation of butylparaben (BPB). Relatively high treatment efficiency was achieved by comparison to photochemical process. Prior to photocatalytic degradation, adsorption (AD) of BPB occurred on the titanium dioxide (TiO2)-supported catalyst. AD was described by Langmuir isotherm (KL = 0.085 L g−1, qm = 4.77 mg g−1). The influence of angle of inclination of the reactor, pH, recirculation flow rate and initial concentration of BPB were investigated. The PC process applied under optimal operating conditions (recirculation flow rate of 0.15 L min−1, angle of inclination of 15°, pH = 7 and 5 mg L−1 of BPB) is able to oxidize 84.9–96.6% of BPB and to ensure around 38.7% of mineralization. The Langmuir–Hinshelwood kinetic model described well the photocatalytic oxidation of BPB (k = 7.02 mg L−1 h−1, K = 0.364 L mg−1).


2011 ◽  
Vol 189-193 ◽  
pp. 2285-2288
Author(s):  
Wen Hua Jia ◽  
Chen Bo Yin ◽  
Guo Jin Jiang

Flow features, specially, flow rate, discharge coefficient and efflux angle under different operating conditions are numerically simulated, and the effects of shapes and the number of notches on them are analyzed. To simulate flow features, 3D models are developed as commercially available fluid flow models. Most construction machineries in different conditions require different actions. Thus, in order to be capable of different actions and exhibit good dynamic behavior, flow features should be achieved in designing an optimized proportional directional spool valve.


2005 ◽  
Vol 127 (5) ◽  
pp. 1029-1037 ◽  
Author(s):  
L. O. Schunk ◽  
G. F. Nellis ◽  
J. M. Pfotenhauer

Growing interest in larger scale pulse tubes has focused attention on optimizing their thermodynamic efficiency. For Stirling-type pulse tubes, the performance is governed by the phase difference between the pressure and mass flow, a characteristic that can be conveniently adjusted through the use of inertance tubes. In this paper we present a model in which the inertance tube is divided into a large number of increments; each increment is represented by a resistance, compliance, and inertance. This model can include local variations along the inertance tube and is capable of predicting pressure, mass flow rate, and the phase between these quantities at any location in the inertance tube as well as in the attached reservoir. The model is verified through careful comparison with those quantities that can be easily and reliably measured; these include the pressure variations along the length of the inertance tube and the mass flow rate into the reservoir. These experimental quantities are shown to be in good agreement with the model’s predictions over a wide range of operating conditions. Design charts are subsequently generated using the model and are presented for various operating conditions in order to facilitate the design of inertance tubes for pulse tube refrigerators. These design charts enable the pulse tube designer to select an inertance tube geometry that achieves a desired phase shift for a given level of acoustic power.


2018 ◽  
Vol 06 (02) ◽  
pp. 95-118 ◽  
Author(s):  
Mohammadreza Radmanesh ◽  
Manish Kumar ◽  
Paul H. Guentert ◽  
Mohammad Sarim

Unmanned aerial vehicles (UAVs) have recently attracted the attention of researchers due to their numerous potential civilian applications. However, current robot navigation technologies need further development for efficient application to various scenarios. One key issue is the “Sense and Avoid” capability, currently of immense interest to researchers. Such a capability is required for safe operation of UAVs in civilian domain. For autonomous decision making and control of UAVs, several path-planning and navigation algorithms have been proposed. This is a challenging task to be carried out in a 3D environment, especially while accounting for sensor noise, uncertainties in operating conditions, and real-time applicability. Heuristic and non-heuristic or exact techniques are the two solution methodologies that categorize path-planning algorithms. The aim of this paper is to carry out a comprehensive and comparative study of existing UAV path-planning algorithms for both methods. Three different obstacle scenarios test the performance of each algorithm. We have compared the computational time and solution optimality, and tested each algorithm with variations in the availability of global and local obstacle information.


2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Elham M. El-Zanati ◽  
Eman Farg ◽  
Esraa Taha ◽  
Ayman El-Guindi ◽  
Heba Abdallah

Abstract Multi-bore hollow fiber membranes were prepared through phase inversion spinning process using new locally designed spinnerets of various geometrical shapes. The spun cylindrical-like, rectangular or ribbon-like, and triangular-like are prepared, dried, and characterized by scanning electronic microscope. Fibers of circular (seven, five, and four bores) shape, rectangular of five bores, and triangular of three bores were chosen to study the effect of both geometrical configuration and the number of bores on the amorphous structure and the mechanical properties of the membranes. Membrane geometry, surface amorphous, and bore arrangements are very sensitive to the operating conditions, especially the extrusion and drawing rates. Three polymeric blends of different compositions are used to prepare multi-bore hollow fiber membranes. This study revealed that the blend composition of PES 16%, PVP 2%, PEG 2%, diethylene glycol 2%, and NMP 78% gives excellent mechanical properties. Optimization of the preparation conditions also developed, where the dope flow rate, the bore flow rate, and the air gap were 1.14 cm3 s−1, 1.1 cm3 s−1, and 0 cm, respectively. Furthermore, this study proved that the circular arrangement has high mechanical strength. The prepared seven-MBHF membranes were applied in the membrane distillation process, a solution of 35 g/l NaCl was used to test the membrane performance, and the achieved flux and rejection were 28.32 L/m2 h and 98.9%, respectively. This performance demonstrated that the prepared membrane in this way is suitable to compete with conventional reverse osmosis technology that uses single track hollow fibers.


Author(s):  
Thomas Ceyrowsky ◽  
Andre Hildebrandt ◽  
Martin Heinrich ◽  
Rüdiger Schwarze

Abstract A volute’s loss coefficient is highly sensitive to Mach number, circumferential velocity and flow rate at volute inlet. In case of a backswept impeller, these parameters are coupled to each other. An increased flowrate leads to a steeper absolute flow angle at impeller exit and hence to a decrease of circumferential velocity. The absolute Mach number is also altered. Therefore, in order to investigate the effects of flowrate and flow angle separately, one would have to vary the diffuser width together with the flowrate, keeping the flow angle constant. This corresponds to coupling the volute with aerodynamically similar impellers, designed for higher and lower flowrates. Since this is elaborate, there is no adequate study available in open literature, assessing a volute’s global loss map. In this work, a new numerical approach for the prediction of a volute’s representative loss map is presented: The volute is calculated by means of steady CFD as a standalone component. The inlet boundary conditions are carefully selected by means of 1D and applied together with different diffuser widths. This allows for separate investigation of the impacts of flow angle, flow rate and Mach number. Validation against full stage CFD confirms the applicability of the standalone model. The results exhibit that minimum losses do not necessarily occur at the theoretical matching point but either when the volute is smaller or bigger, depending on the inlet flow angle. Investigations of the loss mechanisms at different operating conditions provide useful guidelines for volute design. Finally, the validity of these study’s findings for volutes with different geometrical features is examined by comparison with experimental data as well as with fullstage CFD.


Author(s):  
M. Vardelle ◽  
P. Fauchais ◽  
A. Vardelle ◽  
A.C. Léger

Abstract A study of the flattening and cooling of particles plasma-sprayed on a substrate is presented. The characteristic parameters of the splats are linked to the parameters of the impacting particles by using an experimental device consisting of a phase Doppler particle analyzer and a high-speed pyrometer. However, during the long experiments required to get reliable correlations, it was observed that variations in plasma spray operating conditions may alter the particles behavior in the plasma jet. Therefore, a simple and easy-to-use system was developed to control in real time the spray jet. In this paper, the effect of carrier gas flow rate, arc current and powder mass flow rate is investigated. The results on zirconia and alumina powders show the capability of the technique to sense the particle spray position and width.


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