COMPRESSIVE STRENGTH AND EXPLOSIVE CHARACTERISTICS OF POLYMER-BONDED EXPLOSIVES BASED ON HEXOGEN AND FLUOROELASTOMERS

2020 ◽  
pp. 76-83
Author(s):  
Nguyen Trung Toan
Keyword(s):  
Compressive Strength ◽  
Vinylidene Fluoride ◽  
High Energy ◽  
High Chemical ◽  
Energy Characteristics ◽  
Coating Method ◽  
Polymer Bonded Explosives ◽  
Friction Sensitivity ◽  
The Impact ◽  
High Chemical Stability

This paper describes the formulation of two polymer-bonded explosives based on RDX (hexahydro-1,3,5- trinitro-1,3,5-triazine) and fluoroelastomer binders by the water-slurry coating method. The fluoroelastomers are poly(VDF-HFP) (vinylidene fluoride-hexafluoropropene copolymer) and poly(VDF-CTFE) (vinylidene fluoride-chlorotrifluoroethylene copolymer). It has been observed that the impact sensitivity and the friction sensitivity of PBX samples were significantly lower than that of the single RDX. Results also showed that two PBX formulations have high chemical stability, high energy characteristics, and equivalent to some PBX in the world. Finally, the compressive strength of these PBX compositions was found in the range of 8-12 MPa.

scholarly journals Enhanced Crystal Stabilities of ε-CL-20 via Core-Shell Structured Energetic Composites

2020 ◽  
Vol 10 (8) ◽  
pp. 2663 ◽  
Author(s):  
Honglei Zhang ◽  
Qingjie Jiao ◽  
Wanjun Zhao ◽  
Xueyong Guo ◽  
Dayong Li ◽  
...  
Keyword(s):  
Energetic Materials ◽  
In Situ Polymerization ◽  
High Energy ◽  
Morphological Characterization ◽  
Core Shell ◽  
Scanning Calorimetry ◽  
Polymer Bonded Explosives ◽  
Friction Sensitivity ◽  
Energetic Composites

2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (CL-20) is a widely used high-energy explosive for the application of energetic materials. However, the phase transformation from ε-CL-20 to γ-CL-20 restrains its further application in polymer bonded explosives (PBXs) and propellants. To inhibit the phase transition of CL-20, dopamine was first used in an efficient and facile method of in situ polymerization to passivate CL-20 crystals. The core-shell microcapsule particles were obtained, and the morphological characterization demonstrates the formation of a dense core-shell structure. The differential scanning calorimetry (DSC) and in situ X-ray diffraction (XRD) test results show that the compact and dense coating delays the ε-CL-20 crystal transformation temperature by about 30 °C, which enhances thermal stability. In addition, with the coating via polymers, the friction sensitivity of ε-CL-20 crystals decreases significantly. The findings indicate a successful application of dopamine chemistry in high-energy explosives, which provides an attractive method to modify the properties of CL-20 crystals.

scholarly journals Influence of Different Polymeric Matrices on the Properties of Pentaerythritol Tetranitrate

2021 ◽  
Vol 71 (2) ◽  
pp. 177-184
Author(s):  
Ahmed Elbeih ◽  
Mahmoud Abdelhafiz ◽  
Ahmed K. Hussein
Keyword(s):  
Impact Sensitivity ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Pentaerythritol Tetranitrate ◽  
Polymeric Matrices ◽  
Velocity Of Detonation ◽  
Polymer Bonded Explosives ◽  
Friction Sensitivity ◽  
Styrene Butadiene ◽  
The Impact

Six different polymeric matrices were fabricated to reduce the sensitivity of PETN (Pentaerythritol tetranitrate). The polymeric matrices used were individually based on Acrylonitrile butadiene rubber (NBR) softened by plasticizer, styrene-butadiene rubber (SBR) softened by oil, polymethyl methacrylate (PMMA) plasticised by dioctyl adipate (DOA), polydimethylsiloxane (PDMS), polyurethane matrix, and Fluorel binder. A computerised plastograph mixer was utilised for producing three polymer-bonded explosives (PETN-NBR, PETN-SBR, and PETN-PDMS) based on the non-aqueous method. A cast-cured method was used to prepare PBX based on polyurethane (PETN-HTPB), while the slurry technique was used to prepare beads of PETN coated by either fluorel binder (PETN-FL) or based on PMMA forming (PETN-PMMA). The heat of combustion and sensitivities were investigated. The velocity of detonation was measured, while the characteristics of the detonation wave were deduced theoretically by the EXPLO 5 (thermodynamic code). The ballistic mortar experiment was performed to determine the explosive strength. By comparing the results, it was found that PDMS has the highest influence on decreasing the impact sensitivity of PETN, while the cast cured PETN-HTPB has the lowest friction sensitivity. On the other side, PETN-FL has the highest detonation parameters with high impact sensitivity. Several relationships were verified and the matching between the measured results with the calculated ones was confirmed.

Piezoelectric β-polymorph formation of new textiles by surface modification with coating process based on interfacial interaction on the conformational variation of poly (vinylidene fluoride) (PVDF) chains

2020 ◽  
Vol 91 (3) ◽  
pp. 31301
Author(s):  
Nabil Chakhchaoui ◽  
Rida Farhan ◽  
Meriem Boutaldat ◽  
Marwane Rouway ◽  
Adil Eddiai ◽  
...  
Keyword(s):  
High Efficiency ◽  
Vinylidene Fluoride ◽  
Research Work ◽  
Research Area ◽  
Interfacial Interaction ◽  
Tetraethyl Orthosilicate ◽  
Poly Vinylidene Fluoride ◽  
Carbon Nanofillers ◽  
The Impact ◽  
Advanced Applications

Novel textiles have received a lot of attention from researchers in the last decade due to some of their unique features. The introduction of intelligent materials into textile structures offers an opportunity to develop multifunctional textiles, such as sensing, reacting, conducting electricity and performing energy conversion operations. In this research work nanocomposite-based highly piezoelectric and electroactive β-phase new textile has been developed using the pad-dry-cure method. The deposition of poly (vinylidene fluoride) (PVDF) − carbon nanofillers (CNF) − tetraethyl orthosilicate (TEOS), Si(OCH2CH3)4 was acquired on a treated textile substrate using coating technique followed by evaporation to transform the passive (non-functional) textile into a dynamic textile with an enhanced piezoelectric β-phase. The aim of the study is the investigation of the impact the coating of textile via piezoelectric nanocomposites based PVDF-CNF (by optimizing piezoelectric crystalline phase). The chemical composition of CT/PVDF-CNC-TEOS textile was detected by qualitative elemental analysis (SEM/EDX). The added of 0.5% of CNF during the process provides material textiles with a piezoelectric β-phase of up to 50% has been measured by FTIR experiments. These results indicated that CNF has high efficiency in transforming the phase α introduced in the unloaded PVDF, to the β-phase in the case of nanocomposites. Consequently, this fabricated new textile exhibits glorious piezoelectric β-phase even with relatively low coating content of PVDF-CNF-TEOS. The study demonstrates that the pad-dry-cure method can potentially be used for the development of piezoelectric nanocomposite-coated wearable new textiles for sensors and energy harvesting applications. We believe that our study may inspire the research area for future advanced applications.

Effect of combined drink cans and steel fibers on the impact resistance and mechanical properties of concrete

2020 ◽  
Vol 14 (2) ◽  
pp. 6734-6742
Author(s):  
A. Syamsir ◽  
S. M. Mubin ◽  
N. M. Nor ◽  
V. Anggraini ◽  
S. Nagappan ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Compressive Strength ◽  
Reinforced Concrete ◽  
Impact Resistance ◽  
Fiber Reinforced Concrete ◽  
Steel Fibers ◽  
Fiber Reinforced ◽  
Indirect Tensile ◽  
The Impact

This study investigated the combine effect of 0.2 % drink cans and steel fibers with volume fractions of 0%, 0.5%, 1%, 1.5%, 2%, 2.5% and 3% to the mechanical properties and impact resistance of concrete. Hooked-end steel fiber with 30 mm and 0.75 mm length and diameter, respectively was selected for this study.  The drinks cans fiber were twisted manually in order to increase friction between fiber and concrete. The results of the experiment showed that the combination of steel fibers and drink cans fibers improved the strength performance of concrete, especially the compressive strength, flexural strength and indirect tensile strength. The results of the experiment showed that the combination of steel fibers and drink cans fibers improved the compressive strength, flexural strength and indirect tensile strength by 2.3, 7, and 2 times as compare to batch 1, respectively. Moreover, the impact resistance of fiber reinforced concrete has increase by 7 times as compared to non-fiber concretes. Moreover, the impact resistance of fiber reinforced concrete consistently gave better results as compared to non-fiber concretes. The fiber reinforced concrete turned more ductile as the dosage of fibers was increased and ductility started to decrease slightly after optimum fiber dosage was reached. It was found that concrete with combination of 2% steel and 0.2% drink cans fibers showed the highest compressive, split tensile, flexural as well as impact strength.    

scholarly journals Mechanical Behavior of Hydroxyapatite-Chitosan Composite: Effect of Processing Parameters

Minerals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 213
Author(s):  
Hamid Ait Said ◽  
Hassan Noukrati ◽  
Hicham Ben Youcef ◽  
Ayoub Bayoussef ◽  
Hassane Oudadesse ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Compressive Strength ◽  
Mechanical Strength ◽  
Bone Repair ◽  
Mechanical Stability ◽  
Three Dimensional ◽  
Processing Parameters ◽  
Composite Effect ◽  
Solid Liquid ◽  
The Impact

Three-dimensional hydroxyapatite-chitosan (HA-CS) composites were formulated via solid-liquid technic and freeze-drying. The prepared composites had an apatitic nature, which was demonstrated by X-ray diffraction and Infrared spectroscopy analyses. The impact of the solid/liquid (S/L) ratio and the content and the molecular weight of the polymer on the composite mechanical strength was investigated. An increase in the S/L ratio from 0.5 to 1 resulted in an increase in the compressive strength for HA-CSL (CS low molecular weight: CSL) from 0.08 ± 0.02 to 1.95 ± 0.39 MPa and from 0.3 ± 0.06 to 2.40 ± 0.51 MPa for the HA-CSM (CS medium molecular weight: CSM). Moreover, the increase in the amount (1 to 5 wt%) and the molecular weight of the polymer increased the mechanical strength of the composite. The highest compressive strength value (up to 2.40 ± 0.51 MPa) was obtained for HA-CSM (5 wt% of CS) formulated at an S/L of 1. The dissolution tests of the HA-CS composites confirmed their cohesion and mechanical stability in an aqueous solution. Both polymer and apatite are assumed to work together, giving the synergism needed to make effective cylindrical composites, and could serve as a promising candidate for bone repair in the orthopedic field.

scholarly journals Shock interactions in inviscid air and $$\hbox {CO}_2$$–$$\hbox {N}_2$$ flows in thermochemical non-equilibrium

Shock Waves ◽  
2021 ◽  
Author(s):  
C. Garbacz ◽  
W. T. Maier ◽  
J. B. Scoggins ◽  
T. D. Economon ◽  
T. Magin ◽  
...  
Keyword(s):  
Chemical Species ◽  
High Energy ◽  
Ideal Gas ◽  
Shock Interaction ◽  
Interaction Patterns ◽  
Shock Interactions ◽  
Wave Interference ◽  
Type V ◽  
The Impact ◽  
Non Equilibrium

AbstractThe present study aims at providing insights into shock wave interference patterns in gas flows when a mixture different than air is considered. High-energy non-equilibrium flows of air and $$\hbox {CO}_2$$ CO 2 –$$\hbox {N}_2$$ N 2 over a double-wedge geometry are studied numerically. The impact of freestream temperature on the non-equilibrium shock interaction patterns is investigated by simulating two different sets of freestream conditions. To this purpose, the SU2 solver has been extended to account for the conservation of chemical species as well as multiple energies and coupled to the Mutation++ library (Multicomponent Thermodynamic And Transport properties for IONized gases in C++) that provides all the necessary thermochemical properties of the mixture and chemical species. An analysis of the shock interference patterns is presented with respect to the existing taxonomy of interactions. A comparison between calorically perfect ideal gas and non-equilibrium simulations confirms that non-equilibrium effects greatly influence the shock interaction patterns. When thermochemical relaxation is considered, a type VI interaction is obtained for the $$\hbox {CO}_2$$ CO 2 -dominated flow, for both freestream temperatures of 300 K and 1000 K; for air, a type V six-shock interaction and a type VI interaction are obtained, respectively. We conclude that the increase in freestream temperature has a large impact on the shock interaction pattern of the air flow, whereas for the $$\hbox {CO}_2$$ CO 2 –$$\hbox {N}_2$$ N 2 flow the pattern does not change.

scholarly journals Coir Fibers Treated with Henna as a Potential Reinforcing Filler in the Synthesis of Polyurethane Composites

Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1128
Author(s):  
Sylwia Członka ◽  
Anna Strąkowska ◽  
Agnė Kairytė
Keyword(s):  
Mechanical Properties ◽  
High Energy ◽  
Dynamic Mechanical Properties ◽  
Milling Process ◽  
Coir Fiber ◽  
Lawsonia Inermis ◽  
Coir Fibers ◽  
Mechanical Performances ◽  
The Impact ◽  
Reinforcing Filler

In this study, coir fibers were successfully modified with henna (derived from the Lawsonia inermis plant) using a high-energy ball-milling process. In the next step, such developed filler was used as a reinforcing filler in the production of rigid polyurethane (PUR) foams. The impact of 1, 2, and 5 wt % of coir-fiber filler on structural and physico-mechanical properties was evaluated. Among all modified series of PUR composites, the greatest improvement in physico-mechanical performances was observed for PUR composites reinforced with 1 wt % of the coir-fiber filler. For example, on the addition of 1 wt % of coir-fiber filler, the compression strength was improved by 23%, while the flexural strength increased by 9%. Similar dependence was observed in the case of dynamic-mechanical properties—on the addition of 1 wt % of the filler, the value of glass transition temperature increased from 149 °C to 178 °C, while the value of storage modulus increased by ~80%. It was found that PUR composites reinforced with coir-fiber filler were characterized by better mechanical performances after the UV-aging.

scholarly journals Body Mass, Physical Activity and Eating Habits Changes during the First COVID-19 Pandemic Lockdown in Poland

2021 ◽  
Vol 18 (11) ◽  
pp. 5682
Author(s):  
Hubert Dobrowolski ◽  
Dariusz Włodarek
Keyword(s):  
Physical Activity ◽  
Body Weight ◽  
Body Mass ◽  
Social Life ◽  
Eating Habits ◽  
High Energy ◽  
High Energy Density ◽  
Average Weight ◽  
Study Participants ◽  
The Impact

The outbreak of the COVID-19 pandemic caused a number of changes in social life around the world. In response to the growing number of infections, some countries have introduced restrictions that may have resulted in the change of the lifestyle. The aim of our study was to investigate the impact of the lockdown on body weight, physical activity and some eating habits of the society. The survey involving 183 people was conducted using a proprietary questionnaire. The mean age of the study participants was 33 ± 11 and mean height 169 ± 8 cm. An average increase in body weight was observed in 49.18% by 0.63 ± 3.7 kg which was the result of a decrease in physical activity and an increase in food consumption. We also observed a decrease in PAL from 1.64 ± 0.15 to 1.58 ± 0.13 and changes in the amount of food and individual groups of products consumption, including alcohol. Among the study participants who did not lose body mass, there was an average weight gain of 2.25 ± 2.5 kg. In conclusion, an increase of weight was shown in about half of the respondents in the study group which was associated with a decrease in physical activity and an increase in the consumption of total food and high energy density products.

scholarly journals Towards Sustainable Concrete Composites through Waste Valorisation of Plastic Food Trays as Low-Cost Fibrous Materials

2021 ◽  
Vol 13 (4) ◽  
pp. 2073 ◽  
Author(s):  
Hossein Mohammadhosseini ◽  
Rayed Alyousef ◽  
Mahmood Md. Tahir
Keyword(s):  
Compressive Strength ◽  
Low Cost ◽  
Impact Resistance ◽  
Food Tray ◽  
World Population ◽  
Fibrous Materials ◽  
Palm Oil Fuel Ash ◽  
Waste Plastic ◽  
Compressive Strength Of Concrete ◽  
The Impact

Recycling of waste plastics is an essential phase towards cleaner production and circular economy. Plastics in different forms, which are non-biodegradable polymers, have become an indispensable ingredient of human life. The rapid growth of the world population has led to increased demand for commodity plastics such as food packaging. Therefore, to avert environment pollution with plastic wastes, sufficient management to recycle this waste is vital. In this study, experimental investigations and statistical analysis were conducted to assess the feasibility of polypropylene type of waste plastic food tray (WPFT) as fibrous materials on the mechanical and impact resistance of concrete composites. The WPFT fibres with a length of 20 mm were used at dosages of 0–1% in two groups of concrete with 100% ordinary Portland cement (OPC) and 30% palm oil fuel ash (POFA) as partial cement replacement. The results revealed that WPFT fibres had an adverse effect on the workability and compressive strength of concrete mixes. Despite a slight reduction in compressive strength of concrete mixtures, tensile and flexural strengths significantly enhanced up to 25% with the addition of WPFT fibres. The impact resistance and energy absorption values of concrete specimens reinforced with 1% WPFT fibres were found to be about 7.5 times higher than those of plain concrete mix. The utilisation of waste plastic food trays in the production of concrete makes it low-cost and aids in decreasing waste discarding harms. The development of new construction materials using WPFT is significant to the environment and construction industry.

scholarly journals High-energy operator product expansion at sub-eikonal level

2021 ◽  
Vol 2021 (6) ◽  
Author(s):  
Giovanni Antonio Chirilli
Keyword(s):  
Operator Product Expansion ◽  
Evolution Equations ◽  
Energy Operator ◽  
High Energy ◽  
Structure Functions ◽  
Distribution Functions ◽  
Impact Factors ◽  
Operator Product ◽  
The Impact ◽  
New Distribution

Abstract The high energy Operator Product Expansion for the product of two electromagnetic currents is extended to the sub-eikonal level in a rigorous way. I calculate the impact factors for polarized and unpolarized structure functions, define new distribution functions, and derive the evolution equations for unpolarized and polarized structure functions in the flavor singlet and non-singlet case.

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