scholarly journals Transesterifikasi parsial minyak kelapa sawit dengan etanol pada pembuatan digliserida sebagai agen pengemulsi

2018 ◽  
Vol 8 (1) ◽  
pp. 33
Author(s):  
Rita Arbianti ◽  
Tania Surya Utami ◽  
Heri Hermansyah ◽  
Ira Setiawati ◽  
Eki Listya Rini
Keyword(s):  
Surface Tension ◽  
Growth Rate ◽  
Reaction Time ◽  
Palm Oil ◽  
Economic Value ◽  
Renewable Resource ◽  
System Stability ◽  
Water Emulsion ◽  
Oil Water

Partial transesterification of palm oil with ethanol in diglyceride production as emulsifierHigh growth rate of palm oil production has encouraged palm diversification to be other products with higher economic value, which one of them is emulsifier. Emulsifier based on vegetable oil is biodegradable so they won’t soil our environment. Besides that, its continuity of provisioning is also ensured because it is a renewable resource. In production of emulsifier based on palm oil, transesterification reaction is a first step that influences quality of emulsifier produced. The aim of this research is to determine the condition of palm oil partial transesterification. The partial transesterification process used NaOH as catalyst and palm oil. Variables varied were percent weight of NaOH (0.1, 0.2, 0.3, and 0.4 {mole NaOH/kg oil}), transesterification temperature (40, 50, 60, and 70oC), reaction time (15, 20, 25, and 30 minutes), ratio of reactant (1:3, 1:4, 1:5, and 1:6{mole oil:mole ethanol}),  to discuss these effects to diglyceride product activity. Diglyceride product was tested by its ability as emulsifier in system stability of oil/water emulsion and to decrease surface tension of water. Result of this research indicated that diglyceride product has optimum declining of surface tension of water on percent weight of NaOH of 0.3 mole NaOH/kg oil, transesterification temperature of 50 oC, reaction time of 30 minutes, and ratio of reactant of 1:6 mole oil: mole ethanol.Keywords: diglyceride, emulsifier, NaOH, palm oil, transesterification. AbstrakLaju pertumbuhan produksi minyak kelapa sawit yang tinggi mendorong perlunya diversifikasi minyak kelapa sawit menjadi produk lain dengan nilai ekonomis tinggi, salah satunya adalah sebagai agen pengemulsi. Agen pengemulsi yang dibuat dari minyak nabati bersifat biodegradable, sehingga tidak mencemari lingkungan, dan kesinambungan pengadaannya terjamin karena berasal dari sumber daya alam yang dapat diperbaharui. Dalam produksi agen pengemulsi berbahan baku minyak kelapa sawit, reaksi transesterifikasi merupakan tahapan awal yang akan mempengaruhi kualitas produk yang dihasilkan. Penelitian ini bertujuan untuk mengkaji kondisi transesterifikasi parsial minyak kelapa sawit. Proses transesterifikasi menggunakan NaOH sebagai katalis dan minyak kelapa sawit. Variabel yang divariasikan untuk mengkaji pengaruhnya terhadap kinerja produk digliserida yang dihasilkan adalah persen berat katalis NaOH (0,1, 0,2, 0,3, dan 0,4 {mol NaOH/kg minyak}), suhu transesterifikasi (40, 50, 60, dan 70 oC), waktu transesterifikasi  (15, 20, 25, dan 30 menit), dan rasio reaktan (1:3, 1:4, 1:5, dan 1:6 {mol minyak:mol etanol}). Produk digliserida diuji kemampuannya sebagai agen pengemulsi dalam menurunkan tegangan permukaan air, serta dalam menjaga kestabilan emulsi minyak/air. Hasil penelitian menunjukkan bahwa produk digliserida memiliki kemampuan menurunkan tegangan permukaan air optimum pada persen berat katalis NaOH sebesar 0,3 mol NaOH/kg minyak, suhu transesterifikasi 50 oC, waktu reaksi 30 menit, dan rasio reaktan 1:6 mol minyak:mol etanol.Kata kunci: agen pengemulsi, digliserida, minyak kelapa sawit, NaOH, transesterifikasi.

scholarly journals Hydrocolloids Effect on the Quality of Oil-Water Emulsion for Foodstuffs and Beverages

2016 ◽  
Vol 10 (1) ◽  
pp. 97-104
Author(s):  
Oksana Lugovska ◽  
◽  
Vasyl Sydor ◽  
Keyword(s):  
Water Emulsion ◽  
Oil Water

scholarly journals Torrefaction Treatment on Fuel Properties of Bambusa Vulgaris and Gigantochloa Scorthecinii

2019 ◽  
Vol 8 (2S4) ◽  
pp. 492-494
Keyword(s):  
Growth Rate ◽  
Reaction Time ◽  
Calorific Value ◽  
Fuel Properties ◽  
Fuel Quality ◽  
Heating Value ◽  
Bambusa Vulgaris ◽  
The Impact ◽  
Fast Growth Rate

There is a great potential for bamboo to be applied as a biofuel for the future due to its good fuel properties with low alkali index and fast growth rate. Torrefaction treatment can increase the fuel quality of biomass in terms of the calorific value, energy density and storability. The aim of this research was to explore the effect of torrefaction temperature and reaction time on the fuel properties of B. vulgaris and G. scorthecinii. The bamboos were treated at various torrefaction temperatures (200, 250 and 300˚C) and reaction time (15, 30, 45 mins). In overall, the highest higher heating value was obtained from bamboos torrefied at 300ºC for 45 mins. In general, the temperature used in torrefaction has a relatively stronger effect on the higher heating value while the impact of the residence time was considerably lesser.

scholarly journals Influence of the Degumming Process Parameters on the Formation of Glyceryl Esters and 3-MCPDE in Refined Palm Oil: Optimization and Palm Oil Quality Analyses

Foods ◽  
2022 ◽  
Vol 11 (1) ◽  
pp. 124
Author(s):  
Mohammad Saiful Nidzam ◽  
Md. Sohrab Hossain ◽  
Norli Ismail ◽  
Razam Abdul Latip ◽  
Muhammad Khalish Mohammad Ilias ◽  
...  
Keyword(s):  
Reaction Time ◽  
Phosphoric Acid ◽  
Palm Oil ◽  
Oil Quality ◽  
Experimental Conditions ◽  
Rbd Palm Oil ◽  
Degumming Process ◽  
Central Composite ◽  
Phosphoric Acid Concentration

The presence of glyceryl esters (GE) and 3-monochloropropane-1,2-diol esters (3-MCPDE) in refined, bleached, and deodorized (RBD) palm oil is severely concerning to the palm oil consumer. In the present study, the influence of the phosphoric acid degumming process on the formation of GE and 3-MCDE and in the RBD palm oil was determined with varying the acid dose (0.03–0.06 wt%), temperature (70–100 °C), and reaction time (15–45 min). The experimental conditions of the acid degumming process were designed following the central composite design of experiments, and they were optimized using Response Surface Methodology (RSM) based on the minimal formation of GE and 3-MCDE in the RBD palm oil. The optimal experimental conditions of the acid degumming process were a reaction time of 30 min, phosphoric acid concentration of 0.06 wt%, and temperature of 90 °C. Under these experimental conditions, the minimal GE and 3-MCDE formation in RBD palm oil were determined to be 0.61 mg/kg and 0.59 mg/kg; respectively. Several analytical methods were employed to determine RBD palm oil quality, including color, phosphorus, free fatty acids (FFAs), peroxide values, and fatty acid properties. It was found that the phosphoric acid degumming of CPO effectively removed the phosphorus and hydroperoxide content without conceding the quality of palm oil.

scholarly journals Effect of blanching methods on drying kinetics of bell pepper

2011 ◽  
Vol 11 (48) ◽  
pp. 5457-5474
Author(s):  
Toyosi Tunde - Akintunde ◽  
◽  
BO Akintunde ◽  
A Fagbeja ◽  
◽  
...  
Keyword(s):  
Palm Oil ◽  
Water Movement ◽  
Drying Kinetics ◽  
Bell Pepper ◽  
Drying Rate ◽  
Drying Process ◽  
Oil Water ◽  
Drying Rates ◽  
Kinetics Of

Various blanching methods and drying temperatures were applied to bell pepper (Capiscum annum) to investigate the effect on its drying characteristics. Pepper (Capiscum annum) is an abundant and cheap source of vitamins, minerals and fibre. However, its high moisture content makes it susceptible to deterioration. The most common method of preservation is drying but the dried products obtained are of reduced nutritional qualities. Pretreatment of pepper before drying improves the quality of the dried pepper and increases its drying rate. Steam and water blanching as a form of pretreatment has been reported to increase drying rate and improve the quality of dried products but there is not much information on other types of oil/water blanching methods. The effect of blanching (steam, water, palm oil/water and groundnut oil/water) as a pretreatment on the drying kinetics of bell pepper dried at temperatures of 50, 60, 70, 80 and 90o C, was studied. Drying of raw untreated bell pepper was taken as a control. The results indicate that water removal at the initial stage of the drying process was highest and there was a rapid decrease as drying continued until equilibrium was reached at the end of process. The blanched samples generally had higher drying rates (at p<0.05) than the untreated samples. The values for the drying rate for steam and water blanched samples were higher (but not at p<0.05) than the drying rates for samples blanched in oil/water mixtures. The drying rate as well as effective moisture diffusivity, Deff, increased with increasing drying temperature. Values of Deff varied from 3.55 x 10-9 m 2/s to 2.34 x 10-9 m 2/s with the highest being SB (steam blanched) at 80oC and the lowest UB (unblanched) at 50oC. The drying process took place mainly in the falling rate period. The activation energies varied from 39.59 to 83.87 kJ/mol, with PB (palm oil/water blanched) samples having the lowest and UB having the highest Ea value. The lower values for pretreated samples imply that water movement from the internal regions is faster in pretreated samples. This suggests that blanching as a method of pretreatment generally increases water diffusion.

scholarly journals Influence of the reaction time on the quality (physical-chemical properties) of biofuels obtained through catalytic cracking of crude palm oil

2021 ◽  
Vol 17 (6) ◽  
Author(s):  
Silvio Alex Pereira Mota ◽  
Andréia Andrade Mancio ◽  
Jhuliana Silva Santanna ◽  
Valtiane de Jesus Pantoja Gama ◽  
Nélio Teixeira Machado
Keyword(s):  
Reaction Time ◽  
Specific Gravity ◽  
Palm Oil ◽  
Catalytic Cracking ◽  
Kinematic Viscosity ◽  
Chemical Properties ◽  
Operating Conditions ◽  
Crude Palm Oil ◽  
Physical Chemical

The present paper investigated the influence of the reaction time on the quality (physical-chemical properties) of biofuels obtained by catalytic cracking of crude palm oil (CPO). The influence of the reaction time (10, 20, 30, 40, 50, and 60 min) on the quality of crude biofuels denominated organic liquid products (OLP) was investigated through experiments carried out in a cracking pilot plant with capacity of 143 L in the following operating conditions: 20 wt% sodium carbonate (Na2CO3) as catalyst, 450 °C, 1 atm and batch mode operation. The quality of the biofuels produced was certified through physical-chemical analyzes (acid value, saponification value, specific gravity, refractive index, kinematic viscosity, corrosiveness to copper, and flash point). The results show that the physical-chemical properties of OLP decrease as the reaction time increases, in such a way that, catalytic cracking process occurs efficiently in the interval of 10 to 20 min after its start, which can be finalized when it reaches 30 minutes of reaction. In addition, Na2CO3 was essential as a catalyst in the cracking reaction to reduce the physical-chemical properties of OLPs obtained at different times, allowing the specific gravity, kinematic viscosity and corrosivity to copper to be within or very close to the limits established for Diesel S10.

scholarly journals Kinetika Reaksi Sintesis Karboksi Metil Glukomanan

2017 ◽  
Vol 1 (1) ◽  
Author(s):  
Rahmawati Andayani ◽  
Santi Tri Wijayanti ◽  
Fadilah Fadilah
Keyword(s):  
Activation Energy ◽  
Reaction Time ◽  
Economic Value ◽  
Order Reaction ◽  
Degree Of Substitution ◽  
Natural Polymers ◽  
Carboxy Methyl

<p>Cultivation of porang plants now has a promising prospect because it has a high<br />economic value. Glucomannan content in porang is quite high (15-64% dry base).<br />Glucomannan, the natural polymers contained in porang corms, can be modified by<br />carboxymethylation. The synthesis of carboxy methyl glucomannan took place over two<br />steps, alkalization and carboxymethylation. Alkalization was conduct using NaOH in<br />ethanol 70% as the medium. The carboxymethylation steps was conducted by adding<br />sodium chloroacetate as the reagent. The quality of carboxy methyl glucomannan was<br />determined from its Degree of Substitution (DS). The results showed that the highest<br />degree of substitution was 0.47 with 70% ethanol as medium and at temperature 65<br />o<br />C for <br />150 minutes reaction time. From the data obtained, it can be seen that the reaction of<br />glucomannan carboxymethylation proceeded at 1<br />st<br /> order reaction, with the collision factor<br />value (A) of 491.227 J/mol.K and its activation energy (Ea) of 30,994.59 J/mol.K.</p>

Effect of fermentation and palm oil on the performance of broilers receiving cassava diets in the tropics

1979 ◽  
Vol 29 (2) ◽  
pp. 239-244
Author(s):  
S. A. Adeyanju ◽  
P. P. Pido ◽  
A. A. Adegbola
Keyword(s):  
Growth Rate ◽  
Palm Oil ◽  
Broiler Chickens ◽  
Economic Value ◽  
Economic Benefits ◽  
Feed Utilization ◽  
Final Body Weight ◽  
Feed Cost ◽  
Daily Rate ◽  
Comparable Performance

ABSTRACTThe effect of fermentation on cassava meal diets supplemented with 0, 2, 4 and 6% levels of palm oil on the performance, carcass characteristics and economic value of broiler chickens was studied. During the growing phase, fermentation had no influence on growth rate, but resulted in reduced mortality and improved efficiency of feed utilization in the chickens. However, there were greater intakes of fermented cassava meal diets, higher efficiency of feed utilization, better growth rate and reduced mortality during the finishing phase. Abdominal fat was lower during both phases in chickens given the fermented cassava meal diets than those given the cassava meal diets. There was evidence of economic benefits in reduced feed cost, increased gross revenue and higher revenue less feed cost values in fermented cassava meal than in cassava meal diets. There were non-significant reductions in feed intake, mortality rate, daily rate of gain, final body weight and carcass quality, but significant economic benefits during both growing and finishing phases as the level of supplementary palm oil increased in the diets. The results suggest that while about 2% palm oil might be required in fermented cassava meal diets, 2 to 4% would be needed in cassava meal diets by broiler chickens for comparable performance.

Immunoferritin localization of intracellular antigens in positively stained frozen sections

1978 ◽  
Vol 36 (2) ◽  
pp. 168-169
Author(s):  
K. T. Tokuyasu
Keyword(s):  
Surface Tension ◽  
Water Surface ◽  
Thin Layers ◽  
The Other ◽  
Positive Staining ◽  
Frozen Sections ◽  
The Past ◽  
Ultrathin Frozen Sections ◽  
Definition Of

During the past investigations of immunoferritin localization of intracellular antigens in ultrathin frozen sections, we found that the degree of negative staining required to delineate u1trastructural details was often too dense for the recognition of ferritin particles. The quality of positive staining of ultrathin frozen sections, on the other hand, has generally been far inferior to that attainable in conventional plastic embedded sections, particularly in the definition of membranes. As we discussed before, a main cause of this difficulty seemed to be the vulnerability of frozen sections to the damaging effects of air-water surface tension at the time of drying of the sections.Indeed, we found that the quality of positive staining is greatly improved when positively stained frozen sections are protected against the effects of surface tension by embedding them in thin layers of mechanically stable materials at the time of drying (unpublished).

Automation of selected brazes' dynamic properties in high-temperatures' measurement process

2013 ◽  
Vol 18 (2-3) ◽  
pp. 33-41
Author(s):  
Dominik Sankowski ◽  
Marcin Bakala ◽  
Rafał Wojciechowski
Keyword(s):  
Surface Tension ◽  
High Temperatures ◽  
Dynamic Properties ◽  
Automatic Measurement ◽  
Measurement Methodology ◽  
Joining Process ◽  
Wetting Force ◽  
Research Grant

Abstract The good quality of several manufactured components frequently depends on solidliquid interactions existing during processing. Nowadays, the research in material engineering focuses also on modern, automatic measurement methods of joining process properties, i.a. wetting force and surface tension, which allows for quantitative determination of above mentioned parameters. In the paper, the brazes’ dynamic properties in high-temperatures’ measurement methodology and the stand for automatic determination of braze’s properties, constructed and implmented within the research grant nr KBN N N519 441 839 - An integrated platform for automatic measurement of wettability and surface tension of solders at high temperatures, are widely described

Perbandingan Karakteristik Surfaktan Metil Ester Sulfonat dan Sodium Lauril Sulfonat sebagai Bahan Emulsifier

2016 ◽  
Vol 9 (2) ◽  
pp. 167-176
Author(s):  
Eldha Sampepana ◽  
Paluphy Eka Yustini ◽  
Aditya Rinaldi ◽  
Amiroh Amiroh
Keyword(s):  
Fatty Acids ◽  
Surface Tension ◽  
Methyl Ester ◽  
Interfacial Tension ◽  
Palm Oil ◽  
Emulsion Stability ◽  
Raw Material ◽  
Enzymatic Method

Surfactant which is used as raw emulsifier in an industry activity such as Sodium Lauryl Sulfonate is a raw material import, it is petroleum derivative which is not renewable and may cause pollution to the environment, because it is not degraded and are carcinogenic. The purpose of the research is to compare the characteristics of the Quaternary methyl ester sulfonat (MES) and Sodium Lauryl Sulfonat (SLS) as emulsifier. First, make the MES by filtering and eliminating fatty acids of palm oil, then process the MES with enzymatic method become methyl ester, then react it in sulfonation and metanolization process, and also neutralized with NaOH. Next, the MES experiment is compared with SLS and existing MES in the market. The results show that surfactants MES experiment has value hidrofil lipofil balance (HLB) interfacial tension and emulsion stability greater than MES in the market and SLS. And the surface tension of MES experiment is larger than MES in the market, but smaller compared to SLS.ABSTRAKSurfaktan yang digunakan sebagai bahan baku emulsifer dalam aktivitas suatu industri pada saat ini seperti Sodium Lauril Sulfonat  merupakan bahan baku import yang merupakan turunan dari minyak bumi, dengan sifat tidak dapat diperbaharui dan dapat menimbulkan pencemaran terhadap lingkungan karena tidak mudah terdegradasi serta bersifat karsinogenik. Metil ester sulfonat dari bahan minyak sawit merupakan surfaktan dengan sifat mudah terdegradasi yang perlu diketahui karakteristiknya. Penelitian bertujuan untuk membandingkan karakteristik surfaktan metil ester sulfonat (MES) dan Sodium Lauril Sulfonat (SLS) sebagai bahan emulsifier. Mula-mula dilakukan pembuatan MES dengan cara menyaring dan menghilangkan asam lemak minyak sawit terlebih dahulu, kemudian diolah menjadi metil ester secara enzimatis, lalu direaksikan secara sulfonasi dan metanolisis, serta dinetralkan dengan NaOH. Selanjutnya MES hasil percobaan dibandingkan dengan SLS dan MES yang ada dipasaran. Hasil penelitian menunjukkan bahwa surfaktan MES memiliki nilai hidrofil lipofil balance (HLB) tegangan antar muka dan stabilitas emulsi lebih besar apabila dibandingkan dengan MES di pasaran dan SLS, kecuali nilai stabilitas emulsi antara MES dan SLS sama. Dan tegangan permukaan MES hasil percobaan, lebih besar dibandingkan dengan MES dipasaran, dan lebih kecil dibandingkan dengan SLS. Kata kunci :   Metil  ester sulfonat, hidrofil lipofil balance, emulsifier, sodium lauril sulfonat , stabilitas emulsi 

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