Minimizing laboratory waste and improving material reuse through chemical waste exchange: Case of a Brazilian institution

2020 ◽  
Vol 38 (9) ◽  
pp. 1064-1072
Author(s):  
Fabiana Cristina Lima Barbosa ◽  
Marcos Paulo Gomes Mol ◽  
Raphael Tobias de Vasconcelos Barros

Concern over the management of chemical wastes from laboratories has been gaining importance since the 1990s. For a good management of chemical wastes generated from laboratories, it is recommended that managers encourage an environment of cooperation and exchange, thus reusing chemical reagents. The institution under study implemented the Chemical Waste Exchange, whose objective is to capture reagents past their expiry dates that would be discarded and make them available internally to other areas or even to other institutions. A total of 1075 reagents were reused internally and 4382 items were donated for external institutions. As for financial data, between 2011 and 2018, the internal economy was US$16,700.70 and for external institutions it was US$62,633.11. When comparing the waste reuse according to the destination, an internal address showed a significant difference when compared with the external use. Some categories of reagents have greater added value and provide even greater benefits when reused. The strategy of capturing and making available expired reagents through the Chemical Waste Exchange is positive; it helps the management of the waste generated; the economic benefit will depend on the market value of the material; the adopted strategy avoids the need to remove raw material from nature for the production of new reagents and reduces the costs related to treatment and environmentally appropriate final destination.

Author(s):  
Muntasir Muntasir ◽  
Pius Weraman

Community Partnership Program in small home industry of making fish floss brand "Savitri" and "Tiaras" inKupang city in the form of application of electric centrifugation filter model has been implemented. One of the problemsin the production of Savitri and Tiaras fish floss is that there is still a lot of oil in the frying product which is only drainedon a simple sieve and then placed for some time on traditional tools of filter and paper that can cause low quality and lowquality, so it is necessary to reduce the oil yield frying fish floss product. In order to increase the added value and sellingvalue of the products, it is necessary synergy between Universities and Partners in the form of application of the results ofscience and technology to the public. The main components of the composer of the versatile filter are the cylindrical plateas the bucket of the filter, the cylinder filter, the electric dynamo as the centrifuge system rotator and the load-bearingconstruction. The method of this program is the provision of materials, design and manufacture of tools, demonstrationtools and the provision of a versatile filter cylinder system centrifuge model by the team, simulation tools, specialcounseling at the location of partners and suggestions as a follow-up in the endurance of production. The output of thisprogram can provide added value in the form of the use of this tool can improve labor efficiency, increase productivitypartners by producing 40 kg to 50 kg raw material, raw fish marlin, fish meat after cleaning, processed, fried, in andpacked into 80-100 packs of fish floss with the price of Rp. 40,000.00 per package weighing 250 grams. With estimatedpartners will earn a profit of Rp 3,200,000 - 4,000,000.00 per production or 12,800,000.00 - 16,000,000.00 per month incash and consumptions, as well as the abundance of non-greasy, clean and hybrid fish products


2021 ◽  
Vol 22 (1) ◽  
Author(s):  
E. J. de Raaij ◽  
H. Wittink ◽  
J. F. Maissan ◽  
P. Westers ◽  
R. W. J. G. Ostelo

Abstract Background Musculoskeletal pain (MSP) is recognized worldwide as a major cause of increased years lived with disability. In addition to known generic prognostic factors, illness perceptions (IPs) may have predictive value for poor recovery in MSP. We were interested in the added predictive value of baseline IPs, over and above the known generic prognostic factors, on clinical recovery from MSP. Also, it is hypothesized there may be overlap between IPs and domains covered by the Four-Dimensional Symptom Questionnaire (4DSQ), measuring distress, depression, anxiety and somatization. The aim of this study is twofold; 1) to assess the added predictive value of IPs for poor recovery and 2) to assess differences in predictive value for poor recovery between the Brief Illness Perception Questionnaire - Dutch Language Version (Brief IPQ-DLV) and the 4DSQ. Methods An eligible sample of 251 patients with musculoskeletal pain attending outpatient physical therapy were included in a multi-center longitudinal cohort study. Pain intensity, physical functioning and Global Perceived Effect were the primary outcomes. Hierarchical logistic regression models were used to assess the added value of baseline IPs for predicting poor recovery. To investigate the performance of the models, the levels of calibration (Hosmer-Lemeshov test) and discrimination (Area under the Curve (AUC)) were assessed. Results Baseline ‘Treatment Control’ added little predictive value for poor recovery in pain intensity [Odds Ratio (OR) 0.80 (Confidence Interval (CI) 0.66–0.97), increase in AUC 2%] and global perceived effect [OR 0.78 (CI 0.65–0.93), increase in AUC 3%]. Baseline ‘Timeline’ added little predictive value for poor recovery in physical functioning [OR 1.16 (CI 1.03–1.30), increase in AUC 2%]. There was a non-significant difference between AUCs in predictive value for poor recovery between the Brief IPQ-DLV and the 4DSQ. Conclusions Based on the findings of this explorative study, assessing baseline IPs, over and above the known generic prognostic factors, does not result in a substantial improvement in the prediction of poor recovery. Also, no recommendations can be given for preferring either the 4DSQ or the Brief IPQ-DLV to assess psychological factors.


Author(s):  
Lucas Sousa Macedo ◽  
Renato Polese Rusig ◽  
Gustavo Bersani Silva ◽  
Alvaro Baik Cho ◽  
Teng Hsiang Wei ◽  
...  

BACKGROUND: Microsurgical flaps are widely used to treat complex traumatic wounds of upper and lower limbs. Few studies have evaluated whether the vascular changes in preoperative computed tomography angiography (CTA) influence the selection of recipient vessel and type of anastomosis and the microsurgical flaps outcomes including complications. OBJECTIVE: The aim of this study was to evaluate if preoperative CTA reduces the occurrence of major complications (revision of the anastomosis, partial or total flap failure, and amputation) of the flaps in upper and lower limb trauma, and to describe and analyze the vascular lesions of the group with CTA and its relationship with complications. METHODS: A retrospective cohort study was undertaken with all 121 consecutive patients submitted to microsurgical flaps for traumatic lower and upper limb, from 2014 to 2020. Patients were divided into two groups: patients with preoperative CTA (CTA+) and patients not submitted to CTA (CTA–). The presence of postoperative complications was assessed and, within CTA+, we also analyzed the number of patent arteries on CTA and described the arterial lesions. RESULTS: Of the 121 flaps evaluated (84 in the lower limb and 37 in the upper limb), 64 patients underwent preoperative CTA. In the CTA+ group, 56% of patients with free flaps for lower limb had complete occlusion of one artery. CTA+ patients had a higher rate of complications (p = 0.031), which may represent a selection bias as the most complex limb injuries and may have CTA indicated more frequently. The highest rate of complications was observed in chronic cases (p = 0.034). There was no statistically significant difference in complications in patients with preoperative vascular injury or the number of patent arteries. CONCLUSIONS: CTA should not be performed routinely, however, CTA may help in surgical planning, especially in complex cases of high-energy and chronic cases, since it provides information on the best recipient artery and the adequate level to perform the microanastomosis, outside the lesion area.


Foods ◽  
2020 ◽  
Vol 9 (5) ◽  
pp. 584 ◽  
Author(s):  
Mathilde Hirondart ◽  
Natacha Rombaut ◽  
Anne Sylvie Fabiano-Tixier ◽  
Antoine Bily ◽  
Farid Chemat

Nowadays, “green analytical chemistry” challenges are to develop techniques which reduce the environmental impact not only in term of analysis but also in the sample preparation step. Within this objective, pressurized liquid extraction (PLE) was investigated to determine the initial composition of key antioxidants contained in rosemary leaves: Rosmarinic acid (RA), carnosic acid (CA), and carnosol (CO). An experimental design was applied to identify an optimized PLE set of extraction parameters: A temperature of 183 °C, a pressure of 130 bar, and an extraction duration of 3 min enabled recovering rosemary antioxidants. PLE was further compared to conventional Soxhlet extraction (CSE) in term of global processing time, energy used, solvent recovery, raw material used, accuracy, reproducibility, and robustness to extract quantitatively RA, CA, and CO from rosemary leaves. A statistical comparison of the two extraction procedure (PLE and CSE) was achieved and showed no significant difference between the two procedures in terms of RA, CA, and CO extraction. To complete the study showing that the use of PLE is an advantageous alternative to CSE, the eco-footprint of the PLE process was evaluated. Results demonstrate that it is a rapid, clean, and environmentally friendly extraction technique.


Author(s):  
Martijn van Faassen ◽  
Rainer Bischoff ◽  
Ido P. Kema

AbstractBackground:Disturbance of the circadian rhythm has been associated with disease states, such as metabolic disorders, depression and cancer. Quantification of the circadian markers such as melatonin and cortisol critically depend on reliable and reproducible analytical methods. Previously, melatonin and cortisol were primarily analyzed separately, mainly using immunoassays.Methods:Here we describe the validation and application of a high-throughput liquid chromatography in combination with mass spectrometry (LC-MS/MS) method for the combined analysis of melatonin and cortisol in plasma and saliva. The LC-MS/MS method was validated according to international validation guidelines. We used this method to analyze total plasma, free plasma (as obtained by equilibrium dialysis) and saliva melatonin and cortisol in healthy adults.Results:Validation results for plasma and saliva melatonin and cortisol were well within the international validation criteria. We observed no difference between saliva collected by passive drooling or Salivette. Moreover, we noted a significant difference in saliva vs. free plasma melatonin. We observed on average 36% (95% CI: 4%–60%) higher salivary melatonin levels in comparison to free plasma melatonin, suggestive of local production of melatonin in the salivary glands.Conclusions:The novel outcome of this study is probably due to the high precision of our LC-MS/MS assay. These outcomes illustrate the added value of accurate and sensitive mass spectrometry based methods for the quantification of neuroendocrine biomarkers.


2019 ◽  
Vol 20 (12) ◽  
Author(s):  
Ruly Isfatul khasanah ◽  
ENDANG YULI HERAWATI ◽  
ANIK MARTINAH HARIATI ◽  
MOHAMMAD MAHMUDI ◽  
AIDA SARTIMBUL ◽  
...  

Abstract. Khasanah RI, Herawati EY, Hariati AM, Mahmudi M, Sartimbul A, Wiadnya DGR, Asrial E, Yudatomo, Nabil R. 2019. Growth rate of Acropora formosa coral fragments transplanted on different compositions of faba kerbstone artificial reef. Biodiversitas 20: 3593-3598. A counter measure and an alternative technique to reduce coral reef destruction is through transplantation, which requires the relocation or cutting of a live coral, planted in a designated place containing damaged varieties. Faba kerbstone is a product innovation similar to paving block/brick, made from fly and bottom ash (FABA), which is the dominant waste product from PT Jawa Power, Probolinggo, Indonesia. In addition, it has also been widely utilized as a raw material in the creation of paving and concrete blocks, composed by harmless material, with a length, width, and height of 40, 25 and 15 cm, respectively. This study aims to observe the growth rate of Acropora formosa coral fragments transplanted on a faba kerbstone, using five different fly and bottom ash compositions: K1 = 0% Fa, K2 = 25% Fa and 75% Ba, K3 = 50% FA and 50% Ba, K4 = 75% Fa and 25% Ba, while K5 = 100% Fa and 0% Ba. Furthermore, the observations were conducted underwater, using scuba diving for six months, observing the parameters of fragment length, colony diameter, and branches number. In addition, the highest elongation rate of A. formosa coral fragments was identified at K2 (1.313 ± 0.447 cm/month), and K1 (1.185 ± 0.642 cm/month), while the most significant increment in colony diameter was observed in K2 (0.077 ± 0.060 cm/month) and K1 (0.063 ± 0.071 cm/month), and the largest number of branches was also found in K2 (29.50 or 4.28 branches/month) and K1 (25.25 or 3.67 branches/month). Furthermore, the one-way ANOVA and Tukey's HSD test (p = 0.05) showed was no significant difference in the fragments elongation and colony diameters in the K1 and K2 models, although there was substantial variation from the K3, K4, and K5.


2018 ◽  
Vol 8 (1) ◽  
pp. 62-70
Author(s):  
Zuhardi Perdana Putra ◽  
Reswita Reswita Reswita ◽  
Irnad Irnad Irnad

ABSTRACTAgroindustry is an agriculture based industry that has an important role in economic growth in Indonesia. One of the agricultural subsector is horticultural crops, namely onion. The need for onion consumption in Indonesia has always increased. In the Bengkulu city there is a company engaged in the industry of fried onions are "UD. Safari Bawang Goreng". This research is done with consideration of the company has long standing, big enough company, and produce about 336 kg/day. Fried onions are processed products that are processed from the main source of raw material is onion. The processed onion comes from Brebes Java. To know the process can be done by the method of observation, and participation. Processed red onion products produce added value that can be analyzed by Hayami method. The process of onion processing into fried onions consists of several stages, namely the provision of raw materials, onion gaebage, sorting, slicing onion, affixing onion with flour, frying, pressing, packaging. The process of onion treatment into fried onions is called value added. The added value obtained in this study amounted to Rp 9549.65 / Kg BB.Keywords: Fried Onion, Hayami Method, Added Value.


2021 ◽  
Vol 17 (3) ◽  
pp. 179-193
Author(s):  
Elena Klippenshtein ◽  
◽  
Yulia Morozova ◽  
Aleksey Shulikov ◽  
◽  
...  

The review is devoted to the analysis of expert opinions on the interim results of the implementation of the program ‘Development of the fisheries complex’. The high rate of reduction of the fishing fleet, the increasing risks of a lack of production capacity and restrictions on the increase in the volume of production of aquatic biological resources, the low degree of processing of catches on ships and the lack of innovations in the fisheries complex were prerequisites for the development of the Federal Program ‘Development of the Fisheries Complex’, adopted in 2014. It was supposed to solve a number of tasks that ensure the departure from the raw material orientation of exports by stimulating the production of products with a high share of added value through the development of the scientific and technical potential of the fisheries complex. Its implementation has indeed contributed to a sharp increase in investment in the modernization of the existing fishing fleet and in the construction of new vessels due to the change in the principle of quota allocation. However, the analysis of the implementation of investment projects shows a steady lag behind the deadlines for putting new ships into operation, which leads to negative financial consequences for investor companies. Due to the late commissioning of fishing vessels, investor companies are unable to catch products and meet their financial obligations to financial institutions in a timely manner. The change in the historical principle of quota allocation and the introduction of a new ‘keel quota’ mechanism, deprives fishing enterprises of a certain part of the potential income with which these enterprises intended to cover previously made investments in the modernization and re-equipment of the fleet and coastal processing. It can be stated that at present this program supports only the shipbuilding complex, ignoring the financial interests of both fishing and fish processing enterprises. The author’s position is based on the fact that it is necessary to carry out not only the modernization and renewal of the fleet, but also to develop technologies for deep and waste-free processing of extracted aquatic bioresources within the framework of existing food programs. In terms of organizing the processing of waste generated during the extraction of aquatic bioresources, it is necessary to adjust the program ‘Development of the fisheries complex’


2019 ◽  
Vol 16 (2) ◽  
pp. 153-164
Author(s):  
Eny Hari Widowati ◽  
Dewi Larasati

Krai is a group of vegetables that are widely planted by the community in Kasreman Village, Rembang Regency, Krai is planted every dry season with abundant production. the production of abundant krai and sold in fresh form causes low prices of krai even used as cattle feed, this is because krai does not have added value. Krai has the potential to be processed into various food preparations. one of them is processed jelly drink because of the typical water content in vegetables and aroma. Processing of jelly drinks with krai has not been done so that the use of carrageenan needs to be known for its concentration to be accepted by consumers. Research methods: experiment with simple RAK with carrageenan concentration: K1:2%; K2:4%; K3:6%; K4:8%. For organoleptics use student panelists who are accustomed to organoleptic tests with assessment criteria ˃2-3: Dislike; ˃3-4%: Enough Likes; ˃4-5%: Like; ˃5-6%: Very Like. Results:i) Carrageenan concentration against pH: There are significant differences between treatments. The highest pH was found in treatment K4 (4.26) Increase in carrageenan concentration followed by an increase in pH value;ii) Carrageenan Concentration Against Viscosity there is a very significant difference between treatments The less carrageenan concentration, the lower the viscosity or runny; iii) Carrageenan Concentration Against Sineresis: the carrageenan concentration given had a significant effect on the value of sineresis. The syneresis analysis of roasted jelly drink drinks ranged from 4.51 - 13.47 mg / minute The highest synergy was found in treatment K1. iv) The preferred concentration of texture, taste, aroma is concentration at 0.6%.


Author(s):  
Rooganda Elizabeth

The procurement of raw materials for the red chili processing industry, the majority still comes from traders / suppliers. Chili starts procurement, processing to obtain added value, until marketing should be able to anticipate the limitations of the rights of farmers / gapotan groups that are more burdened with obligations. This paper aims to examine and express the role and benefits of chilli in the processing of red chillies to the marketing of processed products, related to efforts to accelerate the development of processing and agribusiness industries to improve the welfare of red chilli farmers. The benefits of partnership for farmer groups are the existence of market certainty, and relatively stable profits. The benefit for partners is the certainty of obtaining raw materials in accordance with the required specifications. The partner still gives the opportunity to sell to the free market if the price is better. The partnership development perspective is still very open, among others due to: (a) both parties obtain mutually beneficial benefits; (b) demand for processed products increases along with population growth. processing business is the transfer of raw material into highly-processed processed products that are able to meet the high demands of quality and hygienic (GMP) processed product requirements, as well as closely related to the increase in income from the acquisition of product value that is expected to realize and prosper farmers and businessmen , able to create jobs and increase interest in young workers on agriculture. The importance of changing the old mindset and paradigm of agriculture through the empowerment and development of chillies in processing and red chili processed agribusiness products is expected to be able to power the development of industrialization and the economy in rural areas.


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